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Copolymerization Of Pyrrole And Carbazole Onto Polyester Textile, Mehmet Akif Küçükkaya, Utku Ustamehmetoğlu, Esma Sezer, Belkıs Ustamehmetoğlu Feb 2024

Copolymerization Of Pyrrole And Carbazole Onto Polyester Textile, Mehmet Akif Küçükkaya, Utku Ustamehmetoğlu, Esma Sezer, Belkıs Ustamehmetoğlu

Turkish Journal of Chemistry

The purpose of this study was the polymerization of carbazole (Cz), pyrrole (Py) and copolymerization of them onto polyester (PES) textile with chemical oxidative method by using FeCl3. First, in order to determine the optimum conditions, the effect of polymerization steps, the immersion order of the PES to the oxidant and monomer solutions, time, monomer, oxidant, and surfactant concentrations and types on the conductivities of PES/PCz composite were investigated and at this conditions, conductive composite, PES/P[Py-co-Cz] was obtained. The highest conductivities were obtained as 12.4 mS/cm and 9.0 mS/cm for PES/PCz and PES/P[Py-co-Cz], respectively. Further characterization of PES/P[Py-co-Cz] was performed …


Voltammetric Measurement Of Catechol-O-Methyltransferase Inhibitor Tolcapone In The Pharmaceutical Form On The Boron-Doped Diamond Electrode, Musa Kiran, Yavuz Yardim Feb 2024

Voltammetric Measurement Of Catechol-O-Methyltransferase Inhibitor Tolcapone In The Pharmaceutical Form On The Boron-Doped Diamond Electrode, Musa Kiran, Yavuz Yardim

Turkish Journal of Chemistry

This study presents an electroanalytical approach to measure the catechol-O-methyltransferase (COMT) inhibitor tolcapone (TOL) using a boron-doped diamond (BDD) electrode. The application of cyclic voltammetry (CV) technique revealed that TOL exhibited a distinct, diffusion-controlled, irreversible anodic peak at a potential of approximately +0.71 V (vs. Ag/AgCl) in a 0.1 mol L–1 phosphate buffer solution (PBS) with a pH of 2.5. The oxidation of TOL is highly dependent on the pH and supporting electrolytes. Based on the data obtained from the pH investigation, a proposed mechanism for the electro-oxidation of TOL is suggested. Using the square wave voltammetry (SWV) technique, a …


Influence Of Convective Heat Transfer Coefficients On Thermal Behaviour Of A Lithium-Ion Cell: A Numerical Study, Uğur Morali Feb 2024

Influence Of Convective Heat Transfer Coefficients On Thermal Behaviour Of A Lithium-Ion Cell: A Numerical Study, Uğur Morali

Turkish Journal of Chemistry

In the current study, the impact of C-ratio, convective heat transfer coefficient, and free stream temperature on the maximal cell temperature and temperature uniformity was computationally and statistically examined. Results revealed that the free stream temperature was the main influential factor for the maximal cell temperature for both natural and forced convection conditions while the C-ratio was the most effective parameter for the temperature uniformity for both natural and forced convections. On the other hand, the contribution of the free stream temperature to the maximum battery temperature increased from 63% to 94% when the conditions were changed from natural convection …


Optimized Intermediate Layer Formation And Electroless Plating Methods To Obtain Supported Dense Pd Surfaces, Gamze Gümüşlü Gür, Berna Toprak Feb 2024

Optimized Intermediate Layer Formation And Electroless Plating Methods To Obtain Supported Dense Pd Surfaces, Gamze Gümüşlü Gür, Berna Toprak

Turkish Journal of Chemistry

Dense metallic membranes, especially Pd and Pd alloys, have been intensely investigated to provide an alternative and economical way to obtain H2 with ultrahigh purity. To overcome the high cost of Pd, composite membrane structures that comprise a thin layer of Pd are utilized. However, it is a challenge to obtain a thin, dense, and uniform Pd layer on the support materials. This study investigates the parametric analysis of γ-Al2O3 interlayer formation and the electroless Pd plating (Pd ELP) procedures on α-Al2O3 supports with the aim to achieve a thin, uniform Pd surface without annealing. Adjustments in PEG/PVA concentration, dipping …


