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Task-Specific Ionic Liquids For Selective Separation And Recovery Of Rare Earth Elements, Mostafa Khodakarami, Lana Alagha

Patents

The present disclosure is directed to novel functionalized ionic liquids (ILs) that are used, for example, for enhanced recovery and separation of rare earth elements from aqueous solutions. The liquids and processes disclosed herein lead to greater separation efficiency, increased stability of separation materials, increased selectivity, and a reduced amount of waste materials.

Cast Iron Alloy For Automotive Engine Applications With Superior High Temperature Oxidation Properties, Larry Alan Godlewski, Mei Li, Carlos Engler-Pinto, Simon Naumovich Lekakh

Patents

A cast iron alloy is provided with a composition in weight percent (wt.%) of carbon between 2.6 to 3.4 wt.%, silicon between 2.4 to 3.2 wt. %, manganese between 0.3 to 0.6 wt. %, molybdenum between 0.4 to 1.2 wt. %, nickel between 0.6 to 1.75 wt.%, magnesium between 0.01 to 0.075 wt.%, aluminum between 1.8 to 3.5 wt.%, sulfur between 0.003 to 0.025 wt.%, zirconium between 0.001 to 0.02 wt. %, cerium between 0.001 to 0.03 wt. %, lanthanum between 0.0005 to 0.02 wt. %, and a balance of iron and unavoidable trace elements. A part formed from the …

Open-Ended Hollow Coaxial Cable Resonator Sensor, Jie Huang, Chen Zhu, Rex E. Gerald Ii

Patents

An open-ended hollow coaxial cable resonator probe configured to receive an aerosol sample for analysis. A metal post shorts the resonator's inner and outer conductors. A metal plate is spaced apart from an open end of the resonator by a dielectric layer that contains the received aerosol sample. Interrogator circuitry coupled to the resonator transmits an electromagnetic wave within the resonator and generates an electric field at the open end of the resonator. The interrogator circuitry is responsive to the generated electric field for determining a resonance frequency and an impedance of the resonator when the aerosol sample is present …

Metal-Ceramic Composite Powders, Lianyi Chen, Minglei Qu

Patents

A process for manufacturing metal-ceramic composite material powder comprising ball milling metal powder and ceramic nanoparticles to yield a metal-ceramic composite powder comprising ceramic nanoparticles embedded in a metal matrix powder particles; wherein the ball milling is performed using a ceramic milling media and a milling vessel having a ceramic interior surface. Metal matrix nanocomposite powders comprising ceramic nanoparticles imbedded in metal matrix powder particles; wherein the metal matrix powder particles have a spherical shape; wherein there is uniform distribution the ceramic nanoparticles; wherein the nanocomposite powders have good flowability.

Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn C. Morrison

Patents

Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO2.

Turbo Receivers For Multiple-Input Multiple-Output Underwater Acoustic Communications, Yahong Rosa Zheng, Weimin Duan, Chengshan Xiao

Patents

Aspects of the present disclosure include methods for communication using a MIMO channel, such as an acoustic channel for underwater communication. An acoustic receiver may receive a signal comprising information encoded in at least one transmitted symbol. Using a twolayer iterative process, the at least one transmitted symbol is estimated. The first layer of the two-layer process uses iterative exchanges of soft-decisions between an adaptive turbo equalizer and a MAP decoder. The second layer of the two-layer process uses a data-reuse procedure that adapts an equalizer vector of both a feedforward filter and a serial interference cancellation filter of the …

Suppressing Aluminum/Silica Exchange Reaction Between High Aluminum Steel And Mold Flux During Continuous Casting Process, Kuanysh Nurbekuly Yermukhanbetov

Masters Theses

"Mold flux plays one of the critical roles in continuous casting of steel. It performs five primary functions: thermal and chemical insulation, lubrication between the steel strand and mold, absorption of inclusions, and promotion of even heat flux. The aluminum/silica exchange reaction occurring between steel and mold flux during the continuous casting process poses significant challenges in the steel industry. This reaction can lead to various defects in the cast product and adversely affect its surface quality, as well as downstream processing.

