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Articles 89311 - 89340 of 719872
Full-Text Articles in Entire DC Network
Protection Of Agrobiodiversity: Model Calculations In Rhineland-Palatia: Costs And Implications For Farmers, H. Bergmann
Protection Of Agrobiodiversity: Model Calculations In Rhineland-Palatia: Costs And Implications For Farmers, H. Bergmann
IGC Proceedings (1977-2023)
Biological conservation and production use the same areas of land in less favoured areas. Grassland in these areas makes an important contribution to the protection of agro-biodiversity. However, under existing market conditions and production needs, the use of low yielding grasslands is not economically efficient. The objective of this study was to analyze the economic consequences of different mowing strategies in a small region in Rhineland-Palatia (Germany) that served the protection of two butterfly species.
Stocking Rate Theory And Profit Drivers In North Australian Rangeland Grazing Enterprises, Neil D. Macleod, A. J. Ash, John G. Mcivor
Stocking Rate Theory And Profit Drivers In North Australian Rangeland Grazing Enterprises, Neil D. Macleod, A. J. Ash, John G. Mcivor
IGC Proceedings (1977-2023)
Setting correct stock numbers is a key decision for successful pastoralism. In marginal environments, typified by northern Australia, this involves careful cattle herd management across landscapes and seasons characterised by heterogeneous land condition and extreme climatic uncertainty. Stocking rate theory which links animal production to stocking rates concentrates only on liveweight gain of sale animals and ignores complex herd (e.g. reproduction, mortality) and pasture dynamics (e.g. land condition) and costs of maintaining stock numbers (e.g. supplementary feeding). Related economic models are generally naïve and incomplete, being based on liveweight gain, meat prices and variable husbandry costs (e.g. Workman, 1986). Modelling …
An Ecological And Economic Risk Avoidance Drought Management Decision Support System, R. K. Heitschmidt, L. T. Vermeire
An Ecological And Economic Risk Avoidance Drought Management Decision Support System, R. K. Heitschmidt, L. T. Vermeire
IGC Proceedings (1977-2023)
Ecologists have long recognized the fundamental impacts of drought on rangeland structure and function. Simulation models have been developed to increase our understanding of these impacts as they relate to forage production, particularly for predictive purposes. Although the capacity of these models to accurately predict quantity and quality of forage produced under varying climatic conditions is often quite good, their ability to serve as an effective and proactive drought management decision support system is often limited. This is in large part because their complexity impedes their use by on-the-ground managers. The objective of this research was to develop a very …
Predicting The Effects Of Management On Upland Birds, Economy And Employment, S. M. Gardner, G. M. Buchanan, J. W. Pearce-Higgins, M. C. Grant, A. Waterhouse
Predicting The Effects Of Management On Upland Birds, Economy And Employment, S. M. Gardner, G. M. Buchanan, J. W. Pearce-Higgins, M. C. Grant, A. Waterhouse
IGC Proceedings (1977-2023)
Livestock farming systems play a significant role in the economy and conservation of the UK uplands and rely heavily upon public financial support. Changes in that support could have far-reaching impacts on the wildlife interest and socio-economics of upland areas. Predicting the impacts of such changes is difficult, since they arise from responses to new economic circumstances. The effect of management change is also influenced by natural variation, such as the mosaic of plant communities, already present in the upland landscape. This paper sets out an approach that integrates theoretical models with field studies to investigate the effects of management …
Managing Resources By Grazing In Grasslands Dominated By Dominant Shrub Species, D. Magda, Cyril Agreil, Michel Meuret, E. Chambon-Dubreuil, P. -L. Osty
Managing Resources By Grazing In Grasslands Dominated By Dominant Shrub Species, D. Magda, Cyril Agreil, Michel Meuret, E. Chambon-Dubreuil, P. -L. Osty
IGC Proceedings (1977-2023)
The European natural grasslands are attracting new attention because of their environmental value as habitats for threatened fauna and flora species and their contribution to the diversity of landscapes. Those responsible for the implementation of the European agri-environmental policy are hence encouraging livestock farmers to adopt grazing practices that contribute to the conservation of grassland biodiversity especially by limiting encroachment by dominant shrubs. However, current scientific knowledge and technical information are often insufficient to connect flock feeding and the impact of grazing on shrub dynamics and livestock farmers are not very enthusiastic about restoring or conserving “plant mosaics” including shrubs …
Challenges In Modelling Live-Weight Change In Grazed Pastures In The Australian Subtropics, C. K. Mcdonald, A. J. Ash
Challenges In Modelling Live-Weight Change In Grazed Pastures In The Australian Subtropics, C. K. Mcdonald, A. J. Ash
