Digital Commons Network^™

Hyper-Local Weather Predictions With The Enhanced General Urban Area Microclimate Predictions Tool, Kevin A. Adkins, William Becker, Sricharan Ayyalasomayajula, Steven Lavenstein, Kleoniki Vlachou, David Miller, Marc Compere, Avinash Muthu Krishnan, Nickolas Macchiarella

Publications

This paper presents enhancements to, and the demonstration of, the General Urban area Microclimate Predictions tool (GUMP), which is designed to provide hyper-local weather predictions by combining machine-learning (ML) models and computational fluid dynamic (CFD) simulations. For the further development and demonstration of GUMP, the Embry–Riddle Aeronautical University (ERAU) campus was used as a test environment. Local weather sensors provided data to train ML models, and CFD models of urban- and suburban-like areas of ERAU’s campus were created and iterated through with a wide assortment of inlet wind speed and direction combinations. ML weather sensor predictions were combined with best-fit …

Intertextuality And Narrativization Of Multiple Perspectives: Covid-19 Pandemic In Popular Songs In Tanzania, Spemba E. Spemba

Journal of Humanities and Social Sciences

Close to the end of 2019, COVID-19, an infectious disease that still wreaks havoc, was discovered in Wuhan – China. The pandemic has become a major worldwide health problem to date. Its socioeconomic and cultural aftermaths have dominated the world’s public discourse. Media and literary artefacts reflect the ongoing debate, education, and communication regarding the pandemic. This paper examines how popular songs represent multiple (social-cultural, economic, and political) perspectives regarding the COVID-19 pandemic in Tanzania. The article focuses on secular and religious song lyrics to ascertain how they convey multiple perspectives regarding an understanding of COVID-19, and whether such views …

Monitoring Personal Exposure To Air Quality Gradients While Biking On An Elevated Urban Trail, Gavin D. Salas

DePaul Discoveries

Air pollution is a major global health concern, specifically as it relates to the human exposome. The EPA criteria pollutants, including particulate matter (PM), carbon monoxide (CO), carbon dioxide (CO₂), and NO_x can have severe impacts on respiratory and cardiovascular health, particularly in populations with chronic illnesses such as asthma, those facing economic hardships and individuals who frequently spend time outdoors, such as bicyclists and runners. To understand the impact of air pollution on human health, it is essential to assess personal exposure. This study aimed to investigate personal exposure to air pollution levels while biking along …

Depaul Discoveries Volume 12 Cover Art, Katherine Petralia

DePaul Discoveries

No abstract provided.

System-Characterized Artificial Intelligence Approaches For Cardiac Cellular Systems And Molecular Signature Analysis, Ziqian Wu

Dartmouth College Ph.D Dissertations

The dissertation presents a significant advancement in the field of cardiac cellular systems and molecular signature systems by employing machine learning and generative artificial intelligence techniques. These methodologies are systematically characterized and applied to address critical challenges in these domains. A novel computational model is developed, which combines machine learning tools and multi-physics models. The main objective of this model is to accurately predict complex cellular dynamics, taking into account the intricate interactions within the cardiac cellular system. Furthermore, a comprehensive framework based on generative adversarial networks (GANs) is proposed. This framework is designed to generate synthetic data that faithfully …

Preface To The Special Issue On Interfactial Regulation And Electrochemical Sensors, Jing-Hong Li, Yang Tian, Yuan-Hong Xu, Li-Min Zhang

Journal of Electrochemistry

No abstract provided.

An Aptamer-Based Microelectrode With Tunable Linear Range For Monitoring Of K+ In The Living Mouse Brain, Yuan-Dong Liu, Jia-Run Li, Li-Min Zhang, Yang Tian

Journal of Electrochemistry

Potassium ion (K⁺) is widely involved in several physiopathological processes, and its abnormal changes are closely related to the occurrence of brain diseases of cerebral ischemia. In vivo acquirement of K⁺ variation is significant to understand the roles of K⁺ playing in brain functions. A microelectrode based on single-stranded DNA aptamers was developed for highly selective detection of K⁺ in brain, in which the aptamer probes were designed to contain an aptamer part for specific recognition of K⁺, an alkynyl group used for stable confinement of aptamer probe on the gold surface, and …

