Digital Commons Network^™

Investigating Chlorate In Water As A Cause Of Chlorate In Milk, Lorna Twomey, D. Gleeson, A. Furey

Physical Sciences Publications

The findings of this laboratory based experiment suggest that waters with increasing total chlorine levels will have increased chlorate levels and should that water come into contact with milk it has the potential to cause chlorate contamination of said milk. This study provides the information needed to design targeted field based experiments that are required to establish the trends and behaviours of chlorate in water when used as part of the cleaning process on dairy farms and its impact on milk residues and is requisite for the betterment of the dairy industry in terms of its understanding of contamination of …

The Resilience Of A School Community During A Pandemic: A Phenomenological Study Of The Trials And Tribulations Of Bishop John Paul Academy, Christopher Aquino

LMU Theses and Dissertations

The COVID-19 pandemic dramatically impacted the world of education. Schools were forced to rapidly adapt to new modes of teaching, learning, and assessment to continue providing education to students safely and effectively. This study examines the experiences of schools during the COVID-19 pandemic, focusing on their challenges, responses, and impact on students, teachers, and staff and how their promotive and protective factors contributed to their resilience.

The qualitative study includes narratives from school administrators, teachers, and students. The results showed that schools had faced numerous challenges during the pandemic, including shifting to remote learning, maintaining student engagement and motivation, addressing …

Implementation Of The Downlink Communication System Of The Lmu Cubesat, Mohammed Alrabeeah

LMU Theses and Dissertations

In this thesis, we present the design and implementation of a CubeSat receiver system using the Universal Software Radio Peripheral (USRP) and GNU Radio. The goal of this project is to develop a low-cost and flexible ground station capable of receiving telemetry and payload data from CubeSats in real time. The CubeSat receiver operates in the UHF frequency range with a center frequency of 435 MHz and uses a software-defined radio (SDR) approach to provide wideband signal processing and demodulation capabilities. The satellite transceiver transmits an Ax.25 Transciever packet every 1 second using the Pumpkin CubeSat kit programmed in MPLab. …

Discovering Dune: Essays On Frank Herbert’S Epic Saga., Edited By Dominic J. Nardi And N. Trevor Brierly, G. Connor Salter

Mythlore: A Journal of J.R.R. Tolkien, C.S. Lewis, Charles Williams, and Mythopoeic Literature

G. Connor Salter reviews Discovering Dune: Essays on Frank Herbert’s Epic Saga, edited by Dominic J. Nardi and N. Trevor Brierly, considering its new contributions to studies of Frank Herbert's work. Essays included fit into four categories (Politics and Power, History and Religion, Biology and Ecology, and Philosophy, Choice and Ethics) and range from Herbert's use of ecology in Dune to how game theory may help explain certain characters' apparent ability to see the future. Discovering Dune also includes an appendix which contains the only up-to-date bibliography of Herbert's work (primary and secondary sources).

Surface And Alloy Engineering Of Halide Perovskite (Cspbx3) Nanocrystals For Efficient And Stable Optoelectronics, Sakiru L. Abiodun

Theses and Dissertations

Organic and inorganic halide perovskite quantum dots (QDs) (in form of ABX₃, where A is organic cation e.g CH₃NH₃⁺ or inorganic cation e.g Cs⁺) have emerged as an intriguing alternative to the widely studied chalcogenide and pnictide QDs. Their excellent optoelectronic properties such as large absorption coefficient, high carrier mobility, wide color gamut, long electron-hole diffusion lengths, and tunable bandgap energy are largely responsible for their wide acceptability in various electronic devices. However, despite this enthusiasm, the problem of purification, long-term stability, lead toxicity and inadequate knowledge of their surface chemistry still …

Development And The Use Of A New Kinetically Limited Linear Driving Force Model For Diffusion-Based Adsorptive Separations, Sulaimon Adedayo Adegunju

Theses and Dissertations

A new kinetically limited linear driving force (KLLDF) model, in terms of a modified extended Langmuir (EL) isotherm, was developed. This KLLDF model augments the equilibrium driving force in the linear driving force (LDF) model in such a way that the equilibrium loading of each component in the LDF model depends on the actual, kinetically limited, loading of the other components in a gas mixture, not their partial pressures. In contrast, the LDF model assumes the presence of a slower diffusing adsorbate in a gas mixture affects the equilibrium of a faster diffusing adsorbate in a pore structure via its …