IGC Proceedings (1977-2023)
In sub-tropical regions there is enormous seasonal, annual and spatial variation in pasture quality and considerable variation in quality between pasture species. The heterogeneous structure of sub-tropical pasture swards means that process based modelling of liveweight change (LWC) is particularly difficult. In response to this complexity LWC has been expressed as a function of the length of the growing season and/or pasture utilization (McKeon et al. 2000), green leaf availability, or pasture availability and climate (Hirata et al. 1993). However, these relationships vary from year to year, often fail when species composition changes, and generally explain
Vegetation Dynamics Of Campos Under Grazing/Fire Regimes In Southern Brazil, Fernando L. F. De Quadros, J. P. P. Trinidade, D. G. Bandinelli, L. Pötter
Vegetation Dynamics Of Campos Under Grazing/Fire Regimes In Southern Brazil, Fernando L. F. De Quadros, J. P. P. Trinidade, D. G. Bandinelli, L. Pötter
IGC Proceedings (1977-2023)
Natural grassland vegetation in Southern Brazil, known as campos, has most likely evolved under a disturbance regime that included fire and grazing (Pillar et al., 1997). Nowadays, the composition of the vegetation of campos is grazing- and fire-dependent (Boldrini et al., 1997). Its importance can be evaluated by the fact that it represents 37 % of the state’s area and provides 77 % of the slaughtered cattle at Rio Grande do Sul (Barcellos et al., 2002). The objective of this experiment was to evaluate the vegetation dynamics of campos under grazing/fire regimes in order to explore the …
Accumulation Of Polyphenols And Major Bioactive Compounds In Plantago Lanceolata L. As A Medicinal Plant For Animal Health And Production, Y. Tamura, K. Yamaki
Accumulation Of Polyphenols And Major Bioactive Compounds In Plantago Lanceolata L. As A Medicinal Plant For Animal Health And Production, Y. Tamura, K. Yamaki
IGC Proceedings (1977-2023)
Producing animals without the use of feed-grade antibiotic growth promoters and chemical medicines is sought. Scientific studies with this aim have focused on medicinal plants to identify and quantify any beneficial effects that they might have on animal production. Plantago lanceolata L. has been used in herbal medicines and is currently being evaluated as a potential pasture species because of its beneficial effects on animal health. In the present study, the accumulation of polyphenols in P. Lanceolata is compared to that in principal pasture species, and genetic variation and environmental changes in the major bioactive compounds in P. Lanceplata are …
Effect Of Urea-Treated Pennisetum Pedicellatum And Supplementation Of Concentrates With Urea On Milk Production Of “Mossi” Ewes, V. M. C. Bougouma-Yameogo, A. J. Nianogo
Effect Of Urea-Treated Pennisetum Pedicellatum And Supplementation Of Concentrates With Urea On Milk Production Of “Mossi” Ewes, V. M. C. Bougouma-Yameogo, A. J. Nianogo
IGC Proceedings (1977-2023)
The “Mossi” sheep is a near parent of “Djallonke” sheep that live in sudano-sahelian area of Burkina Faso. However, there are few available results on dairy production from this breed. The treatment of straw with urea is a technique used in several developing countries to improve the nutritional value of gramineous forages (Sourabié et al., 1995). The aim of this study was to test the influence on the performance of “Mossi” ewes and on milk composition of treatment of Pennisetum pedicellatum (Pp) with urea in comparison with addition of urea to the concentrate feed.
Effect Of Stocking Rate On A Stipa Breviflora Desert Steppe Community Of Inner Mongolia, G. Han, Walter D. Willms, M. Zhao, A. Gao, S. Jiao, David R. Kemp
Effect Of Stocking Rate On A Stipa Breviflora Desert Steppe Community Of Inner Mongolia, G. Han, Walter D. Willms, M. Zhao, A. Gao, S. Jiao, David R. Kemp
IGC Proceedings (1977-2023)
Stocking rate is an important factor in grazing management. The stocking rate defines utilization and ultimately grazing pressure, which in turn affects grassland sustainability. Grassland sustainability is partly defined by its species composition and ultimately by its productivity. These attributes are unique for specific plant communities and the effect of stocking rate must be established for each in order to understand the community response to grazing and to determine its carrying capacity. While some information exists on the effects of stocking rate on livestock production in the Stipa breviflora Griseb. Desert Steppe (Wei et al., 2000), the effects on …
Using The N-Alkane Technique To Estimate The Herbage Intake And Diet Composition Of Cattle Grazing A Miscanthus Sinensis Grassland, Y. Zhang, Y. Togamura, K. Otsuki
Using The N-Alkane Technique To Estimate The Herbage Intake And Diet Composition Of Cattle Grazing A Miscanthus Sinensis Grassland, Y. Zhang, Y. Togamura, K. Otsuki
IGC Proceedings (1977-2023)
Plant wax alkanes are now widely used as marker substances (Dove & Mayes 1991) for the estimation of forage intake and diet composition of grazing herbivores. The objective of this study was to evaluate this method with cattle grazing a M. sinensis grassland in Japan.