Boronate Affinity-Assisted Electrochemically Controlled Atrp For Ultrasensitive Electrochemical Aptasensing Of Carcinoembryonic Antigen, Qiong Hu, Shi-Qi Li, Yi-Yi Liang, Wen-Xing Feng, Yi-Lin Luo, Xiao-Jing Cao, Li Niu

Journal of Electrochemistry

As an acidic glycoprotein, carcinoembryonic antigen (CEA) is of great value as a broad-spectrum tumor marker in the differential diagnosis and surveillance of malignant tumors. In this work, we report an electrochemical aptasensor for the ultrasensitive and highly selective detection of CEA, taking advantage of the dual amplification by the boronate affinity-assisted electrochemically controlled atom transfer radical polymerization (BA-eATRP). Specifically, the BA-eATRP-based electrochemical aptasensing of CEA involves the capture of target antigens by nucleic acid aptamers, the covalent crosslinking of ATRP initiators to CEA antigens via the selective interactions between the phenylboronic acid (PBA) group and the cis-diol group of …

A Performer's Guide To Two Song Collections: “Mementos Of Innocence” And “Three Yeats Songs” By Malaysian Composer Chee Yean Wong, Wu Ji Khoo

LSU Doctoral Dissertations

Despite the flourishing existence of Asian Art Music for over half a century, relatively little has been done to advance its recognition and prominence. Through this project, the author hopes to shed light on the beauty and richness of Asian Art Music and encourage its inclusion in the repertoire of American classical music. The purpose of this document is to supply a comprehensive performer’s guide to Malaysian composer, Chee Yean Wong’s song collections: “Mementos of Innocence” and “Three Yeats Songs.” The collections feature settings of English poems by Jean Blewett, Christina Rossetti, Edwin C. Ranck, Rabindranath Tagore, and William Butler …

Adaptive Quantum Information Processing In Non-Equilibrium Environments, Arshag Danageozian

LSU Doctoral Dissertations

Solid state and condensed matter systems, such as diamond impurities, superconductors, quantum dots, and ion traps, constitute important physical platforms for various applications in quantum information processing (QIP). However, it has consistently been shown that all such modern platforms suffer from non-equilibrium behavior on timescales that are relevant for many important QIP tasks. The causes range from intrinsic non-equilibrium dynamics (e.g. in diamond) to the presence of various impurities with their own internal dynamics (e.g. in superconductors and quantum dots) or variations in the control fields used to stabilize the quantum matter (e.g. in ion traps). When reserving degrees of …

Phase Transitions And Magnetocaloric Effects In Metastable Phases Of Intermetallic Compounds, Tej Bahadur Poudel Chhetri

LSU Doctoral Dissertations

The interplay between spin and lattice degrees of freedom in magnetic materials often results in interesting magnetoresponsive effects. The magnetocaloric effect is one such magnetothermal phenomenon that may be utilized in energy-efficient magnetic cooling systems. This effect becomes more prominent near a coupling of magnetic and structural transitions, i.e., magnetostructural transitions (MSTs). This dissertation investigates phase transitions (magnetic and structural) in metastable phases of MnNiGe- and MnCoGe-based compounds generated through high-pressure synthesis/annealing and thermal quenching techniques and assesses their magnetocaloric effects.

First, the effects of doping, hydrostatic pressure, and thermal quenching on phase transitions and related magnetocaloric effects in Mn …

Metal-Organic Frameworks For Electrochemical And Electrochemiluminescent Immunoassay, Xiao-Li Qin, Zi-Ying Zhan, Sara Jahanghiri, Kenneth Chu, Cong-Yang Zhang, Zhi-Feng Ding

Journal of Electrochemistry

Development of ultrasensitive, highly accurate and selective immunosensors is significant for the early diagnosis, screening, and monitoring of diseases. Electrochemical and electrochemiluminescent (ECL) immunoassays have both attracted great attention and become a current research hotspot due to their advantages such as good stability, high sensitivity and selectivity, wide linear range, and good controllability. Metal-organic frameworks (MOFs), as a new class of porous crystalline materials, have been widely applied in electrochemical and ECL immunosensors owing to their large specific surface area, good chemical stability, as well as adjustable pore size and nanoscale framework structures. Various MOF nanomaterials with different properties for …