Structure-Activity Relationship Of Anticancer Drug Candidate Quinones, Nadire Özenver, Neslihan Sönmez, Merve Yüzbaşıoğlu Baran, Ayşe Uz, Lütfiye Ömür Demi̇rezer Feb 2024

Structure-Activity Relationship Of Anticancer Drug Candidate Quinones, Nadire Özenver, Neslihan Sönmez, Merve Yüzbaşıoğlu Baran, Ayşe Uz, Lütfiye Ömür Demi̇rezer

Turkish Journal of Chemistry

Breast cancer is one of the most prevalent cancer types worldwide. Chemotherapy is a substantial approach in the management of breast cancer despite the occurrence of chemotherapy-associated side effects and the development of multidrug resistance in cancer cells. At this point, a variety of quinone derivatives may represent potential as possible anticancer drug candidates due to possessing structural similarity towards clinically used anticancer drugs like doxorubicin. Therefore, we investigated the cytotoxic effects of various quinone derivatives with structural diversity towards a variety of breast cancer cells. We further determined their toxicity in healthy cells to evaluate their drug capability potential. …


Recent Advances And Applications Of Nanostructured Membranes In Water Purification, Didem Aydin, İlkay Hilal Gübbük, Mustafa Ersöz Feb 2024

Recent Advances And Applications Of Nanostructured Membranes In Water Purification, Didem Aydin, İlkay Hilal Gübbük, Mustafa Ersöz

Turkish Journal of Chemistry

In recent years, water pollution caused by hazardous materials such as metals, drugs, pesticides, and insecticides has become a very serious environmental and health problem that needs to be addressed urgently. The nutritional needs associated with the increasing population also increase the demand for water use and rapidly increase the rate of freshwater consumption. Since most of the water in the universe is in the form of sea water, which cannot be directly used, freshwater resources are limited ,compared to the existing available water. When addressing the purification of all kinds of pollution in environmental research, nanostructured membranes attract attention …


Chromium Speciation In Water Using Magnetic Polyaniline Nanoparticles Coupled With Microsampling Injection-Flame Atomic Absorption Spectroscopy, Osman Çaylak Feb 2024

Chromium Speciation In Water Using Magnetic Polyaniline Nanoparticles Coupled With Microsampling Injection-Flame Atomic Absorption Spectroscopy, Osman Çaylak

Turkish Journal of Chemistry

The chromium speciation procedure was optimized using magnetic polyaniline nanoparticles (Fe3O4@PANI NPs) solid-phase extraction coupled with microsampling injection-flame atomic absorption spectrometry (MIS-FAAS). Chromium speciation was successfully achieved by Fe3O4@PANI NPs at pH 8.0. The recoveries obtained for Cr(III) and Cr(VI) were above 95% and under 5%, respectively. Recoveries of over 95% for Cr(III) from 40.0 mL of the sample were obtained using 25 mg Fe3O4@PANI NPs and 500 µL of 0.2% (w/v) thiourea (TU) solution prepared in 2 mol L–1 HCl as eluent. Total chromium as Cr(III) was extracted quantitatively after reducing the Cr(VI) to Cr(III). The linear range, detection …


Detection And Monitoring Of Plant Pathogens And Pests, Walter F. Mahaffee, Lindsey D. Thiessen, Kevin M. King, Robin A. Choudhury Feb 2024

Detection And Monitoring Of Plant Pathogens And Pests, Walter F. Mahaffee, Lindsey D. Thiessen, Kevin M. King, Robin A. Choudhury

School of Earth, Environmental, & Marine Sciences Faculty Publications

No abstract provided.


