Digital Commons Network^™

Dispositional Optimism And Autonomic Reactivity During Passive-Coping And Active-Coping Stress Tasks, Emma R. Pino

Graduate Theses, Dissertations, and Problem Reports (ETD)

Optimism is a positive psychological factor that has been associated with improved mental and physical health outcomes. To better understand the mechanism through which optimism results in improved health, researchers have examined whether autonomic reactivity to stress moderates this relation. While many studies have examined the relation between optimism and autonomic reactivity to stress, findings are mixed. Although some studies have found optimism to be associated with reductions in heart rate and blood pressure responses to acute stress presentations, many studies exploring this relation have found optimism to be associated with greater blood pressure responses to stress. However, most of …

Investigations Into Indole Formation: Base-Mediated Formation Of N-Hydroxy- And N-Alkoxyindoles, Ancillary Ligand Development For Watanabe-Cenini-Söderberg Cyclization, And Total Synthesis Of Racemosin B, Blaine Thomas Mcclay

Graduate Theses, Dissertations, and Problem Reports (ETD)

A novel, base-mediated cyclization was developed to form N-hydroxy- and N-alkoxyindoles from 2-(2-nitrophenyl)butenoates. Potassium tert-butoxide or sodium tert-pentoxide, with or without the in-situ addition of an electrophile, formed a multitude of N-hydroxy- and N-alkoxyindoles. The formation of these butanoate precursors was improved via a Barluenga coupling reaction. Novel 4,5,6,7-tetramethoxy-1,10-phenanthroline was utilized as an ancillary ligand within the Watanabe-Cenini-Söderberg reductive cyclization reaction conditions. These new reaction conditions produced high yields for sterically hindered 2-nitrostyrenes and the first synthesis of dilemmaone A using this reductive cyclization. Racemosin B was synthesized in a three-step process utilizing a …

Measuring And Modeling How Plant-Microbe Interactions Control Soil Carbon And Nitrogen Cycling In Managed And Unmanaged Ecosystems, Joanna Ridgeway

Graduate Theses, Dissertations, and Problem Reports (ETD)

Our understanding of how plant-microbe interactions regulate carbon (C) and nitrogen (N) retention in soil organic matter (SOM) remains uncertain. Conflicting evidence suggests that microbial decomposition can lead to the loss of unprotected particulate SOM, but also that microbial decomposition produces simpler compounds that preferentially form more persistent aggregate- or mineral-protected SOM pools. Further, uncertainty remains in how plant-microbe interactions alter SOM retention in these different pools through litter chemistry controls on microbial decomposition traits and rhizosphere priming. As a result, this uncertainty limits our ability to sustainably manage ecosystems and understand future feedbacks between terrestrial ecosystems and the global …

Characterizing & Mitigating Interstellar Scattering In Radio Observations Of Pulsars, Jacob E. Turner

Graduate Theses, Dissertations, and Problem Reports (ETD)

Pulsars are rapidly rotating neutron stars that emit concentrated beams of radiation from their magnetic poles. Measuring the arrival of these pulses via pulsar timing is a powerful tool in efforts to detect low frequency gravitational waves (GWs). However, the interstellar medium (ISM) presents a significant source of timing uncertainty that must be mitigated to improve the sensitivity of pulsar timing efforts to these GW signals. By examining the effects of pulsar emission interactions with this medium, we can properly correct for the resulting effects in pulsar timing efforts, as well as study the astronomical unit-to-parsec scale structure and behavior …

Evaluate A Mixer Of Hydrogen Peroxide And Peroxyacetic Acid To Mitigate Microbial Cross-Contamination Of Salmonella Typhimurium And The Surrogate Enterococcus Faecium During Triple-Washing Of Butternut Squash, Jesica M. Temple

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background: Recent foodborne illness outbreaks have been linked to fresh fruits and vegetables. For public safety, awareness of the risks of contamination from foodborne pathogens that can occur during post-harvest farming practices is essential to prevent foodborne outbreaks. Controlling the spread of foodborne pathogens on produce requires proper washing procedures, antimicrobials and doses. Given the speed and diversity of the produce being distributed, local incidents may become international emergencies. Methods: Studies were included if they assessed the efficacy of antimicrobials and various washing procedures and had to conclude the mitigation of cross-contamination of foodborne pathogens on produce grown in the …

Enhancing The Forensic Comparison Process Of Common Trace Materials Through The Development Of Practical And Systematic Methods, Meghan Nicole Prusinowski

Graduate Theses, Dissertations, and Problem Reports (ETD)

An ongoing advancement in forensic trace evidence has driven the development of new and objective methods for comparing various materials. While many standard guides have been published for use in trace laboratories, different areas require a more comprehensive understanding of error rates and an urgent need for harmonizing methods of examination and interpretation. Two critical areas are the forensic examination of physical fits and the comparison of spectral data, which depend highly on the examiner’s judgment.

