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Articles 5761 - 5790 of 933496
Full-Text Articles in Entire DC Network
Evaluating The Service Life Of A Respirator Cartridge When Exposed To Various Volatile Organic Compounds, Neha Murad Alwani
Evaluating The Service Life Of A Respirator Cartridge When Exposed To Various Volatile Organic Compounds, Neha Murad Alwani
ETDs from 2020-2029
Inhalation is the most common exposure pathway. With the significant presence of respiratory exposure, respirator cartridges are widely used as personal protective equipment (PPE) to reduce exposure to gases, vapors, and volatile organic compounds (VOCs). This study evaluated the breakthrough time of respirator cartridges under various VOC environments commonly encountered in beauty salons and automotive repair shops. Breakthrough time is the duration a respirator cartridge can provide protection before contaminants can be inhaled and the respirator cartridge is no longer effective. The breakthrough time of three VOCs was examined: acetone, toluene, and m-xylene. Using a custom designed test chamber equipped …
Nitrite Oxidation During Ozonation Revisited: Mechanisms Of Nitration Reactions, Tarek Manasfi, Christoph Dieziger, Simon A. Rath, Daisuke Minakata, Urs Von Gunten
Nitrite Oxidation During Ozonation Revisited: Mechanisms Of Nitration Reactions, Tarek Manasfi, Christoph Dieziger, Simon A. Rath, Daisuke Minakata, Urs Von Gunten
Michigan Tech Publications
The formation of toxicologically relevant nitro compounds has been observed during ozonation of nitrite-containing secondary wastewater effluents, but their formation mechanism remains unknown. To identify key nitrating species, three reaction systems were investigated: ozonation of nitrite (O3/NO2–), peroxynitrite (ONOOH/ONOO–), and hydroxyl radical oxidation of nitrite with γ-radiolysis (γ/NO2–). Nitrite ozonation (O3/NO2–) yielded significant amounts of the nitrating agent nitrogen dioxide •NO2 (9.4% at pH 7 to 22% at pH 12) besides the main product nitrate. No peroxynitrite formation was detected during ozonation of nitrite-containing waters, suggesting that •NO2 is the …
Production, Purification, And Crystallization Of The Recombinant Her2 Tyrosine Kinase Domain (Her2-Tkd), Edanur Topalan, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇
Production, Purification, And Crystallization Of The Recombinant Her2 Tyrosine Kinase Domain (Her2-Tkd), Edanur Topalan, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇
Turkish Journal of Chemistry
The human epidermal growth factor receptor 2 tyrosine kinase domain (HER2-TKD) is an important therapeutic target in oncology. In this study, we developed a practical and cost-effective approach for producing soluble recombinant HER2-TKD in Escherichia coli as a basis for structure-based drug discovery. The gene encoding HER2-TKD was cloned into a pET28a(+) expression vector and expressed in E. coli. Since the protein was initially obtained as inclusion bodies, solubilization with 1.5% sarcosyl was applied to recover it in soluble form. The purified protein was obtained through size-exclusion chromatography, followed by tag removal using reverse affinity purification. Crystallization trials were performed …
Quantum Engineered Mxene–Graphene–Plasmonic Nanocomposites For Next-Generation Transparent And Flexible Space Photovoltaics, Arash Vaghef-Koodehi
Quantum Engineered Mxene–Graphene–Plasmonic Nanocomposites For Next-Generation Transparent And Flexible Space Photovoltaics, Arash Vaghef-Koodehi
Turkish Journal of Chemistry
This study presents a quantum‑engineered, tricomponent heterostructure comprising Ti3C2T MXene quantum dots (2–5 nm), single‑layer graphene, and plasmonic gold nanoparticles (15 ± 3 nm) uniformly embedded within electrospun polyacrylonitrile nanofibers. This integrated architecture demonstrates a remarkable combination of optical transparency (89.3 ± 1.1%) and power conversion efficiency (19.7 ± 0.4%) under AM0 solar illumination, representing 340% enhancement over state‑of‑the‑art transparent photovoltaic devices. A multiscale computational framework, bridging density functional theory and device‑level drift-diffusion modeling, identifies optimal interlayer spacing (3.4 ± 0.1 Å) as the key to achieving 89.3% charge‑transfer efficiency. Concurrently, localized surface plasmon resonances at 532 nm generate electromagnetic …
