Digital Commons Network^™

Mole Street Journal, September 2007, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

A Computational Chemistry Study Of Spin Traps., Jacob Fosso-Tande

Electronic Theses and Dissertations

Many defects in physiological processes are due to free radical damage: reactive oxygen species, nitric oxide, and hydroxyl radicals have been implicated in the parthenogenesis of cancer, diabetes mellitus, and rheumatoid arthritis. We herein characterize the phenyl-N-ter-butyl nitrone (PBN) type spin traps in conjunction with the most studied dimethyl-1-pyrroline-N-oxide (DMPO) type spin traps using the hydroxyl radical. In this study, theoretical calculations are carried out on the two main types of spin traps (DMPO and PBN) at the density functional theory level (DFT). The energies of the optimized structures, hyperfine calculations in gaseous and aqueous phases of the spin traps …

Mole Street Journal, August 2007, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Wsu Research News, Fall 2007, Office Of Research And Sponsored Programs, Wright State University

WSU Research News

A twenty page newsletter of the WSU Research News. The WSU Research News was published monthly beginning in June of 1968 and issued by the Office of Research Development. This newsletter was created to provide information to the WSU faculty about the availability of outside funds for research and educational programs, new developments that may affect availability of funds, and general information on research and educational activities at Wright State University.

Mole Street Journal, July 2007, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, June 2007, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, May 2007, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Uri Undergraduate And Graduate Course Catalog 2007-2008, University Of Rhode Island

URI Course Catalogs Archive

This is a digitized, downloadable version of the University of Rhode Island course catalog.

Hydrothermally Altered Rock And Hot-Spring Deposits At Yellowstone National Park—Characterized Using Airborne Visible- And Infrared-Spectroscopy Data, K. Eric Livo, Fred A. Kruse, Roger N. Clark, Raymond F. Kokaly, W. C. Shanks Iii

United States Geological Survey: Publications

The hydrothermal system in Yellowstone National Park has created altered rock and hot-spring deposits that were mapped using AVIRIS (airborne visible and infrared imaging spectrometer) data. The mapped minerals are indicative of the geologic processes and environments that controlled their formation. Ongoing volcanic activity is expressed at the surface by geothermal features, earthquakes, and geologically recent caldera formation. Precipitated minerals such as siliceous sinter and travertine on the surface are derived from chloride-rich alkaline solutions that are leaching silica and calcite from the underlying country rock. Siliceous sinter and montmorillonite are associated with hydrothermal systems abundant in hot water, whereas …

Hadron Models And Related New Energy Issues, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

The present book covers a wide-range of issues from alternative hadron models to their likely implications in New Energy research, including alternative interpretation of lowenergy reaction (coldfusion) phenomena. The authors explored some new approaches to describe novel phenomena in particle physics. M Pitkanen introduces his nuclear string hypothesis derived from his Topological Geometrodynamics theory, while E. Goldfain discusses a number of nonlinear dynamics methods, including bifurcation, pattern formation (complex GinzburgLandau equation) to describe elementary particle masses. Fu Yuhua discusses a plausible method for prediction of phenomena related to New Energy development. F. Smarandache discusses his unmatter hypothesis, and A. Yefremov …

The Hydrology And Sediment Transport Of Low-Gradient, Forested Headwater Streams, Philip Saksa

LSU Master's Theses

Understanding stream hydrology of headwater regions is critical in effective land management for downstream water quantity and quality. Although extensive research has been performed on headwater streams in topographically variable areas, fewer studies examine low-gradient headwater stream systems, such as those existing on much of the southeastern coastal plain. This study aims to investigate spatial and temporal variation of headwater stream hydrology in a low-gradient forested watershed, quantify mass loading of suspended and dissolved solids in the watershed, and assess the applicability of a spatially distributed model in predicting hydrologic responses of a flat terrain landscape. Stream discharge and sediments …

De Novo Asymmetric Synthesis Of Mannopeptimycin-E, Novobiocin And Methymycin Analogues, Sanjeeva Rao Guppi

Graduate Theses, Dissertations, and Problem Reports (ETD)

The carbohydrate portion of the natural products plays a crucial role in biology, such as target binding, solubility, tissue targeting, and membrane transportation. The O'Doherty group use a de novo methodology to build the desired functionality and stereochemistry within each sugar, in contrast to the traditional approach using known sugar isomers as starting materials. Recently, we have developed a practical and highly diastereoselective palladium catalyzed glycosylation reaction to control the stereochemistry at the anomeric center. Continuing, our investigations on the utility of this strategy, we turned our attention to the syntheses of the bioactive carbohydrate-based natural product analogues. The targets …

The Missouri Miner, November 2, 2006

The Missouri Miner Newspaper

No abstract provided.