The long-term goal of this study is to advance and modernize the comparative process of physical fit examinations and spectral interpretation. This goal is …

Mapping Infiltration In An Urbanizing Mixed-Land-Use Watershed With Multi-Temporal Satellite Imagery, Sarah J. Higgins

Graduate Theses, Dissertations, and Problem Reports (ETD)

Digital soil mapping (DSM) is a field of soil science that aims to improve traditional soil maps by producing higher resolution predictive maps of soil properties using spatial environmental data. DSM has historically relied primarily on static environmental covariates—such as slope gradient, slope aspect, and other topographic variables derived from digital terrain models—for predicting static soil properties, like soil texture. Advancements in satellite imagery and statistical modeling improve the accuracy of digital soil maps by incorporating multi-temporal data that can capture landscape-scale change over relatively short periods of time. Adding these dynamic environmental covariates may be especially useful for spatial …

Analytical Heat Transfer Modeling Of The Microwave Heating Process: A Focus On Carbon Black, Craig Offutt

Graduate Theses, Dissertations, and Problem Reports (ETD)

Electronic waste (e-waste) has become a significant environmental issue due to the rapid advancement of technology, increasing demand for electronic devices, and shorter lifespan of electronics. One critical step in processing the e-waste involves ball milling as a means of preparing the recycling e-waste for the recovery of critical materials. Ball milling is a technique that involves the mechanical crushing and grinding of electronic waste to reduce its size and improve its reactivity during recovery. Our focused recovery technique is based on a microwave recovery technique of these critical materials from e-waste. The size and distribution of the e-waste with …

Not A Do-Or-Die Affair: Freelance Journalists In Nigeria And Ethical Dilemmas, Tolulope O. Olasoji

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study explores the ethical dilemmas Nigerian freelance journalists face and their implications for their work. It will use in-depth interviews with select freelance journalists. Several studies have established that ethical concerns are rife in—and indeed the bane of—journalism in Nigeria. However, these pieces of research reflect the reality across conventional newsrooms, where, ideally, there is some organizational structure and support. No scholarly attention has been given to freelance journalists, otherwise known as entrepreneurial journalists, due to their autonomous nature, to understand the ethical dilemmas they may be entangled in primarily. This study seeks to address this gap in research. …

Development Of A Model Sustainability Management Plan For The City Of Morgantown, West Virginia, Caitlyn Elizabeth Lewis

Graduate Theses, Dissertations, and Problem Reports (ETD)

This report has been prepared to demonstrate the research for a model planning document with a focus on sustainability in Morgantown, WV. It discusses the role of three categories in the context of sustainability and proposes a design solution for selected areas of concern throughout the City of Morgantown in order to demonstrate opportunities for a sustainable approach toward resolution for city officials.

The City of Morgantown, West Virginia, is a college town along the Monongahela River with a backstory of industrialism that is echoed by many other places in Appalachia. However, distinctively, in Morgantown 25,000 college students populate the …

A Program Evaluation Of The West Virginia University Health Science Center Interprofessional Education First-Year Curriculum, Kathryn Lynn Smalley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background: The Interprofessional Education (IPE) First-Year Program was started at the West Virginia University Health Sciences Center in 2013 with the goal of providing participants introductory knowledge of the IPE Core Competencies as defined by the Interprofessional Education Collaborative (IPEC). This program transfers 16 different disciplines out of their isolated educational silos and allows them to learn about, for, and with one another. Participants are introduced to foundational knowledge through several didactic sessions over the course of an academic year. Although the program has been increasingly incorporated by many health sciences disciplines since its inception, it has never officially …

Evaluating The Degradation Relationship Between Latent Print Impressions And Touch Dna Under Varying Environmental Conditions, Katrina M. Rupert B.S.

