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2025

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Volumetric Video With Skateboarders: Creative Opportunities Of Working With An Emerging Screen Technology Beyond The Studio, Dani Landau, Diego Zamora Dec 2025

Volumetric Video With Skateboarders: Creative Opportunities Of Working With An Emerging Screen Technology Beyond The Studio, Dani Landau, Diego Zamora

School of Art, Design and Architecture

Volumetric video is an emerging moving image technology in which each pixel is recorded witha location in three dimensions. Volumetric videos are normally created in studios using rigs made upof multiple cameras with LiDAR sensors and computers that combine the moving images. We tookthis technology out of the studio to explore variations of this technique in public skateparks. We foundthat as the technology is still in developing stages there are creative constraints: the lidar cameras sense at a limited distance to the subject, the image is of a relatively low resolution, and there are often glitches in theimage. In our …


Advanced Ni-Co And Sn-Based Alloys Electrodeposition From Aqueous And Deep Eutectic Solvents, Narmin M. Hamadamin, Hassan H. Abdallah Dec 2025

Advanced Ni-Co And Sn-Based Alloys Electrodeposition From Aqueous And Deep Eutectic Solvents, Narmin M. Hamadamin, Hassan H. Abdallah

Polytechnic Journal

Electrodeposition is a pivotal technique in materials science, enabling the fabrication of metal and alloy coatings with tailored properties for diverse industrial applications. Traditional aqueous electrolytes, while widely used, present limitations such as narrow electrochemical windows, hydrogen evolution, and environmental concerns. Deep eutectic solvents (DESs) have emerged as promising alternatives, offering broader electrochemical windows, reduced toxicity, and enhanced solubility for metal salts. This review comprehensively examines the principles and advancements in electrodeposition from both aqueous and DES media, focusing on the deposition of Ni-Co and Sn-based alloys, the role of additives, the electrodeposition of metal powders, and surface analysis techniques. …


Visualizing The Effect Of Process Pause On Virus Entrapment During Constant Flux Virus Filtration, Wenbo Xu, Xianghong Qian, Hironobu Shirataki, Daniel Straus, Sumith Ranil Wickramasinghe Dec 2025

Visualizing The Effect Of Process Pause On Virus Entrapment During Constant Flux Virus Filtration, Wenbo Xu, Xianghong Qian, Hironobu Shirataki, Daniel Straus, Sumith Ranil Wickramasinghe

Biomedical Engineering Faculty Publications and Presentations

Virus filtration is an essential unit operation used to validate clearance of adventitious virus during the manufacture of biopharmaceutical products such as monoclonal antibodies. Obtaining at least a 10,000-fold reduction in virus particles in the permeate is challenging as monoclonal antibodies are about half the size of the virus particles. Minute virus of mice, FDA-recommended model adventitious virus, was labeled with a fluorescent dye. Laser scanning confocal microscopy was used to determine the location of virus entrapment within the virus filtration membrane. Three different hollow fiber membranes made of regenerated cellulose and polyvinylidene fluoride were tested. Feed streams consisted of …


Process For The Preparation Of 2-{4-[(3s)-Piperidin-3-Yl]Phenyl}-2h-Indazole 7-Carboxamide 4-Methylbenzenesulfonate And Intermediates Thereof Dec 2025

Process For The Preparation Of 2-{4-[(3s)-Piperidin-3-Yl]Phenyl}-2h-Indazole 7-Carboxamide 4-Methylbenzenesulfonate And Intermediates Thereof

Defensive Publications Series

The present invention provides a process for the preparation of 2-{4-[(3S)-piperidin-3-yl]phenyl}-2H-indazole 7-carboxamide 4-methylbenzenesulfonate represented by the following structural formula-1a and intermediates thereof.