Colorful "Stars" In The Dark, Chao Jing, Yi-Tao Long

Journal of Electrochemistry

Plasmonic nanoparticles such as Au and Ag with localized surface plasmon resonance (LSPR) property exhibit unique scattering and absorption features. The plasmonic scattering and absorption bands are mainly located at visible light region which can be easily applied in visual detections. By modulating the size, shape, and composition of gold and silver colloid solutions, plenty of colorimetric methods have been constructed for the detection of metal ions, biomolecules, and environmental contaminants, etc. For many years, the LSPR-based measurements are implemented in reagent tubes. Since 2000, the plasmon resonance scattering (PRS) light of metal nanoparticles captured by dark-field microscopy enables the …

Recent Advances In Electrochemical Impedance Spectroscopy-Based Pathogenic Bacteria Sensing, Tao Chen, Yuan-Hong Xu, Jing-Hong Li

Journal of Electrochemistry

Pathogenic bacteria have been throwing great threat on human health for thousands of years. Their real-time monitoring is in urgent need as it could effectively halt the spread of pathogenic bacteria and thus reducing the risk to human health. Up till now, diverse technologies such as electrochemistry, optics, piezoelectricity and calorimetry have been developed for bacteria sensing. Therein, electrochemical impedance spectroscopy (EIS)-based sensors show great potential in point-of-care bacterial analysis because of their low-cost, short read-out time, good reproducibility, and portable equipment construction. In this review, we will primarily summarize the typical applications of electrochemical impedance technology in bacteria sensing …

Scanning Photoelectrochemical Microscopic Study In Photoinduced Electron Transfer Of Supramolecular Sensitizers-Tio2 Thin Films Systems, Sheng-Ya Zhang, Min Yao, Ze Wang, Tian-Jiao Liu, Rong-Fang Zhan, Hui-Qin Ye, Yan-Jun Feng, Xiao-Quan Lu

Journal of Electrochemistry

Crafting charge transfer channels at titanium dioxide (TiO₂) based photoanodes remain a pressing bottleneck in solar-to-chemical conversion technology. Despite the tremendous attempts, TiO₂ as the promising photoanode material still suffers from sluggish charge transport kinetics. Herein, we propose an assembly strategy that involves the axial coordination grafting metalloporphyrin-based photosensitizer molecules (MP) onto the surface-modified TiO₂ nanorods (NRs) photoanode, forming the composite MP/TiO₂ NRs photoelectrode. As expected, the resulted unique MP_B/TiO₂ NRs photoelectrode displays significantly improved photocurrent density as compared to TiO₂ NRs alone and MP_A/TiO₂ NRs photoelectrode. Scanning …

Schur Analysis And Discrete Analytic Functions: Rational Functions And Co-Isometric Realizations, Daniel Alpay, Dan Volok

Mathematics, Physics, and Computer Science Faculty Articles and Research

We define and study rational discrete analytic functions and prove the existence of a coisometric realization for discrete analytic Schur multipliers.

Unraveling The Neural Basis Of Emotions: Advancing Understanding With Ecologically Valid Paradigms And High-Resolution Intracranial Eeg, Tiankang Xie

Dartmouth College Ph.D Dissertations

Background

Emotion arises from integrating information about the external world with memories of past experiences, current homeostatic states, and future goals. They play a vital role in regulating our thoughts, feelings and behaviors, significantly impacting our mental health. Thus, it is important to understand the neurobiological mechanisms that give rise to emotions. While there has been considerable work investigating the neural basis of emotions, progress has been hampered by several methodological limitations. For example, prior work has relied on relatively simple and isolated stimuli, which often fail to effectively capture the dynamic and multifaceted nature of emotional experiences in real-life …

Optical Response Of 3d Model Topological Nodal-Line Semimetal, Sita Kandel, Godfrey Gumbs, Oleg L. Berman

Publications and Research

Wepresent a semi-analytical expression for both longitudinal and transverse optical conductivities of a model TNLSM employing the Kubo formula with emphasis on the optical spectral weight redistribution, deduced from appropriate Green’s func tions. In this semimetal, the conduction and valence bands cross each other along a one- dimensional curve protected by certain symmetry group in the 3D Brillouin zone. Although the crossing cannot be removed by any perturbations, it can be adjusted by continuous tuning of the Hamiltonian with a parameter α. When α>0, the two bands cross each other near the Γ point in the (kx,ky) plane of …

