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Research On Control System Of Drill Pipe Conveying Device Based On Fuzzy Particle Swarm Optimization, Zhang Ning, Liu Qi, Shao Junjie, Chang Jianghua, Luo Pengping, Zou Zujie Mar 2023

Research On Control System Of Drill Pipe Conveying Device Based On Fuzzy Particle Swarm Optimization, Zhang Ning, Liu Qi, Shao Junjie, Chang Jianghua, Luo Pengping, Zou Zujie

Coal Geology & Exploration

In the tripping operation of large-diameter rescue well construction, the drill pipe conveying device used for large-diameter drilling tool transportation and drill string connection. In view of the problem that it is difficult to quickly and accurately lift the drill pipe to the angle of power head for make-up due to its easy vibration in the process of positioning, the structural characteristics and working principle of the drill pipe conveying device were analyzed at first. The kinematic model for the lifting of drill pipe was deduced with the structural relationship, obtaining the mapping relationship in the motion law of the …

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Pattern Formation From The Gierer–Meinhardt Model On The Stanford Bunny, Grady Wright Mar 2023

Pattern Formation From The Gierer–Meinhardt Model On The Stanford Bunny, Grady Wright

Research Computing Days 2023

Snapshot from a simulation the Gierer–Meinhardt model on the Stanford Bunny computed using the radial basis function finite difference (RBF-FD) method. This model is consists of activator/inhibitor system of reaction diffusion equations and is known to generate Turing patterns that mimic the coats of some animals found in nature.

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Convection Modeling Of Ice-Ocean Interaction, Yao Gahounzo, Michal Kopera Mar 2023

Convection Modeling Of Ice-Ocean Interaction, Yao Gahounzo, Michal Kopera

Research Computing Days 2023

Ice-ocean interaction is an essential component of the Earth's climate system and is one of the key challenges in climate modeling. It has profound consequences for the ocean, such as transforming the water masses through the melting or freezing of ice. The present-day climate models cannot satisfactorily resolve the fine-scale process at an ice face, especially the plume of an order of 10 m that rises at the ice face. We investigate the melting and the plume when vertical ice dissolves into seawater through convection under Antarctic Ocean conditions using the Non-hydrostatic Unified Model of the Ocean (NUMO), a high-resolution …

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Integrating Empirical Orthogonal Functions (Eofs) Into Machine Learning Model, Kachinga Silwimba Mar 2023

Integrating Empirical Orthogonal Functions (Eofs) Into Machine Learning Model, Kachinga Silwimba

Research Computing Days 2023

The representation of soil moisture in Earth System Models, like the Community Earth System Model (CESM), is an essential facet in modeling the response of the Earth System to climate change. Since their inception, land models have grown to represent critical processes like carbon cycling, ecosystem dynamics, terrestrial hydrology, and agriculture. They serve as a lower boundary condition for atmospheric general circulation models. With increasing process representation, they are computationally expensive. Hydrologists and modelers use several parameterization schemes to describe the water and energy balance. However, this is regarded as computationally expensive. Alternative tools called emulators (e.g., machine learning and …

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Numerical Simulation Of Co2 Storage In Bedded Salt Rock Storage Cavern In Subei Basin, Zong Shi, Liu Shiqi, Xu Hui, Wang Wenkai, Cao Bo, Huang Fansheng Mar 2023

Numerical Simulation Of Co2 Storage In Bedded Salt Rock Storage Cavern In Subei Basin, Zong Shi, Liu Shiqi, Xu Hui, Wang Wenkai, Cao Bo, Huang Fansheng

Coal Geology & Exploration

Underground salt cavern is an effective geological body for CO2 storage. The leakage of CO2 along the weak interlayer of salt rock and the interface of salt layer and interlayer is the key to restrict the safe storage of CO2 in underground salt cavern. A fluid-solid coupling mathematical model of CO2 storage in bedded salt cavern gas storage was established based on the CO2 salt cavern storage in Jintan area of Subei basin. On this basis, the leakage and migration law of CO2 in salt rock and mudstone interlayer, as well as its influence …

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Final 2021 Unreclaimed Sites Sampling Ur-40 Site Evaluation Summary Report, Pioneer Technical Services, Inc. Mar 2023

Final 2021 Unreclaimed Sites Sampling Ur-40 Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

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Minutes, Curriculum Committee Meeting, Tuesday, March 28, 2023, Curriculum Committee Mar 2023

Minutes, Curriculum Committee Meeting, Tuesday, March 28, 2023, Curriculum Committee

Curriculum Committee Minutes

No abstract provided.

