Digital Commons Network^™

The Evolution Of Global Gold And Copper Trade Networks, Oleksandr Hulianskyi

Northeast Journal of Complex Systems (NEJCS)

Gold and copper have emerged as two of the most vital commodities in global trade. Despite serving distinct purposes, their international trade networks reveal interconnected patterns, critical to understanding the dynamics of global economics. This paper studies these attributes and their evolution during the last 36 years for both metals and finds correlations between them. The first part of the research is focused on the sustainability of networks through efficiency and robustness indexes; the second part is dedicated to interconnectedness – the Louvain and Bayesian SBM algorithms, partition, and modularity instruments are used. Community detection algorithms provide valuable insights into …

Exploring The Potential Of Large Language Models (Llms) To Simulate Social Group Dynamics: A Case Study Using The Board Game "Secret Hitler", Kaj Hansteen Izora, Christof Teuscher

Northeast Journal of Complex Systems (NEJCS)

This study explores the capacity of large language model-powered agents to simulate human-like behavior in multi-agent social systems. Using Secret Hitler — a hidden-role board game centered on trust, deception, and strategic communication — we evaluate how LLM agents navigate dynamic group interactions. Our findings show that agents exhibit human-like behaviors, including strategic temporal adaptation, contextual reasoning, and complex social cognition such as theory of mind and implicit coordination. Notably, 85% of agent decisions factored in at least two other players’ mental states, highlighting their capacity for multi-agent mental state inference. However, they struggled with key aspects of human gameplay, …

Alternate Form Reliability Of Nine Possible Four-Subtest Combinations Of The Cognitive Proficiency Index For The Wechsler Adult Intelligence Scale-Iv (Wais-Iv) In A Clinical Sample, Joseph J. Ryan, David S. Kreiner, Charles Golden, Gordon Teichner, Samuel T. Gontkovsky

Archives of Assessment Psychology

Performance on the core working memory (Digit Span + Arithmetic) and processing speed (Coding + Symbol Search) subtests of the WAIS-IV is summarized by the Cognitive Proficiency Index (CPI). If a working memory subtest is spoiled, Letter-Number Sequencing is substituted. An invalidated processing speed subtest is replaced by Cancellation. These tasks are supplementary. The core and supplementary subtests yield nine four-subtest composites. Using the standardization sample, Campbell, Rossini, and Johnson (2022) demonstrated that all CPI tetrads had excellent alternate form reliability. In the present study, a clinical sample (n = 90) produced equally high reliabilities. Four of the new …

7 Questions With Dr. Bear Jiang, University Of Dayton

Blog: The Dayton Engineer

We sat down with Dr. Bear Jiang, post-doc to tenure track fellow in the Department of Civil and Environmental Engineering and Engineering Mechanics, to learn more about his career and research.

Enhanced And Proficient Chitosan Membranes Embedded With Polyaniline-Tio2 Core-Shell Nanocomposites For Fuel-Cell Hydrogen Storage, Mallikarjunagouda Patil, Sridhar N. Mathad, Arun Y. Patil, Abdulaziz Abdulah Al-Kheraif, Sachin Naik, Sajith Vellapally

Turkish Journal of Chemistry

This study investigates the preparation and properties of aniline polymerized in situ onto a nanosized TiO2 surface to form core-shell nanoparticles at ambient temperatures. The in situ polymerization of aniline to polyaniline (PANI), in conjunction with the utilization of an anionic surfactant, was employed in this investigation. The prepared PANI-TiO2 core-shell nanoparticles were integrated with chitosan at a gravimetric ratio and cast as core-shell nanocomposite membranes. The nanocomposites were subjected to structural analysis using Fourier transform infrared spectroscopy and X-ray diffraction patterns. The surface morphologies of the PANI and its nanocomposites were analyzed using scanning electron microscopy. Direct current conductivity …

1,3,4-Thiadiazole Derivatives As Pi3ks Inhibitor: Design, In Silico Studies, Synthesis, Characterization, And Antimicrobial Evaluation, Dharmvir Singh, Pankaj Kumar, Anoop Kumar, Vivek V. Bhosale, Kalicharan Sharma, Deepak Kumar, Ramchander Khatri, Tanuj Hooda, Amit Lather