Efficient Heterogeneous Photo-Fenton Degradation Of Azo Dyes Using The Nanocomposite Mgfe2o4/Mos2, Zahra Zeinali, Leila Ershadi Afshar, Naz Chaibakhsh, Farnaz Isapour
Efficient Heterogeneous Photo-Fenton Degradation Of Azo Dyes Using The Nanocomposite Mgfe2o4/Mos2, Zahra Zeinali, Leila Ershadi Afshar, Naz Chaibakhsh, Farnaz Isapour
Turkish Journal of Chemistry
In the present work, a facile hydrothermal route was employed to synthesize the nanocomposite MgFe2O4/MoS2, which acted as a heterogeneous photo-Fenton catalyst for the degradation of a synthetic diazo dye, Acid Blue 113 (AB113). The nanocatalyst produced underwent analysis using multiple characterization techniques. The parameters influencing the oxidative reaction were statistically modeled and optimized using response surface methodology. Optimal degradation efficiency for AB113 (94.92%) was attained at pH 8.79 using 10 mg of MgFe2O4/MoS2 nanocatalyst, 1.6 mL of H2O2, and a reaction duration of 27 min. The synergistic effect resulting from the formation of electron-hole pairs renders the combined photocatalysis …
Electrochemical Biosensing Of Alpha-Fetoprotein Based On Carboxylated Multi-Walled Nanotube-Polyazur A (In Des)-Gold Nanoparticles, Merve Yilmaz Çilçar, Meli̇ke Bi̇lgi̇ Kamaç
Electrochemical Biosensing Of Alpha-Fetoprotein Based On Carboxylated Multi-Walled Nanotube-Polyazur A (In Des)-Gold Nanoparticles, Merve Yilmaz Çilçar, Meli̇ke Bi̇lgi̇ Kamaç
Turkish Journal of Chemistry
AFP, a cancer biomarker, is monitored during fetal development and in the serum of pregnant women. Sensitive and rapid monitoring of AFP is crucial for effective management. In this study, screen-printed carbon electrodes (SPCEs) modified with multi-walled carbon nanotubes (MWCNT-COOH), polyAzur A (PAA), which was prepared in a deep eutectic solution (DES), and gold nanoparticles (AuNP) were fabricated. AFP biosensors were developed for practical, sensitive, low-cost, and rapid detection of AFP. Optimizations of nanostructures (MWCNT-COOH, AuNP) and polymers (PAADES) were performed. The MWCNT-COOH, PAADES, and AuNP-modified SPCEs were characterized by FE-SEM-EDX, FTIR, and XRD techniques. The amounts of 6-MOH, APTES, …
[H]-Mediated Enhancement Of The Fenton Reaction Over A Pd/Uio-66(Zr)-F4 Catalyst, Juanhong Li, Suqin Wang, Xin Liu, Feng Liu
[H]-Mediated Enhancement Of The Fenton Reaction Over A Pd/Uio-66(Zr)-F4 Catalyst, Juanhong Li, Suqin Wang, Xin Liu, Feng Liu
Turkish Journal of Chemistry
A [H]-accelerated catalytic Fenton system was developed using Pd/UiO-66(Zr)-F4 as the catalyst. This system enabled the regeneration of Fe²⁺ and facilitated the continuous generation of both ·OH and 1O2 through [H]-mediated electron transfer at ambient temperature and pressure. Under the conditions of 0.2 g L−1 catalyst (Pd loading 0.516 wt%), 25 μM Fe2+, 60 mL min−1 H2 flow (as the [H] source), 20 mM H2O2, and pH 3, approximately 89% of carbamazepine (initial concentration 20 mg L−1) was degraded within 3 h using trace iron. However, the catalytic activity of Pd/UiO-66(Zr)-F4 gradually declined from 89% to 53% over six reaction …
Alcohol-Based Microextraction Of Rhodamine 6g From Soft Drink, Food, And Cosmetic Samples, Mustafa Soylak, Esra Yamaner, Özgür Özalp
Alcohol-Based Microextraction Of Rhodamine 6g From Soft Drink, Food, And Cosmetic Samples, Mustafa Soylak, Esra Yamaner, Özgür Özalp
Turkish Journal of Chemistry
By using alcohol-based solvent extraction without tetrahydrofuran, a liquid–liquid microextraction technique was developed for the separation–enrichment of trace levels of Rhodamine 6G from complex matrices, including soft drinks, food, cosmetics, hygiene products, and natural waters. Numerous experimental parameters were tuned, including pH, alcohol volume, ultrasonication time, and sample and eluent volume. The enrichment factor (EF), limit of detection (LOD), and limit of quantification (LOQ) were used to assess the analytical performance of the suggested approach. The LOD and LOQ were 6.92 ng mL−1 and 23 ng mL−1, respectively, and the EF was 14. Through the use of the standard addition …