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What To Look For In Relationships: Development, Inter-Rater Reliability, And Initial Validity Estimates For A Young Child-Caregiver Relationship Assessment, Joy D. Osofsky, Margaret A. Fields-Olivieri, Andrew L. Frazer, Rebecca A. Graham, Bethany H. Mccurdy, Carl F. Weems Mar 2023

What To Look For In Relationships: Development, Inter-Rater Reliability, And Initial Validity Estimates For A Young Child-Caregiver Relationship Assessment, Joy D. Osofsky, Margaret A. Fields-Olivieri, Andrew L. Frazer, Rebecca A. Graham, Bethany H. Mccurdy, Carl F. Weems

School of Medicine Faculty Publications

Introduction: Observational assessments are important for understanding a range of behaviors and emotions in the young child-caregiver relationship. This paper provides initial data on a multidimensional assessment for professionals who work with young children and their caregivers, the What to Look for in Relationships (WLR). The WLR was designed to assist providers in evaluating strengths and areas for improvement in five areas of young child-caregiver relationship dimensions. This paper reports on the development, interrater reliability, initial convergent and discriminant validity, and incremental utility of the scales. Methods: Data were collected from caregiver-child dyads, who participated in a semi-structured observational caregiver-child …

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Lithium And Lithium Isotope Behavior During High Temperature Solid/Fluid Exchanges: Examples From Iceland And The Izu-Bonin Forearc, Alex Maruszczak Mar 2023

Lithium And Lithium Isotope Behavior During High Temperature Solid/Fluid Exchanges: Examples From Iceland And The Izu-Bonin Forearc, Alex Maruszczak

USF Tampa Graduate Theses and Dissertations

The development of a method for lithium isotopic measurement was developed using a quadrupole, single-collector ICP-MS. Measured precision was ±1.00‰ 2σ over a 15-month period based on measurements of international rock standards. A 1-hour leach using cold, HCl was sufficient to remove alteration-related Li in minimally to moderately altered seafloor basalts. Measurements on the Holocene ages lavas from the neovolcanic zones of Iceland suggest no systematic Li isotopic variability among the differing Icelandic sources. Felsic samples from Hekla and Pumice contain elevated Li contents of >18ug/g while the tholeiitic and alkaline basalts are <8ug/g Li. Most of the island lies around MORB values of ~+3 to +5‰ with the exception of Western Volcanic Zone samples that show evidence for seawater inputs. The RN-17 drillcore, which penetrates >3000m through a hydrothermal system in the …

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Two Birds With One Stone Through Mdl Interlocutory Appeal: Lessons From Rule 23(F), Jared Stehle Mar 2023

Two Birds With One Stone Through Mdl Interlocutory Appeal: Lessons From Rule 23(F), Jared Stehle

NULR Online

No abstract provided.

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Image-Based Corrosion Detection In Ancillary Structures, Amrita Das, Eberechi Ichi, Sattar Dorafshan Mar 2023

Image-Based Corrosion Detection In Ancillary Structures, Amrita Das, Eberechi Ichi, Sattar Dorafshan

Civil Engineering Faculty Publications

Ancillary structures are essential for highways’ safe operationality but are mainly prone to environmental corrosion. The traditional way of inspecting ancillary structures is manned inspection, which is laborious, time-consuming, and unsafe for inspectors. In this paper, a novel image processing technique was developed for autonomous corrosion detection of in-service ancillary structures. The authors successfully leveraged corrosion features in the YCbCr color space as an alternative to the conventional red–green–blue (RGB) color space. The proposed method included a preprocessing operation including contrast adjustment, histogram equalization, adaptive histogram equalization, and optimum value determination of brightness. The effect of preprocessing was evaluated against …

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Mechanism Of Coal Fine-Bubble Coupling In The Unsaturated Flow Stage Of Coalbed Methane Drainage, Han Wenlong, Li Yong, Chen Xiangsheng, Zhuo Qiming, Wang Yanbin Mar 2023

Mechanism Of Coal Fine-Bubble Coupling In The Unsaturated Flow Stage Of Coalbed Methane Drainage, Han Wenlong, Li Yong, Chen Xiangsheng, Zhuo Qiming, Wang Yanbin