In this work, effectiveness of two approaches, namely slag dopant additions and electrochemical techniques, in suppressing the exchange …

Sentiment Strength And Topic Recognition In Sentiment Analysis, Esi A.R. Adeborna

Masters Theses

"Current sentiment analysis methods focus on determining the sentiment polarities (negative, neutral or positive) in users’ sentiments. However, in order to correctly classify users’ sentiments into their right polarities, the strengths of these sentiments must be considered. In addition to classifying users’ sentiments into their correct polarities, it is important to determine the sources and topics under which users’ sentiments fall. Sentiment strength helps as to understand the levels of customer satisfaction toward products and services. Sentiment topics on the other hand, helps to determine the specific product/service areas associated with user sentiments. This paper proposes two sentiment analysis approaches. …

Incorporating Novel Sensors For Reading Human Health State And Motion Intent Into Real-Time Computing Systems, Adam Sawyer

Masters Theses

"Integrating sensors that read states of the human body into everyday life is an increasing desire, especially with the rise of deep learning which requires vast stores of data to make predictions. This work explores integrating these sensors into the human experience through two methods and recording the results. The first of these methods integrates a MXene based field-effect transistor sensor for the 2019-nCov spike protein with a mobile app. This allows the user to read how saturated their breath is with Covid-19. The second method integrates 3D-printed pressure sensors, and a motion capture system, into a glove to read …

Scalable And Continuous Fabrication Of Dendrimer Based Gene And Protein Delivery Systems, Joseph Johnston

Masters Theses

"Gene and protein therapeutics play critical roles in the drug market and represent the future of biopharmaceuticals. Polymeric nanoparticle-based gene/protein delivery systems are promising owing to their ability to protect the cargo from degradation, improving intracellular delivery and transfection efficiency as well as abundant sources and flexibility to be modified. Yet the successful industrialized production and clinical application of polymeric nanoparticle-based delivery systems have long been limited by unsatisfied delivery efficiency and the lack of reproducible and scalable methods for the preparation of uniform nanoparticles with good batch to batch consistency. To address the unsatisfied efficacy and difficulty in scale-up …

A Hybrid Framework For Critical Infrastructures Interdependency Modeling, Simulation, And Analysis, David Corder Hinton

Masters Theses

"Flow system models, also known as flow network models, encompass vastly complex, ever-expanding problem sets which comprise the foundation for maintenance, operation, and improvement of critical infrastructures around the world. The stable operation of these vast critical infrastructures is fundamental to the continued advancement of modern society. These infrastructures are tightly interdependent and vulnerable to interruption by both natural circumstance and malicious targeting. This necessitates representation of such critical infrastructures and their multi-domain interdependencies in defense focused constructive and virtual simulation environments as a matter of national interest and security. By breadth exploration of the problem space, this work body …

A Network Of Low-Cost Multi-Pollutant Air Quality Sensors For Evaluating Fine-Scale Exposure Disparity In Twin Cities, Mn, P M Varuni Abhayaratne

Masters Theses

"Poor air quality is detrimental to health and is a leading environmental risk factor for early death globally. The massive scale of urbanization and population growth has led urban air quality to become a global concern as the release of air pollutants into the atmosphere continues to increase. Air quality has traditionally been monitored using reference-grade monitoring stations that are expensive and sparsely distributed. Low-cost sensors can complement existing regulatory networks to provide more spatial detail, capturing fine-scale variations. This study investigates spatiotemporal pollutant patterns, exposure disparities and environmental justice using data collected from a two-year (2019-2021) deployment of a …

Tropospheric Correction For Insar Using Machine Learning, Ngo Hi Kenny Yue

Masters Theses

"Interferometric Synthetic Aperture Radar (InSAR) is a popular technique for studying Earth's surface deformation caused by phenomena like earthquakes and subsidence. However, its accuracy is limited by tropospheric delays caused by water vapor in the atmosphere. This limitation can be overcome by using methods that correct for tropospheric noise, such as statistical, empirical, and predictive approaches. This study explores the potential of using machine learning algorithms to predict the zenith total delay caused by tropospheric effects in InSAR measurements. The study employs two different machine learning algorithms, random forest and neural networks, to learn the relationship between numerical weather prediction …

Computer Vision In Adverse Conditions: Small Objects, Low-Resoltuion Images, And Edge Deployment, Raja Sunkara

Masters Theses

"Computer vision based on deep learning is an essential field that plays a significant role in object detection, image classification, semantic segmentation, instance segmentation, and other applications. However, these models face significant challenges in adverse conditions, such as small objects, low-resolution images, and edge deployment. These challenges limit the accuracy and efficiency of computer vision algorithms, making it difficult to obtain reliable results.