Reasons For The Premature Decline In Astragalus Adsurgens Stands In Kerqin Sandy Land, Qizhong Sun, Z. L. Wang, J. G. Han, Y. W. Wang, G. R. Liu
Reasons For The Premature Decline In Astragalus Adsurgens Stands In Kerqin Sandy Land, Qizhong Sun, Z. L. Wang, J. G. Han, Y. W. Wang, G. R. Liu
IGC Proceedings (1977-2023)
Diseases partly account for reductions in Astragalus adsurgens stand longevity. The effect of some cultural practices on the control of pests and diseases have been reported (Hou, 1986; Nan, 1996), but few reports have detailed the relationship among soil fertiliser status, diseases and premature stand decline. This study was conducted to investigate these relationships in order to extend the longevity of Astragalus adsurgens stands.
Selecting Grassland Species For Saline Environments, M. E. Rogers, A. D. Craig, T. D. Colmer, R. Munns, S. J. Hughes, P. M. Evans, P. G. H. Nichols, R. Snowball, D. Henry, J. Deretic, B. Dear, M. Ewing
Selecting Grassland Species For Saline Environments, M. E. Rogers, A. D. Craig, T. D. Colmer, R. Munns, S. J. Hughes, P. M. Evans, P. G. H. Nichols, R. Snowball, D. Henry, J. Deretic, B. Dear, M. Ewing
IGC Proceedings (1977-2023)
In Australia, around 5.7 million hectares of agricultural land are currently affected by dryland salinity or at risk from shallow water tables and this figure is expected to increase over the next 50 years (LWRA, 2001). Most improved grassland species cannot tolerate the combined effects of salt and waterlogging and, therefore, the productivity of sown grasslands in salt-affected areas is low. However, there is potential to overcome the lack of suitably adapted fodder species by introducing new, salt and waterlogging-tolerant species and by diversifying the gene pool of proven species. Potential species include exotic, naturalised and native Australian grass, legumes, …
Effects Of The Stage Of Growth And Inoculation On Proteolysis In Field Pea Silage, L. Cavallarin, G. Borreani, S. Antoniazzi, E. Tabacco
Effects Of The Stage Of Growth And Inoculation On Proteolysis In Field Pea Silage, L. Cavallarin, G. Borreani, S. Antoniazzi, E. Tabacco
IGC Proceedings (1977-2023)
Ensiling legumes is a good way of providing home-grown protein in dairy farms but severe protein degradation can occur when conserving legumes. Peas (Pisum sativum L.) are legumes with a high crude protein and starch content, that provide a high forage yield in a short growing period. Very little information is available on the protein value of field pea silage. The aim of the study was to investigate the effect of stage of maturity and inoculant application on proteolysis in field pea silage in the Po Valley, NW Italy.
Grass Silage: Factors Affecting Efficiency Of N Utilisation In Milk Production, P. Huhtanen, K. J. Shingfield
Grass Silage: Factors Affecting Efficiency Of N Utilisation In Milk Production, P. Huhtanen, K. J. Shingfield
IGC Proceedings (1977-2023)
Key points
- Low efficiency of N utilisation for milk production in cows fed grass silage-based diets is mainly due to excessive N losses in the rumen.
- The type and extent of in silo fermentation can alter the balance of absorbed nutrients.
- There is very little experimental evidence that the capture of N in the rumen can be improved by a better synchrony between energy and N release in the rumen. Nitrogen losses in the rumen can be reduced by decreasing the ratio between rumen degradable N and fermentable energy.
