Digital Commons Network^™

Co-Constructing The Common Ground: Responses In American Sign Language Conversation, Deborah Wager

Linguistics ETDs

Common ground between two people consists of the things they both know, that they know they both know. This body of knowledge grows in conversation, through both verbal and nonverbal responses. Responses communicate whether what has been said was accepted into the common ground, and return responses acknowledge this acceptance in turn (H. H. Clark, 1996). In addition to the semantic content of utterances, stance is communicated through a variety of means, and alignment with that stance is also communicated through responses.

This study explores ways in which responses are used in American Sign Language (ASL) conversation to co-construct the …

Directed Searches For Gravitational Waves From Ultralight Vector Boson Clouds Around Merger Remnant And Galactic Black Holes During The First Part Of The Fourth Ligo-Virgo-Kagra Observing Run, The Ligo Scientific Collaboration, The Virgo Collaboration, The Kagra Collaboration, Marc Favata, Shoan Ghosh, Rodica M. Martin

Department of Physics and Astronomy Faculty Scholarship and Creative Works

We present the first directed searches for long-transient and continuous gravitational waves from ultralight vector boson clouds around known black holes (BHs). We use LIGO data from the first part of the fourth LIGO-Virgo-KAGRA observing run. The searches target two distinct types of BHs and use two new semicoherent methods: hidden Markov model (HMM) tracking for the remnant BHs of the mergers GW230814_230901 and GW231123_135430 (referred to as GW230814 and GW231123 in this study) and a dedicated method using the Band Sampled Data (BSD) framework for the galactic BH in the Cygnus X-1 binary system. Without finding evidence of a …

You Can't Teach Kids From A Book: Language, Authority And Revitalization In Jicarilla Apache Life, Mariann Skahan

Anthropology ETDs

This dissertation examines how Jicarilla Apache is learned, taught, and used across community life, with particular attention to contemporary language revitalization. Based on ethnographic research with elders, educators, language workers, families, and community institutions, it follows language practices across classrooms, culture camps, homes, ceremonial settings, and collaborative archival projects. I show that linguistic knowledge does not carry the same authority or consequences in every setting. Words may be recognized without being taken up, speakers may possess linguistic knowledge without being authorized to teach or correct, and archival texts may preserve linguistic forms without preserving the relations needed to interpret and …

A Dynamic Web Design Strategy For Increased Customer Engagement And Sales, Sherline Jones

Walden Dissertations and Doctoral Studies

Nonprofit organizations risk losing customers, revenue, and mission impact when leaders fail to adapt digital strategies to evolving customer expectations. Nonprofit leaders are concerned because digital strategy adoption is essential to strengthening sustainability and expanding mission-centered services. Grounded in the Baldrige Excellence Framework, the purpose of this qualitative single case study research project was to explore effective strategies nonprofit business leaders use to leverage technology to attract new customers, retain existing customers, and increase sales. The participants were two senior leaders from a Florida nonprofit organization in the southern United States. Data collection included semistructured interviews, internal archival data, and …

The Mediating Role Of Moral Disengagement In The Relationship Between Facets Of Empathy And Aggression, Romiere J. Horace

Theses

Aggression is a major social and public health concern with economic, psychological, and interpersonal implications. Extensive research has examined the potential antecedents for aggressive behavior, with many different environmental, biological, and intrapsychic factors being significantly associated with aggression. Researchers have also focused on cognitive mechanisms, like empathy, as a protective factor for aggression. More specifically, research has linked lower levels of empathy to higher levels of aggression; however, the underlying mechanisms of this relationship remain underexplored. A potential explanatory mechanism is moral disengagement, which allows individuals to justify harmful behaviors and avoid self-sanctions. However, limited research has examined these constructs …

Technology Platform (Peer Plus) Supporting The Work Of Peer Recovery Coaches And The Communication Needs Of Individuals In Recovery From Substance Use Disorder: Protocol For An R21 Development And Usability Trial., Amanda Coupe, Jessica Pater, Rachel Pfafman, Victor P Cornet, Elisabeth Andrews, Mindy Flanagan, Dana Albright, Abhinay Balasani, Christopher Becker, Brian Parise, Erik Hess, Tammy Toscos

