Digital Commons Network^™

Rans-Dns Simulations For Uncertainty Quantification In Dns Data Of Turbulent Mixing Layer, Mohamed Abuhegazy

Mechanical Engineering ETDs

Mixing layer flow is one of the canonical free shear flows in fluid dynamics. Such a flow is formed when two fluid streams move along one another with different velocities. Investigation of this flow development has been an active topic of research for many decades not only due to a wide range of environmental and technological applications where this flow may be observed, but also because of large discrepancies in the results obtained experimentally and numerically regardless this flow simple geometry. In this dissertation, the quality and uncertainty of extracted turbulent statistics of mixing layer flow are analyzed by applying …

Librarian' Understanding, Perception, And Attitudes Regarding Cloud Computing In Academic Libraries Punjab, Pakistan: A Survey, Shahid Mehmood, Prof.Dr.Rais Ahmed Samdani, Muhammad Wahid

Library Philosophy and Practice (e-journal)

People who used the University of Sargodha library were asked what they thought about Cloud Computing for the study. The goal of this study was to find out more about how people feel about cloud computing in general and how well they understand it. There were both descriptive and quantitative methods used in the study. Over sixty-nine people were asked to take part in the study, and 65 were randomly picked from the census. The study used SPSS version 21 to turn table data with numbers into percentages and rates. Most people know what Cloud Computing is and how it …

Open Educational Resources (Oer) Repositories: A Comprehensive Analysis Of Usage Patterns And Impact On Education, Dr. Rajib Kumar Das, Dr. Anuradha Singha

Library Philosophy and Practice (e-journal)

The significance of this research lies in its potential to inform educators, policymakers, and stakeholders about the transformative influence of OER on contemporary education. By understanding the utilization patterns and outcomes associated with OER repositories, educational institutions can make informed decisions to enhance teaching methodologies, improve resource allocation, and contribute to the overall advancement of inclusive education. This study serves as a guide for navigating the evolving educational landscape shaped by OER.

Originality of the Study:

This research stands out in its originality by offering a holistic examination of the entire lifecycle of OER, from adoption to impact. The detailed …

Fabrication & Characterization Of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators Via Fusion Deposition Modeling, Khaled El Toukhy

Theses and Dissertations

This thesis aims to discuss the potential of using piezoelectric and triboelectric nanogenerators (PTENGs) for energy harvesting, particularly in the sportswear industry. PTENG's main advantage is that it offers good flexibility making it suitable for high-strain applications. The piezoelectric effect is induced by embedding piezoelectric nanofillers into one of the two triboelectric layers. PTENGs can generate both piezoelectric and triboelectric signals when strained resulting in an enhanced output compared to regular piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs). TPU was adopted as the matrix for PTENGs advantageous due to their flexibility, low electrical resistivity, and compatibility with additive manufacturing techniques. …

Best Practices For English Learners With Disabilities In Us Schools – A Systematic Review, Samiratu Bashiru, Jennifer E. Smith

Journal of English Learner Education

This systematic review investigated best practices for enhancing academic achievement among English Learners with Disabilities (ELDs) in US schools. By examining 17 peer-reviewed articles and comparing them to the CEC 2014 Quality Indicators, the study identifies significant practices, including culturally responsive methods, technology integration, evidence-based strategies, addressing service delivery challenges, and improving assessment tools. This review has limitations related to inconsistent terminology and highlights the need for standardized language and continued research. It recommends integrating culturally responsive practices, leveraging technology, and refining inclusive assessment tools. This review provides educators, policymakers, and researchers insights, emphasizing ongoing teacher development and policy alignment …

Factors Influencing The Occurrence Of Rework In Terms Of Risk-Based Communication Management In Construction Projects, Virani Mayniana, Rossy Armyn Machfudiyanto

Smart City

Rework in a construction project is an unplanned and unwanted activity that requires an action to repeat part or all the work to meet project standards or requirements and, in its implementation, causes increased work, time, and costs. Based on previous studies that discuss the factors that cause rework, poor communication management or coordination between stakeholders is one of the causes of rework. Therefore, a literature study was conducted to identify project communication management risks that allow rework to occur and resulted in 54 communication management risk factors. Furthermore, the results of the literature study were validated by experts who …

Mental Health Effects Of The Covid-19 Pandemic On Aging Lesbian, Gay, Bisexual, Transgender, And Queer Populations., Iliza Minaya, Samuel Raine, Arkene Levy, Chasity B O'Malley

HPD Articles

INTRODUCTION: The COVID-19 pandemic affected numerous subpopulations of people in unique ways. This study evaluated the impact of the COVID-19 pandemic on the mental health status of Broward County's aging lesbian, gay, bisexual, transgender, and queer (LGBTQ) seniors and identified strengths, weaknesses, and opportunities for interventions to enhance positive mental health outcomes. The study was performed from April 2021 through July 2021.