- Rapeseed meal has increased milk protein output more than isonitrogenous soybean …
Decision Support For Grassland Systems In Developing Countries, P. K. Thornton
Decision Support For Grassland Systems In Developing Countries, P. K. Thornton
IGC Proceedings (1977-2023)
Key points
1. Information flows in complex systems are often themselves highly complex, and decision support approaches based on linear input-output processes may have only limited impact.
2. How decisions are made, and how they can be appropriately supported, is often incompletely understood, in part because of inadequate understanding of the objectives and attitudes of all the decision makers involved.
3. Much of the developing world faces daunting problems in the coming 30 years, and appropriate information could play a critical role in dealing with these.
4. System complexity, household variability, and institutional intricacies have to be embraced rather than …
Polyvinylpyrrolidone-Passivated Fluorescent Iron Oxide Quantum Dots For Turn-Off Detection Of Tetracycline In Biological Fluids, Sri Sudewi, Lutfi Chabib, Muhammad Zulfajri, Gangaraju Gedda, Genin Gary Huang
Polyvinylpyrrolidone-Passivated Fluorescent Iron Oxide Quantum Dots For Turn-Off Detection Of Tetracycline In Biological Fluids, Sri Sudewi, Lutfi Chabib, Muhammad Zulfajri, Gangaraju Gedda, Genin Gary Huang
Journal of Food and Drug Analysis
Tetracycline is an antibiotic that has been prescribed for COVID-19 treatment, raising concerns about antibiotic resistance after long-term use. This study reported fluorescent polyvinylpyrrolidone-passivated iron oxide quantum dots (IO QDs) for detecting tetracycline in biological fluids for the first time. The as-prepared IO QDs have an average size of 2.84 nm and exist a good stability under different conditions. The IO QDs’ tetracycline detection performance could be attributed to a combination of static quenching and inner filter effect. The IO QDs displayed high sensitivity and selectivity toward tetracycline and achieved a good linear relationship with the corresponding detection limit being …
High-Resolution 1h Nmr Analysis Of Continuous And Discontinuous Thermo-Oxidative Susceptibility Of Culinary Oils During Frying At 180℃, Gilbert Ampem, Adam Le Gresley, Martin Grootveld, Declan P Naughton
High-Resolution 1h Nmr Analysis Of Continuous And Discontinuous Thermo-Oxidative Susceptibility Of Culinary Oils During Frying At 180℃, Gilbert Ampem, Adam Le Gresley, Martin Grootveld, Declan P Naughton
Journal of Food and Drug Analysis
Lipid oxidations products (LOPs) are reactive mutagenic and carcinogenic species known to be generated in thermally stressed culinary oils. Mapping the evolution of LOPs in culinary oils exposed to standard frying practices – both continuous and discontinuous thermo-oxidation – at 180℃ is vital to our understanding of these processes, and to the development of scientific solutions for their effective suppression. Modifications in the chemical compositions of the thermo-oxidised oils were analysed using a high-resolution proton nuclear magnetic resonance (1H NMR) technique. Research findings acquired showed that polyunsaturated fatty acid (PUFA)-rich culinary oils were the most susceptible to thermo-oxidation. …
Investigation Of Monacolin K, Yellow Pigments, And Citrinin Production Capabilities Of Monascus Purpureus And Monascus Ruber (Monascus Pilosus), Tzu-Shing Lin, Shih-Hau Chiu, Chien-Chi Chen, Chih-Hui Lin
Investigation Of Monacolin K, Yellow Pigments, And Citrinin Production Capabilities Of Monascus Purpureus And Monascus Ruber (Monascus Pilosus), Tzu-Shing Lin, Shih-Hau Chiu, Chien-Chi Chen, Chih-Hui Lin
Journal of Food and Drug Analysis
Red mold rice (RMR) is a traditional Chinese medicine prepared using Monascus fermentation. M. ruber (pilosus) and M. purpureus have a long history of use as food and medicine. As an economically important starter culture, the relationship between the taxonomy of Monascus and production capabilities of secondary metabolites is crucial for the Monascus food industry. In this study, monacolin K, monascin, ankaflavin, and citrinin production by M. purpureus and M. ruber were genomically and chemically investigated. Our findings suggest that M. purpureus can produce monascin and ankaflavin in a correlated manner, whereas M. ruber produces monascin with minimum …
Hybridizing Gaining–Sharing Knowledge And Differential Evolution For Large-Scale Power System Economic Dispatch Problems, Qinghua Liu, Guojiang Xiong, Xiaofan Fu, Ali Wagdy Mohamed
Hybridizing Gaining–Sharing Knowledge And Differential Evolution For Large-Scale Power System Economic Dispatch Problems, Qinghua Liu, Guojiang Xiong, Xiaofan Fu, Ali Wagdy Mohamed
Faculty Journal Articles
No abstract provided.