Turkish Journal of Chemistry

Since PI3Ks are targeted by a variety of bacterial pathogens, they represent a promising target for host-directed immune therapy and may be beneficial in managing persistent bacterial infections. In the present study, computational studies of 5-(pyridin-4-yl)-1,3,4-thiadiazol-2-amine derivatives for phosphoinositide-3-kinases (PI3Ks) inhibitors were carried out using dock scores, Glide scores, and the MMGBSA dG method, with comparison to standard drugs (ofloxacin and fluconazole). A series of 5-(pyridin-4-yl)-1,3,4-thiadiazol-2-amine derivatives (D1-D17) were synthesized and evaluated for their in vitro antimicrobial activity against both gram-positive and gram-negative bacterial strains, as well as fungal strains, using the tube dilution method. The synthesized compounds were characterized …

A Single Batch Synthesis Of Pure Phase Mo2c From Ammonium Molybdate: Pathway And Properties, Melek Cumbul Altay

Turkish Journal of Chemistry

This study presents an original, effective, and environmentally friendly method for synthesizing pure molybdenum carbide (Mo2C) from ammonium molybdate tetrahydrate (AMT) without generating carbon dioxide, a greenhouse gas. The process involves the sequential transformation of AMT to Mo2C, which follows the reaction pathway of (NH4)6Mo7O24→MoO3→MoO2→Mo→Mo2C. This transformation is achieved by strategically altering the gas atmosphere, switching from Ar to H2 at 800 K and then from H2 to CH4 at 1000 K. Thermal analysis, X-ray diffraction (XRD), and scanning electron microscopy (SEM) techniques were used to characterize AMT and the products. Mass measurements were used to follow the conversion of …

Common Fixed Points Results For Three Mappings Under Generalized Contraction Of Suzuki-Type In Ƀ-Metric Spaces With Application, Surjeet Singh Chauhan Gonder, Manju Devi, Manish Jain, Mohammad Sajid

Baghdad Science Journal

Suzuki used a brilliant strategy in his seminal publications to expand the Banach contraction theorem (BCT). This has undergone numerous intriguing generalizations and extensions during the past few decades and led to a new trend of coincidence and fixed points for countless Suzuki-type contractive and non-expansive maps in the various spaces. In this article, in the setup of ƀ-metric spaces, the aim is to produce a common fixed point of three mappings subjected to a generalized contraction of the Suzuki type. The present work generalizes well- known results of Suzuki, Chandra et al., Roshan et al. and several other results …

Tweaking Ml-Kem (Kyber) And Ml-Dsa (Dilithium), Kumar Rahul

Master’s Dissertations

Lattice-based cryptography is the use of conjectured hard problems on point lattices in Rn as the foundation for secure cryptographic systems. Attractive features of lattice cryptography include apparent resistance to quantum attacks (in contrast with most number-theoretic cryptography), high asymptotic efficiency and parallelism, security under worst-case intractability assumptions, and solutions to long-standing open problems in cryptography. This work surveys the structure, security, and optimization potential of two leading lattice-based cryptographic schemes: ML-KEM (Kyber) and ML-DSA (Dilithium). Special attention is given to their applicability in government-oriented post-quantum cryptographic systems, focusing on performance, implementation considerations, and resilience against known quantum threats. In …

Effective Strategies For Empowering Women In Aerospace: Shaping The Future Of Leadership, Mariel R. Forster

Walden Dissertations and Doctoral Studies

Some aerospace leaders face challenges in implementing effective strategies to advance women in leadership roles in the industry. Executive leaders are concerned with the lack of strategies to retain women, which contributes to their underrepresentation in aerospace leadership. Grounded in transformational leadership theory, the purpose of this qualitative pragmatic inquiry was to explore the strategies aerospace leaders use to advance women in aerospace leadership. The participants were seven aerospace leaders from the Southeastern United States who had implemented successful retention strategies. Data were collected through semistructured interviews and a review of public documents. Through thematic analysis eight themes were identified: …