The primary objective of this thesis is to assess the performance of deep learning- based computer vision models in challenging conditions and provide viable solutions to overcome the obstacles. The study will specifically address three key challenges, …

Selecting Consolidation Procedures For Making Concrete Specimens, Paige Marie Toebben

Masters Theses

"The goal of this research was to reevaluate ASTM C31 Standard Practice for Making and Curing Concrete Test Specimens in the Field, as well as deepen our understanding of the relationship between the consolidation process, concrete composition, and workability. An improved understanding of this area will help to reduce variability in concrete quality. The project involved evaluating the effect of different consolidation methods on concrete specimens with changing levels of workability. To do this, concrete cylinders were created with varying viscosities by adjusting the water-to-cement ratio (w/c) and water-reducing agent. More cylinders were created with varying paste volumes while keeping …

Static I-V Curve And Aging Test For Pim Characterization In Metallic Contacts, Kalkidan Anjajo

Masters Theses

"Spring clips and fabric-over-foams (FOFs) are widely used in mobile devices for electrical connection purposes. However, the imperfect metallic connections tend to induce passive intermodulation (PIM), resulting in a receiver sensitivity degradation, known as RF desensitization. Due to the complexity of the PIM characterization, there is not yet a way to evaluate PIM performance using a simple setup for environments like factories. In this study, a current-voltage (I-V) behavior-based PIM evaluation method is proposed and validated with various metallic contacts and contact forces. The test results demonstrated the feasibility of the PIM performance evaluation based on the measured static I-V …

Real-Time Air Gap And Thickness Measurement Of Continuous Caster Mold Flux By Extrinsic Fabry-Perot Interferometer, Abhishek Prakash Hungund, Hanok Tekle, Bohong Zhang, Ronald J. O'Malley, Jeffrey D. Smith, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

Mold Flux plays a critical role in continuous casting of steel. Along with many other functions, the mold flux in the gap between the solidifying steel shell and the mold serves as a medium for controlling heat transfer and as a barrier to prevent shell sticking to the mold. This manuscript introduces a novel method of monitoring the structural features of a mold flux film in real-time in a simulated mold gap. A 3-part stainless-steel mold was designed with a 2 mm, 4 mm and, 6 mm step profile to contain mold flux films of varying thickness. An Extrinsic Fabry-Perot …

Characterization Of Virgin, Re-Used, And Oxygen-Reduced Copper Powders Processed By The Plasma Spheroidization Process, M. Hossein Sehhat, David Perez-Palomino, Connor Wiedemeier, Tristan Cullom, Joseph William Newkirk

Materials Science and Engineering Faculty Research & Creative Works

Fabrication of parts with high mechanical properties heavily depend on the quality of powder deployed in the fabrication process. Copper powder in three different powder types were spheroidized using radio-frequency inductively coupled plasma (ICP) spheroidization process (TekSphero-15 system). The characterized powders include virgin powder as purchased from the powder manufacturer, powder used in electron beam powder bed fusion (EB-PBF) process, and reconditioned powder, which was used powder that underwent an oxygen-reduction treatment. The goal of spheroidizing these powder types was to evaluate the change in powder morphology, the possibility of enhancing the powder properties back to their as-received conditions, and …

Thermal And Electrical Properties Of Spark Plasma Sintered (Ti,Cr)B2 Ceramics, Steven M. Smith, Lun Feng, William Fahrenholtz, Gregory E. Hilmas, Laura Silvestroni

Materials Science and Engineering Faculty Research & Creative Works

Thermal and electrical properties were measured for TiB2 ceramics containing varying CrB2 contents up to 33 mol%. The room-temperature thermal diffusivity decreased with increasing Cr content from 0.330 ± 0.003 cm2/s for pure TiB2 to 0.060 ± 0.003 cm2/s for (Ti0.66Cr0.33)B2. The amount of anisotropy in the coefficients of thermal expansion increased with increasing Cr content and the c-axis had the greatest dependence on Cr addition, with an increase of more than 25% in the thermal expansion for 33 mol% CrB2 compared to TiB2, whereas the a-axis only increased by about 8%. The electrical conductivity was the lowest for (Ti0.66Cr0.33)B2 …

Thermal And Electrical Properties Of Spark Plasma Sintered (Ti,Cr)B2 Ceramics, Steven M. Smith, Lun Feng, William Fahrenholtz, Gregory E. Hilmas, Laura Silvestroni

