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Predicting Forage Provision Of Grasslands Across Climate Zones By Hyperspectral Measurements, F. A. Männer, J. Muro, J. Ferner, S. Schmidtlein, A. Linstädter Feb 2024

Predicting Forage Provision Of Grasslands Across Climate Zones By Hyperspectral Measurements, F. A. Männer, J. Muro, J. Ferner, S. Schmidtlein, A. Linstädter

IGC Proceedings (1977-2023)

The potential of grasslands’ fodder production is a crucial management measure, while its quantification is still laborious and costly. Remote sensing technologies, such as hyperspectral field measurements, enable fast and non-destructive estimation. However, such methods are still limited in transferability to other locations or climatic conditions. With this study, we aim to predict forage nutritive value, quantity, and energy yield from hyperspectral canopy reflections of grasslands across three climate zones. We took hyperspectral measurements with a field spectrometer from grassland canopies in temperate, tropical and semi-arid grasslands, and analyzed corresponding biomass samples for their quantity (BM), metabolizable energy content (ME) …


Themeda Triandra As A Perennial Seed Crop In South-Eastern Australia: What Are The Agronomic Possibilities And Constraints, And Future Research Needs?, D. Male, J. Hunt, C. Celestina, J. Morgan, D. Gupta, Dja Dja Wurrung People Feb 2024

Themeda Triandra As A Perennial Seed Crop In South-Eastern Australia: What Are The Agronomic Possibilities And Constraints, And Future Research Needs?, D. Male, J. Hunt, C. Celestina, J. Morgan, D. Gupta, Dja Dja Wurrung People

IGC Proceedings (1977-2023)

In Australia, the development of native perennial seed crops is an area of increasing interest. Reasons for this include the production of high-value seed, the significance of native plants to Aboriginal people and the importance of diversified cropping in building more resilient farming systems. One species of interest is Themeda triandra, a C4 perennial tussock grass that dominated grasslands and woodlands across Australia prior to European invasion. Djaara, the traditional owner group representing the Dja Dja Wurrung people of Djandak (Dja Dja Wurrung country in central Victoria), is one group who seek to return T. triandra to the landscape …


Quality Of Life In Orthodontics, Claudia Eisenhuth, Gabriel Eisenhuth, Connor Schwartz, Amir Mohajeri, Man Hung, Tiffany Nelson, Ryann Glenn Feb 2024

Quality Of Life In Orthodontics, Claudia Eisenhuth, Gabriel Eisenhuth, Connor Schwartz, Amir Mohajeri, Man Hung, Tiffany Nelson, Ryann Glenn

Annual Research Symposium

Orthodontic treatment goes beyond mere cosmetic enhancement; it significantly impacts various aspects of an individual's quality of life. Beyond the physical benefits of improved oral function and prevention of dental issues, orthodontics also yields profound psychological benefits. Aligned teeth enhance self-confidence, reduce social anxiety, and contribute to better relationships and professional opportunities. Moreover, addressing dental concerns through orthodontic treatment reduces psychological distress and promotes overall happiness and satisfaction. Real-life case studies vividly illustrate the transformative effects of orthodontic interventions, emphasizing the importance of considering quality of life outcomes in dental care.


Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág Feb 2024

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …


Heavy Metal Movement Through Insect Food Chains In Pristine Thermal Springs Of Yellowstone National Park, Braymond Adams, John Bowley, Monica Rohwer, Erik Oberg, Kelly Willemssens, Wendy Wintersteen, Robert K.D. Peterson, Leon G. Higley Feb 2024

Heavy Metal Movement Through Insect Food Chains In Pristine Thermal Springs Of Yellowstone National Park, Braymond Adams, John Bowley, Monica Rohwer, Erik Oberg, Kelly Willemssens, Wendy Wintersteen, Robert K.D. Peterson, Leon G. Higley

School of Natural Resources: Faculty Publications

Yellowstone National Park thermal features regularly discharge various heavy metals and metalloids. These metals are taken up by microorganisms that often form mats in thermal springs. These microbial mats also serve as food sources for invertebrate assemblages. To examine how heavy metals move through insect food webs associated with hot springs, two sites were selected for this study. Dragon-Beowulf Hot Springs, acid-sulfate chloride springs, have a pH of 2.9, water temperatures above 70 oC, and populations of thermophilic bacterial, archaeal, and algal mats. Rabbit Creek Hot Springs, alkaline springs, have a pH of up to 9, some water temperatures …