Design Of A Tvsa Cycle For Co2 Removal From Spacecraft Cabins Using A Structured Adsorbent, Pravin Bosco Charles Antony Amalraj

Theses and Dissertations

Pressure Swing Adsorption (PSA) and Temperature Swing Adsorption (TSA) are some of the most used cyclic adsorption technologies that is used for separating gas components from its mixture. Carbon Dioxide Removal Assembly (CDRA) in the International Space Station (ISS) facilitates the continuous removal of CO2 by the cyclic adsorption process. The use of structured adsorbents has drawn attention due its several advantages over traditional beaded adsorbents. This work evaluates the role of different design variables on the effective thermal conductivity of a structured adsorbent bed for its possible application in a temperature swing adsorption (TVSA) process for space applications. The …

Cashing The Check Of Democracy The American Revolution And Citizenship In The Black Freedom Struggle 1960-1970, Zachary Earle Clary

Theses and Dissertations

Separated into three interconnected parts, this thesis first proposes a reconfiguration of the vocabulary that historians use when classifying the memory and legacy of the American Revolution in the twentieth century. From there, I offer a comparative analysis of the Black Freedom Struggle’s relationship to the Declaration of Independence and other components of the American Revolution to demonstrate that the Revolution, while useful as a rhetorical tool or a conceptual model, functioned primarily as a counterpoint to the twentieth-century quest for Black citizenship. In other words, the American Revolution was a formidable example of radical protest in the American past, …

Detecting Spatially Varying Coefficient Effects With Conditional Autoregressive Models: A Simulation Study Using Social Determinants Of Health Screening Data, Reid J. Demass

Theses and Dissertations

Generalized linear models which include spatially varying coefficient terms allow researchers to determine if the association between predictor and outcome variables vary across geographic space. Such models are particularly applicable to research with public health data where interventions and limited health care resources must be allocated carefully. The integrated nested Laplace approximation (INLA) methodology available in the R INLA package is a popular tool to estimate spatially varying coefficients. To assess the performance of the estimation procedure, patient emergency department (ED) visits were simulated from data sourced from a pilot study at Prisma Health. The INLA technique was used to …

On The Algebraic And Geometric Multiplicity Of Zero As A Hypergraph Eigenvalue, Grant Ian Fickes

Theses and Dissertations

We consider the algebraic and geometric multiplicity of hypergraph eigenvalues, paying particular attention to nullities of hypertrees. Conjecture surrounds the relationship between these two multiplicites, but little work appears in the literature on this topic. Predominantly, we are interested in identifying the geometric structure of the nullvariety of certain hypergraph classes by listing the irreducible components and their accompanying dimensions. When applicable, we use this description to verify a conjecture relating the algebraic and geometric nullity. Furthermore, we refine these geometric structure tools to graph theoretic trees, defining a matroid on trees and relating skew zero forcing to the existence …

Bayesian Dependence Structure Analysis For Ordinal Data, Yang He

Theses and Dissertations

This dissertation explores different methods to study the dependence structure among many ordinal variables under the Bayesian framework.

Chapter 1 introduces ordinal data analysis methods, and the related literature works are briefly reviewed. An outline of the dissertation is put forward.

In Chapter 2, Gaussian copula graphical models with different priors of graphical Lasso, adaptive graphical Lasso, and spike-and-slab Lasso on the precision matrix are assessed and compared. The proposed models are well illustrated via simulations and a real ordinal survey data analysis.

In Chapter 3, adaptive spike-and-slab Lasso prior is proposed as an extension of Chapter 2. The developed …

Engineering Of Bio-Based And Synthetic Polymers: Synthesis And Application In Superabsorbent Materials And Antibacterial Agents, Jihyeon Hwang

Theses and Dissertations

A polymer consists of a large number of monomer units, which can be obtained naturally or via a chemical process called polymerization. Polymers are important materials that are used in our daily life. Life would not be possible without these polymers, either from plant biomass or petroleum-derived synthetic polymers. The substitution of petroleum-derived to biomass-based polymers has been highlighted to mitigate adverse environmental impact. However, the use of bio-based polymers is still a significant challenge for more demanding applications. In this dissertation work, the engineering of both bio-based and synthetic polymers and their properties are investigated.