Graduate Theses, Dissertations, and Problem Reports (ETD)

Latent prints have been processed as a source of touch DNA evidence in the hopes of attaining partial or even full DNA profiles. However, the relationship between the latent quality and the DNA quality has not yet been fully explored, resulting in gaps in understanding how the two are connected. A common source of touch DNA is from latent print evidence, which is typically processed and photographed at a scene, and subsequently processed for DNA in the laboratory. However, there is skepticism in the forensic community around touch DNA as laboratory procedures are often manipulated beyond standard operating procedures to …

Enabling Technologies For Chemical Synthesis: I. Selective Microwave Heating; Ii. Synthesis And Regioselective Cyclotrimerizations Of Tethered 1,6-Diynes, Amir Tavakoli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Reaction discoveries, method developments, and technology advancements lie at the heart of synthetic organic chemistry. These innovations are essential for creating and manipulating complex molecules, which are the building blocks of many important chemical compounds, including pharmaceuticals, materials, and agrochemicals. Here, we first describe new methods to prepare neopentylene-tethered (NPT) 1,6-diynes which are valuable substrates for reaction discovery and target-oriented synthesis, especially in benzannulation strategies toward illudalane natural products. NPT 1,6-diynes have been employed as coupling partners in cyclotrimerization reactions for the synthesis of highly substituted benzene rings which present a persistent challenge in chemical synthesis and are underrepresented scaffolds …

Living Your Best Life: The Mindful Pursuit Of Student-Athlete Thriving, Andrew Augustus

Graduate Theses, Dissertations, and Problem Reports (ETD)

Thriving, or the concurrent experience of healthy well-being and high-level performance, may serve as a valuable construct when studying the optimal student-athlete experience and mindfulness-based interventions (MBIs) have been shown to positively impact well-being and performance. The purpose of the present study began to examine the impact of an MBI for improving student-athlete experiences of thriving via a quasi-experimental longitudinal design. NCAA Division II student-athletes (n = 55) from three sports were randomly assigned to either a control or a 7-session MBI. While comprehensive measures of thriving did not yield significant change for those in the MBI relative to …

Businesses Supposedly Held The Key To The Ada, But They Dropped The Ball: Can Marketing Be The Shot In The Arm America Needs To Bring The Spirit Of The Ada Back To Life?, Elizabeth T. Gratz

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research investigates the historical and current focus of the field of marketing on the disability community and considers whether marketers can positively impact attitudes toward the group through their firm media content. My first essay uses the Rocky Road to Policy Pavers model to discuss the importance of this large and underserved consumer group, and highlights several opportunities for the marketing community to reduce existing barriers to disabled consumers in the marketplace. One way that marketers can reduce stigma and improve attitudes toward the disability community is by strategically portraying individuals with disabilities in their firm media content. My …

Enantioselective Dearomatization Facilitated By Non-Covalent Interactions Of N-Heterocyclic Carbene Catalysts And Pyridinium Salts, Jack A. Patterson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Dihydropyridines are a practical organic scaffold commonly used for their pharmaceutical properties. Nucleophilic dearomatization of pyridines has proven to be a useful method in obtaining dihydropyridines. By using N-heterocyclic carbene (NHC) organocatalysts, dihydropyridines can be synthesized with high regioselectivity of the 1,4 regioisomer over the 1,2- regioisomer but often with low enantioselectivity. By incorporating non-covalent interaction contact points, we hypothesize that enantioselectivity can be enhanced. By synthesizing numerous NHCs, each proposed to exhibit a different type of non-covalent interaction (i.e., hydrogen bonding or ion pairing), an understanding of the secondary interactions within this reaction system can be studied and …

Frp Pedestrian Bridges, Joseph Ryan Virga

Graduate Theses, Dissertations, and Problem Reports (ETD)

Advanced fiber-reinforced polymer (FRP) composites are being used as mainstream structural materials to build complex infrastructure systems. Such application of FRP composites can be attributed to their high strength-to-weight and stiffness-to-weight ratios, corrosion resistance, higher energy absorption, durability, and competitive life-cycle costs. FRP composites are increasingly being considered as suitable alternative structural materials to traditional construction materials such as timber, concrete, and steel.