Health Services and Informatics Research

BACKGROUND: Substance use disorder (SUD) represents a significant public health concern in the United States. SUD recovery is complex and individualized, and support provided by peer recovery coaches (PRCs) can improve outcomes. The PRC-client relationship requires bidirectional mediated communication that is often informal but should be trackable, efficient, and aligned with health care privacy and security regulations. Current workflows and available apps do not meet these needs, illustrating the opportunity for client-centered technology tools. We have developed Peer PLUS (People Leveraging Urgent Support; Parkview Health System, Inc), a HIPAA (Health Insurance Portability and Accountability Act)-compliant mobile app and client management …

Tracking Daily Coparenting Quality: Validation And Utility Of The Polish D‐Cop, Dorota M. Jankowska, Boguslawa Lachowska, Brandon T. Mcdaniel

Health Services and Informatics Research

Objective: To adapt and validate the Polish Daily Coparenting Scale (D- Cop PL) and to test its utility for modeling day-to-day coparenting quality.

Background: Daily coparenting quality varies across daily contexts; brief, ecologically valid tools to capture within-person change are scarce.

Methods: A 7-day diary study with 178 dual-income Polish parents of young children was conducted. Confirmatory factor analysis tested the two-factor structure (positive and negative daily coparenting dimensions), reliability, and convergent validity; measurement invariance examined factorial equivalence across mothers and fathers. Generalized Additive Models for Location, Scale, and Shape (GAMLSS) estimated same-day daily associations between coparenting quality: parental negative …

Final 2022 Unreclaimed Sites Sampling: Ur-07 Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Butte Priority Soils Operable Unit Final 2022 Unreclaimed Sites Sampling: Ur-27 Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Urban Climatic And Health Impacts Of Aerosols, Yuezhi Li

McKelvey School of Engineering Graduate Student Theses & Dissertations

Aerosols, also known as particulate matter (PM), strongly influence the climate and pose considerable risks to human health. As short-lived climate forcers, aerosols alter the Earth’s radiative budget by absorbing and scattering incident solar radiation, thereby affecting global and regional temperatures, atmospheric circulation, cloud formation, and precipitation patterns. From a public health perspective, exposure to particulate matter, particularly fine and ultrafine particles, has been associated with a wide range of adverse outcomes, including respiratory diseases, neurodegenerative disorders, and premature mortality. In addition, aerosols can transport pathogens and represent a critical pathway for the transmission of airborne infectious diseases. Despite contributing …

Functionalization Of The Amine Group For Access To 4-Imidazolidinone-Sulfadiazine Hybrid Derivatives And Study Of Their Biological Activities, Sabaa A. Yousif, Rafid S. Dawood

Baghdad Science Journal

The work successfully synthesized twelve novel derivatives of 4-imidazolidinone bearing a sulfadiazine moiety using a one-pot reaction. This was done by condensation of sulfadiazine with twelve different aldehydes to afford the corresponding imines as intermediates, which were then followed by a cyclization reaction with glycine to furnish the desired products 1-12 in 56-85% yields. The structures of these products were identified by FT-IR and ¹H NMR spectroscopy. In addition, a number of the produced compounds demonstrated diverse antibacterial and antioxidant activities. In terms of the antibacterial activity, the compounds 1, 2, 3, 4, …

Synthesis, Characterization, And Biological Evaluation Of A New Azo Dye Ligand 1-[2,4,6-Trihydroxy-3-(2-Hydroxy-Phenylazo)-Phenyl-Ethanone] And Its Complexes With Co(Ii), Ni(Ii), Cu(Ii), Zn(Ii), And Cd(Ii), Ban Hasan Al-Agele, Areej Kamal Assim Aldabbagh

Baghdad Science Journal

1-[2,4,6-trihydroxy-3-(2-hydroxy-phenylazo)-phenyl-ethanone] is a new azo dye ligand (H₂L), which was used to form a number of new azo dye-metal complexes by reaction with salt chlorides of Co, Ni, Cu, Zn and Cd(II). The complexes were characterized using mass spectroscopy, infrared analysis, ultraviolet-visible spectrophotometry, ¹H-, ¹³C-NMR spectroscopy, conductivity, magnetic susceptibility, DSC, TGA, C.H.N., metal content, and melting point. The results highlighted the ligand's trigonal behavior and that all the complexes yielded tetrahedral geometry, with the exception of Co and Ni, which produced octahedral geometry. They are all non-electrolytic. The compounds' capacity to function as antioxidants was used …

Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu

Journal of Electrochemistry

Green hydrogen production via alkaline seawater electrolysis offers an environmentally sustainable and potentially cost-effective route to address both energy and climate challenges. Achieving long-term anode stability under complex ionic environments and industrial current densities remains a central bottleneck. Specifically, Ni-based anodes exhibit intense surface reconstruction during the oxygen evolution reaction, necessitating dynamic anti-corrosion strategies. This mini review systematically summarizes reconstruction engineering approaches to develop anti-corrosion Ni-based anodes of alkaline seawater electrolysis across increasingly complex ionic environments from simulated seawater to real seawater: (i) Cl^– dominated; (ii) Cl^– with co-existing oxyanions, and (iii) Cl^–  with co-existing Br^{– …}

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn₂O₅-NiMn₂O₄ (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …

In Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu

Journal of Electrochemistry

Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …

Modeling For You: A Personalized Approach To Residential Energy Simulation And Distributional Reinforcement Learning, Nestor Gabriel Pereira

Electrical and Computer Engineering ETDs

The growing complexity and uncertainty of residential energy use, driven by electric

vehicles and renewable technologies, demand more intelligent and robust

management systems. Traditional methods often fail when faced with unpredictable

electricity prices and user behavior. This dissertation addresses this gap by presenting

a novel personalized framework combining detailed household energy modeling with

a risk-aware reinforcement learning agent for appliance scheduling.

The first contribution is a probabilistic, bottom-up simulation model that captures

the interdependent behaviors of occupants, appliances, and electric vehicles to

generate realistic, high-fidelity load profiles. The second contribution is a lightweight,

tabular Distributional Q-Learning (D-QL) algorithm that schedules …

Ionophore-Based Plga Nanosensor For Selective Ion Detection And Imaging, Zhiyu Tang

Electronic Theses and Dissertations 2020 - Present

Accurate detection of electrolyte ions is essential for biological research, disease diagnosis, and the investigation of cellular function. In this study, we developed ionophore-based PLGA nanosensors for the optical detection of biologically important ions. The nanosensors were prepared by encapsulating ionophores, chromoionophore III, and ion exchangers within PLGA nanoparticles. The resulting nanosensors showed uniform morphology, good colloidal stability, and concentration-dependent optical responses toward Na⁺, K⁺, and Ca²⁺ over the range of 10⁻⁶ to 10⁻¹ M. Reversible fluorescence responses under repeated ion concentration changes confirmed the stability and robustness of the sensors. The nanosensors also demonstrated reliable analytical performance for K⁺ …

Load Balancing Algorithms For Cloud Computing Systems, Mark Rakesh Christian

Electronic Theses and Dissertations 2020 - Present

Cloud computing depends on load balancing to allocate user requests among virtual machines (VMs), affecting response time, utilization, and scalability. Round Robin, Equally Spread Current Execution, and standard Throttled scheduling are widely used; however, standard Throttled selects among eligible VMs using an implementation-dependent order with no explicit preference. This thesis proposes the Weighted Throttled Load Balancing (WTLB) algorithm, which introduces an explicit, deterministic selection priority among eligible VMs, implemented by modifying the Throttled scheduler within CloudAnalyst.

Evaluated under an identical six-region, multi-data-center configuration against Round Robin, ESCE, and standard Throttled, WTLB preserves the aggregate response-time, processing-time, and cost profile of …

Acute Inflammation At Host-Biomaterial Interfaces: Development Of Neutrophil-Mediating Therapeutics And Biomaterials, Evan Norman Main

Electronic Theses and Dissertations Archive

Neutrophils, key mediators of the acute host response to implanted biomaterials, engage in inflammatory signaling, form neutrophil extracellular traps (NETs), and generate reactive oxygen species (ROS). Upon contact with foreign materials, neutrophils release pro-inflammatory cytokines and chemokines that recruit additional immune cells and promote pro-inflammatory phenotypes in neutrophils and macrophages. Neutrophils may also undergo NETosis, a process involving the release of chromatin-based NETs to sequester and degrade foreign material. In excess, NET formation can impede tissue integration by physically isolating biomaterial surfaces while amplifying inflammation through the release of degradative enzymes and inflammatory mediators. Neutrophil-derived ROS contribute to oxidative stress …