Formula-1a


Machine Learning Framework For Automatic Classification Of Nano-Seismic Signals Preceding Earthquakes, Ghada Ali, Ali G. Hafez, Sayed Hasaneen, Hamed Nofel, Nabeel Al-Atwan, Ahmed Mohamed Dec 2025

Machine Learning Framework For Automatic Classification Of Nano-Seismic Signals Preceding Earthquakes, Ghada Ali, Ali G. Hafez, Sayed Hasaneen, Hamed Nofel, Nabeel Al-Atwan, Ahmed Mohamed

Almaaqal Journal of Sustainability and Emerging Technology

Nano-seismicity preceding earthquakes has many applications in fault prediction, in structure health monitoring, and in enhancing fault and source parameter determination. Not all earthquakes are preceded by these precursors; therefore, there is a need to identify P-wave arrivals that are preceded by these nano signals, which will eliminate errors in P-wave arrival timing. The current work introduces topologies capable of automatically categorizing the arrivals with nano-seismic precursors. The proposed methods are trained on datasets extracted from stations belonging to Egyptian National Seismic Network (ENSN). These records contain both P-wave arrivals preceded by such nano precursors and other records without these …


Optimizing Bioethanol Production Using Design Of Experiments For Sustainable Biofuel Development, Hussein M. Hussein, Yahya H. Shahin, Ihab A. Moneam Dec 2025

Optimizing Bioethanol Production Using Design Of Experiments For Sustainable Biofuel Development, Hussein M. Hussein, Yahya H. Shahin, Ihab A. Moneam

Almaaqal Journal of Sustainability and Emerging Technology

This study presents a statistically optimal approach for bioethanol production from sugarcane bagasse (SCB) using alkaline pretreatment, enzymatic hydrolysis, and fermentation processes. To maximize cellulose yield, four extraction parameters—solvent type, concentration, temperature, and time—were optimized using a Taguchi statistical model. The Taguchi-optimized extraction yields 11.3% increased cellulose recovery relative to cellulose recovered via non-optimized extraction methods (i.e., alkaline treatment with 6% NaOH at 90 °C for 3 hours). This yielded 45.20% cellulose (w/w), with 37.80% weight loss (predicted weight loss was 36.94%). Statistical analysis of extraction results verified solvent type (p = 0.0022) and temperature (p = 0.0007) to be …


A Method For Advance Detection Of Underground Concealed Water Hazards In Coal Mines Based On Borehole Transient Electromagnetic Method And Vector Synthesis, Fan Tao, Hao Yue, Li Ping, Zhao Rui, Liu Zaibin, Ma Liang, Li Peng, Yan Junsheng Dec 2025

A Method For Advance Detection Of Underground Concealed Water Hazards In Coal Mines Based On Borehole Transient Electromagnetic Method And Vector Synthesis, Fan Tao, Hao Yue, Li Ping, Zhao Rui, Liu Zaibin, Ma Liang, Li Peng, Yan Junsheng

Coal Geology & Exploration

Background The advance detection of underground concealed water hazards in coal mines is crucial to ensuring the safe and efficient roadway tunneling. The borehole transient electromagnetic (TEM) method allows for long-distance advance detection. However, due to the limitation of the spatial structure of boreholes, currently available techniques can only effectively identify low-resistivity anomalies (e.g., water-bearing structures) in the radial direction, leaving blind areas in the primary tunneling direction (i.e., the axial direction of boreholes). Objective and Method To address this challenge, this study proposed a method for the advance detection of concealed water hazards in the axial direction of boreholes …


Application Of Long-Distance Tunneling And Detection For Advance Detection In Excavation Using Shield Tunneling Machines, Chen Chao, Li Ping, Li Wei, Wei Rong Dec 2025

Application Of Long-Distance Tunneling And Detection For Advance Detection In Excavation Using Shield Tunneling Machines, Chen Chao, Li Ping, Li Wei, Wei Rong

Coal Geology & Exploration

Objective and Method During the rapid excavation process using shield tunneling machines in coal mines, the advance detection of concealed geological anomalies encounters challenges of limited space and insufficient accuracy. To overcome these issues, this study investigated highly-located drainage roadway 3211 in the Tiandi Wangpo Coal Mine in Jincheng City, Shanxi Province using the long-distance tunneling and detection technology, the core of which is long directional boreholes combined with comprehensive borehole geophysical prospecting. This roadway is located in the roof of the No.3 coal seam, and it is necessary to conduct shield construction in the stable sandstone layer located from …


