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Transferred Benefits In Inter-Community Beach Nourishment: A Field Study On Efficiency, Owen Thomas Aug 2024

Transferred Benefits In Inter-Community Beach Nourishment: A Field Study On Efficiency, Owen Thomas

Theses, Dissertations and Culminating Projects

To combat the effects of relative sea level rise and the natural erosional processes affecting the sandy, diffusive beaches of New Jersey, most communities utilize beach nourishment to stabilize their beaches. Beach nourishment, the practice of artificially widening the beach berm with sand from other areas, not only stabilizes beaches but also protects oceanfront homes from storm surges, while adding recreational space and tourism value. These benefits are reflected in increased property values, most notably in oceanfront properties. The diffusive nature of these beaches, however, means that individual nourishment events are inherently shared with neighboring communities as sand is readily …


Evolving Teacher Pedagogy Through Implementation Of Mathematical Modeling And Participation In Responsively Designed Professional Development, Geena Taite Aug 2024

Evolving Teacher Pedagogy Through Implementation Of Mathematical Modeling And Participation In Responsively Designed Professional Development, Geena Taite

Theses, Dissertations and Culminating Projects

Modeling with mathematics (MP4) is a mathematical practice standard that can be used to engage students in mathematical content standards as well as additional mathematical practice standards. Research has shown the benefits of mathematical modeling (e.g., Aguirre et al., 2019; Cirillo et al., 2016a), but also the challenges teachers can face implementing modeling (e.g., Asempapa & Sturgill, 2019; Manouchehri, 2017). This dissertation aimed to explore how mathematical modeling professional development was responsively designed and facilitated to support teachers’ pedagogical goals (RQ1). This dissertation also aimed to explore how my role as the designer and facilitator of professional development evolved (RQ2) …


An Interdisciplinary Analysis Of Freshwater Wetlands With A Focus On Ecosystem Functions And Services, Michael Viteritto Aug 2024

An Interdisciplinary Analysis Of Freshwater Wetlands With A Focus On Ecosystem Functions And Services, Michael Viteritto

Theses, Dissertations and Culminating Projects

Wetlands are one of the most productive ecosystems on Earth, though they only occupy a very small portion of the planet’s surface. They are highly sensitive ecosystems that have been undergoing an extended period of loss because of anthropogenic stress. Freshwater wetlands number among the most numerous on the planet, and in the United States they make up the overwhelming majority of wetland area. Geographically isolated wetlands (GIWs) are not directly connected to other surface water in a watershed. Freshwater wetlands provide a number of beneficial ecosystem services including climate control, erosion protection, nutrient removal and storage, flood control, food …


Onset Of Antarctic Glaciation At The Eocene-Oligocene Transition In The Weddell Sea And Its Impact On Ocean Circulation, Victoria Hojnacki Aug 2024

Onset Of Antarctic Glaciation At The Eocene-Oligocene Transition In The Weddell Sea And Its Impact On Ocean Circulation, Victoria Hojnacki

Theses, Dissertations and Culminating Projects

The Eocene – Oligocene Transition (EOT) (34 Ma) represents a greenhouse to icehouse climate transition that is marked by the appearance of permanent ice sheets in Antarctica. Studying this period of climate change allows us to understand how different Earth systems reacted under changing atmospheric CO₂ conditions. Though the timing of the development of the East Antarctic Ice Sheet is well supported, the development of the West Antarctic Ice Sheet is still up for debate. Ocean Drilling Program Site 696 is the only paleoarchive of the EOT in the Weddell Sea region and offers an opportunity to better constrain the …


The Roughrider Carbon Storage Hub, University Of North Dakota. Energy And Environmental Research Center Aug 2024

The Roughrider Carbon Storage Hub, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet regarding the Roughrider Carbon Storage Hub, a CarbonSAFE project. The Roughrider Carbon Storage Hub project is investigating the feasibility of safe, permanent storage of CO2 in McKenzie County, North Dakota.