Materials Science and Engineering Faculty Research & Creative Works

Thermal and electrical properties were measured for TiB₂ ceramics containing varying CrB₂ contents up to 33 mol%. The room-temperature thermal diffusivity decreased with increasing Cr content from 0.330 ± 0.003 cm²/s for pure TiB₂ to 0.060 ± 0.003 cm²/s for (Ti_0.66Cr_0.33)B2. The amount of anisotropy in the coefficients of thermal expansion increased with increasing Cr content and the c-axis had the greatest dependence on Cr addition, with an increase of more than 25% in the thermal expansion for 33 mol% CrB₂ compared to TiB₂, whereas the …

Superheating Field In Superconductors With Nanostructured Surfaces, W. P. M. R. Pathirana, A. Gurevich

Physics Faculty Publications

We report calculations of a dc superheating field H_sh in superconductors with nanostructured surfaces. Numerical simulations of the Ginzburg-Landau (GL) equations were performed for a superconductor with an inhomogeneous impurity concentration, a thin superconducting layer on top of another superconductor, and superconductor-insulator-superconductor (S-I-S) multilayers.The superheating field was calculated taking into account the instability of the Meissner state with a nonzero wavelength along the surface, which is essential for realistic values of the GL parameter κ. Simulations were done for the materials parameters of Nb and Nb₃Sn at different values of κ and the mean free paths. We …

Searching For Prompt And Long-Lived Dark Photons In Electroproduced E⁺ E⁻ Pairs With The Heavy Photon Search Experiment At Jlab, P. H. Adrian, N. A. Baltzell, M. Battaglieri, M. Bondí, S. Boyarinov, S. Bueltmann, P. Butti, V. D. Burkert, D. Calvo, T. Cao, M. Carpinelli, A. Celentano, G. Charles, L. Colaneri, W. Cooper, D. Crowe, C. Cuevas, A. D'Angelo, N. Dashyan, B. Wojtsekhowski, Et Al.

Physics Faculty Publications

The heavy photon search experiment (HPS) at the Thomas Jefferson National Accelerator Facility searches for electroproduced dark photons. We report results from the 2016 engineering run consisting of 10 608  nb⁻¹ of data for both the prompt and displaced vertex searches. A search for a prompt resonance in the e⁺e⁻ invariant mass distribution between 39 and 179 MeV showed no evidence of dark photons above the large QED background, limiting the coupling of ε²≳10⁻⁵, in agreement with previous searches. The search for displaced vertices showed no evidence of excess signal over background …

Temperature, Rf Field, And Frequency Dependence Performance Evaluation Of Superconducting Niobium Half-Wave Coaxial Cavity, N. K. Raut, G. Ciovati, S. U. De Silva, J. R. Delayen, P. Dhakal, B. D. Khanal, J. K. Tiskumara

Physics Faculty Publications

Recent advancement in superconducting radio frequency cavity processing techniques, with diffusion of impurities within the RF penetration depth, resulted in high quality factor with increase in quality factor with increasing accelerating gradient. The increase in quality factor is the result of a decrease in the surface resistance as a result of nonmagnetic impurities doping and change in electronic density of states. The fundamental understanding of the dependence of surface resistance on frequency and surface preparation is still an active area of research. Here, we present the result of RF measurements of the TEM modes in a coaxial half-wave niobium cavity …

First Measurement Of The Emc Effect In ¹⁰B And ¹¹B, A. Karki, D. Biswas, F. A. Gonzalez, W. Henry, C. Morean, A. Nadeeshani, A. Sun, D. Abrams, Z. Ahmed, B. Aljawrneh, S. Alsalmi, R. Ambrose, D. Androic, W. Armstrong, J. Arrington, D. Asaturyan, K. Assumin-Gyimah, C. Ayerbe Gayoso, A. Bandari, J. Zhang, Et Al., Hall C. Collaboration

Physics Faculty Publications

The nuclear dependence of the inclusive inelastic electron scattering cross section (the EMC effect) has been measured for the first time in ¹⁰B and ¹¹B. Previous measurements of the EMC effect in A ≤ 12 nuclei showed an unexpected nuclear dependence; 10^B and 11^B were measured to explore the EMC effect in this region in more detail. Results are presented for ⁹Be, ¹⁰B, ¹¹B, and ¹²C at an incident beam energy of 10.6 GeV. The EMC effect in the boron isotopes was found to be similar to …

Crab Cavities For Ilc, P. A. Mcintosh, S. A. Belomestnykh, G. Burt, R. Calaga, S. U. De Silva, J. R. Delayen, I. V. Gonin, T. N. Khabiboulline, A. Lunin, T. Okugi, Y. M. Orlov, S. Verdú-Andrés, B. P. Xiao, V. P. Yakovlev, A. Yamamoto