An Analysis Of Lichen Presence On Quercus And Non-Quercus In Chicagoland Area, Shelby Johnson

DePaul Discoveries

Both anthropogenic change and the spread of invasive species have led to changes in urban and forest tree diversity. Oak rust, acute oak decline, and emerald ash borer have all had a detrimental effect on tree species in the Chicagoland area. Quercus species are well known habitats for lichen species including Physcia millegrana, Physcia stellaris, Punctelia rudecta, Flavoparmelia caperata, Xanthomendosa, and Candeleria concolor. Due to the decrease in the traditional Quercus habitats for lichen and the increase in nonnative and nontraditional tree species being introduced, particularly in cities, this study aimed to compare the number and diversity of …

Instrument Building For Detection Of Triplet Signal From Quinolinone Molecules, Brooke Weitzel

DePaul Discoveries

Conjugated organic molecules such as the 2-quinolinone family can be used as energy-donor molecules in photocatalysis because of their light absorbing and energy transmitting qualities. Good donor molecules have triplet excited states that are useful for photocatalysis due to their long lifetimes. The goal of this research was to build a near-infrared emission spectroscopy instrument to observe a triplet signal in a set of five previously synthesized 2-quinolinone molecules. A near-infrared absorbance instrument was built successfully with accurate measurements; however, there was no detection of the desired triplet emission signal.

Modeling Exciton Migration In Two-Dimensional Space, Christian D. Etnyre

DePaul Discoveries

Computational analysis through density matrix quantum mechanics was performed to model exciton migration in two-dimensional space for a zinc-substituted tetraazaphthalocyanine. The model produced resembles a two-dimensional sheet of molecules. Energy transport mechanisms, controlled by point dipole couplings, were evaluated while altering the size of the crystal lattice. It was determined that energy transport was much more significant with a decreasing size of the crystal lattice. Likewise, the result of increasing the size of the crystal lattice had the effect of dampening the rate of energy transport. It was of interest to determine, with varying crystal lattice dimensions, the time that …

Calculating And Comparing Bioaccessible Lead Concentrations In Soils From The Garfield Ridge, West Elsdon, And Lakeview Community Areas Using A Pbet And A Mehlich-3 Digestion Method, Emma Sznewajs

DePaul Discoveries

Lead exposure through soil poses potential health risks to those in areas with higher soil-Pb levels, specifically urban areas. The soil-lead concentrations recommended by the EPA are based on measurement of total lead concentration, yet only a percentage of the total lead can actually be absorbed into the body. The percentage of lead in soil that can be absorbed into the blood through ingestion is reffered to as bioaccessible lead and can be a more accurate way of measuring potential dangers of lead in soils. This study measured the amount of bioaccessible lead in the community areas of West Elsdon, …

Particulate Matter Emissions From Prescribed Burns In The Chicagoland Area, Katherine Petralia

DePaul Discoveries

Prescribed burns are a land management tool currently used to aid in fire mitigation and promotion of plant growth of desired species and reduction of undesired species, which are often invasive species. Currently there is public stigma surrounding prescribed burns which limits their use in certain parts of the US. There are also particular challenges of conducting prescribed burns in urban and suburban areas. A better understanding of prescribed burns and their impact on atmospheric chemistry and air quality can allow for better communication with the public about their positive impacts and also acknowledge and quantify any potential drawbacks. This …

The Influence Of Vehicular Traffic And Land Use Typology On The Spatial Patterns And Concentrations Of Soil Lead (Pb) In The Uptown Community Area Of Chicago, Andreas 'Dre' Harris

DePaul Discoveries

Lead (Pb) is a harmful element whose presence threatens the well-being of living organisms and their environments. There are higher concentrations and an increased risk of Pb exposure in areas that provide fewer natural pathways for Pb to accumulate into. In urban areas, the soil is one of the most common and available environmental sinks for Pb accumulation. This study examines the total soil Pb concentrations in relation to land-use types and average daily traffic volumes (cars/day) in each census tract in the Uptown Community Area of Chicago. This study provides insight into how land use and traffic volume may …