Generative Mechanisms Of Ai Implementation: A Critical Realist Perspective On Predictive Maintenance, Alexander Stohr, Philip Ollig, Robert Keller, Alexander Rieger Feb 2024

Generative Mechanisms Of Ai Implementation: A Critical Realist Perspective On Predictive Maintenance, Alexander Stohr, Philip Ollig, Robert Keller, Alexander Rieger

Information Systems Faculty Publications and Presentations

Artificial intelligence (AI) promises various new opportunities to create and appropriate business value. However, many organizations – especially those in more traditional industries – struggle to seize these opportunities. To unpack the underlying reasons, we investigate how more traditional industries implement predictive maintenance, a promising application of AI in manufacturing organizations. For our analysis, we employ a multiple-case design and adopt a critical realist perspective to identify generative mechanisms of AI implementation. Overall, we find five interdependent mechanisms: experimentation; knowledge building and integration; data; anxiety; and inspiration. Using causal loop diagramming, we flesh out the socio-technical dynamics of these mechanisms …


Sustainability Of Biogas Production From Anaerobic Digestion Of Food Waste And Animal Manure, Sharath Kumar Ankathi, Utkarsh S. Chaudhari, Robert Handler, David R. Shonnard Feb 2024

Sustainability Of Biogas Production From Anaerobic Digestion Of Food Waste And Animal Manure, Sharath Kumar Ankathi, Utkarsh S. Chaudhari, Robert Handler, David R. Shonnard

Michigan Tech Publications

Anaerobic digestion (AD) involves a set of microbiological reactions and physio-chemical processes to generate biogas, a mixture of predominantly CH4 and CO2. It is commercialized globally; however, AD has limited commercial applications in the U.S. compared to other regions of the world. The main objective of this article is to review different studies on socio-economic and environmental aspects and policies of biogas/biomethane production and to focus on resource availability. The key outcome from this review shows that the anaerobic digestion of food waste and animal manure has great potential to achieve economic and environmental benefits compared to other waste management …


Observed Epochal Variations In X-Ray Lines From The O Supergiant Ζ Puppis Do Not Require Substantial Changes In The Wind Mass Flux, Sean J. Gunderson, Kenneth G. Gayley, David P. Huenemoerder, Pragati Pradhan, Nathan A. Miller Feb 2024

Observed Epochal Variations In X-Ray Lines From The O Supergiant Ζ Puppis Do Not Require Substantial Changes In The Wind Mass Flux, Sean J. Gunderson, Kenneth G. Gayley, David P. Huenemoerder, Pragati Pradhan, Nathan A. Miller

Publications

We fit the high-resolution Chandra X-ray spectra of the O supergiant ζ Puppis using the variable boundary condition (VBC) line model to test the stability of its mass-loss rate between two epochs of observation: 2000 March and 2018 July – 2019 August. At issue is whether the observed variations are induced by global changes in the cool (unshocked) wind itself or are isolated to the local pockets of hot gas (i.e. changes in the frequency and location of the shocks). Evidence in the literature favoured the possibility of a 40 per cent increase in the mass flux of the entire …


Acs Measurement Science Au In 2024, Shelley Minteer Feb 2024

Acs Measurement Science Au In 2024, Shelley Minteer

Chemistry Faculty Research & Creative Works

No abstract provided.


Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, And Mechanism, Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran Feb 2024

Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, And Mechanism, Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran

Chemistry Faculty Research & Creative Works

The first general enantioselective alkyl-Nozaki-Hiyama-Kishi (NHK) coupling reactions are disclosed herein by employing a Cr-electrocatalytic decarboxylative approach. Using easily accessible aliphatic carboxylic acids (via redox-active esters) as alkyl nucleophile synthons, in combination with aldehydes and enabling additives, chiral secondary alcohols are produced in a good yield with high enantioselectivity under mild reductive electrolysis. This reaction, which cannot be mimicked using stoichiometric metal or organic reductants, tolerates a broad range of functional groups and is successfully applied to dramatically simplify the synthesis of multiple medicinally relevant structures and natural products. Mechanistic studies revealed that this asymmetric alkyl e-NHK reaction was enabled …


Cover And Contents Feb 2024

Cover And Contents

Turkish Journal of Physics

No abstract provided.


Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün Feb 2024

Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün

Turkish Journal of Physics

The work presented considers a class of minimally constructed Yukawa unified SUSY GUTs - NUHM2 - and explores their implications when their soft supersymmetry breaking Lagrangian is generalized by the nonholomorphic terms which provide extra contributions to the Higgsino mass and couple the supersymmetric scalar fields to the wrong Higgs doublets. With such a simple extension, it can be found several regions with interesting implications which cannot be realized in the usual restricted models. It is observed that the Yukawa unification solutions can be compatible with a relatively light mass spectrum and acceptable low fine-tuning measurements. In the restricted models …


Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan Feb 2024

Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan

Turkish Journal of Physics

In this work, we examine the reheating constraints to symmetry-breaking mechanism, which is associated with Coleman-Weinberg inflation in the early universe. We consider the Coleman-Weinberg inflation potential, where the inflaton has a v ̸= 0 after inflation. Setting Treh = 105 GeV, we first show wreh dependency on ns , r , and N∗ for AV case. Then, we demonstrate the results of ns , r , N∗ , α = dns/d ln k for different reheating temperatures and compare the results with the latest BICEP/Keck data. We also present that ns −r and ns −N∗ planes and the effect …


Novel Design And Analysis For Rare Disease Drug Development, Shein-Chung Chow, Annpey Pong, Susan S. Chow Feb 2024

Novel Design And Analysis For Rare Disease Drug Development, Shein-Chung Chow, Annpey Pong, Susan S. Chow

Student Publications

For rare disease drug development, the United States (US) Food and Drug Administration (FDA) has indicated that the same standards as those for drug products for common conditions will be applied. To assist the sponsors in rare disease drug development, the FDA has initiated several incentive programs to encourage the sponsors in rare disease drug development. In practice, these incentive programs may not help in achieving the study objectives due to the limited small patient population. To overcome this problem, some out-of-the-box innovative thinking and/or approaches, without jeopardizing the integrity, quality, and scientific validity of rare disease drug development, are …


Comparative Study Between Virgin And Agriculture Soil Radon Activity Concentration And Their Radiological Risks, Hiwa Hamad Azeez, Jahfer Majeed Smail, Hemn Muhammad Salh, Habeeb Hanna Mansour, Saddon Taha Ahmad, Hawbash H. Hamadamin Karim Feb 2024

Comparative Study Between Virgin And Agriculture Soil Radon Activity Concentration And Their Radiological Risks, Hiwa Hamad Azeez, Jahfer Majeed Smail, Hemn Muhammad Salh, Habeeb Hanna Mansour, Saddon Taha Ahmad, Hawbash H. Hamadamin Karim

Polytechnic Journal

The present study is to compare the radon activity concentration in agricultural and virgin soils from various locations along the Little Zab River (LZR) in the Iraqi Kurdistan region. We conducted 24 measurements of soil samples using long tube techniques equipped with an electric radon detector called RAD7 in our research. The findings revealed that the radon activity concentrations ranged from 37.3 ± 7.52 Bq m-3 to 298.25 ± 50.09 Bq m-3 in virgin soil, and from 33.03 ± 10.85 Bq m-3 to 320.25 ± 34.62 Bq.m-3 in agriculture soil. The annual effective dose was also calculated to be from …


Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty Feb 2024

Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty

Physics & Astronomy Faculty Publications

Neutron star (NS) binaries can be potentially intriguing gravitational wave sources, with both high- and low-frequency radiation from the possibly aspherical individual stars and the binary orbit, respectively. The successful detection of such a dual-line source could provide fresh insights into binary geometry and NS physics. In the absence of electromagnetic observations, we develop a strategy for inferring the spin-orbit misalignment angle using the tight dual-line double NS system under the spin-orbit coupling. Based on the four-year joint detection of a typical dual-line system with the Laser Interferometer Space Antenna and Cosmic Explorer, we find that the misalignment angle and …


Performance Predictors For Multi-Event Athletes, Francesca Aquilino, Raquel J. Cavazos, Ernesto Balderrama, Chaehyun Byun, Shelby Gerner, Cheyenne Martinez, Austin Riffe, Vipa Bernhardt, Michael D. Oldham Feb 2024