Atmospheric Chemistry Of A 33–34 Hour Old Volcanic Cloud From Hekla Volcano (Iceland): Insights From Direct Sampling And The Application Of Chemical Box Modeling, William I. Rose, Genevieve A. Millard, Tamsin A. Mather, Donald E. Hunton, Bruce Anderson, Clive Oppenheimer, Brett F. Thornton, Terrence M. Gerlach, Albert A. Viggiano, Yutaka Kondo, Thomas M. Miller, John O. Ballenthin

Department of Geological and Mining Engineering and Sciences Publications

On 28 February 2000, a volcanic cloud from Hekla volcano, Iceland, was serendipitously sampled by a DC-8 research aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE I). It was encountered at night at 10.4 km above sea level (in the lower stratosphere) and 33–34 hours after emission. The cloud is readily identified by abundant SO2 (≤1 ppmv), HCl (≤70 ppbv), HF (≤60 ppbv), and particles (which may have included fine silicate ash). We compare observed and modeled cloud compositions to understand its chemical evolution. Abundances of sulfur and halogen species indicate some oxidation of sulfur gases but …

Career Paths Of Women Clinical Laboratory Scientists Who Have Become Higher Education Administrators, Suzanne Campbell

Department of Educational Administration: Dissertations, Theses, and Student Research

More women are joining their male colleagues as higher education administrators. However, only a small percentage of these women possess an academic background as clinical laboratory scientists. This qualitative case study sought to investigate and document the career paths of women clinical laboratory scientists that have transitioned from the clinical setting to the higher education arena and held an administrative position at the dean’s level, including assistant and associate dean positions.

Through face-to-face semi-formal interviews, the experiences of this purposive sample population were recorded. Areas of inquiry included a description of their career paths; an identification of the skills, training, …

Washington University Record, May 19, 2006

Washington University Record

No abstract provided.

University Magazine Spring 2006, University News Service, Office Of Alumni Relations

University Publications

We hope you get engaged!||The Year of the cat||Views of RIT||Born to build||The Art of making art||Ice talk||On campus||Letters||RIT works!||Parent priorities||Class notes||Alumni activities

Cather-Pound Redesign, Jason Seckman

Architecture Masters of Science Program: Theses

Cather Pound - Redesign addresses the redevelopment of the Cather Pound Residence Complex located on north 17th Street on the University of Nebraska, Lincoln campus. These upperclassmen dormitories were hastily built in the 1960’s during a period of rapid growth for the university. These corridor style dorms were originally designed for double occupancy, but are now more often used by only one student. As our student culture changes the university is building more popular suite and apartment style residences. The archaic nature of dense student housing that these new units are replacing, becomes more apparent, and thus a redesign of …

Animal Husbandry At Tell El Hesi (Israel): Results From Zooarchaeological And Isotopic Analysis, Shannon Marie Peck-Janssen

USF Tampa Graduate Theses and Dissertations

Located in today’s southern Israel, Tell el Hesi provides archaeologists with important clues to political and social changes in the ancient Near East. Zooarchaeological and stable isotopic analyses were conducted to evaluate shifts in animal husbandry practices during changing socioeconomic and sociopolitical conditions in the southern Levant.

During the Early Bronze Age, Tell el Hesi thrived as an agricultural grain producing center for the southern Levant. The acropolis served as both a storage and redistribution center for the inhabitants of Tell el Hesi. Coinciding with the collapse of the southern Levant, Tell el Hesi was abandoned throughout the Middle Bronze …

Solvent Targeting, Avoidance And Recovery Trials (Start), Kealan Allen

Theses

Solvent is the largest-volume raw material used at Janssen Pharmaceutical (Ire) Ltd. Over 2.2 million m³ were used in 2004. The top 13 solvents make up 99% of this amount. There are two main uses for solvent on site, processing and cleaning. Processing uses 55% of the total solvent used on site, cleaning uses the remainder.

Waste solvent forms the majority of the hazardous waste produced at Janssen. Three treatment options exist at present for this waste: incineration, recovery for reuse and energy recovery. All of the hazardous waste produced on site must be exported for these treatment options, …

Uri Undergraduate And Graduate Course Catalog 2006-2007, University Of Rhode Island

URI Course Catalogs Archive

This is a digitized, downloadable version of the University of Rhode Island course catalog.

An Organizational And Functional Classification Of The Stone Tool Assemblage From The Bridge River Archaelogical Site (Eer14) (2003 And 2004 Field Seasons), David S. Clarke

Graduate Student Theses, Dissertations, & Professional Papers

No abstract provided.