Multi-Field Coupling-Based Numerical Simulations Of Co2 Storage In Saline Aquifers: A Case Study Of The Dingji Coal Mine, Huainan Mining Area, Li Dianshang, Zheng Sijian, Liao Qingfa, Miao Wei, Tian Yuchen, Zhang Helong, Liu Yanzhi, Liu Shiqi Dec 2025

Multi-Field Coupling-Based Numerical Simulations Of Co2 Storage In Saline Aquifers: A Case Study Of The Dingji Coal Mine, Huainan Mining Area, Li Dianshang, Zheng Sijian, Liao Qingfa, Miao Wei, Tian Yuchen, Zhang Helong, Liu Yanzhi, Liu Shiqi

Coal Geology & Exploration

Background Saline aquifers are characterized by extensive distribution, abundant reserves, and substantial potential for CO2 storage, establishing them as the most promising geological media for carbon capture, utilization, and storage (CCUS). CO2 storage in saline aquifers plays a crucial role in mitigating the greenhouse effect and achieving the goals of peak carbon dioxide emissions and carbon neutrality. Thoroughly investigating CO2 storage in deep saline aquifers within the Huainan mining area helps alleviate the regional pressure of carbon emission reduction while also providing important support for expanding the technical pathways of CCUS and promoting its engineering applications. Methods …


Environmental Risk Assessment Of Co2 Storage Combined With The Overlying Coal Mining, Gu Leiyu, Li Wenhui, Huang Wei, Zhou Quanchao, Zhu Yalong, Li Xiaying, Liu Guizhen, Li Qi Dec 2025

Environmental Risk Assessment Of Co2 Storage Combined With The Overlying Coal Mining, Gu Leiyu, Li Wenhui, Huang Wei, Zhou Quanchao, Zhu Yalong, Li Xiaying, Liu Guizhen, Li Qi

Coal Geology & Exploration

Objective Carbon capture, utilization, and storage (CCUS) technology serves as a key method for carbon neutrality. However, large-scale engineering applications of CCUS are still confronted with serious challenges of environmental risks. Therefore, systematic environmental risk assessment plays an essential role in ensuring the environmental safety and social acceptability of CO2 geological storage projects. Methods Targeting the CO2 geological storage project combined with overlying coal mining in Zhengning County, Gansu Province, this study performed the environmental risk assessment of CO2 leakage based on the requirements of the Technical Guideline on Environmental Risk Assessment for Carbon Dioxide Capture, Utilization, …


Water Quality Characteristics And Reutilization Of Goaf Water From Shallow Coal Seams Within The Datong Mining Area, Shanxi Province, China, Li Jun, Gui Herong, Ding Pengfei, Chen Yongqing, Wan Heyong, Li Weiqi, Huang Dawei, Peng Weihua, Hu Yang, Guo Yan Dec 2025

Water Quality Characteristics And Reutilization Of Goaf Water From Shallow Coal Seams Within The Datong Mining Area, Shanxi Province, China, Li Jun, Gui Herong, Ding Pengfei, Chen Yongqing, Wan Heyong, Li Weiqi, Huang Dawei, Peng Weihua, Hu Yang, Guo Yan

Coal Geology & Exploration

Objective The Datong mining area in Shanxi Province of China faces serious threats from goaf water hazards, while the goaf water drainage is constrained by environmental protection policies. Therefore, the reutilization of goaf water serves as an effective approach to eliminating mine water hazards, protecting water environments, and mitigating water scarcity in the mining area. Methods This study investigated goaf water from shallow coal seams in the Datong mining area. Based on water quality assessment theories and a range of hydrogeochemical indices, including saturation index (SI), chloro-alkaline index (CAI), and sodium adsorption ratio (SAR), this study conducted a joint determination …