Synthesis Of Two Hofmann-Type-Like Clathrates, Characterizations, And Investigation Of Their Structures, Spectroscopic And Theoretical Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal
Synthesis Of Two Hofmann-Type-Like Clathrates, Characterizations, And Investigation Of Their Structures, Spectroscopic And Theoretical Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal
Turkish Journal of Chemistry
This study concerns two Hofmann-type-like clathrates using 4-aminopyridine (4AP) as ligands and the transition metal atoms copper (Cu) and zinc (Zn). These clathrates have the structural features of heteronuclear tetracyanonickelate(II) and contain H2O and 4AP molecules as guest molecules, respectively. These two clathrates were characterized by infrared spectroscopy (IR), elemental analysis, and single crystal X-ray diffraction (SC-XRD) techniques. Based on elemental and spectral data, the structural formulae describing these clathrates were found to be [Cu(II)(4AP)4Ni(μ-CN)2(CN)2]·H2O (1) and [Zn(II)(4AP)4Ni(μ-CN)2(CN)2]·(4AP) (2). In addition, the values of some optical, electronic, and thermochemical properties of the two obtained clathrates calculated with the Gaussian 03 …
Physically Mixed Graphene Aerogel:Carbon Black (Ga:Cb)-Supported Pt Or Hydrothermally Synthesized Ga-Pt/Cb Hybrid Electrocatalysts For Pem Fuel Cells, Emi̇ne Teke Öner, Meli̇s Irmak Aydin, Merve Ni̇da Dursunoğlu, Ayşe Bayrakçeken
Physically Mixed Graphene Aerogel:Carbon Black (Ga:Cb)-Supported Pt Or Hydrothermally Synthesized Ga-Pt/Cb Hybrid Electrocatalysts For Pem Fuel Cells, Emi̇ne Teke Öner, Meli̇s Irmak Aydin, Merve Ni̇da Dursunoğlu, Ayşe Bayrakçeken
Turkish Journal of Chemistry
Graphene aerogels (GAs), having the superior properties of graphene and aerogel structures, are promising support materials for Pt nanoparticles to be used as electrocatalysts for PEM fuel cells. In this study, two routes were followed to synthesize GA-based electrocatalysts. In the first route, after GA synthesis it was physically mixed with carbon black (CB) by changing the mass ratios from 0% to 100% with 25% increments and then decorated with Pt nanoparticles via microwave irradiation, resulting in Pt/GA:CB electrocatalysts. In the second route, firstly, Pt/CB electrocatalyst was synthesized and then GA was hydrothermally added to the Pt/CB by changing the …
A Nonenzymatic Electrochemical Glucose Sensor Depending On A Ninps/Co3o4/Functionalized Graphene Oxide-Modified Working Electrode, Sümeyra Pekmez, Muhammet Güler
A Nonenzymatic Electrochemical Glucose Sensor Depending On A Ninps/Co3o4/Functionalized Graphene Oxide-Modified Working Electrode, Sümeyra Pekmez, Muhammet Güler
Turkish Journal of Chemistry
In the present research, the aim was to develop a novel electrochemical enzyme-free glucose sensor dependent upon a nickel nanoparticles (NiNPs)/cobalt (II, III) oxide (Co3O4)/carboxylated graphene oxide (GO-COOH)-modified glassy carbon (GC) electrode. The electrocatalytic performance of the electrode was tested using various electrochemical methods such as amperometry and cyclic voltammetry (CV). The NiNPs@Co3O4/GO-COOH/GC electrode showed noticeably superior electrocatalytic behavior for glucose oxidation in 0.1 M NaOH media, ascribed to the good synergistic impact between NiNPs, Co3O4, and GO-COOH. The amperometric response of the NiNPs@Co3O4/GO-COOH/GC electrode to glucose exhibited two linear determination ranges at +0.55 V potential. The first one was …
Gold Medal Girl: Media Representations Of Aly Raisman During The Larry Nassar Scandal Through Lenses Of Whiteness, Vulnerability, And "Good" Patriarchy, Anna Mischelle Dean
Gold Medal Girl: Media Representations Of Aly Raisman During The Larry Nassar Scandal Through Lenses Of Whiteness, Vulnerability, And "Good" Patriarchy, Anna Mischelle Dean
Electronic Theses and Dissertations Archive
This thesis analyzed two media texts about former Olympic gymnast Aly Raisman and how these texts constructed her identity during and after the Larry Nassar scandal. I analyzed these texts through the lenses of whiteness, vulnerability, and carceral feminism. Looking at how the media acts as a disciplinary apparatus in this case, I argue that women athletes’ bodies are portrayed as having a vulnerability to abuse that only the "good" patriarchy can address. I seek to show that the media use depictions of women’s vulnerability and need for patriarchal help to remind women athletes that, in cases of abuse, who …