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Thomas Hartmann

Fuels Campaign (TRP)

A wide variety of fuel concepts are considered for advanced reactor technology including metals, metal oxides or metal nitrides as solid solutions or composite materials. Nitride fuels have appropriate properties for advanced fuels including high thermal conductivity, thermal stability, solid-state solubility of actinides, fissile metal density, and suitable neutronic properties. A drawback of nitride fuels involves their synthesis. A key parameter for preparing oxide fuels is the precipitation step in the sol-gel process. For nitride fuels, the current synthetic route is carbothermic reduction from the oxide to the nitride. This process step is based on solid phase reactions and for …

The Development Of The Web Based Co2sys Program, Shigui Yuan

Graduate Student Theses, Dissertations, & Professional Papers

A web-based version of CO2SYS program has been implemented to replace the current DOS based version system. The user does not have to download anything to a local computer, instead they can run the calculations online freely. For this new designed program, all the user inputs and options are displayed in one single window instead of several small black and white DOS screens. All the calculation results are listed in a single page, as well. The user can change any inputs and constants before and after the data calculation, i.e., recalculation. Much more powerful error checking has been built into …

Synthesis Of Vic-Dioxime Derivatives With Hydrazone Side Groups And Their Metal Complexes, İlknur Babahan, Hüseyi̇n Anil, Nursabah Sarikavakli

Turkish Journal of Chemistry

Two novel vic-dioxime (L^1H_2, L^2H_2) compounds bearing hydrazone side groups and their transition metal complexes Ni(II), Co(II), Cu(II), and Zn(II) were synthesized. The vic-dioxime ligands bearing hydrazone side groups were synthesized by reacting anti-glyoximehydrazine (GH_2) with 4-nitroacetophenone and 4-methylacetophenenone, respectively. Ligands form mononuclear complexes [(LH)_2M] with a metal to ligand ratio of 1:2 with M=Co(II)(H_2O)_2, Ni(II), and Cu(II). Zn(II) forms complexes [(LH)(H_2O)(Cl)Zn] with a metal to ligand ratio of 1:1. The Co(II) complexes of the ligands are proposed to be octahedral with water molecules as axial ligands, the Ni(II) and Cu(II) complexes are proposed to be square planar, and the …

Afci Quarterly Input – Unlv October 1 Through December 31, 2005, Harry Reid Center For Environmental Studies. Nuclear Science And Technology Division

Transmutation Research Program Reports (TRP)

Quarterly report highlighting research projects, activities and objectives of the Transmutation Research Program at the Nuclear Science & Technology Division, Harry Reid Research Center.

The University of Nevada, Las Vegas supports the AFCI through research and development of technologies for economic and environmentally sound refinement of spent nuclear fuel. The UNLV program has four components: infrastructure, international collaboration, student-based research, and management and program support.

Atr-Ftir Spectroscopic Analysis Of Sorption Of Aqueous Analytes Into Polymer Coatings Used With Guided Sh-Saw Sensors, Yolanda K. Jones, Zhonghui Li, Michael M. Johnson, Fabien Josse, Jeanne Hossenlopp

Chemistry Faculty Research and Publications

Attenuated total internal reflectance Fourier transform infrared (ATR-FTIR) spectroscopy was used for the investigation of sorption of aqueous solutions of analytes into polymer coatings. A series of simple model polymers, such as poly(dimethylsiloxane), poly(epichlorhydrin), and poly(isobutylene), and films and analytes, such as aqueous solutions of ethylbenzene, xylenes, toluene, and nitrobenzene, were used to evaluate the use of ATR-FTIR spectroscopy as a screening tool for sensor development. The ratios of integrated infrared absorption bands provided a simple and efficient method for predicting trends in partition coefficients. Responses of polymer-coated guided shear horizontal surface acoustic wave (SH-SAW) sensor platforms to the series …

Influence Of A Thermal Denuder On Diesel Exhaust Particle Size Distributions, Bobby John

Graduate Theses, Dissertations, and Problem Reports (ETD)

Particle size distributions in diesel exhaust were studied using a thermal desorption technique to determine the volatile and non-volatile fractions. A thermal denuder was designed and characterized for optimal operating parameters and its influence on the exhaust chemistries studied using diesel engine exhaust. The study was conducted on a 1992 DDC Series 60 engine mounted on a heavy-duty direct current dynamometer and exercised over steady state and transient cycles. The particle size distributions were recorded upstream and downstream of the denuder maintained at different temperatures to determine the behavior of the volatile fraction. The volatilization technique was also applied to …

Chapman Remembers Dr. Arnold O. Beckman, Chapman University Media Relations

Chapman Press Releases 2003-2011

No abstract provided.

Export Of Carbon, Nitrogen And Major Solutes From A Boreal Forest Watershed: The Influence Of Fire And Permafrost, Kevin Christopher Petrone

Biological Sciences

Detailed observations of stream, soil, and groundwater chemistry were used to determine the role of fire, permafrost and snowmelt processes on the fluxes of carbon, nitrogen and major solutes from interior Alaskan catchments. We examined an experimentally burned watershed and two reference watersheds that differ in permafrost coverage (high, 53%; medium-burn, 18%; and low, 4%) during the FROSTFIRE prescribed burn in July 1999. The fire elevated stream nitrate concentrations for a short period during the first post-fire storm, but nitrate declined thereafter, suggesting that less severe fires that leave an intact riparian zone may have only a short-term effect on …