A Two-Phase Service Access Beside Retrial Queues, Orbit Mechanism, Working Vacation Policies For Single Server Environments, Bharathy S, M.C. Saravanarajan

Baghdad Science Journal

This paper analyzes the M/G (P1, P2)/1 queue using a single server that provides essential services in both the first phase (FPS) and the second phase (SPS). It was assumed that the server undertakes unreliability due to starting failure (SF) during the beginning of the first phase with probability (α) or service begins by the idle server successfully with probability (1-α) for the arriving or retrial customer. Then immediately took the failed server for repair and launched the customer into orbit. Also, the server operates at varying rates instead of fully ceasing service during its vacation. …

Inverse Problem Of Class Of Delay Differential Equations And Fast Estimation Of Parameters, Ibrahim Makki Khalil, Jehan Mohammed Khudhir

Baghdad Science Journal

This article introduces an integral representation formula to solve delay nonlinear ordinary differential equations (DDEs) as an improvment to the method proposed by Tyukin I, et al. of solving a class of ordinary differential equations. The integral formula depends on the parameters of the systems explicitly as nonlinear parameterized computable functions. It features both linear and nonlinear equations and show an effective form for estimating unknown parameters. Solutions of DDEs are represented as sums of computable integrals which are implicitly dependent on the initial condition and the unknown parameters. This allows invoking parallel computational streams using Matlab tools of sums …

Numerical Solution Of Distributed Order Fractional Differential Equations Using Spectral Mittag-Leffler Weight Function Based On Chelyshkov Polynomials, Abdulrazzaq T. Abed, Ekhlass S. Al-Rawi

Baghdad Science Journal

In many studies, spectral methods based on one of the orthogonal polynomials and weighted residual methods (WRMs) have been used to convert the distributed-order fractional differential equation (DOFDEs) into a system of linear or nonlinear algebraic equations, and then solve this system to obtain the approximate solution. In this paper, a numerical method is presented for solving DOFDEs. The approximate solution is imposed as an orthogonal Chelyshkov polynomial with unknown coefficients. The required coefficients are obtained using WRMs, which transform the DOFDEs into a system of algebraic coefficients. The Mittag-Leffler function is proposed as a suitable weight function. The method …

Mostly Oscillation For A System Of Half Linear Neutral Differential Equations Of The Second Order With Several Arguments, Noor Abdulamer Abdulkarem, Taghreed Hussein Abed, Farah Abdulameer Abdulkareem, Hussain Ali Mohamad

Baghdad Science Journal

This paper studies the oscillation properties and asymptotic behavior of all solutions of the 2×2 system of second-order half-linear neutral differential equations. Four results are obtained in this research. The first and second results are auxiliary results while the third and fourth results are main results. All possible cases of non-oscillating bounded solutions for this system are estimated and analyzed. It is noted that the parameters that affect the volatility of the solutions are Qi,Ri on the one hand and r1 and r2 on the other hand. For this purpose, and through investigation, it is shown that there are only …

Improving Golden Eagle Optimization Algorithm Through Using Wavelet Mutation, Ebtehal Talib, Abeer Salim Jamil, Nidaa Flaih Hassan

Baghdad Science Journal

The Golden Eagle Optimization (GEO) algorithm is another amazing nature inspired optimization algorithm based on the foraging behavior of the Golden Eagles. GEO is an excellent behavioral model of how Golden Eagles interact with one another while searching for prey, consisting of a population of virtual “eagles” that together represent potential solutions to the optimization problem. The “eagles” interact with one another and together communicate and move as a single unit towards something, in this case the optimal solution. In this paper, we expand upon this idea with a new version of the GEO algorithm, called Wavelet Mutation Golden Eagle …

Cancer Detection Framework Using Cellular Automata Based Segmentation And Deep Learning, Rupashri Barik, Nazma B J Naskar, Aleena Swetapadma

Baghdad Science Journal

Image processing plays vital role in medical sciences. Medical image processing reduces diagnosis time and cost. Early detection of cancer may reduce life risk. Earlier works on cancer detection mostly focused on specific organs and imaging modalities. This work aims a generalized framework for detecting tumors in various organs by analyzing different imaging modalities. Here, Cellular Automata helps in image segmentation through region growing, and deep learning algorithms made performance analysis in terms of accuracy and loss. Analyzing CT-Scan, MRI images of brain, breast, lungs, the proposed framework may assist to detect the region of mass being developed. Proposed CA-based …