In this work, detailed experimental investigation has been carried out on different types of glass FRP composite pedestrian bridges with FRP and/or timber deck. Four full-scale FRP pedestrian bridges, including 70`×8.5’ and 70’×10’ single-span bridges, a 16’×8’ …

The B-Cell Role In Autoimmunity, Marissa Marie Mindt

Microbiological Sciences

This review is focused on B-cell’s role in autoimmunity and was conducted by reading current papers across a variety of journals and compiling the information learned in this process. Specifically, this review paper encompasses an analysis of what autoimmune diseases are, as well as some of the characteristics of autoimmune diseases the introduction section of this paper serves as a crash course on B-cell. The disease write-up is where autoimmune diseases that are affected and mediated by B-cells, such as systemic lupus erythematosus, multiple sclerosis, and Chron’s disease, are explored. The next section will compare the mechanisms behind each of …

Survival Of Listeria Monocytogenes On Organic Honeycrisp And Fuji Apples During Storage At 5, 12 And 22.5◦C, Connor S. Freed

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study aimed to evaluate and model the survival of Listeria monocytogenes on organic HoneyCrisp (HC) and Fuji (FJ) apples during storage at various temperatures. Fresh organic HC and FJ apples (without wax coating) obtained from a local wholesale market were inoculated with a 2-strain mix of L. monocytogenes followed by storage at 5.0 (22.9% RH), 12.0 (37.0% RH), and 22.5oC (50.4% RH) for 60, 35, 7 days, respectively, and periodically (day-0 to 60) analyzing microbial populations. Surviving L. monocytogenes were spread-plated on Modified-Oxford agar after 10 or 100-fold serial dilution. Data were analyzed using the mixed-model procedure of SAS …

Intercultural Competence In The Esl Classroom: Challenges And Successes, Breno Santos Rodrigues Pereira

Graduate Theses, Dissertations, and Problem Reports (ETD)

This action-based research study investigated the challenges and successes involved in the teaching of intercultural competence in the English as a Second Language (ESL) classroom. Most studies on intercultural competence take place in English as a foreign language classroom, and very few are centered on ESL instruction. It is this gap in the research that motivated the present study, in which the following research questions were posed: 1) How do targeted training practices in the classroom promote the development of intercultural competence as demonstrated by quantitative data?; 2) What challenges are associated with teaching intercultural competence to ESL learners?; 3) …

Emission Spectroscopy Of Ingaas Quantum Dots Via High-Resolution Fabry-Perot Interferometer, Raju Bhai Kc

Graduate Theses, Dissertations, and Problem Reports (ETD)

Single photons emitted from self-assembled quantum dots have been widely studied to use as a promising qubit for quantum information processing. Therefore, it is critical to fully understand the emission spectra from the quantum dot's excitation if we want to use a single photon as a quantum bit. It is almost impossible to produce rotationally symmetric quantum dots due to various growth conditions and restrictions. So the real quantum dots do not have a perfectly symmetric structure. A broken rotational symmetry causes an asymmetric exchange interaction between electron and hole, leading to a fine structure splitting between two excited states. …

Giving Power To Corporate Social Responsibility: A Case Study Of The Organization-Public Relationship Between A Public Utility And Its Community Stakeholders, Rhyanna C. Wiethe

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of this research is to examine how, if at all, relationships between public utility companies and their stakeholders changes following a corporate social responsibility (CSR) initiative, and based on the results, how can companies restructure their initiatives to better serve their publics in order to build stronger, more positive relationships. A multi-method case study using in-depth interviews and two content analyses (a social media analysis and a news coverage analysis) was used to explore the relationship between a public utility company and a community affected by the implementation of a CSR initiative. The findings suggest that the relationship …

Three Essays On Emotional Cues, Clay Collins

Graduate Theses, Dissertations, and Problem Reports (ETD)

The first paper investigates the relationship between intimate partner violence (IPV) and United States presidential elections. There exists a sizeable literature studying IPV that occurs during or after stressful events (such as a sports team loss), and a considerable non-economics literature examining election-related stress. However, very limited research has been done studying potential negative outcomes after a political loss (when one’s candidate loses), and these findings in other fields have not been synthesized into the economics lexicon. By interacting with the margin of victory for each state, I find large and significant decreases in IPV in states that vote for …

Effects Of Invasive Species On Ohio River Zooplankton, Samuel John Johnston

Graduate Theses, Dissertations, and Problem Reports (ETD)