Naval Engineering For Grades 4-6, Patrick Young
Naval Engineering For Grades 4-6, Patrick Young
Publications & Research
Reading The Girl with a Mind for Math, we learn about the career of Raye Montague, an African-American woman who broke every barrier to pioneer computer-aided ship design and become the first female program manager in the United States Navy. Lessons are provided for using free, online software to design ships while exercising several Common Core Math standards and NGSS standards for engineering design.
A Multiscale Mechanistic Model Of Human Dendritic Cells For In-Silico Investigation Of Immune Responses And Novel Therapeutics Discovery, Sara Sadat Aghamiri, Bhanwar Lal Puniya, Rada Amin, Tomáš Helikar
A Multiscale Mechanistic Model Of Human Dendritic Cells For In-Silico Investigation Of Immune Responses And Novel Therapeutics Discovery, Sara Sadat Aghamiri, Bhanwar Lal Puniya, Rada Amin, Tomáš Helikar
Department of Biochemistry: Faculty Publications
Dendritic cells (DCs) are professional antigen-presenting cells (APCs) with the unique ability to mediate inflammatory responses of the immune system. Given the critical role of DCs in shaping immunity, they present an attractive avenue as a therapeutic target to program the immune system and reverse immune disease disorders. To ensure appropriate immune response, DCs utilize intricate and complex molecular and cellular interactions that converge into a seamless phenotype. Computational models open novel frontiers in research by integrating large-scale interaction to interrogate the influence of complex biological behavior across scales. The ability to model large biological networks will likely pave the …
A Dialogue With Professor Ellen Veomett: The Intersections Of Mathematics & Gerrymandering, Ellen Veomett
A Dialogue With Professor Ellen Veomett: The Intersections Of Mathematics & Gerrymandering, Ellen Veomett
SMC Community Engagement
No abstract provided.
Numerical Simulation Of Steady-State Thermal Blooming With Natural Convection, Jeremiah S. Lane, Justin Cook, Martin Richardson, Benjamin F. Akers
Numerical Simulation Of Steady-State Thermal Blooming With Natural Convection, Jeremiah S. Lane, Justin Cook, Martin Richardson, Benjamin F. Akers
Faculty Publications
This work investigates steady-state thermal blooming of a high-energy laser in the presence of laser-driven convection. While thermal blooming has historically been simulated with prescribed fluid velocities, the model introduced here solves for the fluid dynamics along the propagation path using a Boussinesq approximation to the incompressible Navier–Stokes equations. The resultant temperature fluctuations were coupled to refractive index fluctuations, and the beam propagation was modeled using the paraxial wave equation. Fixed-point methods were used to solve the fluid equations as well as to couple the beam propagation to the steady-state flow. The simulated results are discussed relative to recent experimental …
Call Numbers, Oh Call Numbers On Ebooks, Why Have You Forsaken Us!, David Schuster, Sasha Frizzell
Call Numbers, Oh Call Numbers On Ebooks, Why Have You Forsaken Us!, David Schuster, Sasha Frizzell
Library Scholarship
ILS vendor Knowledge bases (KB) are built in a black box. The quality of the metadata is not the concern of the ILS vendor which then leads to missing data, which impacts discoverability. Comparing records of two ILS vendors KBs has shown a disparity in how they manage metadata. We are evaluating multiple ebook publishers’ data in the KB based on the availability of call numbers and subject headings while looking at resource usage. Exploring ways to improve access by including call numbers and subject headings and discovering the larger problem.
Finite Element Modeling Of Meniscal Tears Using Continuum Damage Mechanics And Digital Image Correlation, Derek Q. Nesbitt, Dylan E. Burruel, Bradley S. Henderson, Trevor J. Lujan
Finite Element Modeling Of Meniscal Tears Using Continuum Damage Mechanics And Digital Image Correlation, Derek Q. Nesbitt, Dylan E. Burruel, Bradley S. Henderson, Trevor J. Lujan
Mechanical and Biomedical Engineering Faculty Publications and Presentations
Meniscal tears are a common, painful, and debilitating knee injury with limited treatment options. Computational models that predict meniscal tears may help advance injury prevention and repair, but first these models must be validated using experimental data. Here we simulated meniscal tears with finite element analysis using continuum damage mechanics (CDM) in a transversely isotropic hyperelastic material. Finite element models were built to recreate the coupon geometry and loading conditions of forty uniaxial tensile experiments of human meniscus that were pulled to failure either parallel or perpendicular to the preferred fiber orientation. Two damage criteria were evaluated for all experiments: …
Breeding Milestones Correspond With Changes To Wheat Rhizosphere Biogeochemistry That Affect P Acquisition, Rebecca Kay Mcgrail, David A. Van Sanford, David H. Mcnear Jr.