Coal Geology & Exploration

To reveal the mechanism of interaction between coal fines and gas in the unsaturated flow stage of coalbed methane (CBM) drainage, it is essential to formulate the drainage system and improve the gas production. The effect of air bubbles with different diameters on coal fines with different particle sizes and densities was systematically experimented through the experiment device for microscopic interaction between the air bubble and the coal fines. Meanwhile, the influence of air bubbles on the migration trajectory and velocity of coal fines and the characteristics of coal fine capturing by air bubbles were also analyzed. The results show …

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Optimization Of Cemented Filling Material Ratio Based On Rsm-Bbd Method And Engineering Application, Wang Shushuai, Xu Bin, Li Yang, Yang Zhen Mar 2023

Optimization Of Cemented Filling Material Ratio Based On Rsm-Bbd Method And Engineering Application, Wang Shushuai, Xu Bin, Li Yang, Yang Zhen

Coal Geology & Exploration

In view of the problems of large stacking of solid waste caused by roof caving method in coal seam mining and imbalance between mining and filling in long-wall cemented backfilling, the No.31 ming area of Chahasu Coal Mine in Inner Monogolia uses continuous mining and filling roadway cemented backfilling mining technology, adopting the “mining at intervals of three” mining method and the “three with high strength filling and one with low strength filling” filling mode. The filling material ratio has an important influence on the filling cost and effect. In order to solve the problems of high cement consumption and …

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Mechanical Properties And Mechanism Of Co-Curing Saline Soil With Coal Solid Waste, Dong Chenxi, Wang Nianqin, Li Jiangshan, Chen Xin, Yan Xusheng, Ma Wei Mar 2023

Mechanical Properties And Mechanism Of Co-Curing Saline Soil With Coal Solid Waste, Dong Chenxi, Wang Nianqin, Li Jiangshan, Chen Xin, Yan Xusheng, Ma Wei

Coal Geology & Exploration

Under the research background of resource utilization of solid wastes in the arid and semiarid regions, a new curing material was developed with the coal wastes (such as the coal gangue (CG) and coal metakaolin (CMK)), the carbide slag (CS) that is a waste material readily available in the arid region, and the ordinary Portland cement (OPC). Besides, its mechanical properties and microscopic change mechanism in curing of saline soil in the arid and semi-arid regions were discussed. Based on the laboratory experiment, the unconfined compressive strength (UCS) characteristics of curing saline soil in different ages were studied by replacing …

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Wavefield Separation Of P- And S-Waves Based On Modified Pseudo-Helmholtz Decomposition Operator In Transverse Isotropic Media, Liu Zhaoshun, Du Qizhen, Lyu Wenhao, Zhou Shihao, Fu Liyun Mar 2023

Wavefield Separation Of P- And S-Waves Based On Modified Pseudo-Helmholtz Decomposition Operator In Transverse Isotropic Media, Liu Zhaoshun, Du Qizhen, Lyu Wenhao, Zhou Shihao, Fu Liyun

Coal Geology & Exploration

The separation of P- and S-wave fields is a significant step in elastic reverse-time migration (ERTM), which can effectively eliminate the waveform crosstalk and image artifacts, thus improving the precision of imaging. In anisotropic media, nonstationary spatial filters or low-rank approximation methods are commonly used to separate the wavefields. However, the application of multiple Fourier transforms results in the high computation costs of the above wavefield separation methods. Based on the idea of constructing the isotropic decoupling equations of P- and S- waves with the Helmholtz operator, a modified pseudo-Helmholtz decomposition operator was proposed to eliminate the amplitude distortion. Then, …

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Forward Modeling Of Radio-Magnetotelluric Method Based On Julia Acceleration And Study On Effect Of Displacement Current, Mei Zhuxu, Yuan Yuan, Zhou Feng, Zhou Cong, Zhang Lincheng Mar 2023

Forward Modeling Of Radio-Magnetotelluric Method Based On Julia Acceleration And Study On Effect Of Displacement Current, Mei Zhuxu, Yuan Yuan, Zhou Feng, Zhou Cong, Zhang Lincheng

Coal Geology & Exploration

Radio-magnetotelluric method (RMT) is one of the important tools for shallow surface electromagnetic exploration. Since the exploration frequency band is 10‒300 kHz, the propagation of electromagnetic fields is greatly affected by the dielectric permittivity of the earth. The electromagnetic response calculated with traditional quasi-static conditions severely restricts the accuracy of RMT forward modeling and further affects the resolution of the inversion imaging. In response to this problem, a numerical simulation method of full-current RMT electromagnetic response based on Julia parallel acceleration was proposed. Then, the calculation of each frequency point was sent through the distributed computing in Julia to different …