METHODS: Online surveys measuring anxiety, depression, social support, and resilience were delivered by email to 47 residents of Wilton Manors, Florida. Study data were collected and collated using research electronic data capture tools with bivariate analysis using the …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu

Turkish Journal of Chemistry

In this paper, a novel Fenton reaction system which was called MHACF-MIL-100(Fe) was constructed. In this system, based on active hydrogen-accelerated FeIII reduction, the hydroxyl radical was continuously produced with a trace amount of total iron. The MIL-100(Fe) modified with the nano-Pd0 particle could be used to activate the H2. Under normal temperature and pressure, the target organic pollutants, such as sulfamethazine and 4-chloro phenol, could be degraded fast. In the condition of initial aqueous solution pH 3, 2 g L–1 dosage of MIL-100(Fe) catalyst loaded with nano-Pd0, Pd/MIL-100(Fe), 20 mM 30 wt% hydrogen peroxide, 25 μM ferrous chloride and …

Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin

Turkish Journal of Chemistry

In the present work novel conductive organic-inorganic nanocomposites were produced by grafting of pyrrole monomer onto silanized Laponite RD utilizing emulsion graft polymerization. Influence of some important factors like concentration of monomer, initiator and surfactant were investigated on grafting efficiency. Grafting of polypyrrole chains onto modified Laponite RD was verified by Fourier transform infrared spectroscopy (FT-IR). Scanning electron microscope (SEM) revealed the spherical particles of nanocomposite with average diameter of 271.5 nm. XRD pattern showed that molecular framework of pure polypyrrole almost remains same in nanocomposite. Surface area and pore volume of Laponite RD, measured by Brunauer-Emmett-Teller (BET) analysis, was …

Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat

Turkish Journal of Chemistry

The transport properties of Co2+ ions from the aqueous donor phase to aqueous acceptor phase with the recently developed multidroplet liquid membrane (MDLM) extraction system were studied. This system serves as a continuous process for the transportation of ions and requires fewer reagents for starting and conducting the procedure. Moreover, the procedure results in fewer waste chemicals and mixtures in comparison to traditional extraction methods. During extraction, bis(2-ethylhexyl) phosphate (D2EHPA) was used as a carrier material and 5% potassium thiocyanate (KSCN) solution was used to obtain a colored complex for UV-Vis detection. By means of several experiments, the optimum D2EHPA …

Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya

Turkish Journal of Chemistry

A weak acidic complex ester (CE) in solid form was prepared by a condensation reaction between very weak boric acid (BA: H3BO3) and (D)-mannitol (MA: C6H14O6) by the molar ratio of BA/MA = 2. A boron carbide (B4C) precursor was obtained from heating of the CE at 400 °C for 4 h. The precursor was pyrolyzed under argon flow in the interval of 1300–1550 °C for 4 h and at 1400 °C for 1–4 h, respectively. The materials were examined using several techniques such as X-ray diffraction analysis, thermal analysis, scanning electron microscopy, particle size distribution, and nitrogen adsorption/desorption. The …

Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül

Turkish Journal of Chemistry

Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …

Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang

Turkish Journal of Chemistry

In this study, mixed matrix membranes (MMMs) composed of poly(vinyl alcohol) (PVA) and porous ZSM-5 zeolite are thoroughly investigated for concentrating alcohols of ethanol and n-propanol via dewatering pervaporation. The effects of the zeolite content (10–30 wt.%), feed composition (5–30 wt.% water), and feed temperature (50–90 °C) on the pervaporation flux/separation factor and component permeance/selectivity of these MMMs are examined in detail. These MMMs achieve higher separation efficiency and pervaporation flux than their pure PVA counterparts as expected, even if the dehydration results strongly depend on the pervaporation conditions. The disparity in pervaporation performances acquired for different alcohol solutions may …

Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel

Turkish Journal of Chemistry

This study aimed to investigate the photocatalytic and photodynamic actions of a 2,6-diiodinated-BODIPY (2,6-diI2-Bod) photosensitizer (PS) covalently linked to TiO2 nanoparticles (NPs). The TiO2 NPs were synthesized utilizing the hydrothermal technique, yielding an average particle size of 4–5 nm as ascertained by transmission electron microscopy and 6.4 nm as determined by dynamic light scattering measurements. The integration of the nonsoluble Bod PS to TiO2 NPs provided increased dispersibility in physiological media, making it more applicable to photodynamic therapy applications. Bod-TiO2 NPs exhibited moderate efficiency of 56.9% in singlet oxygen generation. Additionally, the photocatalytic behavior of the TiO2 NPs was evaluated …

Photophysical, Thermal, And Dft Studies On A Tetraaryl-Azadipyrromethene Ligand And Its Zinc(Ii) Complex, Gökhan Sevi̇nç

Turkish Journal of Chemistry

An azadipyrromethene ligand (H1) and homoleptic zinc(II) (H1-Zn) complex were synthesized. The resulting structures were elucidated by NMR, FTIR, and HRMS techniques. The photophysical properties and effects of complexing the zinc(II) atom to azadipyrromethene ligands in solution were studied by means of UV-Vis absorption and fluorescence spectroscopy. Experimental findings were elucidated using density functional theory computations and interfragment charge transfer (IFCT) and electron-hole analyses. The fluorescence features were found to be negligible. The ligand molecule decayed at a rate of 3% while the complex decayed at 2% upon photoirradiation based on photostability experiments. The singlet oxygen quantum yields of the …

Synthesis And Singlet Oxygen Generation Of Boron- 2-(4,5-Dibromo-1h-Imidazole-2-Yl)-3,5-Dipyrazolopyridine Complex For Antimicrobial Photodynamic Therapy, Zeynep Ekmekçi̇, Seda Karaoğlu

Turkish Journal of Chemistry

In this study, the pyridine side of a boron 2-(2'-pyridyl) imidazole (BOPIM) core, which has very few derivatives synthesized in the literature and can show fluorescence properties in solid form, was derivatized with 1-methylpyrazole, predicted to have activity against fungi or bacteria according to the literature. Additionally, its imidazole side was brominated to increase the efficiency of singlet oxygen production by increasing the intersystem crossing. The photophysical properties of the new synthesized BOPIM derivative were investigated in general organic solvents with different polarities. While the wavelength of the maximum absorbance was determined as 406 nm in CH2Cl2 and THF, the …

Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t

Turkish Journal of Chemistry

Cr(VI), which has toxic effects, is a heavy metal and it must be removed from the environment due to the various damages it causes. In this study, the removal of Cr(VI) pollutants from aqueous solutions with Fe3O4-based materials using a batch adsorption technique was investigated. Magnetically modified graphene nanoplatelet (GNP)-based nanocomposites were prepared and their structures were characterized by FTIR, XRD, SEM, BET, and TGA techniques. The effects of various physicochemical parameters such as adsorbent dose, contact time, initial Cr(VI) solution concentration, pH, and the presence of coexisting ions (NaCl) on the adsorption process were investigated. Accordingly, the optimum conditions …

Intercalation Of Pyrazolone-Based Oxalamide Metal Complexes Into Na-Montmorillonite For Catalytic Liquid-Phase Oxidation Of Phenol Using H2o2, Serhat Uzan, Eyüp Başaran

Turkish Journal of Chemistry

The intercalation of pyrazolone-based oxalamide metal complexes into Na-montmorillonite (Na-MMT) for catalytic liquid-phase oxidation of phenol using H2O2 was undertaken by a flexible ligand method using metal ions including Mn(II), Zn(II), and Sn(II). First, the metal ions were exchanged with the sodium ions of Na-MMT, and then these metal ions were complexed with a new pyrazolone-based oxalamide ligand. The intercalated metal complexes were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, elemental analysis, and thermogravimetric analysis. Phenol was successfully oxidized by heterogeneous catalysts based on Mn(II), Zn(II), and Sn(II) pyrazolone-based oxalamide complexes intercalated into …