Invasive species have the potential to dramatically change both aquatic and terrestrial ecosystems with rates of introduction only expected to increase across the Globe. In the Mississippi River basin filter feeding silver (Hypophthalmichthys molitrix) and bighead carp (Hypophthalmichthys nobilis) collectively known as invasive carp were introduced into aquaculture ponds where they subsequently escaped and spread to interconnected basins. Invasive carp have not yet completely established throughout the entire Ohio River. Managers recognize three distinct phases of carp invasion: establishment front, invasion front and presence front. In the Illinois River invasive carp are very well established and …

Development Of Machine Learning Based Approach To Predict Fuel Consumption And Maintenance Cost Of Heavy-Duty Vehicles Using Diesel And Alternative Fuels, Sasanka Katreddi

Graduate Theses, Dissertations, and Problem Reports (ETD)

One of the major contributors of human-made greenhouse gases (GHG) namely carbon dioxide (CO2), methane (CH4), and nitrous oxide (NOX) in the transportation sector and heavy-duty vehicles (HDV) contributing to about 27% of the overall fraction. In addition to the rapid increase in global temperature, airborne pollutants from diesel vehicles also present a risk to human health. Even a small improvement that could potentially drive energy savings to the century-old mature diesel technology could yield a significant impact on minimizing greenhouse gas emissions. With the increasing focus on reducing emissions and operating costs, there is a need for efficient and …

Longest Path And Cycle Transversal And Gallai Families, James A. Long Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

A longest path transversal in a graph G is a set of vertices S of G such that every longest path in G has a vertex in S. The longest path transversal number of a graph G is the size of a smallest longest path transversal in G and is denoted lpt(G). Similarly, a longest cycle transversal is a set of vertices S in a graph G such that every longest cycle in G has a vertex in S. The longest cycle transversal number of a graph G is the size of a smallest longest cycle transversal in G and …

Selective Recovery Of Rare Earth Elements From Acid Mine Drainage Treatment Byproduct, Zeynep Cicek

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements (REEs) are critical in emerging clean energy, advanced technologies, and military defense applications due to their unique physical, chemical, optical, and luminescent properties. Given the potential supply chain restrictions imposed by one country's dominance in the global REE market and the consistently growing demand for REEs, developing the US domestic REE supply chain is imperative. Thus, alternative sources are crucial to supply the demand and prevent interruption in manufacturing products that consume REEs. Concurrently, acid mine drainage (AMD) is a long-standing and widespread global challenge the mining industry encounters. AMD is generated in large volumes and continuously …

Stability Properties Of A System Of Receptors In The Presence Of Attractive Domains, Basim Mohammed Al-Maliki

Graduate Theses, Dissertations, and Problem Reports (ETD)

I use mathematical modeling to understand aspects of molecular processes in living cells. Specifically, we look at the first few steps in cell signaling. Signal initiation requires that receptors located on the cell membrane bind together to form dimers. Microscopic imaging of receptors on the cell membrane revealed that receptors tend to accumulate in small areas (clusters). Studies also show that the membrane has a complex landscape consisting of domains and barriers of various origin.

Here we study the way receptor dimerization is influenced by domains on the cell membrane. Our underlying hypothesis is that the physical and chemical properties …

Influences On Perceptions Of Students With Disabilities Regarding Services And Supports Rendered At Their Collegiate Institution, Taylor Leanne Mikalik

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over the past several generations numerous policies and laws have been established that have allowed people with disabilities to further their education. Students with disabilities enter higher education with varied experiences, which allow for a wide array of perceptions of the services and supports provided on this level. The purpose of this dissertation was to study what these perceptions are and how these perceptions were formed; in hopes to encourage more students with disabilities to self-disclose and access beneficial services in the future. A semi-structured narrative interview was conducted with 8 students willing to self-disclose and who received services and …

Multimodal Neuron Classification Based On Morphology And Electrophysiology, Aqib Ahmad

Graduate Theses, Dissertations, and Problem Reports (ETD)

Categorizing neurons into different types to understand neural circuits and ultimately brain function is a major challenge in neuroscience. While electrical properties are critical in defining a neuron, its morphology is equally important. Advancements in single-cell analysis methods have allowed neuroscientists to simultaneously capture multiple data modalities from a neuron. We propose a method to classify neurons using both morphological structure and electrophysiology. Current approaches are based on a limited analysis of morphological features. We propose to use a new graph neural network to learn representations that more comprehensively account for the complexity of the shape of neuronal structures. In …