Adding To The Efficacy Of Cover, Copy, Compare For Improving Single-Digit Multiplication Fluency And Supporting Classwide Intervention Differentiation, Erika Korzeniewski Aug 2024

Adding To The Efficacy Of Cover, Copy, Compare For Improving Single-Digit Multiplication Fluency And Supporting Classwide Intervention Differentiation, Erika Korzeniewski

Legacy Theses & Dissertations (2009 - 2024)

Cover, Copy, Compare (CCC) has been shown to be an effective intervention at improving single-digit multiplication fluency within the academic intervention literature. The application of the three-term contingency trial embedded within CCC provides the intervention with several key components of evidence-based interventions. Given that teachers across the nation are struggling to find resources to meet current deficits in student mathematics skills, the current study aimed to address this issue by investigating two versions of CCC: Traditional- CCC (T-CCC) and CCC- Answer Only (CCC-AO) through an instructional hierarchy paradigm. The study hypothesized that both T-CCC and CCC-AO would be more effective …


Wii Need Clarity: A Proposed Federal Amendment To Trademark Confusion Tests Through The Lens Of Esports And Electronic Word Marks, Patrick K. Doll Aug 2024

Wii Need Clarity: A Proposed Federal Amendment To Trademark Confusion Tests Through The Lens Of Esports And Electronic Word Marks, Patrick K. Doll

Marquette Sports Law Review

No abstract provided.


Palynostratigraphy And Bayesian Age Stratigraphic Model Of New Ca-Id-Tims Zircon Ages From The Walloon Coal Measures, Surat Basin, Australia, K. Sobczak, J. Cooling, T. Crossingham, H. G. Holl, M. Reilly, J. Esterle, J. L. Crowley, C. Hannaford, M. T. Mohr, Z. Hamerli, S. Hurter Aug 2024

Palynostratigraphy And Bayesian Age Stratigraphic Model Of New Ca-Id-Tims Zircon Ages From The Walloon Coal Measures, Surat Basin, Australia, K. Sobczak, J. Cooling, T. Crossingham, H. G. Holl, M. Reilly, J. Esterle, J. L. Crowley, C. Hannaford, M. T. Mohr, Z. Hamerli, S. Hurter

Geosciences Faculty Publications and Presentations

The Surat Basin hosts significant coal and coal seam gas resources. New high-precision CA-TIMS U/Pb zircon ages from tuffs and Bayesian age stratigraphic models are combined with palynology from fine-grained sedimentary rocks and zircon trace elements to provide further chronostratigraphic and biostratigraphic constrains on the Walloon Coal Measures in the eastern margin of the Surat Basin and infer the palaeoenvironment and tectonic setting. The tuff ages range from 165.88 ± 0.11 Ma to 158.84 ± 0.05 Ma, with those from the stratigraphically lower Taroom Coal Measures ranging from 165.88 ± 0.11 to 163.05 ± 0.08 Ma and Juandah Coal Measures …


Engineering The Properties Of Magnesium Aluminate Spinel Through Solid State Solutions, Robin Conner Aug 2024

Engineering The Properties Of Magnesium Aluminate Spinel Through Solid State Solutions, Robin Conner

All Theses

Magnesium aluminate spinel solid state solutions were prepared via the coprecipitation method and calcined in air at 900 °C for 2 h. The manipulation of magnesium aluminate spinel’s microstructure through the formation of solid state solutions with zinc and gadolinium substituting for magnesium was investigated. X-ray diffraction (XRD) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR) confirmed the formation of a single cubic crystalline phase. The luminescence properties were investigated by radioluminescence (RL) under X-ray excitation and thermoluminescence (TL) measurements. In the case of zinc, all concentrations of the solid state solutions showed similar luminescence with bands at …


Structure-Function Relationships In Neurodegenerative And Infectious Diseases: Biophysical Characterization Of Rna Secondary Structures By Computational Techniques, Kendy Guarinoni Aug 2024

Structure-Function Relationships In Neurodegenerative And Infectious Diseases: Biophysical Characterization Of Rna Secondary Structures By Computational Techniques, Kendy Guarinoni

Electronic Theses and Dissertations

The research described in this dissertation focuses on the investigation of the structure and dynamics of regions of RNA implicated in two diseases: COVID-19 and amyotrophic lateral sclerosis/frontotemporal dementia (ALS/FTD). Both studies sought to create experimentally corroborated models that were used to characterize the structure and dynamics of the C9orf72 repeat expansion and the s2m region in coronaviruses, respectively and provided the foundation for future work. In our work involving the s2m region of SARS-CoV-2, the virus responsible for COVID-19, we determined that the homology modeling approach commonly used to derive atomistic structures when no coordinates are available yields a …


"Wait, Watch This....What Do You See?": Conceptualizing Mentor Practice In The Context Of A Video Club For Induction Mentors, Victor Vega Aug 2024

"Wait, Watch This....What Do You See?": Conceptualizing Mentor Practice In The Context Of A Video Club For Induction Mentors, Victor Vega