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One Surface Borehole With Multi-Usage Gas Drainage Key Technology For Abandoned Well And Its Application, Fu Junhui Mar 2023

One Surface Borehole With Multi-Usage Gas Drainage Key Technology For Abandoned Well And Its Application, Fu Junhui

Coal Geology & Exploration

Gas drainage from mining area could be realized through the reconstruction and reuse of abandoned surface gas wells in the coal mine area , which has multiple economic and environmental benefits such as ensuring the safe production of mining, the effective utilization of gas resources, and reducing the pressure of gas escape on the environment. In view of this purpose, the idea of “one surface borehole with multi-usage” gas drainage technology for abandoned wells was proposed based on the characteristics of the surface borehole and the abandoned wells in the mining area. By analyzing the conditions of the mining technology, …

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New Understanding Of Coal Seam Distribution Law: Coal Accumulation Model Controlled By Paleoclimate Evolution, Hou Haihai, Chen Hongzhen, Shao Longyi, Pan Zizi Mar 2023

New Understanding Of Coal Seam Distribution Law: Coal Accumulation Model Controlled By Paleoclimate Evolution, Hou Haihai, Chen Hongzhen, Shao Longyi, Pan Zizi

Coal Geology & Exploration

It is very important for coal and coal-measure gas exploration to correctly understand the distribution law of coal seam and its main control factors in different coal accumulation models. Based on the review of the theories and models of paleogeographic coal control, coal accumulation in sequence stratigraphy, allochthonous coal accumulation and multiple coal accumulation theoretical system, a new coal accumulation model under the control of climatic revolution was proposed through the analyses of the Jurassic coal-bearing strata in the southern margin of Junggar Basin. The paleotemperature and paleohumidity during Badaowan Formation(coal accumulation period), Sangonghe Formation, Xishanyao Formation (coal accumulation period) …

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A New Model Of Surface And Underground Integrated Three-Dimensional Prevention And Control Of Rock Burst In Binchang Mining Area, Wu Xueming, Ma Xiaohui, Lyu Dazhao, Zheng Kaige, Wang Dongjie Mar 2023

A New Model Of Surface And Underground Integrated Three-Dimensional Prevention And Control Of Rock Burst In Binchang Mining Area, Wu Xueming, Ma Xiaohui, Lyu Dazhao, Zheng Kaige, Wang Dongjie

Coal Geology & Exploration

With the continuous increase of coal mining intensity, the mine gradually moves to the deep, bringing about increasingly serious rock burst hazard. The deep rock burst mines often have one or more layers of hard and thick rock strata. These hard roofs are thick and strong integrity. When they suddenly rupture, they can release a large amount of elastic energies, which can easily to cause rock burst accidents and seriously restrict the safety of mine production. Herein, appropriate treatment measures were put forward for the special situation of deep burial depth of coal seam and general presence of many kinds …

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Co2-Ecbm Simulation Study Considering Klinkenberg Factor State, Sa Zhanyou, Wu Jingbo, Yang Yongliang, Zhang Xin, Lu Shouqing, Liu Jie, Wang Hao Mar 2023

Co2-Ecbm Simulation Study Considering Klinkenberg Factor State, Sa Zhanyou, Wu Jingbo, Yang Yongliang, Zhang Xin, Lu Shouqing, Liu Jie, Wang Hao

Coal Geology & Exploration

In order to explore the role of Klinkenberg effect and Klinkenberg factor in different states in the process of CO2-Enhanced Coal Bed Methane (CO2-ECBM), the effects of Klinkenberg factor of zero, fixed Klinkenberg factor and dynamic Klinkenberg factor on CO2-ECBM were simulated and analyzed by COMSOL finite element software. The dynamic changes of CH4 and CO2 pressure with this factor were studied, and the CH4 gas production was compared with the engineering practice. The results show that the effective permeability of CH4 and CO2 increases slowly at first, then …

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Study On The Time Law Of Water-Rock Interaction In Coal Mine Groundwater Reservoir, Zhang Kai, Liu Shuyu, Cao Zhiguo, Gao Ju, Chen Xiangyu, Yan Jiayu Mar 2023