Subject-Package Measures To Understand The Value Provided By Journal Packages, Heidi J. Southworth, Evan Rusch, Nat Gustafson-Sundell Feb 2024

Subject-Package Measures To Understand The Value Provided By Journal Packages, Heidi J. Southworth, Evan Rusch, Nat Gustafson-Sundell

Library Services Publications

At Minnesota State University Mankato (MNSU), we have been exploring new Key Performance Indicators (KPIs) for journal packages. Most recently, we started developing subject-package measures as a category, including as a measure of utility or as a measure of supply. Although we could previously combine filters per subject and per package, this caused us to narrow data to a single subject. Now, we can display the results for all subjects and packages as one table, which empowers us to make comparisons easily, to understand the value we gain from our packages better, and to see any subject impacts of cancellations …


A Case For Hope In A Warming World, Noreen L. Herzfeld Feb 2024

A Case For Hope In A Warming World, Noreen L. Herzfeld

Reuter Professorship of Science and Religion Publications

It is difficult to feel hopeful in a rapidly warming world. But hope is not just a feeling. It is an active verb, one that calls for courage, solidarity, a clear vision, and hard work. First, knowing that each fraction of a degree counts, humanity is called not to despair but to use every technology and means, technologies we already have. Second, we can be encouraged by a vision of a new world and society that works for everyone. Third, we can be heartened by nature’s resilience and an evolutionary theology that looks toward the future.


A Return To Rationality: Restoring The Rule Of Law After Daubert's Disastrous U-Turn, Andrew Jurs, Scott Devito Feb 2024

A Return To Rationality: Restoring The Rule Of Law After Daubert's Disastrous U-Turn, Andrew Jurs, Scott Devito

New Mexico Law Review

Consistency and rationality are central to the legitimacy of the modern court system. Considerable recent attention has been focused on the Court’s overturning of established precedent on abortion in Dobbs v. Jackson Women’s Health Organization. Yet, as we empirically demonstrate, the courts, through the decisions of individual judges over thirty years, have reversed the meaning of the Daubert standard for admission of scientific evidence, thereby threatening the legitimacy of the very heart of the civil justice system. In the initial years after the Daubert decision, litigants saw its reliability standard as a stricter standard than the previously used Frye “general …


The Role Of Humor In Sustainability: Well-Being, (In)Equity, And Community, Mia Ocean Feb 2024

The Role Of Humor In Sustainability: Well-Being, (In)Equity, And Community, Mia Ocean

Sustainability Research & Practice Seminar Presentations

Professor Mia Ocean, Graduate Social Work, shares an interactive presentation on The Role of Humor in Sustainability: Focusing on Well-Being, (In)equity, and Community


The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu Feb 2024

The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu

Turkish Journal of Chemistry

Sol-gel combustion was used to produce the perovskite-type La0.6Sr0.4FeO3 (LSF) and La0.6Sr0.4Fe0.9Pd0.1O3 (LSFP) materials and assessed as supercapacitor electrodes. The synthesized materials’ crystal structure, morphology, and electrochemical performance were thoroughly analyzed. The partial substitution of Pd in the B site of the LSF structure affected the electrochemical properties of this compound and improved its performance. In fact, the greatest effect of Pd substitution was on the content of oxygen vacancies, which are known as the active sites of the perovskite surface in the supercapacitor cell. The specific capacitance obtained for the sample containing Pd was about 80 F.g–1 at a …


Cover And Contents Feb 2024

Cover And Contents

Turkish Journal of Physics

No abstract provided.


Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan Feb 2024

Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan

Turkish Journal of Physics

In this work, we examine the reheating constraints to symmetry-breaking mechanism, which is associated with Coleman-Weinberg inflation in the early universe. We consider the Coleman-Weinberg inflation potential, where the inflaton has a v ̸= 0 after inflation. Setting Treh = 105 GeV, we first show wreh dependency on ns , r , and N∗ for AV case. Then, we demonstrate the results of ns , r , N∗ , α = dns/d ln k for different reheating temperatures and compare the results with the latest BICEP/Keck data. We also present that ns −r and ns −N∗ planes and the effect …


Detection And Characterization Of The Pichia Manshurica Biofilm On The Traditionally Produced Homemade Apple Vinegar, Zeynep İşlek Koklu, Pınar Akkuş Süt, Esra Eskihoran Üçüncüoğlu, Sadık Kalayci, Fikrettin Şahi̇n Feb 2024

Detection And Characterization Of The Pichia Manshurica Biofilm On The Traditionally Produced Homemade Apple Vinegar, Zeynep İşlek Koklu, Pınar Akkuş Süt, Esra Eskihoran Üçüncüoğlu, Sadık Kalayci, Fikrettin Şahi̇n

Turkish Journal of Chemistry

Pichia yeasts are capable of forming biofilms during vinegar production and causing spoilage in various beverages. In addition, there exists a significant likelihood of encountering yeast contamination which can prevent vinegar production. The present study investigates the detection and characterization of the Pichia manshurica (P. manshurica) biofilm on traditionally produced homemade apple vinegar. The unique characteristics of vinegar were analyzed with a focus on the constituent, known as the “mother of vinegar”, whose composition is comprised of cellulosic biofilm and acetic acid bacteria, including Gluconobacter oxydans (G. oxydans) Briefly, P. manshurica was isolated from apple vinegar and characterized in terms …


Exploration Of Novel 6,8,9-Trisubstituted Purine Analogues: Synthesis, In Vitro Biological Evaluation, And Their Effect On Human Cancer Cells, Muhammed Fatih Polat, İrem Durmaz Şahi̇n, Rengül Atalay, Meral Tunçbi̇lek Feb 2024

Exploration Of Novel 6,8,9-Trisubstituted Purine Analogues: Synthesis, In Vitro Biological Evaluation, And Their Effect On Human Cancer Cells, Muhammed Fatih Polat, İrem Durmaz Şahi̇n, Rengül Atalay, Meral Tunçbi̇lek

Turkish Journal of Chemistry

Cancer, a leading global cause of mortality, demands continuous advancements in therapeutic strategies. This study focuses on the design and synthesis of a novel series of purine derivatives, specifically 6-(substituted phenyl piperazine)-8-(4-phenoxyphenyl)-9-cyclopentyl purine derivatives (5–11). The motivation behind this endeavor lies in addressing acquired resistance mechanisms in cancer cells, a significant hurdle in current treatment modalities. The synthesis, starting from 4,6-dichloro-5-nitropyrimidine, involves a multi-step process, resulting in seven new purine derivatives. Biological evaluation against human liver, colon, and breast cancer cells (Huh7, HCT116, and MCF7, respectively) was performed using the SRB assay. Among the synthesized analogs, compounds 5 and 6, …


Nonoxidative Dehydrogenation Of Propane Using Boron-Incorporated Silica-Supported Pt Sites Synthesized By Atomic Layer Deposition, Gokhan Çeli̇k Feb 2024

Nonoxidative Dehydrogenation Of Propane Using Boron-Incorporated Silica-Supported Pt Sites Synthesized By Atomic Layer Deposition, Gokhan Çeli̇k

Turkish Journal of Chemistry

Nonoxidative dehydrogenation of propane to propylene using Pt-based supported catalysts is an active research area in catalysis because catalyst attributes of Pt sites can be controlled by careful design of active sites. One way to achieve this is by the addition of a second metal that may impart a change in the electron density of active sites, which in turn affects catalytic performance. In this study, bimetallic Pt and B sites were deposited on powder SiO2 using atomic layer deposition (ALD). Boron was first deposited on SiO2 via half-cycle ALD using triisoproplyborate as the B source. Following calcination, Pt deposition …


Comment On “Photons Can Tell ‘Contradictory’ Answer About Where They Have Been”, Gregory Reznick, Carlotta Versmold, Jan Dziewior, Florian Huber, Harald Weinfurter, Justin Dressel, Lev Vaidman Feb 2024

Comment On “Photons Can Tell ‘Contradictory’ Answer About Where They Have Been”, Gregory Reznick, Carlotta Versmold, Jan Dziewior, Florian Huber, Harald Weinfurter, Justin Dressel, Lev Vaidman