Accelerating Face Mask Detection Training Model Based On Multi-Gpus And Multi-Core Cpu, Ammar Hussein Jassim, Nada Hussain Ali, Ahmed Al-Taie, Doaa Mohammad Majed

Baghdad Science Journal

Modern machine-learning applications require GPUs, and modern platforms can leverage numerous GPUs on one or more machines to increase performance. Contemporary deep-learning models are too huge for CPU or GPU training. Training these models with many GPUs without performance degradation is necessary to train them rapidly and maximize GPU consumption. Thus, training deep convolutional neural networks (DCNN) with multiple GPUs has become necessary for improving training. Therefore, we presented a parallel design and development of an efficient model for enhancing face mask CNN performance and improving resource efficiency. This DCNN model is a parallel training system over multiple GPUs, a …

Assessing The Effects Of Design Modifications On The Use Of Wildlife Exits Designed For Endangered Texas Ocelots, Rupesh Maharjan, Jamie E. Langbein, John H. Young, Kevin W. Ryer, Alejandro Fierro-Cabo, Md Saydur Rahman, Richard Kline

School of Earth, Environmental, & Marine Sciences Faculty Publications

Roadside exclusionary fencing is commonly used on highways to prevent wildlife-vehicle collisions. Although it can mitigate wildlife road mortality by limiting their access to the road, it can also create a barrier for wildlife stranded within the right-of-way. On State Highway 100 in Texas, the Texas Department of Transportation installed 10 wildlife exits (WEs) to allow endangered ocelots and other wildlife to escape the fenced roadway and minimize wildlife-vehicle collisions. Our study compared three types of WE designs within the same area from 2019 to 2024 to assess their effectiveness. The first design (Design A) was without a door and …

Pyrene-Based Hole Transport Materials For Efficient Perovskite Solar Cells, Madiha Irfan, Aamer Saeed, Sania Tahir, Muhammad Rehman Yaqoob, Sohaib Ahmed Zia, Muhammad Usama, Junaid Mukhtar, Usama Farrukh, Sara Rehman

Turkish Journal of Chemistry

In the past few years, perovskite solar cells (PSCs) have gained a lot of attention and become a well-known topic in solar studies due to their lower manufacturing costs and improved efficiencies. Previously utilized hole transport materials (HTMs), such as poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] and 2,2ʹ,7,7ʹ-tetrakis(N,N-di-p-methoxyphenylamine)-9,9ʹ-spirobifluorene, are challenging due to their high price, complicated synthesis, limited carrier mobility, and poor device stability. Developing HTMs for PSCs that are inexpensive and high-performance has gained much interest. Currently, many HTMs of organic molecules are used to improve photovoltaic qualities and reduce synthesis costs. Effectively using HTMs is essential for producing the best photovoltaic efficiency in …

Determination Of Mitoxantrone In Environmental Waters: A Spectrophotometric Method With Preconcentration By Salt Saturated Pipette-Tip Micro Solid Phase Extraction Using Molecularly Imprinted Polymer, Sayyed Hossein Hashemi, Massoud Kaykhaii, Ahmad Jamali Keikha, Mina Esmailiun

Turkish Journal of Chemistry

In this research, a fast and simple spectrophotometric method is presented for mitoxantrone determination in various aqueous samples. It utilizes preconcentration by salt saturated pipette-tip micro solid phase extraction with a selective molecularly imprinted polymer adsorbent packed in a micropipette tip. Prior to sample loading, they were saturated with a mixture of NaCl, Mg (NO3)2.6H2O and KNO3 salts, enhancing extraction efficiency by 27.5% compared to salt-free conditions. Key microextraction parameters (amount of molecularly imprinted polymer, sample pH, eluent type/volume, and adsorption/desorption cycles) were optimized using response surface methodology and one-variable-at-a-time methods. The method achieves a low detection limit (0.2 μg …