Performance Predictors For Multi-Event Athletes, Francesca Aquilino, Raquel J. Cavazos, Ernesto Balderrama, Chaehyun Byun, Shelby Gerner, Cheyenne Martinez, Austin Riffe, Vipa Bernhardt, Michael D. Oldham

International Journal of Exercise Science: Conference Proceedings

Decathletes and heptathletes track performance using a point system after each event, and after each day to determine standings and progress. Predicting point potentials is a sought-after commodity at all levels of track and field competition. PURPOSE: The principal aim of this study was to identify the events in which athletes representing the U.S. national team attained lower scores compared to Olympic medal winners (OLY). The secondary aim was to provide predictive algorithms using low-tech field-testing and high-tech motion analysis methods to identify movements highly associated with event performance. METHODS: 18 current U.S. national track and field athletes, decathlon ( …


Exploring The Interconnected Role Of The Oral Microbiome And Periodontal Disease In The Development And Progression Of Oral Squamous Cell Carcinoma, Malak Al-Regib, Claudia M. Tellez Freitas Feb 2024

Exploring The Interconnected Role Of The Oral Microbiome And Periodontal Disease In The Development And Progression Of Oral Squamous Cell Carcinoma, Malak Al-Regib, Claudia M. Tellez Freitas

Annual Research Symposium

This comprehensive review explores the complex linkage among the oral microbiome, periodontal disease, and the onset and progression of oral squamous cell carcinoma (OSCC).


World-Class Research An D Development Management; Customer And Supplier Value Chain; Strategic Management Guidelines, Society Of Management Accountants Of Canada, American Institute Of Certified Public Accountants (Aicpa), Australian Society Of Certified Practising Accountants Feb 2024

World-Class Research An D Development Management; Customer And Supplier Value Chain; Strategic Management Guidelines, Society Of Management Accountants Of Canada, American Institute Of Certified Public Accountants (Aicpa), Australian Society Of Certified Practising Accountants

Guides, Handbooks and Manuals

No abstract provided.


Biological Stimulants Increase Fertilizer Efficiency And Pasture Legume Content, P. R. Espie, S. Haswell, A. Barton Feb 2024

Biological Stimulants Increase Fertilizer Efficiency And Pasture Legume Content, P. R. Espie, S. Haswell, A. Barton

IGC Proceedings (1977-2023)

The effects of a soil biological stimulant (SS) and biologically activated reactive phosphate rock (BAP) on pasture yield and botanical composition were examined in a field trial in low-fertility New Zealand rangeland. BAP application significantly increased pasture yield by 60% and BAP plus biostimulant increased yield by 120%. BAP significantly increased resident legume cover by 75% and BAP with biostimulants by 85%. Alfalfa, direct drilled as an indicator test species, increased in establishment from 0 to 3.8 plants m-2 with BAP and to 4.2 plants m-2 with BAP plus biostimulant. Biostimulant applied alone increased yield by 17%, legume cover by …


Uf-Accelerate To Industry (A2i): Bringing Industry Into Academia, J. A. Estrada Feb 2024

Uf-Accelerate To Industry (A2i): Bringing Industry Into Academia, J. A. Estrada

IGC Proceedings (1977-2023)

University stakeholders are targeting candidates with competency in a wide range of professional skills, including team building and leadership, multi-modal communication, intercultural awareness, emotional intelligence, and mental flexibility. We developed UF-Accelerate to Industry (A2i) to deliver these skills to our graduate students and better prepare them to enter a competitive, rapidly evolving workforce. UF-A2i is delivered as day-long “immersion” events, consisting of presentations, panel discussions, skills workshops, and group projects. All activities are led by industry sponsors or career preparation specialists and are focused on building industry-identified skills that will give attendees a competitive edge in the job market. Since …


The Use Of Livestock Gps Trackers To Determine The Grazing Patterns Of Herded And Free Ranging Cattle In The Communal Rangelands Of The Eastern Cape Province, South Africa, A. Finca, T. C. Zondani, J. T. Tjelele, M. P. Mavuso Feb 2024