Education (PhD) Dissertations

Due to current teacher shortages, there is renewed interest in mentoring beginning teachers for induction. Induction is an intellectually rigorous process of enculturating novice teachers into the professional teaching community (Carver-Thomas et al., 2020). Induction programs build on novice teachers’ experiences in university teacher preparation programs by providing intensive mentor support (Commission on Teacher Credentialing, 2016). Induction programs are required to establish robust mentoring systems, which include training and meaningful support for mentors. This study examined how a video club model (van Es & Sherin, 2004) supported induction mentors in their professional learning. Understanding mentor professional learning in the context …


Public School And District Leaders’ Understanding Of Cybersecurity Practices And Policies, Jaye-Jaye Johnson Aug 2024

Public School And District Leaders’ Understanding Of Cybersecurity Practices And Policies, Jaye-Jaye Johnson

Walden Dissertations and Doctoral Studies

Educational technology (EdTech) interoperability throughout cyberspace provides the financial opportunity for collecting and selling of student privacy information. The research problem addressed throughout this study is the public school district leaders' (SDLs) understanding of EdTech cyber security practices and policies (EdTechCSPP). Little is known regarding SDLs’ understanding of EdTechCSPP in schools because of oblique EdTech business practices. The purpose of this quantitative study was to determine differences in SDLs’ EdTechCSPP response scores between independent variables (IV) of SDLs’ gender, educational achievements, age ranges, or types of school districts. The theoretical framework was based on Nissenbaum’s contextual integrity theory. Four research …


Impact Of Teacher Support Systems On Advanced Placement Achievement Outcomes, Yolanda Gomez Aug 2024

Impact Of Teacher Support Systems On Advanced Placement Achievement Outcomes, Yolanda Gomez

Education Theses and Dissertations

In the realm of Advanced Placement (AP) education, a persistent achievement gap exists, with low-socioeconomic students consistently underperforming compared to their affluent peers. This disparity is particularly notable in AP English Language and Composition, where 93% of students fail to achieve a score of three or higher, the score for earning college credit. This study hypothesizes that this gap is partly due to inadequate support for AP teachers, particularly the lack of collaborative planning time. In most high schools, AP English Language and Composition teachers have no dedicated time for collaboration, instead focusing on other areas like End of Course …


Impact Of Pre-Harvest Fungicide Application On The Storage Performance Of Tomato Fruits, Zhifu Lan, Jing Huang, Komivi S. Akutse, Yongwen Lin Aug 2024

Impact Of Pre-Harvest Fungicide Application On The Storage Performance Of Tomato Fruits, Zhifu Lan, Jing Huang, Komivi S. Akutse, Yongwen Lin

All Peer-Reviewed Publications

To examine the impact of pre-harvest fungicide applications on the postharvest storage performance of tomato fruits, we measured the lycopene content, hardness, soluble solids content, rotting rate, and weight loss rate of the fruits, as well as conducted a sensory assessment. Protective and systematic fungicides were sprayed on tomatoes 20 days before harvest in order to prevent rotting and weight loss during storage. Our findings showed that, the fungicide-treated tomatoes had a significantly lower rotting rate of 16.00% and a weight loss rate of 3.96%. However the control group experienced 65.33% rotting rate and 6.90% weight loss rate on 12th …


Even Laypeople Use Legalese, Eric H. Martinez, Francis Mollica, Edward Gibson Aug 2024

Even Laypeople Use Legalese, Eric H. Martinez, Francis Mollica, Edward Gibson

Faculty Scholarship

Whereas principles of communicative efficiency and legal doctrine dictate that laws be comprehensible to the common world, empirical evidence suggests legal documents are largely incomprehensible to lawyers and laypeople alike. Here, a corpus analysis (n=59 million words) first replicated and extended prior work revealing laws to contain strikingly higher rates of complex syntactic structures relative to six baseline genres of English.

Next, two pre-registered text generation experiments (n=286) tested two leading hypotheses regarding how these complex structures enter into legal documents in the first place. In line with the magic spell hypothesis, we found people tasked with writing official laws …


I’M A Forest, Not A Saltmarsh, Captain: Carbon And Sap Flow Dynamics In Coastal Forested Wetlands Of The Southeastern United States, Chris Shipway Aug 2024

I’M A Forest, Not A Saltmarsh, Captain: Carbon And Sap Flow Dynamics In Coastal Forested Wetlands Of The Southeastern United States, Chris Shipway

All Theses

Coastal forested wetlands are identified as some of the highest-priority ecosystems for climate change mitigation. Here, we present two studies conducted in these unique ecosystems.