In Chapter 1, the …

Structural And Immunological Characterization Of Inhaled Allergens And Their Complexes With Antibodies, Kriti Khatri

Theses and Dissertations

Allergy is an outcome of an allergen-antibody reaction (1). Potent airborne allergens from dust mites and pets are major causative factors for allergic conditions among predisposed individuals. Group-2 allergen Der p 2 from Dermatophagoides pteronyssinus is a major allergen which causes allergic conditions in more than 80% of mite-allergic subjects (2). Similarly, airborne allergen Can f 1 from dog (Canis familiaris) is also a major risk allergen which affects 10-20% of the population worldwide (3). Considering the increasing prevalence of inhalant allergens in the environment, antigenic characterization is crucial for improving allergy diagnostics and management. This study focuses …

Vaccinia Virus And Measles Virus As Oncolytic Vaccines: The Modulation Of The Viral Infectivity Via Surface Conjugations, Monchupa Kingsak

Theses and Dissertations

Oncolytic virus (OV) therapy has been shown to be an effective targeted cancer therapy treatment in recent years, providing an avenue of treatment that poses no damage to surrounding healthy tissues. Not only do OVs cause direct oncolysis, but they also amplify both innate and adaptive immune responses generating long-term antitumor immunity. However, a key challenge facing oncolytic virotherapy is neutralizing antibodies in vaccinated patients, leading to the viral clearance after systemic administration and failure in the treatment. The encapsulation of OVs using biocompatible polymers is one of the promising methods to prevent the viral clearance from antiviral immune responses. …

The Kinetic Control Of Polymer Micelles; Chemical Functionality, Material Interactions, And Equilibration, Taylor Larison

Theses and Dissertations

Polymer micelles have found significant uses in areas such as, energy storage devices, catalysis, opto-electronics, drug-delivery, oil additives, and nanoreactors. In many of these applications the overall micelle size (aggregation number) and chemical functionalization determines performance. To progress towards more advanced materials synthesized from the facile bottom-up approach with polymeric micelles the implementation and study of thermodynamic handles were investigated. Here the kinetic control of micelles was studied across a range of applications; independent control over micelle functionality, the spatial orientation of multiple metal oxide nanoparticles in mesoporous materials via self-assembly, and the use of small-angle neutron scattering (SANS) to …

Coordination Environment And Thermodynamics Of Colloidal Quantum Dots In Polar Solvents, Nuwanthaka Prasad Jayaweera Millaniyage

Theses and Dissertations

Colloidal semiconductor quantum dots (QDs) have been extensively investigated due to their attractive properties such as size-tunable absorption and emission spectra, large molar extinction coefficients, and significant photostability. These properties make them promising candidates for optoelectronic, photocatalytic, and biomedical applications. Common synthetic procedures of QDs produce nanocrystals capped with long-chain fatty acid derivatives which are stabilized in high boiling point solvents. Especially for bioimaging applications, the exchange of these native hydrophobic ligands with hydrophilic ligands should be performed, while preserving the smaller hydrodynamic radius. The coordination environment and thermodynamic parameters of the ligand exchanges should be carefully investigated to engineer …

Biochemical, Structural, And Immunological Characterization Of Selected Panallergens, Andrea Leigh O'Malley

Theses and Dissertations

Allergies throughout the world are increasing in prevalence and severity. Although the direct causes of the development of allergies are not confirmed, study of proteins that cause reactions will lead to a deeper understanding of allergy. This work focuses on three panallergen families, profilins, parvalbumins, and arginine kinases, to further elucidate the background of allergy from the point of view of the allergens themselves. In Chapter 1, we evaluate pollen, fruit, and mite profilins in the context of allergy, showing the relevance of conserved cysteine residues in stability and oligomerization as well as the first data on cross-reactivity between plant …

Reactive End Capped Polybenzimidazole Oligomers For High Temperature Thermosets And Improved Membranes For Electrochemical Devices, Caroline Marie Rohlfing