Breeding Milestones Correspond With Changes To Wheat Rhizosphere Biogeochemistry That Affect P Acquisition, Rebecca Kay Mcgrail, David A. Van Sanford, David H. Mcnear Jr.
Plant and Soil Sciences Faculty Publications
Breeding wheat (Triticum aestivum L.) has resulted in small gains in improved nutrient acquisition and use as numerous traits are involved. In this study, we evaluated the impact of breeding on P-acquisition and identified both plant and soil variables that could be used to inform the selection of germplasm with increased P acquisition efficiency. We previously screened a historic panel of winter wheat cultivars for root system architecture and root tip organic acid content when grown in P-deficient solution/agar and used these characteristics together with breeding history to develop a predicted P extraction potential (PEP). We tested the validity …
Using Game Theory To Model Tripolar Deterrence And Escalation Dynamics, Grace Farson
Using Game Theory To Model Tripolar Deterrence And Escalation Dynamics, Grace Farson
Honors Program: Senior Projects (Public)
The study investigated how game theory can been utilized to model multipolar escalation dynamics between Russia, China, and the United States. In addition, the study focused on analyzing various parameters that affected potential conflict outcomes to further new deterrence thought in a tripolar environment.
A preliminary game theoretic model was created to model and analyze escalation dynamics. The model was built upon framework presented by Zagare and Kilgour in their work ‘Perfect Deterrence’. The model is based on assumptions and rules set prior to game play. The model was then analyzed based upon these assumptions using a form of mathematical …
Towards Meaningful Research And Engagement: Indigenous Knowledge Systems And Great Lakes Governance, Deborah Mcgregor, Nicole Latulippe, Rod Whitlow, Kristi Leora Gansworth, Lorrilee Mcgregor, Stephanie Allen
Towards Meaningful Research And Engagement: Indigenous Knowledge Systems And Great Lakes Governance, Deborah Mcgregor, Nicole Latulippe, Rod Whitlow, Kristi Leora Gansworth, Lorrilee Mcgregor, Stephanie Allen
Articles & Book Chapters
For thousands of years, Indigenous peoples governed their relations in the Great Lakes region, guided by distinct political, legal, governance, and knowledge systems. Despite historic and ongoing exclusion of Indigenous peoples from Great Lakes governance in the Canadian context and other assaults on Indigenous sovereignty, authority, jurisdiction and responsibilities, Indigenous peoples have maintained their relationships with the Great Lakes. In recent years, Indigenous knowledge systems (IKS) have made inroads in Great Lakes governance, thanks primarily to First Nation political advocacy. However, it remains a challenge to include Indigenous knowledge and implement approaches that bridge Indigenous and Western ways of knowing. …
Amplifying Reactivity Of Metal Hydrides: A Heterotrimetallic Nial2(Μ2-H)2 Catalyst For The Dearomatization Of N-Heterocycles, Edgardo De Leon, Fernando Gonzalez, Preetika Bauskar, Sergio Gonzalez-Eymard, David De Los Santos, Manar Shoshani
Amplifying Reactivity Of Metal Hydrides: A Heterotrimetallic Nial2(Μ2-H)2 Catalyst For The Dearomatization Of N-Heterocycles, Edgardo De Leon, Fernando Gonzalez, Preetika Bauskar, Sergio Gonzalez-Eymard, David De Los Santos, Manar Shoshani
School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)
Identifying methods to modulate the reactivity of metal hydrides is lacking yet highly desirable given the role they play in a plethora of catalytic applications. Herein we report novel methodology to amplify the reactivity of metal hydrides through the design of well-defined heterometallic bridged hydride species. Catalytic hydroboration of quinolines was dramatically altered by the addition of a secondary metal to bridge the Al–hydride species LAlH. Specifically, the addition of Ni(COD)2 led to the formation of novel heterotrimetallic species 1 which features Ni participating in 3-center bonding with sterically accessible Al–H species and exhibits catalytic hydroboration of sterically encumbered quinolines …