The first assessed changes in aboveground vegetative C stocks along the estuarine-riverine gradients of the Winyah Bay in South Carolina and the Savannah River in Georgia, using a space-for-time substitution to increase understanding of the impacts to upper estuarine forested wetlands from relative sea level rise. Standing C stocks on the Savannah River averaged 183.6 Mg C ha-1, while sites on the Winyah system averaged 162.3 Mg C ha-1. The largest …


Investigations Of Sulfurized Polymers For Their Use In Lithium-Sulfur Cells, Alan M. Rowland Aug 2024

Investigations Of Sulfurized Polymers For Their Use In Lithium-Sulfur Cells, Alan M. Rowland

All Theses

With the invention of the Lithium-Ion cell in the latter half of the 20th century, there has been a continued endeavor for innovation in compact energy-storage. Combined with the ever-growing need to move away from fossil fuels, electrochemical energy storage has seen a myriad of research projects in the pursuit of finding the ‘beyond-lithium’ cell. One of these projects that I personally assisted with was lithium-sulfur cells, which allow for a significantly greater energy storage capacity when compared to lithium-ion cells. In investigating a popular cathode in lithium-sulfur cells, sulfurized polyacrylonitrile (SPAN), it was hinted that there may be more …


Unraveling Wetland Ecology: The Effect Of Abiotic Heterogeneity And Habitat Size On Wetland Plant Diversity In The Piedmont, Gregory T. Gilmore Aug 2024

Unraveling Wetland Ecology: The Effect Of Abiotic Heterogeneity And Habitat Size On Wetland Plant Diversity In The Piedmont, Gregory T. Gilmore

All Theses

Ecosystems around the world are seeing an unprecedented decline in biodiversity. However, to better prevent this decline we cannot only understand the drivers of biodiversity loss, but also the factors that support diversity. Traditional ecological hypotheses such as the Habitat Heterogeneity Hypothesis (HHH) and the Theory of Island Biogeography (TIB) have provided frameworks for understanding biodiversity drivers. However, recent research suggests a more nuanced relationship between heterogeneity, habitat size, and diversity than previously thought. This study looks to bridge existing research gaps by examining the ecologically and conservational important habitat of wetlands. Specifically, the study focuses on the plant diversity …


Silence In Stem? The Impact Of Experienced Social Identity Threats On Women, Madison Brumbaugh Aug 2024

Silence In Stem? The Impact Of Experienced Social Identity Threats On Women, Madison Brumbaugh

All Theses

Despite making up a similar proportion of the workforce, women are grossly underrepresented in STEM occupations compared to men (65% vs. 35%). Prior research suggests that women’s underrepresentation in STEM results in negative consequences, such as increased psychological burnout and decreased work engagement (Hall et al., 2015; Hall et al., 2018), through the mechanism of social identity threat. Academics have yet to explore how experiencing social identity threat impacts silence behaviors for underrepresented women in STEM. Building off social identity theory and prior research on social identity threat, the current study sought to compare women working in STEM occupations who …


Caught On Camera: Evaluating Wood Duck (Aix Sponsa) Cavity Occurrence And Trapping Efficiency, Cindy L. Von Haugg Aug 2024

Caught On Camera: Evaluating Wood Duck (Aix Sponsa) Cavity Occurrence And Trapping Efficiency, Cindy L. Von Haugg

All Theses

Wood ducks (Aix sponsa) garner significant ecologic and economic importance as the second most harvested waterfowl species in two of the four migratory flyways in North America, but the accuracy of population monitoring, relative to other duck species, is stifled by the wood duck’s secretive nature and nesting habitat. As an alternate, population models would improve current assessments, but more data on the demographic vital rates of cavity-nesting wood ducks is needed. I aimed to help bridge this knowledge gap by developing a method to increase data collection efficiency, and with it, accomplish two objectives: 1) Calculate the relative abundance …


Evaluation Of Future Sea-Level Impacts Using A Sharp Interface Saltwater Intrusion Model, Caroline Hiott Aug 2024

Evaluation Of Future Sea-Level Impacts Using A Sharp Interface Saltwater Intrusion Model, Caroline Hiott