Theses and Dissertations

Polybenzimidazoles (PBI) are heterocyclic polymers that possess high thermal and oxidative stability. The inherent strength and chemical and thermal stability of PBI make it ideal for use in extreme environments; however, the current processing of PBI molded parts makes the process practically and economically unfavorable. These intrinsic properties make PBIs of particular interest for many industrial applications, varying from fabrics to membrane materials to molded parts. Processing these molded parts is extremely difficult, as the high glass transition temperature and extremely high melting point (>500°C) of PBI result in poor flow properties of PBI resins even at high temperatures. …

A Study Of Single Molecule Detection With Graphene Hall Bars, Kenneth Stephen Stephenson

Theses and Dissertations

In 2007, detection of individual molecules with a solid-state gas sensor was reported for first time by Schedin et al. where they used micromechanically-cleaved graphene for their sensing material, which exhibits isotropic and homogeneous conduction [1]. However, despite the novelty and popularity of their work, it has never been repeated. Further, we found their associated calculations to be self-inconsistent by a factor of 103 . So, hoping to account for and resolve this discrepancy, we outline the plan we had to reproduce their experiment. We also justify any substantial modifications, particularly our choice to use epitaxial graphene instead. Then, we …

The Effects Of Problem-Based Learning On Mathematics Motivation In A Flipped Classroom Instructional Environment, Joshua David Harrison

Theses and Dissertations

In response to decreasing motivation in high school math classrooms, teachers are transforming classrooms with various instructional techniques. Traditional math instruction relies on direct instruction and memorization of content, processes, and skills. Teachers are transitioning to more constructivist student-led approaches. Utilizing multiple instructional designs provides teachers more opportunities to access the major components of the ARCS Model: attention, relevance, confidence, and satisfaction.

Therefore, the purpose of this action research was examining problem-based learning in a flipped classroom instructional environment and measuring its effect on students’ motivation and achievement in Algebra 2. The study addressed the following research questions: 1) What …

Expanding Tailorable Nanomaterial Synthesis With Persistent Micelle Templates, Eric R. Williams

Theses and Dissertations

The control of block polymer micelle dimensions while in solution is critical for a range of emerging applications in diverse fields from drug delivery and nanoreactors to use as sacrificial templates for porous nanomaterials. When under kinetic control, micelles will maintain a constant average size and thus aggregation number (N_agg) through the suppression of chain exchange mechanisms. Such kinetic control effectively enables the decoupling of micelle dimensions from solution conditions. In other words, kinetically trapped micelles can resist reorganizations brough about by e.g., the addition of metal nanoparticles. However, such micelles are traditionally governed by a fickle �� …

Impact Of Virtual Models On Students’ Multilevel Understanding Of An Organic Reaction, Eli Martin

Theses and Dissertations

As the number of STEM opportunities and the need for a scientifically literate society increases, educators in STEM fields require tools that help support these needs. Chemistry is one STEM content area that would benefit from exploring educational technology that supports conceptual understanding. An action research study was conducted to understand how students engage with the content and virtual representation to develop their understanding of a chemical reaction. This convergent mixed methods study looked at the effect of dynamic virtual molecular representation on students' ability to understand a reaction mechanism at the symbolic and subparticulate level by measuring content knowledge …

Digital Literacy Integrated Into Academic Content Through The Collaboration Of A Librarian And A Core Content Teacher, Jeri Leann Jeffcoat

Theses and Dissertations

The purpose of this mixed methods action research study was to investigate the impact of collaborative teaching involving a school librarian and a social studies teacher on sixth-grade students’ unit projects, classroom engagement, and digital literacy skills. This study's innovation was twofold: academic content was infused with digital literacy skills instruction, and the librarian/researcher co-taught the unit with a regular academic content teacher. The study was designed to answer three research questions involving how instruction that integrates digital literacy and social studies content taught collaboratively by a librarian and social studies teacher influences sixth-grade social studies students’ performance on summative …

Electronic Portfolios In A High School Community Of Practice: Action Research Exploring Writing Experiences In An Advanced Placement Writing Course, Archibald Franklin Harrison Iv

Theses and Dissertations

The underlying assumption of this study is that writing as a process has profound implications for success and fulfillment both in and beyond the classroom. A second assumption is that electronic portfolios provide students a space to write, revise, reflect, share, and explore themselves as writers. Students who engage with and embrace the writing process to the point that they self-identify as writers may be more likely to not only succeed at academic writing tasks but to integrate writing into their future lives (Lengelle and Meijers, 2014). For writing to play a prolonged role in this level of academic, professional …

Timing Deterministic Structural Model Updating Considering Impact And Fatigue Damage, Jason Michael Smith Jr.