The Use Of Livestock Gps Trackers To Determine The Grazing Patterns Of Herded And Free Ranging Cattle In The Communal Rangelands Of The Eastern Cape Province, South Africa, A. Finca, T. C. Zondani, J. T. Tjelele, M. P. Mavuso

IGC Proceedings (1977-2023)

This study was set in the Eastern Cape Province of South Africa which is predominantly rural and where livelihood sustainability is largely dependent on agricultural outputs including livestock production. Land in many of the rural, former homeland areas is held under communal land tenure which means access, utilisation and management is on a collective basis. A number of grazing strategies have been applied over the last hundred years including camp rotational grazing system. However, due to a number of factors including the absence of the communal rangeland and camp boundary fence, most villages do not have a rangeland management strategy …


Preparing Grasslands Scientists For Careers In International Agriculture, M. Eilittä Feb 2024

Preparing Grasslands Scientists For Careers In International Agriculture, M. Eilittä

IGC Proceedings (1977-2023)

Livelihoods of a billion poor people depend on grasslands. Dedicated and trained experts are needed to support grasslands’ sustainable development under increasing pressures in the future. For some grasslands scientists, a career in international agriculture is the principal focus from the start of their education. For others, interest in international agriculture emerges during their careers. All require international opportunities to ensure that their efforts are focused on important priorities, that they understand the environment they work in, and that their professional networks are up to date. This paper reflects on ways for grassland scientists to be engaged in international agriculture …


How ‘Pasture For Life (Championing 100% Pasture-Fed Ruminant Products) Has Taken Off In The Uk – From The Bottom Up!, S. J. Gregson Feb 2024

How ‘Pasture For Life (Championing 100% Pasture-Fed Ruminant Products) Has Taken Off In The Uk – From The Bottom Up!, S. J. Gregson

IGC Proceedings (1977-2023)

Ten years ago Pasture for Life (PfL) was a collection of around 50 UK farmers who were producing high quality ruminant food products wholly from pasture. They were regenerative farming pioneers and PfL was run by volunteers and funded through various grants. In the past two to three years, membership has increased significantly, nearing 1,000 with almost 150 certified Pasture for Life (100% grass-fed). The organisation is now run by a paid executive and is bursting with energy, conversation, and learning. Members are mainly farmers, but also include butchers, chefs, vets, academics and consumers – all keen to champion the …


Rotational Stocking With Virtual Fences: Effects On Grassland Diet Digestibility, Livestock Performance And Stress Levels Of Heifers, N. A. Grinnell, D. Hamidi, M. Komainda, F. Reisch, J. Horn, I. Traulsen, R. Palme, J. Isselstein Feb 2024

Rotational Stocking With Virtual Fences: Effects On Grassland Diet Digestibility, Livestock Performance And Stress Levels Of Heifers, N. A. Grinnell, D. Hamidi, M. Komainda, F. Reisch, J. Horn, I. Traulsen, R. Palme, J. Isselstein

IGC Proceedings (1977-2023)

Virtual fencing is an innovative technology for simplified, less laborious dynamic grazing management and remote animal monitoring. The effect of this novel technology on animal welfare is still a matter of debate. Previous research suggests no differences in stress experience responses of cattle between the two fencing systems on continuously stocked pastures. This study investigated differences in diet organic matter digestibility, livestock performance and fecal cortisol metabolite concentrations of heifers on pastures in a rotational grazing system, fenced with a virtual fence (Nofence, Batnfjordsøra Norway) compared to heifers fenced with a traditional electric wire fence. The study was conducted in …


Curricular Changes Proposed For 2023-2025 Morris Catalog, Curriculum Committee Feb 2024

Curricular Changes Proposed For 2023-2025 Morris Catalog, Curriculum Committee

Curriculum Committee Reports

No abstract provided.


Campus Assembly Minutes 02/20 & 02/22/2024, Campus Assembly Feb 2024

Campus Assembly Minutes 02/20 & 02/22/2024, Campus Assembly

Campus Assembly

No abstract provided.