All Theses

Saltwater intrusion is a growing problem that is being exacerbated by climate change. Saltwater intrusion is the process by which saltwater moves towards freshwater supplies driven by saltwater’s greater density compared to freshwater. Saltwater intrusion can contribute to the salinization of freshwater resources, degradation of underground storage tanks, communication systems, and pipelines, as well as lead to groundwater flooding (Ketabchi et al., 2016). Numerical modeling can be used to simulate saltwater intrusion along coastal areas. One of the more computationally efficient modeling tools is the sharp interface approach, SWI2, that is a part of the MODFLOW 2005 suite (Werner et …


High-Resolution Ion Mobility Analysis Of Isomeric Bile Acids Using Structures For Lossless Ion Manipulations (Slim) Im-Ms, Emmaleigh D. Efird Aug 2024

High-Resolution Ion Mobility Analysis Of Isomeric Bile Acids Using Structures For Lossless Ion Manipulations (Slim) Im-Ms, Emmaleigh D. Efird

All Theses

Bile acids are an essential part of the human digestion system and play an important role in lipid absorption, bacteria movement in the small intestine, and regulation of the farnesoid X receptor (FXR) and G protein-coupled bile acid receptors (GPBAR) responsible for homeostasis. They are synthesized in the liver, stored in the gallbladder and the excess is carried on to the small intestine. Many liver and intestinal diseases are diagnosed based on bile acid metabolism pathways and the structures of those bile acids. Therefore, the bile acid structure determines the function of the molecule. Many bile acids are similar in …


Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, Cooper L. Tillman Aug 2024

Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, Cooper L. Tillman

All Theses

This work successfully demonstrates solvent extraction methods for separation of oil from the by-products when two commercially available vacuum pump oils were exposed to an intense neutron and gamma-ray radiation environment. Nuclear fusion power at a commercial scale has accelerated the need for radiation resistant vacuum technology, such as oil-based diffusion pumps. Polyphenyl ether and aromatic silicone oils were irradiated at the Rhode Island Nuclear Science Center (RINSC) up to MGy absorbed doses with neutron and gamma-ray radiation. Solvent extractions were performed using hexane and isopropanol to characterize the oil extraction as a function of total absorbed dose. The by-products …


Using Efficient Vision Transformers To Improve Perception Systems In Autonomous Off-Road Vehicles, Adam S. Pickeral Aug 2024

Using Efficient Vision Transformers To Improve Perception Systems In Autonomous Off-Road Vehicles, Adam S. Pickeral

All Theses

The development of autonomous vehicles has become one of the greatest research endeavors in recent years. These vehicles rely on many complex systems working in tandem to make decisions. For practical use and safety reasons, these systems must not only be accurate, but also be quick to make decisions. In Autonomous Vehicle research, the environment perception system is one of the key com- ponents of development. The environment perception system allows the vehicle to understand its surroundings using cameras, light detection and ranging (LiDAR), and other sensor systems or modalities. Deep learning computer vision algorithms have shown to be the …


Chain-Of-Exemplar: Enhancing Distractor Generation For Multimodal Educational Question Generation, Haohao Luo, Yang Deng, Ying Shen, See-Kiong Ng, Tat-Seng Chua Aug 2024

Chain-Of-Exemplar: Enhancing Distractor Generation For Multimodal Educational Question Generation, Haohao Luo, Yang Deng, Ying Shen, See-Kiong Ng, Tat-Seng Chua

Research Collection School Of Computing and Information Systems

Multiple-choice questions (MCQs) are important in enhancing concept learning and student engagement for educational purposes. Despite the multimodal nature of educational content, current methods focus mainly on text-based inputs and often neglect the integration of visual information. In this work, we study the problem of multimodal educational question generation, which aims at generating subject-specific educational questions with plausible yet incorrect distractors based on multimodal educational content. To tackle this problem, we introduce a novel framework, named Chain-of-Exemplar (CoE), which utilizes multimodal large language models (MLLMs) with Chain-of-Thought reasoning to improve the generation of challenging distractors. Furthermore, CoE leverages three-stage contextualized …


Interpretable Tensor Fusion, Saurabh Varshneya, Antoine Ledent, Philipp Liznerski, Andriy Balinskyy, Purvanshi Mehta, Waleed Mustafa, Marius Kloft Aug 2024

Interpretable Tensor Fusion, Saurabh Varshneya, Antoine Ledent, Philipp Liznerski, Andriy Balinskyy, Purvanshi Mehta, Waleed Mustafa, Marius Kloft