Study On The Time Law Of Water-Rock Interaction In Coal Mine Groundwater Reservoir, Zhang Kai, Liu Shuyu, Cao Zhiguo, Gao Ju, Chen Xiangyu, Yan Jiayu

Coal Geology & Exploration

The retention time of mine water in the coal mine underground reservoir will affect the ion concentration of effluent, but the time law of water-rock interaction during operation of the reservoir is still unclear. In order to reveal the occurrence type and intensity of water-rock interaction in different operation stages of coal mine underground reservoir, two groups of static simulation tests of water-rock interaction were designed based on the test and analysis on-site samples, namely the fine sandstone-mine water (S-K) and mudstone-mine water (N-K). The types of water-rock interaction were analyzed from two aspects: the change of rock composition and …

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Deformation Prediction Of Open-Pit Mine Slope Based On Abc-Grnn Combined Model, Ning Yongxiang, Cui Ximin, Cui Jianguo Mar 2023

Deformation Prediction Of Open-Pit Mine Slope Based On Abc-Grnn Combined Model, Ning Yongxiang, Cui Ximin, Cui Jianguo

Coal Geology & Exploration

Accurate prediction of slope deformation in open-pit mine is an important guarantee for effective disaster early warning of slope. The traditional slope deformation prediction method is unable to characterize and comprehensively analyze the effect of various factors on slope deformation. In view of this, the combined prediction model (ABC-GRNN) of an artificial bee colony algorithm (ABC) and the optimized generalized regression neural network (GRNN) was proposed for slope deformation in open-pit mine. In this prediction model, the following 5 factors affecting the slope deformation of open-pit mine are considered comprehensively: mining disturbance, rainfall, rainfall duration, temperature and humidity. Herein, the …

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Influence Of Coal Mining Disturbance On Soil Physiochemical Properties And The Response Mechanism Of Microbial Community, Song Ziheng, Liu Gang, Sun Liping, Wang Fei, Guo Junting Mar 2023

Influence Of Coal Mining Disturbance On Soil Physiochemical Properties And The Response Mechanism Of Microbial Community, Song Ziheng, Liu Gang, Sun Liping, Wang Fei, Guo Junting

Coal Geology & Exploration

The ecological problems caused by coal mining in Yellow River Basin are becoming more serious. In order to explore the influence characteristics of coal mining disturbance on soil factors and microbial community in Yellow River Basin, and to clarify the differences in soil microbial communities between the marginal coal mining subsidence area and the unmined area, equidistant sampling was performed from the marginal subsidence area, the start point (HD), to the unmined area in the study area of Shangwan Mine in Inner Mongolia. Specifically, sampling points at 150 (D1), 300 (D2), 450 (D3), 600 (D4) and 750 m (D5) from …

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Feasibility Study Of Nature Source In-Seam Exploration, Hu Ze’An, Cao Lingkai, Liu Qinjie, Ji Guangzhong, Xi Chaoqiang, Wu Rongxin Mar 2023

Feasibility Study Of Nature Source In-Seam Exploration, Hu Ze’An, Cao Lingkai, Liu Qinjie, Ji Guangzhong, Xi Chaoqiang, Wu Rongxin

Coal Geology & Exploration

The conventional explosive seismic sources are very tightly controlled in high-gas mine, and a novel non-explosive channel wave method is urgently needed as an alternative. Therefore through the theoretical analysis and numerical simulation experiments, we demostrated that the coal seam satisfied the geophysical conditions to develop the nature source in-seam wave. The time-domain numerical simulation experiment of the passive source channel wave was successfully realized by constructing the nature source in-seam wave model with three stochastic terms, including the stochastic spatial position, stochastic initial excitation time and stochastic amplitude of seismic source. We performed frequency dispersion spectrum calculation on the …

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Inversion Of Self-Potential Data Based On Improved Sparrow Search Algorithm, Lang Jianxiang, Tang Hongzhi, Ai Hanbing Mar 2023

Inversion Of Self-Potential Data Based On Improved Sparrow Search Algorithm, Lang Jianxiang, Tang Hongzhi, Ai Hanbing

Coal Geology & Exploration

Self-potential (SP) method is a natural source geophysical prospecting technology with low cost and simple operation for field observation. Generally, the inversion of SP data has the characteristics of ill-posedness and non-linearity. The conventional inversion algorithms are classified into the types of local optimization and global search. However, it is hard for the gradient-based local optimization algorithm to obtain the global optimal solution, and the inversion results are dependent on the construction of initial model. The traditional global search algorithm has the disadvantages of low convergence rate, insufficient ability of escaping local minima and instability. Thus, a new global optimization …