Pengaruh Video Edukasi Unsafe Action Terhadap Tingkat Pengetahuan Dan Perilaku Pekerja Weaving Di Pt X, Ajay Abdiel Ferrall, Maria Paskanita Widjanarti, Jihan Faradisha Dec 2025

Pengaruh Video Edukasi Unsafe Action Terhadap Tingkat Pengetahuan Dan Perilaku Pekerja Weaving Di Pt X, Ajay Abdiel Ferrall, Maria Paskanita Widjanarti, Jihan Faradisha

National Journal of Occupational Health and Safety

The textile industry is one of the leading sectors in Indonesia, playing a crucial role in providing employment and driving economic growth. However, this industry also carries significant potential for occupational safety and health hazards, particularly due to unsafe actions. Observations at PT X revealed that workers' level of knowledge and behavior regarding unsafe actions remained low. This study was conducted with the aim of analyzing the effectiveness of an educational video intervention on unsafe actions on workers' knowledge and behavior. This quantitative research employed a quasi-experimental design using a non-equivalent control group model. The study was carried out at …


Efektivitas Pemberian Buah Pisang Raja Untuk Menurunkan Kelelahan Kerja Pada Operator Sewing Umkm Garmen X Karanganyar, Virginia Bernardine Gavra Prachristma Sujudi, Tyas Lilia Wardani, Rizqy Kartika Sari Dec 2025

Efektivitas Pemberian Buah Pisang Raja Untuk Menurunkan Kelelahan Kerja Pada Operator Sewing Umkm Garmen X Karanganyar, Virginia Bernardine Gavra Prachristma Sujudi, Tyas Lilia Wardani, Rizqy Kartika Sari

National Journal of Occupational Health and Safety

Work fatigue is a common problem that can reduce productivity and increase the risk of workplace accidents. At UMKM Garmen X Karanganyar, the lack of supplementary food intake causes energy deficits and fatigue among workers. This condition underlies the research to analyze the effectiveness of giving banana raja (Musa paradisiaca L.) as an additional snack in reducing work fatigue among sewing operators at UMKM Garmen X Karanganyar. The research was conducted using a true experimental method with a pre-test and post-test design with a control group. 42 sewing operators were selected from 47 workers using simple random sampling, divided into …


Investigating Surface-Borehole Transient Electromagnetic Responses From Veined Orebodies Considering Induced Polarization Effects, Li Jianhui, Wang Yao, Wang Wenchuang, Xie Shaojian, Zhu Siwei Dec 2025

Investigating Surface-Borehole Transient Electromagnetic Responses From Veined Orebodies Considering Induced Polarization Effects, Li Jianhui, Wang Yao, Wang Wenchuang, Xie Shaojian, Zhu Siwei

Coal Geology & Exploration

Objective The observational data derived using the surface-borehole transient electromagnetic (TEM) method tend to feature complex curve morphologies, a problem posing significant challenges to data processing and interpretation. This study aims to ascertain the mechanisms behind the generation of such complex responses using forward modeling.Methods Using the vector finite element-based spectral method and the Cole-Cole model, this study developed a 3D forward modeling technique incorporating the induced polarization (IP) effect. By constructing a typical theoretical model of low-resistivity veined orebodies, it systematically analyzed the electromotive force (EMF) responses excited by transmitter loops at different orientations. Results and Conclusions The …


Performance And Migration Path Tracing Of Magnetic Grouts For Fractured Rock Masses, Shang Hongbo, Wang Hao, Wang Xiaodong, Qiao Wei, Wang Tiantian, Sun Junqing, Sun Jie Dec 2025

Performance And Migration Path Tracing Of Magnetic Grouts For Fractured Rock Masses, Shang Hongbo, Wang Hao, Wang Xiaodong, Qiao Wei, Wang Tiantian, Sun Junqing, Sun Jie

Coal Geology & Exploration

Objective For coal mining areas in the middle reaches of the Yellow River basin, sealing mining-induced fractures via grouting serves as an effective approach to preventing water inrushes from coal seam roofs while also protecting groundwater resources. However, accurately identifying the migration paths of grouts remains a bottleneck for the further application of grouting modification technology to fractured rock masses. Methods This study investigated a coal mine threatened by both water inrushes from the coal seam roof and a short supply of water resources within the Jurassic coalfield in the middle reaches of the Yellow River basin, focusing on the …