Research Collection School Of Computing and Information Systems

Conventional machine learning methods are predominantly designed to predict outcomes based on a single data type. However, practical applications may encompass data of diverse types, such as text, images, and audio. We introduce interpretable tensor fusion (InTense), a multimodal learning method training a neural network to simultaneously learn multiple data representations and their interpretable fusion. InTense can separately capture both linear combinations and multiplicative interactions of the data types, thereby disentangling higher-order interactions from the individual effects of each modality. InTense provides interpretability out of the box by assigning relevance scores to modalities and their associations, respectively. The approach is …


Reachability-Aware Fair Influence Maximization, Wenyue Ma, Maximilian K. Egger, Andreas Pavlogiannis, Yuchen Li, Panagiotis Karras Aug 2024

Reachability-Aware Fair Influence Maximization, Wenyue Ma, Maximilian K. Egger, Andreas Pavlogiannis, Yuchen Li, Panagiotis Karras

Research Collection School Of Computing and Information Systems

How can we ensure that an information dissemination campaign reaches every corner of society and also achieves high overall reach? The problem of maximizing the spread of influence over a social network has commonly been considered with an aggregate objective. Less attention has been paid to achieving equality of opportunity, reducing information barriers, and ensuring that everyone in the network has a fair chance to be reached. To that end, the fairness objective aims to maximize the minimum probability of reaching an individual. To address this inapproximable problem, past research has proposed heuristics, which, however, perform less well when the …


Understanding And Tuning Magnetism In Van Der Waals-Type Metal Thiophosphates, Rabindra Basnet, Jin Hu Aug 2024

Understanding And Tuning Magnetism In Van Der Waals-Type Metal Thiophosphates, Rabindra Basnet, Jin Hu

Physics Faculty Publications and Presentations

Over the past two decades, significant progress in two-dimensional (2D) materials has invigorated research in condensed matter and material physics in low dimensions. While traditionally studied in three-dimensional systems, magnetism has now been extended to the 2D realm. Recent breakthroughs in 2D magnetism have attracted substantial interest from the scientific community, owing to the stable magnetic order achievable in atomically thin layers of the van der Waals (vdW)-type layered magnetic materials. These advances offer an exciting platform for investigating related phenomena in low dimensions and hold promise for spintronic applications. Consequently, vdW magnetic materials with tunable magnetism have attracted significant …


Crystal Structure Of A Tris-(2-Aminoethyl)Methane Capped Carbamoylmethylphosphine Oxide Compound, Brandon G. Wackerle, Eric J. Werner, Richard J. Staples, Shannon Biros Aug 2024

Crystal Structure Of A Tris-(2-Aminoethyl)Methane Capped Carbamoylmethylphosphine Oxide Compound, Brandon G. Wackerle, Eric J. Werner, Richard J. Staples, Shannon Biros

Open Access Publishing Support Funded Articles

The mol­ecular structure of the tripodal carbamoyl­methyl­phosphine oxide compound diethyl {[(5-[2-(di­eth­oxy­phosphor­yl)acetamido]-3-{2-[2-(di­eth­oxy­phos­phor­yl)acetamido]­eth­yl}pent­yl)carbamo­yl]meth­yl}phospho­nate, C25H52N3O12P3, features six intra­molecular hydrogen-bonding inter­actions. The phospho­nate groups have key bond lengths ranging from 1.4696 (12) to 1.4729 (12) Å (P=O), 1.5681 (11) to 1.5811 (12) Å (P—O) and 1.7881 (16) to 1.7936 (16) Å (P—C). Each amide group adopts a nearly perfect trans geometry, and the geometry around each phophorus atom resembles a slightly distorted tetra­hedron.


Rotational State-To-State Transition Rate Coefficients For H2O + H2O Collisions At Nonequilibrium Conditions, Bikramaditya Mandal, Michal Zoltowski, Martin Cordiner, François Lique, Dmitri Babikov Aug 2024

Rotational State-To-State Transition Rate Coefficients For H2O + H2O Collisions At Nonequilibrium Conditions, Bikramaditya Mandal, Michal Zoltowski, Martin Cordiner, François Lique, Dmitri Babikov

Chemistry Faculty Research and Publications

Aims. The goal is to develop a database of rate coefficients for rotational state-to-state transitions in H2O + H2O collisions that is suitable for the modeling of energy transfer in nonequilibrium conditions, in which the distribution of rotational states of H2O deviates from local thermodynamic equilibrium.

Methods. A two-temperature model was employed that assumed that although there is no equilibrium between all possible degrees of freedom in the system, the translational and rotational degrees of freedom can be expected to achieve their own equilibria independently, and that they can be approximately characterized by Boltzmann …