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Development Of Storage Equipment Of Continuous Cable Pipe For Borehole Rescue, Gao Ke, Niu Xin, Zhao Yan, Qin Xiaolin, Lyu Xiaoshu, Xie Xiaobo Mar 2023

Development Of Storage Equipment Of Continuous Cable Pipe For Borehole Rescue, Gao Ke, Niu Xin, Zhao Yan, Qin Xiaolin, Lyu Xiaoshu, Xie Xiaobo

Coal Geology & Exploration

The double-bit bionic self-balancing continuous drilling technology has the advantages including requiring no drilling rig, high drilling speed and slight disturbance to the borehole wall. It is one of the key potential technologies for constructing the security and rescue passages against mine disasters. In this technology, as there are passages for power supply, signal, chip removal and other aspects that are built in the continuous cable pipe, it is required that there shall be no such interference, extrusion or arrangement of dynamic/static conductive electric conduction link as in using the existing drum hoist to store continuous pipes during storage. Therefore, …

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A Fault Diagnosis Method Of Rescue Lifting Vehicle Based On Spectral Clustering, Li Lijing, Chang Dashuai, Li Lei, Chai Junfei Mar 2023

A Fault Diagnosis Method Of Rescue Lifting Vehicle Based On Spectral Clustering, Li Lijing, Chang Dashuai, Li Lei, Chai Junfei

Coal Geology & Exploration

In allusion to the characteristics of complex structure of rescue lifting vehicle, the poor independence of working condition and fault data, and the difficulty in fault diagnosis, we proposed a fault diagnosis algorithm of rescue lifting vehicle with the semi-supervised support vector machine in this paper. In the algorithm, the information on hidden features of the original fault data was mined with the idea of spectral clustering, to effectively distinguish the independent structural features of the fault information in the component system with different degrees of coupling. Firstly, a fault map was established based on the original input data. Then, …

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The Ontological Grounds Of Reason: Psychologism, Logicism, And Hermeneutic Phenomenology, Stanford L. Howdyshell Mar 2023

The Ontological Grounds Of Reason: Psychologism, Logicism, And Hermeneutic Phenomenology, Stanford L. Howdyshell

USF Tampa Graduate Theses and Dissertations

The following dissertation explains the psychologism debate as it played out in the 19thand early 20th Centuries and then shows how Martin Heidegger radicalized the debate by undermining its key themes and assumptions. First, I explain each side of the psychologism debate, starting with the psychologicists. I explore the philosophies of Jakob Friedrich Fries and John Stuart Mill in order to encapsulate the full spectrum of psychologism in the 19th Century, from Neo-Kantian to British Empiricist. The investigation will show a set of common themes within psychologism, such as the grounding of logic in the constitution of the human subject, …

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Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang Mar 2023

Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang

Journal of Electrochemistry

All solid-state lithium-sulfur batteries (ASSLSBs) are considered to be one of the most promising next-generation energy storage systems, due to the promises of high energy density and safety. Although the use of solid-state electrolytes could effectively suppress the "shuttle effect" and self-discharge of the conventional liquid lithium-sulfur (Li-S) battery, the commercialization of ASSLSBs has been seriously hampered by the electrolyte degradation, electrode/electrolyte interfacial deterioration, electrochemo-mechanical failure, lithium dendrite growth and electrode pulverization, etc. This paper provides a comprehensive review of recent research progresses on the solid-state electrolytes, sulfur-containing composite cathodes, lithium metal and lithium alloy anodes, and electrode/electrolyte interfaces in …

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Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang Mar 2023

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang

Journal of Electrochemistry

Practical applications of lithium-sulfur (Li-S) batteries are hindered mainly by the low sulfur utilization and severe capacity fading derived from the polysulfide shuttling. Catalysis is an effective remedy to those problems by promoting the conversion of polysulfides to reduce their accumulation in the electrolyte, which needs the catalyst to have efficient adsorption ability to soluble polysulfides and high activity for their conversion. In this work, we have proposed a bimetallic compound of NiCo2S4 anchored onto sulfur-doped graphene (NCS@SG) to fabricate a catalytic interlayer for Li-S batteries. Compared to CoS, the NiCo2S4 demonstrated much higher …

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