Co2-Water Displacement Characteristics Of Saturated Sandstones With Different Pore Structures, Liu Ting, Li Jinglin, Li Yi, Dan Wendong, Diao Yujie, Ma Xin Dec 2025

Co2-Water Displacement Characteristics Of Saturated Sandstones With Different Pore Structures, Liu Ting, Li Jinglin, Li Yi, Dan Wendong, Diao Yujie, Ma Xin

Coal Geology & Exploration

Objective The pore structures of clastics play a crucial role in assessing the potential of saline aquifers for geologic CO2 sequestration. Current studies on pore structures during CO2 sequestration focus primarily on artificial cores. However, compared to artificial cores, natural cores feature more complex pore size distributions and stronger heterogeneity. Methods This study examined a natural core from deep reservoirs in the Ordos Basin and two artificial cores with different porosities through CO2-water displacement experiments under water-saturated conditions. Using a nuclear magnetic resonance (NMR) analysis and imaging system for multiphase fluid displacement, this study analyzed the …


Synthesis Of Biogenic Silver Nanoparticles From Apricot Kernel Extracts For The Colorimetric Determination Of Gold, Ayça Gi̇rgi̇n, Hi̇lal Akbiyik, Buse Tuğba Zaman, Omid Nejati, Ayça Bal Öztürk, Gülten Çeti̇n, Sezgi̇n Bakirdere Dec 2025

Synthesis Of Biogenic Silver Nanoparticles From Apricot Kernel Extracts For The Colorimetric Determination Of Gold, Ayça Gi̇rgi̇n, Hi̇lal Akbiyik, Buse Tuğba Zaman, Omid Nejati, Ayça Bal Öztürk, Gülten Çeti̇n, Sezgi̇n Bakirdere

Turkish Journal of Chemistry

Gold is abundant in nature, however, precise and reliable analytical methods for its detection are required stemming from its increasing prevalence in environmental, biological, and industrial systems, as well as the growing interest in understanding its function in living organisms and its effects on human health. This study investigates the use of biogenically synthesized silver nanoparticles (AgNPs) for the preconcentration and determination of gold ions prior to determination by UV-Vis spectrophotometry. AgNPs were synthesized by reducing silver nitrate through the use of an apricot kernel extract as both reducer and stabilizer agent. The colloidal yellowish AgNPs interacted with gold ions, …


Solving Data Mining Challenges In Neutrosophic Environments Using Bio-Inspired Optimization Techniques, Samia Mandour, Abduallah Gamal, Mohamed Belal Dec 2025

Solving Data Mining Challenges In Neutrosophic Environments Using Bio-Inspired Optimization Techniques, Samia Mandour, Abduallah Gamal, Mohamed Belal

Neutrosophic Sets and Systems

No abstract provided.


A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu Dec 2025

A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu

Coal Geology & Exploration

Objective During the exploration and development of fractured-vuggy carbonate reservoirs, acoustic reflection imaging logging technology enables the detection of fractured-vuggy bodies around wells. However, this technology suffers from unclear response characteristics and a strong multiplicity of solutions. Focusing on the Tarim Oilfield, this study aims to establish a tailored interpretation method by integrating geological and geophysical characteristics. The purpose is to enhance the identification accuracy and reliability of fractured-vuggy bodies in these reservoirs. Methods Based on the distribution characteristics of fractured-vuggy carbonate reservoirs in the Tarim Oilfield, this study established the numerical simulation models of three typical fractured-vuggy bodies: inter-breccia …


Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing Dec 2025

Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing

Coal Geology & Exploration

Objective and Method The diffusivity of methane (CH4) in coal seams significantly influences the surface extraction of coalbed methane (CBM) and underground gas drainage. However, the visualized characterization of the diffusion and migration processes of CH4 in coals remains challenging. To address this issue, this study systematically demonstrated the similarity between krypton (Kr) and CH4 in their adsorption and diffusion behavior in coals. Utilizing Kr—a gas with high X-ray attenuation—as a tracer substitute for CH4, this study achieved the transparent observation of the dynamic gas migration process in low-porosity, low-permeability, and heterogeneous coals using …


Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun Dec 2025

Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun

Coal Geology & Exploration

Background Borehole geophysical prospecting technology for coal mines integrates the advantages of both drilling and geophysical prospecting. Accordingly, multiple critical advances have been achieved in its applications to the technologies and equipment for intelligent coal mining in recent years, enabling long-distance, relatively high-precision geological exploration. This technology plays an increasingly important role in a range of fields, including deep mineral resource exploration and the reconnaissance surveys of hidden disaster-causing factors, providing robust support for safe and efficient coal mining. Advances This study systematically reviews the development history of borehole geophysical prospecting technology, elaborating advances in research on the methodology, theories, …


Process Activities Of A Neutrosophic-Based Smart Simulation Framework For Islamic Sacred Rituals, Nabil M. Abdelaziz, Mohamad S. Al-Thenyan Dec 2025

Process Activities Of A Neutrosophic-Based Smart Simulation Framework For Islamic Sacred Rituals, Nabil M. Abdelaziz, Mohamad S. Al-Thenyan

Neutrosophic Sets and Systems

No abstract provided.


Evaluasi Keselamatan Alat Permainan Edukatif (Ape) Dan Penataan Area Bermain Outdoor Di Dua Taman Kanak-Kanak, Auri Willyado, Novrikasari Novrikasari, Mona Lestari, Dina Waldani, Desheila Andarini Dec 2025

Evaluasi Keselamatan Alat Permainan Edukatif (Ape) Dan Penataan Area Bermain Outdoor Di Dua Taman Kanak-Kanak, Auri Willyado, Novrikasari Novrikasari, Mona Lestari, Dina Waldani, Desheila Andarini

National Journal of Occupational Health and Safety

Educational Play Equipment (APE) is one of the facilities provided by Early Childhood Education (PAUD) institutions to support the learning process through play. This study aims to assess the compliance of APE and the arrangement of outdoor play areas with the 2018 Guidelines for Managing PAUD Classroom Space, SNI 9169:2023, the Ministry of Education and Culture’s 2021 Safe APE Guidelines for Early Childhood, and Ministerial Regulation No. 3 of 2022. The study employs a qualitative design with a descriptive approach through facility observations, interviews with teaching staff, and a review of school documents. The data analysis process includes data reduction, …


Cover And Content Dec 2025

Cover And Content

Turkish Journal of Chemistry

No abstract provided.


Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee Dec 2025

Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee

Turkish Journal of Chemistry

Paclitaxel (Pac) is an important anticancer bioactive compound, and the availability of an accurate and robust analytical method for its quantification is of utmost importance. In this investigation, a novel, direct, and reliable spectrophotometric method has been proposed for the estimation of Pac via a complex formation reaction with osmium (Os). The method was based on the reaction of Pac with Os tetroxide, which produced a yellowish-brown complex. The resulting complex is soluble in water and displays a maximum absorption peak at 482 nm. The reaction conditions, including reactant concentration, pH, temperature, and reaction time, were optimized to obtain the …


Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman Dec 2025

Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman

Turkish Journal of Chemistry

In this work, electrochemical biosensors utilizing tyrosinase (Tyr) for the detection of the nonselective beta-adrenergic agonist isoproterenol (ISO) are presented. Three different configurations for immobilizing Tyr on a graphite electrode (GE) are compared: (1) GE modified with poly(diallyldimethylammonium chloride) (PDADMAC), PDADMAC/Tyr/GE; (2) PDADMAC combined with iridium nanoparticles (IrNPs) in a stepwise preparation, resulting in PDADMAC/IrNPs/Tyr/GE; and (3) a composite of PDADMAC and IrNPs mixed with Tyr at a 1:1 (v:v), forming PDADMAC/(IrNPs-Tyr)/GE. Surface morphology was characterized using scanning electron microscopy (SEM). Cyclic voltammetry (CV) and amperometry were applied to characterize the biosensor’s performance. Within the linear range of 5 μM …


Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh Dec 2025

Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh

Turkish Journal of Chemistry

Hydrazone chemistry has become important and plays a key role in the development of organic compounds. Hydrazones can be useful pharmacophores for creating novel derivatives, owing to their broad range of activities. In this study, a series of N-((2-hydroxy-3-(2-(substitutedbenzylidene)hydrazine-1-carbonyl)naphthalen-1-yl)(3-nitro-phenyl/3,4-dimethoxyphenyl)methyl)acetamide derivatives were prepared, characterized by FTIR, 1H-NMR, 13C-NMR, and mass spectroscopy, and evaluated for their antimicrobial, antiinflammatory, and antioxidant activities along with in silico studies. The substituted derivatives were synthesized by the reaction of acetonitrile, chlorosulphonic acid, and substituted benzaldehyde with the hydrazones. The antimicrobial evaluation showed that compound 3i had more antimicrobial potential than the other tested molecules. Compound 3j …


Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat Dec 2025

Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat

Turkish Journal of Chemistry

This study highlights the potential of organometallic carbonyl complexes as selective markers for biomolecules, enabling sensitive infrared (IR) detection. The regio- and stereoselective coupling of N-acetylhistamine, a histidine analogue, with the precursor complex 1 [Fe(CO)₃(1,4-η⁵-N-pyridiniocyclohexa-1,3-diene)] BF₄ affords the labeled complex 3 [Fe(CO)₃(1,4-η⁵-N-acetylhistaminocyclohexa-1,3-diene)]. X-ray diffraction (XRD) confirms the exo stereochemistry and reveals a rigid, well-defined architecture. IR and 1H nuclear magnetic resonance spectroscopic studies combined with IR-monitored acid–base titration demonstrate the complex’s stability in aqueous media between pH 5 and 8, alongside a modest increase in basicity relative to the free ligand. These findings establish the Fe(CO)₃ moiety as a robust …


Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz Dec 2025

Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz

Turkish Journal of Chemistry

This study investigates the extraction behavior of Y³⁺ ions using a Multi-Dropped Liquid Membrane (MDLM) system that employs di(2-ethylhexyl) phosphoric acid (D₂EHPA) as the carrier ligand. The focus is on the system’s ability to transport ions between aqueous phases selectively. The extracted complex was analyzed spectrophotometrically via ultraviolet–visible (UV–Vis) measurements after complexation with 0.05% Arsenazo III. The aim of this study was to determine the influence of the optimum D₂EHPA carrier concentration, together with the pH and temperature conditions of the donor and acceptor phases, on the system’s extraction performance. Accordingly, a series of extraction experiments was performed at different …


A Pilot Qualitative Study To Better Understand The Factors Related To Suicides And Inform Public Health Action Across A Predominantly Coastal And Rural Area: Cornwall, Southwest Of England: International Journal Of Environmental Research And Public Health, Paula Chappell, Jane Horrell, Kerryn Husk, Beth Simons, Richard A. Sharpe Dec 2025

A Pilot Qualitative Study To Better Understand The Factors Related To Suicides And Inform Public Health Action Across A Predominantly Coastal And Rural Area: Cornwall, Southwest Of England: International Journal Of Environmental Research And Public Health, Paula Chappell, Jane Horrell, Kerryn Husk, Beth Simons, Richard A. Sharpe

Peninsula Medical School

Background: Better understanding factors leading to suicide and prevention opportunities is a global public health priority. This qualitative pilot study tested whether reviewing inquest recordings could generate insights during COVID-19 and inform public health prevention programmes across a predominantly rural and coastal area where there are significant health inequalities. Methods: Fifty-five inquest recordings reached a suicide conclusion between March 2020 and January 2021. Stratified sampling was used to obtain two samples from each month. Template analysis was employed to thematically analyse data from 30 inquests. Results: Risk factors during this period were social isolation, anxiety, difficulty in routine creation and …