Digital Badge In Critical Thinking: A Collaborative Approach, Christa De Brun, Emmett Cullinane
Digital Badge In Critical Thinking: A Collaborative Approach, Christa De Brun, Emmett Cullinane
Irish Journal of Academic Practice
This article explores the collaborative development of a digital badge in Critical Thinking, created through the partnership of a subject matter expert and a learning designer. Rooted in a shared commitment to student-centred learning, the project aims to equip students with the intellectual tools necessary for deep reflection, nuanced analysis, and responsible engagement with emerging technologies, including artificial intelligence. The article discusses the pedagogical importance of critical thinking, outlines the design and implementation process of the badge, and highlights the value of interdisciplinary collaboration in educational innovation. Central to the initiative is the integration of core critical thinking principles - …
Driving Innovation: Transatlantic Attitudes To The Bionics Bus As A Vehicle For Health Transformation And Stem Engagement, Christopher James, Sarang Shankar, Madeleine Dale, Bhathika Perera, Richard Laugharne, Matthew Allen, Maria Feijoo‐Renones, Rohit Shankar
Driving Innovation: Transatlantic Attitudes To The Bionics Bus As A Vehicle For Health Transformation And Stem Engagement, Christopher James, Sarang Shankar, Madeleine Dale, Bhathika Perera, Richard Laugharne, Matthew Allen, Maria Feijoo‐Renones, Rohit Shankar
Peninsula Medical School
Emerging mobile health and STEM engagement platforms are increasingly recognised as catalysts for improving public understanding of biomedical technologies and supporting digitally enabled models of healthcare delivery. The Bionics Bus (https://bionicsbus.org/) is a novel mobile laboratory designed to democratise access to robotics, artificial intelligence, prosthetics and digital diagnostics by delivering hands-on experiences directly to schools, communities and healthcare settings. This study provides the first transatlantic comparison of public attitudes toward the Bionics Bus within the United Kingdom and the United States of America (USA), two countries with contrasting healthcare systems and digital transformation priorities. Using a mixed-methods cross-sectional design, 78 …
A Taxonomy Of Children And Young People's Social Prescribing Models: A Multi-Site Implementation Case Study In England, Vashti Berry, Siobhan Mitchell, Joe Coombes, Marcello Bertotti, Daniel Hayes, Lucy Cartwright, Kerryn Husk
A Taxonomy Of Children And Young People's Social Prescribing Models: A Multi-Site Implementation Case Study In England, Vashti Berry, Siobhan Mitchell, Joe Coombes, Marcello Bertotti, Daniel Hayes, Lucy Cartwright, Kerryn Husk
Peninsula Medical School
Introduction.Social prescribing for children and young people (CYP) is expanding across England, yet there is limited understanding of how local services interpret and configure its core components—individual need, referrer, linking function and community activity—particularly for CYP presenting with mental health difficulties.Methods.Using a multi-site case study design, we examined five CYP-focused social prescribing pathways selected for their diversity of institutional anchors and implementation maturity. Data collection included pathway visualization with site leads and 34 semi-structured interviews with referrers, link workers, managers and practitioners. Thematic analysis was used to compare pathway structures and functions across cases to support development of an empirically …
“He’S Got The Whole World In His Hands”: Seed Sovereignty And Agricultural Decision Making In Southeastern Kenya, Caroline Stahley
“He’S Got The Whole World In His Hands”: Seed Sovereignty And Agricultural Decision Making In Southeastern Kenya, Caroline Stahley
USF Tampa Graduate Theses and Dissertations