Removal Of Heavy Metal Iron(Ii) Ions From Wastewater Using An Ultrasonic System With Climbazole-Alcohol, Melek Gökmen Karakaya, Bahdi̇şen Gezer, Abdullah Menzek, Özlem Gündoğdu Aytaç

Turkish Journal of Chemistry

Climbazole (CBZ) is an antifungal active pharmaceutical ingredient often used in antidandruff products. In this study, the ketone group in the racemic CBZ molecule was reduced to synthesize CBZ-alcohol, named 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-ol, and the optimum adsorption conditions were investigated for removing iron(II) (Fe2+) ions from wastewater by adsorption from aqueous solutions using the economical and environmentally friendly ultrasonic method. The parameters and levels used in the study were designed using response surface methodology and model equations were derived to optimize the results. The independent variables selected were the initial pH (1, 3, and 5), adsorption time (30, 45, and 60 min), …

Removal Of Ddt, Ddd, And Dde From Washing Extracts Of Contaminated Soil Using Polyaniline/Bagasse Composite Material, Hop Quang Nguyen, Bach Xuan Nguyen, Thien Quang Tran, Anh Van Nguyen

Turkish Journal of Chemistry

Polyaniline (PANi) was hybridized with a bagasse (BG) substrate to treat Dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethylene (DDE), and dichlorodiphenyldichloroethane compounds, which are persistent organic pollutants (POPs) causing environmental contamination. The PANi/bagasse (PA/BG) composite was synthesized using ammonium persulfate and sulfuric acid, achieving efficiencies ranging from 82.63% to 86.92% with different ratios of PANi monomer to BG. Infrared spectroscopy (IR) and scanning electron microscopy (SEM) were used to characterize the synthesized materials. The adsorption capacities of DDT, DDD, and DDE compounds were investigated under various conditions, including adsorbent type, adsorption time, adsorbent dosage, and adsorbate concentration. Both Langmuir and Freundlich isotherm models were …

Dispersive Micro Solid Phase Extraction Of Cadmium On Mil-53(Al)@Batio3 Nanocomposite From Seafood Samples, Mustafa Soylak, Eda Bora, Furkan Uzcan

Turkish Journal of Chemistry

This study’s main goal was to produce a user-friendly dispersive micro solid phase extraction (dmSPE) technique with a MIL-53(Al)@BaTiO3 nanocomposite for the extraction and preconcentration of cadmium (Cd) in various seafood matrices, followed by using high-resolution continuum source flame atomic absorption spectrometry (HR-CS-FAAS). The MIL-53(Al)@BaTiO3 nanocomposite was synthesized and characterized using a range of techniques, including Fourier-transform infrared spectroscopy, field emission scanning electron microscopy, scanning transmission electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller analysis. The dmSPE technique involved the dispersion of the MIL-53(Al)@BaTiO3 material in the sample solution, followed by its separation from the sample matrix. The optimized method exhibited a …

Pt-Enhanced Wo3 Nanoparticles For Efficient Hydrogen Production: Synthesis And Electrochemical Evaluation, Merve Akbayrak

Turkish Journal of Chemistry

In this study, Pt/WO3 nanoparticles were synthesized using a simple room-temperature impregnation-reduction method and characterized by advanced techniques including ICP, TEM-EDX, FE-SEM-EDX, and XRD. The ICP-OES analysis confirmed a 1.0 wt. %Pt loading on the WO3 support. TEM and FE-SEM analyses revealed that the Pt nanoparticles were well dispersed with an average size of approximately 3.7 nm. The XRD patterns showed characteristic WO3 peaks without any detectable Pt diffraction peaks, indicating the high dispersion of Pt. Electrochemical evaluations demonstrated that the Pt/WO3 catalyst exhibited outstanding hydrogen evolution reaction (HER) performance, with –27.8 mV vs. RHE onset potential and –37.4 mV …

Determination Of P53 Biomarker With A Smart Electrochemical Biosensor Based On Brush Polymer-Functionalized Disposable Electrode, Muhammet Aydin