Mathematics, Physics, and Computer Science Faculty Articles and Research

Yuan and Feng (Eur. Phys. J. Plus 138:70, 2023) recently proposed a modification of the nested Mach–Zehnder interferometer experiment performed by Danan et al. (Phys. Rev. Lett. 111:240402, 2013) and argued that photons give “contradictory” answers about where they have been, when traces are locally imprinted on them in different ways. They concluded that their results are comprehensible from what they call the “three-path interference viewpoint,” but difficult to explain from the “discontinuous trajectory” viewpoint advocated by Danan et al. We argue that the weak trace approach (the basis of the “discontinuous trajectory” viewpoint) provides a consistent explanation of the …


Apollonian Packings And Kac-Moody Root Systems, Ian Whitehead Feb 2024

Apollonian Packings And Kac-Moody Root Systems, Ian Whitehead

Mathematics & Statistics Faculty Works

We study Apollonian circle packings using the properties of a certain rank 4 indefinite Kac-Moody root system ϕ. We introduce the generating function Z(s) of a packing, an exponential series in four variables with an Apollonian symmetry group, which is a symmetric function for ϕ. By exploiting the presence of affine and Lorentzian hyperbolic root subsystems of ϕ, with automorphic Weyl denominators, we express Z(s) in terms of Jacobi theta functions and the Siegel modular form Δ₅. We also show that the domain of convergence of Z(s) is the Tits cone of ϕ, and discover that this domain inherits the …


Generative Mechanisms Of Ai Implementation: A Critical Realist Perspective On Predictive Maintenance, Alexander Stohr, Philip Ollig, Robert Keller, Alexander Rieger Feb 2024

Generative Mechanisms Of Ai Implementation: A Critical Realist Perspective On Predictive Maintenance, Alexander Stohr, Philip Ollig, Robert Keller, Alexander Rieger

Information Systems Faculty Publications and Presentations

Artificial intelligence (AI) promises various new opportunities to create and appropriate business value. However, many organizations – especially those in more traditional industries – struggle to seize these opportunities. To unpack the underlying reasons, we investigate how more traditional industries implement predictive maintenance, a promising application of AI in manufacturing organizations. For our analysis, we employ a multiple-case design and adopt a critical realist perspective to identify generative mechanisms of AI implementation. Overall, we find five interdependent mechanisms: experimentation; knowledge building and integration; data; anxiety; and inspiration. Using causal loop diagramming, we flesh out the socio-technical dynamics of these mechanisms …


Sustainability Of Biogas Production From Anaerobic Digestion Of Food Waste And Animal Manure, Sharath Kumar Ankathi, Utkarsh S. Chaudhari, Robert Handler, David R. Shonnard Feb 2024

Sustainability Of Biogas Production From Anaerobic Digestion Of Food Waste And Animal Manure, Sharath Kumar Ankathi, Utkarsh S. Chaudhari, Robert Handler, David R. Shonnard

Michigan Tech Publications

Anaerobic digestion (AD) involves a set of microbiological reactions and physio-chemical processes to generate biogas, a mixture of predominantly CH4 and CO2. It is commercialized globally; however, AD has limited commercial applications in the U.S. compared to other regions of the world. The main objective of this article is to review different studies on socio-economic and environmental aspects and policies of biogas/biomethane production and to focus on resource availability. The key outcome from this review shows that the anaerobic digestion of food waste and animal manure has great potential to achieve economic and environmental benefits compared to other waste management …


Observed Epochal Variations In X-Ray Lines From The O Supergiant Ζ Puppis Do Not Require Substantial Changes In The Wind Mass Flux, Sean J. Gunderson, Kenneth G. Gayley, David P. Huenemoerder, Pragati Pradhan, Nathan A. Miller Feb 2024

Observed Epochal Variations In X-Ray Lines From The O Supergiant Ζ Puppis Do Not Require Substantial Changes In The Wind Mass Flux, Sean J. Gunderson, Kenneth G. Gayley, David P. Huenemoerder, Pragati Pradhan, Nathan A. Miller

Publications

We fit the high-resolution Chandra X-ray spectra of the O supergiant ζ Puppis using the variable boundary condition (VBC) line model to test the stability of its mass-loss rate between two epochs of observation: 2000 March and 2018 July – 2019 August. At issue is whether the observed variations are induced by global changes in the cool (unshocked) wind itself or are isolated to the local pockets of hot gas (i.e. changes in the frequency and location of the shocks). Evidence in the literature favoured the possibility of a 40 per cent increase in the mass flux of the entire …


Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün Feb 2024

Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün

Turkish Journal of Physics

The work presented considers a class of minimally constructed Yukawa unified SUSY GUTs - NUHM2 - and explores their implications when their soft supersymmetry breaking Lagrangian is generalized by the nonholomorphic terms which provide extra contributions to the Higgsino mass and couple the supersymmetric scalar fields to the wrong Higgs doublets. With such a simple extension, it can be found several regions with interesting implications which cannot be realized in the usual restricted models. It is observed that the Yukawa unification solutions can be compatible with a relatively light mass spectrum and acceptable low fine-tuning measurements. In the restricted models …


Intellectual Property And Entrepreneurship, Dale Andersen Feb 2024

Intellectual Property And Entrepreneurship, Dale Andersen

Space Dynamics Laboratory Publications

What is Intellectual Property

- Tangible vs. Intangible Property, Costs

How Your Business Acquires IP: Employment Inventions / Employment Copyrights

- Employment Agreements: IP Assignment, Non-Disclosure Agreement, Non-Competes

Know-how

Trade Secrets

- Trade Secret Misappropriation

- Non-Disclosure Agreements: Limitations and Liabilities

Copyright

- Definition, What Copyright Protects and Does Not Protect,

- How Copyright is Protected / Life of a Copyright

- Software Licenses

Trademark

- Use and Protection

- First Mover / Flood the Market

Patent

- Definition, Types, What is Patentable, Patentability Limits

- What’s in a patent?

- Example Patent Application Filing

- Example Portfolios

- Costs, …


Quantifying Wildfire Drivers And Predictability In Boreal Peatlands Using A Two-Step Error-Correcting Machine Learning Framework In Tefire V1.0, Rongyun Tang, Mingzhou Jin, Daniel M. Ricciuto, Anping Chen, Yulong Zhang Feb 2024

Quantifying Wildfire Drivers And Predictability In Boreal Peatlands Using A Two-Step Error-Correcting Machine Learning Framework In Tefire V1.0, Rongyun Tang, Mingzhou Jin, Daniel M. Ricciuto, Anping Chen, Yulong Zhang

Biological and Agricultural Engineering Faculty Publications and Presentations

Wildfires are becoming an increasing challenge to the sustainability of boreal peatland (BP) ecosystems and can alter the stability of boreal carbon storage. However, predicting the occurrence of rare and extreme BP fires proves to be challenging, and gaining a quantitative understanding of the factors, both natural and anthropogenic, inducing BP fires remains elusive. Here, we quantified the predictability of BP fires and their primary controlling factors from 1997 to 2015 using a two-step correcting machine learning (ML) framework that combines multiple ML classifiers, regression models, and an error-correcting technique. We found that (1) the adopted oversampling algorithm effectively addressed …


Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty Feb 2024

Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty

Physics & Astronomy Faculty Publications

Neutron star (NS) binaries can be potentially intriguing gravitational wave sources, with both high- and low-frequency radiation from the possibly aspherical individual stars and the binary orbit, respectively. The successful detection of such a dual-line source could provide fresh insights into binary geometry and NS physics. In the absence of electromagnetic observations, we develop a strategy for inferring the spin-orbit misalignment angle using the tight dual-line double NS system under the spin-orbit coupling. Based on the four-year joint detection of a typical dual-line system with the Laser Interferometer Space Antenna and Cosmic Explorer, we find that the misalignment angle and …


Evaluating Sojump.Com As A Tool For Online Behavioral Research In China, Alessandro Del Ponte, Lianjun Li, Lina Ang, Noah Lim, Wei Jie Seow Feb 2024

Evaluating Sojump.Com As A Tool For Online Behavioral Research In China, Alessandro Del Ponte, Lianjun Li, Lina Ang, Noah Lim, Wei Jie Seow