Physics Faculty Publications

For the 14 mrad crossing angle proposed, crab cavity systems are fundamentally anticipated for the viable operation of the International Linear Collider (ILC), in order to maximise its luminosity performance. Since 2021, a specialist development team have been defining optimum crab cavity technologies which can fulfil the operational requirements for ILC, both for its baseline centre-of-mass energy of 250 GeV, but also extending those requirements out to higher beam collision intensities. Five design teams have established crab cavity technology solutions, which have the capability to also operate up to 1 TeV centre-of-mass. This presentation showcases the key performance capabilities of …

Machine-Assisted Discovery Of Integrable Symplectic Mappings, T. Zolkin, Y. Kharkov, S. Nagaitsev

Physics Faculty Publications

We present a new automated method for finding integrable symplectic maps of the plane. These dynamical systems possess a hidden symmetry associated with an existence of conserved quantities, i.e., integrals of motion. The core idea of the algorithm is based on the knowledge that the evolution of an integrable system in the phase space is restricted to a lower-dimensional submanifold. Limiting ourselves to polygon invariants of motion, we analyze the shape of individual trajectories thus successfully distinguishing integrable motion from chaotic cases. For example, our method rediscovers some of the famous McMillan-Suris integrable mappings and ultradiscrete Painlevé equations. In total, …

Simulations Of Radiations Reaction In Inverse Compton Scattering, E. Breen, E. Rogers, E. Johnson, B. Terzić, G. Krafft, G. Wilson

Physics Faculty Publications

The effect of radiation reaction is often negligible in inverse Compton scattering. However, in the nonlinear Compton regime, at high laser fields and high electron beam energies where electron recoil must be properly accounted for, there is experimental data which demonstrates the onset of radiation reaction * . We model the radiation reaction as a series of emissions from individual electrons with decreasing energy. This allows us to use the code we previously developed for simulating single-emission inverse Compton scattering events ** . We use the new code to simulate the experiment reported in Cole et al. 2018, and to …

Development Of A Novel Readout Concept For An Eic Dirc, K. Dehmelt, A. Deshpande, R. Dzhygadlo, T. K. Hemmick, Md. I. Hossain, C. E. Hyde, Y. Ilieva, G. Kalicy, P. Nadel-Turonski, C. Schwarz, J. Schwiening, N. Shankman, J. Stevens, N. Wickramaarachchi, C. Woody

Physics Faculty Publications

The objective of this program is to pursue opportunities to reduce the material budget and the cost of the DIRC counter for the EIC, without loss of performance, by investigating fundamental DIRC performance limits and new optical configurations. The barrel high-performance DIRC (hpDIRC) has been adopted for the ePIC detector and is an attractive solution for Detector-2. In this program, we study the DIRC performance with an innovative optical configuration consisting of narrow, thin radiator bars coupled to wide plates, focusing lenses, and small expansion volume prisms. The outcomes of these studies would be applicable to both ePIC and, in …

Analytic And Numerical Calculation Of Collider Luminosity With Crab Dynamics, H. Huang, T. Satogata, Y. Zhang, Y. Roblin, F. Lin, S. Zhao

Physics Faculty Publications

For an integral part of electron-ion collider (EIC) design, the crab crossing scheme provides a head-on collision for beams with a nonzero crossing angle. Recently we provided a framework for accurate numerical simulations of beam-beam effects with crabbing crossing dynamics. The framework was implemented in a simulation code package named “CASA BeamBeam”. We offer com-prehensive formulas for calculation of collider luminosity for various cases in the code package. The luminosity calculation module of CASA Beam-Beam now includes the hourglass effect, the beam-tilt effects and the beam offset effect. The benchmarking results show good agreement between the numerical calculation and analytic …

Orbital Stabilization Of Underactuated Systems Using Time Period Regulation, Nilay Kant, Ranjan Mukherjee

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A new approach to orbital stabilization of under-actuated systems with one passive degree-of-freedom (DOF) is presented. Virtual holonomic constraints are enforced using partial feedback linearization; this results in a dense set of periodic orbits on a constraint manifold. Every orbit on the constraint manifold is associated with a unique time-period. A desired orbit is selected, and the impulse controlled Poincaré map (ICPM) approach is utilized to stabilize the orbit by regulating the time-period. By treating the time period as the output, it is possible to design a dead-beat controller that achieves orbital stabilization in a single time-step. The effectiveness of …