Understanding The Effect Of Ranching On Quercus Brandegeei Recruitment In The Sierra La Laguna Biosphere Reserve, Xavier O. Espinoza

DePaul Discoveries

In this study, we attempt to deepen our understanding of the mechanisms responsible for Quercus brandegeei’s observed lack of regeneration by identifying which animal species (wild and domesticated) most frequently were observed eating, passing by, or searching for seeds and seedlings. We established 10 paired plots (10 enclosed and 10 immediately outside enclosures) and positioned one motion-activated camera in each plot to observe animal visitations to Quercus brandegeei individuals over the course of several months (October 2019 – March 2020). No seeds and seedlings survived outside of enclosed areas at the end of the study based on their absence. Very …

2023 Chairs’ Welcome, Daniel Moreira, Aparna Bharati, Cecilia Pasquini, Yassine Yousfi

Computer Science: Faculty Publications and Other Works

Welcome to the 11th edition of the ACM Workshop on Information Hiding and Multimedia Security (IH&MMSec ‘23). This year’s workshop continues the tradition of representing one of the prime events in information hiding and multimedia security, attracting researchers and practitioners worldwide. Carrying on with the efforts of the previous edition to overcome the Pandemics and reunite the IH&MMSec community to present and discuss their work, this year’s meeting is held fully in person at the Water Tower Campus of Loyola University Chicago, located right at the heart of the Windy City. Bathed by the fresh waters of Lake Michigan, Chicago …

Synthesis Of Constrained N-Heterocyclic Peptidomimetics And Development Of Strain-Release Reagents, Kyle P. Pedretty

USF Tampa Graduate Theses and Dissertations

Part 1:The initial portion of this dissertation delves into the enhancement of β-sheet secondary structure stability through modification of the peptide backbone while examining the conformational characteristics of peptides featuring N-amino substituents. The investigation consists of two major studies, presented in separate sections. The first study outlines various approaches to achieve stable β-hairpin folds by introducing N-amino substituents to peptide strands. A novel method utilizing on-resin Mitsunobu cyclization between α-hydrazino acid residues and a serine or homoserine side chain was utilized to incorporate pyrazolidinone and tetrahydropyridazinone dipeptide constraints. To evaluate the impact of cyclic N-amino peptide building blocks on β-hairpin …

A Novel Peptide 'T14' Reflects Age And Photo-Aging In Human Skin, Sheila Rocha, Sara Garcia Ratés, Tumisang Moswete, Kristopher Kalleberg, Anna Villa, Jason P Harcup, Susan A Greenfield

Faculty, Staff and Student Publications

T14 is a 14mer peptide derived from the C-terminus of acetylcholinesterase (AChE). Once cleaved, it is independently bioactive of the parent molecule and enhances calcium influx in different cell types, in a range of scenarios: it binds to an allosteric site selectively on the alpha-7 receptor, where it modulates calcium influx and is thus a potential trophic agent, as already reported in a range of normal developmental scenarios. However, if inappropriately activated, this erstwhile beneficial effect converts to a toxic one, resulting in pathologies as disparate as Alzheimer’s and various metastatic cancers. Given that epidermal keratinocyte cells have the same …

Polysaccharide-Based Hydrogel From Seeds Of Artemisia Vulgaris: Extraction Optimization By Box–Behnken Design, Ph-Responsiveness, And Sustained Drug Release, Muhammad Ajaz Hussain, Arshad Ali, Tariq G Alsahli, Nadia Khan, Ahsan Sharif, Muhammad Tahir Haseeb, Omar Awad Alsaidan, Muhammad Tayyab, Syed Nasir Abbas Bukhari

Faculty, Staff and Student Publications

The current research work focuses on the extraction and optimization of the hydrogel (AVM) from the seeds of Artemisia vulgaris using Box–Behnken design-response surface methodology (BBD-RSM). The AVM was obtained through a hot water extraction process. The influence of different factors, including pH (U = 4 to 10), temperature (V = 25 to 110 °C), seed/water ratio, i.e., S/W ratio (W = 1/10 to 1/70 w/v), and seed/water contact time, i.e., S/W time (X = 1 to 12 h) on the yield of AVM was evaluated. The p-value for the analysis of variance (ANOVA) was found …

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