Political Science Faculty Articles and Research

SoJump.com (wjx.cn; in short: SoJump) is a survey company that allows researchers to build and deploy inexpensive online surveys in China. Here we evaluate SoJump’s data quality and similarity to the national benchmark. In the first study, we compare SoJump’s performance in China to MTurk’s performance against national benchmarks in the United States and India. In the second study, we compare three Chinese platforms in two-wave panel studies. We conducted the panels on SoJump, Credamo (SoJump’s major competitor), and Cint (national benchmark). We included attention and comprehension checks, economic games, cognitive tasks, and a framing experiment. We find that SoJump’s …


Simulation Of The Multi-Wake Evolution Of Two Sandia National Labs/National Rotor Testbed Turbines Operating In A Tandem Layout, Apurva Baruah, Fernando L. Ponta, Alayna Farrell Feb 2024

Simulation Of The Multi-Wake Evolution Of Two Sandia National Labs/National Rotor Testbed Turbines Operating In A Tandem Layout, Apurva Baruah, Fernando L. Ponta, Alayna Farrell

Michigan Tech Publications

The future of wind power systems deployment is in the form of wind farms comprised of scores of such large turbines, most likely at offshore locations. Individual turbines have grown in span from a few tens of meters to today’s large turbines with rotor diameters that dwarf even the largest commercial aircraft. These massive dynamical systems present unique challenges at scales unparalleled in prior applications of wind science research. Fundamental to this effort is the understanding of the wind turbine wake and its evolution. Furthermore, the optimization of the entire wind farm depends on the evolution of the wakes of …


Data Encoding For Healthcare Data Democratization And Information Leakage Prevention, Anshul Thakur, Tingting Zhu, Vinayak Abrol, Jacob Armstrong, Yujiang Wang, David A Clifton Feb 2024

Data Encoding For Healthcare Data Democratization And Information Leakage Prevention, Anshul Thakur, Tingting Zhu, Vinayak Abrol, Jacob Armstrong, Yujiang Wang, David A Clifton

Faculty, Staff and Student Publications

The lack of data democratization and information leakage from trained models hinder the development and acceptance of robust deep learning-based healthcare solutions. This paper argues that irreversible data encoding can provide an effective solution to achieve data democratization without violating the privacy constraints imposed on healthcare data and clinical models. An ideal encoding framework transforms the data into a new space where it is imperceptible to a manual or computational inspection. However, encoded data should preserve the semantics of the original data such that deep learning models can be trained effectively. This paper hypothesizes the characteristics of the desired encoding …


Sustainable Bio-Based Solid Phase Extraction Adsorbent For The Determination Of Various Types Of Organic Compounds, Mustafa Zafer Ozel, James H. Clark, Avtar S. Matharu Feb 2024

Sustainable Bio-Based Solid Phase Extraction Adsorbent For The Determination Of Various Types Of Organic Compounds, Mustafa Zafer Ozel, James H. Clark, Avtar S. Matharu

Turkish Journal of Chemistry

A sustainable, bio-based, mesoporous material, Starbon A800, was explored for use as an adsorbent in solid phase extraction (SPE). A solution containing seven nitrosamines was first used as a standard to optimise conditions for extraction efficiency with Starbon A800. After optimising conditions, 25 compounds of varying polarity (terpenes, phenolics, pesticides, PAHs, amines, and nitrosamines) were extracted with SPE using either Starbon® A800, C18 or Porous Graphitic Carbon (PGC) as the adsorbent, for comparison purposes. At the same time, 3 different elution solvents (heptane, dichloromethane, and ethanol) were used for each type of adsorbent. Hansen solubility parameters can be used to …


Hydroxyl- Terminated Dendrimers With Sulfonimide Linkers As Binders For Metals Of Industrial Significance, Khaleel Abu Sbeih, Mohammad Al Harahsheh Feb 2024

Hydroxyl- Terminated Dendrimers With Sulfonimide Linkers As Binders For Metals Of Industrial Significance, Khaleel Abu Sbeih, Mohammad Al Harahsheh

Turkish Journal of Chemistry

First- and second-generation hydroxyl- terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe3+, Al3+, and UO22+ separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe3+ selectively from mixtures with Al3+.


Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan Feb 2024

Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan

Turkish Journal of Chemistry

Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd2+ ions using NaBH4 as reducing agent. The Pd/La2O3 displayed good catalytic activity in H2(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La2O3 was found to be an active catalyst procuring three equiv. H2(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La2O3. Moreover, Pd/La2O3 with various Pd loadings were prepared and tested as …