Theses and Dissertations

Naval ship structures such as support trusses, hull sections, driving machinery, and load-bearing beams are subjected to various damage states that develop on short-term (i.e. impact) and long-term (i.e. fatigue) timescales. Naval structures fitted with a structural health monitoring system with damage detection abilities will enable appropriate real-time adjustments to the ships’ posture and control policies and thus have increased survivability and lethality. A digital twin can provide real-time condition assessment of naval structures when conjoined with a decision-making framework will increase naval ship survivability through informed response management. A fundamental challenge for the development of digital twins is reliable …

The Impact Of Opendyslexic Font On The Reading Comprehension Of Tier Ii And Tier Iii Reading Intervention Students, William David Whitmire

Theses and Dissertations

This mixed methods action research project measured the effect of OpenDyslexic font on the reading comprehension of MTSS Tier II and Tier III reading intervention students. A review of the literature revealed little research about OpenDyslexic font or its effect on reading comprehension. The study consisted of a 7-week period with 4^th grade Tier II and Tier III reading intervention students using OpenDyslexic font while reviewing previously taught comprehension strategies before end of the year testing. Results show positive growth for Tier II reading intervention students and results were inconclusive for Tier III students.

Extreme Covering Systems, Primes Plus Squarefrees, And Lattice Points Close To A Helix, Jack Robert Dalton

Theses and Dissertations

This dissertation considers three different topics.

In the first part, we prove that if the least modulus of a distinct covering system is 4, its largest modulus is at least 60; also, if the least modulus is 3, the least common multiple of the moduli is at least 120; finally, if the least modulus is 4, the least common multiple of the moduli is at least 360. The constants 60, 120, and 360 are best possible, they cannot be replaced by larger constants. We also show that there do not exist distinct covering systems with all of the moduli in …

Mathematics Teachers’ Attitudes And Intentions Towards Instructional Videos As Part Of A Flipped Learning Model, Jessica Lee Lambert

Theses and Dissertations

Teachers’ attitudes and intentions play an integral role in the integration of technology into their lesson designs for mathematics. All K-8 students at the research site are now one to one with a device, either a tablet or laptop, depending on their grade level. It is up to teachers to determine how and when to integrate technology into their instructional design for mathematics. The purpose of this action research was to evaluate and describe mathematics teachers’ attitudes and intentions for integrating instructional videos as part of a flipped learning instructional model. The following questions served to guide this cycle of …

The Impact Of The Flipped Classroom Model On Elementary Students’ Achievement And Motivation For Learning Geometry, Kimberly M. Smalls

Theses and Dissertations

National and state data show students in poverty perform lower on math standardized assessments than their peers who are not students in poverty. The purpose of this action research was to evaluate the implementation of the flipped classroom model on the achievement and motivation towards mathematics for fourth-grade students at an elementary school in the Southeast United States. Traditional teaching methods such as teacher-led modeling, the use of manipulatives, and small-group math instruction present barriers which have not led to overall academic improvement for these students. This study focused on three overarching questions: (1) Is there a difference in fourth-grade …

Genetic Testing For Autism: The Autistic Adult Perspective, Thomas Scott Dent

Theses and Dissertations

Many professional medical organizations recommend some level of genetic testing as standard of care for those diagnosed with autism spectrum disorder. However, genetic testing related to the diagnosis of autism is seen as controversial by many in the autistic community. While opinions about genetic testing have been well-documented from the perspective of the parents of autistic children, our understanding of the autistic adult perspective remains limited. We implemented a descriptive, web-based survey of autistic adults to assess their awareness of, attitudes towards, and interests in genetic testing for autism (n = 145). Our data demonstrated that half of our participants …