Increasing corporate control of the global seed supply and restrictions to local exchange threaten the autonomy of smallholder farmers and Indigenous communities. This project contributes to agricultural sovereignty movements by examining the decisions farmers make to address climate uncertainty, market volatility, and development agendas. Specifically, how is seed saving practiced and understood in relation to sovereignty? It reimagines what global food systems might look like if investment were directed to producers rather than intermediaries, arguing that cultivators lack support, not knowledge or capacity. Across these domains, seeds act as a motif to describe the concerns, innovations, and visions of farmers.
Amending Planting Media With Typha-Derived Biochar For Sustainable Horticulture, Elissa Touma
Amending Planting Media With Typha-Derived Biochar For Sustainable Horticulture, Elissa Touma
USF Tampa Graduate Theses and Dissertations
Constructed wetlands are widely used to improve water quality by removing excess nutrients from wastewater and stormwater. Nutrients are stored within wetland vegetation, particularly in fast-growing plants such as Typha. Harvesting vegetation provides an opportunity to permanently remove these nutrients while generating biomass suitable for beneficial reuse. Converting harvested biomass into value-added products such as compost and biochar can support nutrient recovery and sustainable biomass management. In addition, increasing concerns regarding the environmental impacts of peat extraction have created interest in renewable alternatives for horticultural growing media. Therefore, the objective of this study was to evaluate the potential of harvested …
Affect And Identification In Hereditary And Huesera: A Critique Of Neoliberal Motherhood In Post-Horror, Jared M. Lamanati
Affect And Identification In Hereditary And Huesera: A Critique Of Neoliberal Motherhood In Post-Horror, Jared M. Lamanati
USF Tampa Graduate Theses and Dissertations
This thesis examines the implications of affect and identification in post-horror and the consequences they present for motherhood. Specifically, I argue Hereditary (Ari Aster, 2018) and Huesera (Michelle Garza Cervera, 2023) make use of their maternal protagonists to complicate spectatorial identification and critique the cruel attachments of neoliberalism which idealize a heteronormative, homogenous vision of mothering. Following David Church’s postulation of affect, neoliberalism, and the maternal melodrama as central to “post-horror,” I look towards Linda Williams’s and Lauren Berlant’s paradigms of pathos and sentimental politics. While Williams addresses the complicated pains and pleasures of pathetic identification in the maternal melodrama, …
Testing The Impact Of Sexual Minority Stress On Endorsement Of Prospective Behaviors Related To Borderline Personality Disorder Among Lesbian, Gay, Bisexual, And Queer Adults, E. Elisa Carsten
USF Tampa Graduate Theses and Dissertations
Sexual minority individuals face increased risk for numerous forms of psychopathology compared to heterosexual individuals, including borderline personality disorder (BPD). Previous investigation into the causes of these mental health disparities highlights several sexual minority-specific factors that may render sexual minority individuals uniquely vulnerable to meeting criteria for a BPD diagnosis, including chronic exposure to minority stressors, such as sexual orientation-based discrimination and stigmatizing beliefs. Some scholars have argued that the relevance of these minority-specific stressful experiences hampers the utility of a BPD diagnosis among members of this historically marginalized population. The present study experimentally tested the influence of minority stressors …
Beyond Public And Private: Arbitrability Of Data Privacy Disputes, Thejas Velaga, Srishti Pandey
Beyond Public And Private: Arbitrability Of Data Privacy Disputes, Thejas Velaga, Srishti Pandey
Indian Journal of Law and Technology