Essays In Real Estate Finance: Risk, Frictions And Market Outcomes, Jason De Freitas

Electronic Theses and Dissertations Archive

This dissertation consists of two essays in empirical real estate that examine how risk and market frictions shape asset valuation and market outcomes, using real estate markets as the primary empirical setting. The first essay investigates how localized crime risk influences the capitalization of urban green infrastructure into residential property values. The second essay examines how market frictions and local risk conditions affect the timing of asset disposition in distressed property markets. The first essay investigates how crime, as a localized risk factor, influences the capitalization of urban green infrastructure into residential property values. While greenlines and greenways are typically …

Constructing Heroes In The Classroom: A Rhetorical Analysis Of Abeka’S Evangelical K-12 Curriculum, Jeff S. Miller

Electronic Theses and Dissertations Archive

This study critically analyzes the rhetoric of four textbooks published by Abeka, Inc., a popular producer of curriculum for both American evangelical Christian K-12 school and homeschoolers through the lens of heroic rhetoric and anthropologist Ernest Becker’s hero systems, examining institutions’ and communities’ rhetorical construction of hero systems that provide or claim to provide relief to members’ mortality anxiety. Hero systems for each of the four textbooks are identified and examined for the ways that they function to build and maintain power hierarchies. Additionally three significant thematic threads of what constitutes heroism are identified in the textbook: biblicism, unidirectional influence, …

Civilian Threat Reduces Distance Perceptions And Officer Punishment In Police Use-Of-Force Encounters, Stephanie Cárdenas, Kristyn Jones, Yael Granot, Emily Balcetis

Faculty Journal Articles

People turn to video evidence to make judgments about the justifiability of an officer’s actions in use-of-force incidents. Despite beliefs that video offers an objective account of events, use-of-force footage elicits different judgments among those watching it. Across four experiments (N_total = 2615), we investigated whether discrepant punishment judgments arise in part because of differences in perceptions of the physical space that separates an officer and civilian. We focus on third-party observers’ subjective perceptions, as they shape public discourse and justice outcomes, influence institutional accountability, and fuel public response. Despite watching the same video, civilians appeared physically closer …

Impact Of Chronic Pain On The Families Of U.S. Adults, Jennifer S. De La Rosa, Katherine E. Herder, Rita D. Romero, De'sha S. Wolf, Tally M. Largent-Milnes, Mohab M. Ibrahim, Stacy S. Pigott, Greg T. Chism, Beth E. Meyerson, Julie G. Pilitsis, Multiple Additional Auhors

School of Social Work Faculty Publications and Presentations

Introduction:. Chronic pain (CP) can profoundly strain family systems, yet few population studies have explored prevalence and population dynamics of CP with high impact on families. Objectives:. Examining prevalence and phenomenological characteristics of chronic pain with high impact on the families of U.S. adults. Situating HICP-family within a tiered cascade of functional impact. Methods:. Prevalence estimated using 2023 National Health Interview Survey Data (n = 29,522) Results:. Findings are as follows: (1) the population prevalence of CP with high impact on families (high-impact chronic pain [HICP]-Family) is 4.4% among U.S. adults, 18.1% among U.S. adults with CP, and 46.3% among …

Impact Of Gas Interactions With Nano Porous Geological Material In The Presence Of Water Vapor, Matthew D. Powell

Chemical and Biological Engineering ETDs

Predicting gas transport in nanoporous geological material requires understanding competitive adsorption and transport under humid conditions. However, most adsorption studies rely on single-component equilibrium measurements that do not capture these effects. This dissertation develops an experimental methodology to directly quantify multicomponent gas adsorption and breakthrough behavior under controlled relative humidity. The method was first applied to the Kr/Xe–N2–H2O system, where it resolved competitive adsorption behavior in humid porous media and produced a bivariate model relating noble gas adsorption to noble gas partial pressure and water saturation. The methodology was then extended to the CO2–N2 H2O system. Results showed that water …

Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo

Chemical and Biological Engineering ETDs

Photosynthetic light-harvesting complexes harvest solar energy and direct electronic excitations toward reaction centers with exceptional efficiency. This dissertation models the Fenna--Matthews--Olson complex of green sulfur bacteria, coupled to the PscA1 reaction center, as a chromophoric network. Forster resonance energy transfer theory, validated against numerically exact hierarchical equations of motion, was implemented in kinetic Monte Carlo simulations to resolve fine-grained excitation-transport pathways. The predicted charge-transfer efficiency of 77\% agrees with experiment, with the FMO2 monomer and its gateway pigment governing interfacial transfer. Systematic single, multi, and symmetry-preserving site removals, interpreted through Mobius inversion, identify critical pigments and show that cooperative effects …

Effect Of Geothermal Conditions On Silica Flour Modified Wellbore Cement, Travis Benjamin Broadhurst

Civil Engineering ETDs

Considerable work has been conducted on modified wellbore cements, but a knowledge gap exists in the effects of downhole conditions on cement, especially tensile strength. In this study, a pressure vessel simulates representative downhole conditions (200⁰C, 1.5 MPa) with a reference solution for geothermal brine and naturally occurring geothermal gases. Samples are removed after 28-days for unconfined compressive strength testing, Brazilian tensile strength testing, elastic moduli measurement, and chemical analyses by X-ray diffraction and electron microprobe. Aqueous chemical analysis suggests multiple active reactions between the geothermal fluid and cement that are exacerbated by higher temperatures, but do not …

Exploring The Nature And Role Of Local Cation Ordering In Disordered Rock Salt Cathodes For Li- And Na-Ion Batteries, You Wang

Chemistry and Chemical Biology ETDs

Cation-disordered rock-salt (DRX) cathodes provide a highly tunable platform for next-generation Li- and Na-ion batteries, but their electrochemical behavior is strongly influenced by local structural features hidden in average crystal structures. This dissertation systematically investigates local cation ordering in Li- and Na-based DRX cathodes to understand its effects on Li+/Na+ transport, redox activity, structural evolution, and electrochemical performance. In Li-based systems, Raman spectroscopy and electrochemical analysis reveal that local layered cation ordering in Mn- and Fe-based DRX cathodes is closely correlated with electrochemical behavior. Over-stoichiometric Li-based DRX oxyfluorides further demonstrate that excess Li can regulate local cation ordering, improve Li+ …

Developing Simulation To Improve G3p3 Efficiencies, Andrew Gaudette

Mechanical Engineering ETDs

Concentrated solar power (CSP) systems offer a promising method of renewable energy generation by using heliostats to focus sunlight onto a falling particle receiver. At the National Solar Thermal Testing Facility (NSTTF), particles absorb and store solar energy for later power generation. A major source of efficiency loss is wind-driven particle escape through the receiver aperture. This thesis develops computational fluid dynamics (CFD) simulations to characterize wind flow around the G3P3 falling particle receiver and support future wind mitigation strategies. Numerical studies were conducted to establish an appropriate simulation methodology. Iteration studies showed that 2,000 iterations were sufficient for convergence, …

Control Of Reshock In A Shock Tube, Alexander Sweis

Mechanical Engineering ETDs

Reshocks can pose a threat to the structural integrity of structures and buildings. While incident shock waves pose larger threats, the study of reshocks and reshock attenuation is important to consider. This thesis investigates methods for controlling and attenuating reshock strength within a shock tube through material-based damping and modifications to baffle box geometric configurations. Experiments are performed using a custom-built shock tube in the University of New Mexico fluid mechanics laboratory. Four baffle box configurations are examined: a foam-lined configuration, a foam-lined configuration with ”egg crate-like” textured foam, an empty (no foam) configuration, and a configuration which incorporates a …

Investigating Light-Matter Interactions In Low-Dimensional Silicon Carbide, Nishan Shrestha

Mechanical Engineering ETDs

Recent advances in materials science have transformed the study and application of low-dimensional materials, with two-dimensional (2D) systems and nanoscale structures exhibiting properties beyond their bulk counterparts. Despite significant progress in materials such as graphene and silicon, the nanoscale exploration of silicon carbide (SiC) remains relatively underdeveloped, despite its critical importance in photonics and electronics and high temperature applications. Motivated by the transformative potential of nanoscale material design and the technological importance of SiC, this dissertation investigates structure and properties of low-dimensional silicon carbide structures. It explores the synthesis and optical properties of SiC nanosheets and nanowires using a variety …