Turkish Journal of Chemistry

A label-less impedimetric biosensor modified with poly(thiophene)-graft-poly(glycidyl methacrylate) polymer (PThi-g-PGM) was manufactured for p53 protein quantification in human serum samples. In this study, PThi-g-PGM polymer was synthesized, and this polymer matrix was coated using the spin-coating technique on the single-use indium tin oxide (ITO) substrate for anti-p53 antibody immobilization. The anti-p53 antibodies with high affinity for p53 proteins were covalently attached onto the PThi-g-PGM-coated electrode surface. In addition, the affinity of anti-p53 for the p53 protein was monitored at a constant frequency. Under optimized conditions, the impedimetric changes were linearly related to the p53 concentrations, ranging from 0.05 to 15 …

Physical And Chemical Characterization Of Recycled Glass Sand For Environmental Restoration, Shehbaz Ahmad, Julie P. Vanegas, Nicholas Borne, Natalia Butler, Toby Mendels, Leah A. Michaeloff, Diego Molina, Mary Salvaggio, Samantha Tamayo, Franziska Trautmann

Physics & Astronomy Faculty Publications

Introduction

We rely on coastal resources for food, water, and energy. However, over 75% of U.S. coastlines are eroding. Concurrently, the U.S. recycles less glass than other developed countries, landfilling hundreds of millions of tons every year. Recycled glass sand has many potential benefits over natural sand for combatting land loss; for example, it can be produced with controlled particle size to better resist erosion, making it an excellent—and underutilized—material for environmental restoration.

Objectives

This research compares the physical and chemical properties of recycled glass sand to natural sands (beach and dredge) from the U.S. Gulf Coast to assess environmental …

Highly Sensitive And Selective Detection Of Klk4 In Human Serum With A Low-Cost Electrochemical Biosensor, Eli̇f Burcu Aydin

Turkish Journal of Chemistry

An ultrasensitive impedimetric immunosensor was fabricated using a poly(glycidyl methacrylate) (PGMA) polymer-covered indium tin oxide (ITO) platform for the quantification of kallikrein 4 (KLK4), an important prostate cancer biomarker. PGMA had suitable biocompatibility and nontoxicity for loading of antiKLK4 antibodies on the ITO substrate surface. Anti-KLK4 biomolecules were directly attached to the PGMA-covered electrode surface via epoxy groups of the PGMA polymer. The preparation method for the PGMA matrix-modified electrode was simple and inexpensive. The proposed biosensor immobilization layers coated on the ITO electrode were characterized with electrochemical techniques. The experimental parameters that affect biosensor response were optimized, and the …

A Contextual Analysis Of The Early Work Of Andrzej Trautman And Ivor Robinson On Equations Of Motion And Gravitational Radiation, Donald Salisbury, Daniel Kennefick

Physics Faculty Publications and Presentations

In the mid-1950s, Andrzej Trautman published a series of papers connected with his dissertation work written under Leopold Infeld. In these, he drew upon the slow motion approximation developed by Infeld, the general covariance-based strong conservation laws enunciated by Bergmann and Goldberg, the Riemann tensor attributes explored by Goldberg and related geodesic deviation exploited by Pirani, the permissible metric discontinuities identified by Lichnerowicz, O'Brien and Synge, and finally Petrov's classification of vacuum spacetimes. With several significant additions he produced a comprehensive overview of the state of research in equations of motion and gravitational waves that was presented in a widely …

Advancing Political Science With Machine Learning: A Gaussian Process Approach, Yehu Chen

McKelvey School of Engineering Graduate Student Theses & Dissertations

The proliferation of data in recent decades including including survey, image and text data, has significantly transformed the landscape of political science research. Machine learning methods have played an instrumental role in analyzing these datasets, yet their application poses challenges in areas where political concepts are not directly measurable or the primary focus of inference is causality. In addition, the essence of machine learning algorithms being trained for prediction performance in a black-boxed manner, makes their outputs hardly interpretable and even unappreciated. This dissertation addresses these issues by proposing a novel methodological framework that employs Gaussian Process (GP) models, a …

Re: Revised Draft Final Butte Priority Soils Operable Unit (Bpsou) Insufficiently Reclaimed Sites: Bres No. 158 (Waste Rock Dump) Remedial Action Work Plan (Rawp), Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.