The commodification of personal data and the proliferation of Data Processing Agreements (DPAs) have rendered the arbitrability of data privacy disputes an urgent and underexplored question in Indian commercial law. This paper examines the arbitrability of disputes arising under the Digital Personal Data Protection Act, 2023, with particular focus on subject-matter arbitrability as crystallised in Vidya Drolia v. Durga Trading Corporation. It argues that while such disputes are contractual in nature, their arbitrability remains contested insofar as they implicate the rights of third-party data principals, introducing a public dimension that complicates referral to arbitration. The paper further advances two reforms: …
Medical Staff Journal, 1994-95, V4 N3, Winter, Advocate Health - Midwest
Medical Staff Journal, 1994-95, V4 N3, Winter, Advocate Health - Midwest
Historical Documents - Combined
Lutheran General Hospital, Park Ridge, IL: Quarterly publication produced by and for medical staff at Lutheran General Hospital. This issue includes case studies, professional activities, and a directory of new staff members.
Medical Staff Journal, 1994, V4 N1, Spring, Advocate Health - Midwest
Medical Staff Journal, 1994, V4 N1, Spring, Advocate Health - Midwest
Historical Documents - Combined
Lutheran General Hospital, Park Ridge, IL: Quarterly publication produced by and for medical staff at Lutheran General Hospital. This issue includes case studies, professional activities, and a directory of new staff members.
Aurora Today : The Aurora Health Care Employee Newsletter, 2004 July, Advocate Health - Midwest
Aurora Today : The Aurora Health Care Employee Newsletter, 2004 July, Advocate Health - Midwest
Historical Documents - Combined
Aurora Health Care, Milwaukee, WI: Aurora Today is published monthly for the employees of Aurora Health Care. This newsletter publishes news and updates from around the Aurora Health Care system.
Medical Staff Journal, 1991, V1 N2, Spring, Advocate Health - Midwest
Medical Staff Journal, 1991, V1 N2, Spring, Advocate Health - Midwest
Historical Documents - Combined
Lutheran General Hospital, Park Ridge, IL: Quarterly publication produced by and for medical staff at Lutheran General Hospital. This issue includes case studies, professional activities, and a directory of new staff members.
Caring, 1985 Fall/Winter, Advocate Health - Midwest
Caring, 1985 Fall/Winter, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Quarterly community education publication for IMMC. This issue includes news and updates, events, professional activites, and an article on the opending of a new Eye Center.
Caring, 1984 Summer, Advocate Health - Midwest
Caring, 1984 Summer, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Quarterly community education publication for IMMC. This issue includes news and updates, events, professional activites, and an article on cardiac diseases and treatments.
Caring Annual Report, 1991, Advocate Health - Midwest
Caring Annual Report, 1991, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Annual report published as an issue of Caring, the quarterly community publication for Illinois Masonic Medical Center. Included are a financial report, statistical report, and updates from the past year.
Caring Annual Report, 1992, Advocate Health - Midwest
Caring Annual Report, 1992, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Annual report published as an issue of Caring, the quarterly community publication for Illinois Masonic Medical Center. Included are a financial report, statistical report, and updates from the past year. This year IMMC became the primary teaching affiliate with Rush University. The Philanthropy Report is included as an insert.
Caring Annual Report, 1990, Advocate Health - Midwest
Caring Annual Report, 1990, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Annual report published as an issue of Caring, the quarterly community publication for Illinois Masonic Medical Center. Included are a financial report, statistical report, and updates from the past year.
Caring Annual Report, 1989, Advocate Health - Midwest
Caring Annual Report, 1989, Advocate Health - Midwest
Historical Documents - Combined
Illinois Masonic Medical Center, Chicago, IL: Annual report published as an issue of Caring, the quarterly community publication for Illinois Masonic Medical Center. Included are a financial report, statistical report, and updates from the past year.