Production Of Gelatin Fibrous Mats Using Different Nanofiber Production Methods For Medical Applications And Comparison Of Their Properties, Melike Güngör, Kevser Sağlamkol, Zeynep Yağmur Baydemi̇r, Ali̇ Kiliç

Turkish Journal of Chemistry

In the literature, there are studies on medical applications using different nanofiber production methods with natural polymers. However, each system has different fiber-forming capabilities. For this reason, in this study, we investigated the production of nanofibers from a biodegradable natural polymer, gelatin, using four separate nanofiber production methods, namely electrospinning (ES), electroblowing (EB), solution blowing (SB), and centrifugal spinning (CS). Our aim was to determine the most suitable fibrous web structure for medical applications and contribute to science in this respect. It was observed that the thinnest fibers (386 nm) and the heaviest mats (15.975 g m–2) were produced by …

Ph Responsive Curcumin Released From Urea-Amine Group Functionalized Mesoporous Organosilica Nanoparticles, Osman Tayyar Arli, Yaşar Gök, Hali̇l Zeki̇ Gök

Turkish Journal of Chemistry

Studies on natural products with anticancer properties have gained more importance in recent years in order to not damage healthy tissues during cancer treatments or to perform the treatment causing the least damage. Curcumin is a common natural product with anticancer properties, but its low solubility, instability, and bioavailability have limited its use in clinical applications in cancer research. As a proposed solution to this problem, a new mesoporous organosilica nanocarrier (MON-A) functionalized with a 1,2-diphenylethane-1,2-diamine structure capable of pH-controlled release was prepared in this study. MON-A was characterized by TGA, BET, XRD, FT-IR, and SEM-EDS analyses. Dispersion of MON-A …

Quaternized Chitosan/Pva/Natural Bioactive Agent Electrospun Wound Scaffolds: Production, Characterization, And Investigation Of Release Kinetics, Ezgi Eren Belgin, Cankiz Gi̇zem Deli̇balta

Turkish Journal of Chemistry

Quaternized chitosan (HTCC) was synthesized and characterized to increase chitosan solubility. Then HTCC was electrospun with poly (vinyl alcohol) (PVA) and prepared natural bioactive agent (Calendula officinalis) extract was loaded onto fibers for wound scaffold applications. Morphological, structural, and mechanical characterization of the produced wound scaffolds was performed and their in vitro bioactive component release behavior was investigated. As a result, it was observed that the degree of quaternization of chitosan was 0.89, and synthesized HTCC was soluble in acidic, basic, alkaline media and could be electrospun with PVA in the presence of a natural bioactive agent. The presence of …

Determining The Presence And Size Of Shoulder Lesions In Sows Using Computer Vision, Shubham Bery, Tami M. Brown-Bandl, Bradley T. Jones, Gary A. Rohrer, Sudhendu Raj Sharma

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Shoulder sores predominantly arise in breeding sows and often result in untimely culling. Reported prevalence rates vary significantly, spanning between 5% and 50% depending upon the type of crate flooring inside a farm, the animal’s body condition, or an existing injury that causes lameness. These lesions represent not only a welfare concern but also have an economic impact due to the labor needed for treatment and medication. The objective of this study was to evaluate the use of computer vision techniques in detecting and determining the size of shoulder lesions. A Microsoft Kinect V2 camera captured the top-down depth and …

Design Optimization Of The Lift Mechanism In The Robotic Walking Training Device Using The Engineering Design Methodology, Austin Bourgeois, Brian Rice, Chung-Hyun Goh

Mechanical Engineering Faculty Publications and Presentations

Partial paralysis caused by spinal cord injury (SCI) or stroke are two of the most prevalent forms of physical disability. Through proper gait training, people with incomplete SCI have more potential to retain or regain the ability to walk than those with complete SCI. To help patients who have these disabilities regain the function of walking unassisted, the robotic walking training device (RWTD) has been developed to perform gait rehabilitation. This research plays a pivotal role in advancing medical robotic technology and gait rehabilitation by conducting a comprehensive evaluation and comparison of three lift mechanisms. Specifically, the lift mechanisms are …

Enhanced Solar Tracking System Using Internet Of Things Technology, Qawiem Naif Qisti, Noramalina Abdullah, Khairul Azman Ahmad

Platform: A Journal of Engineering

Solar energy has grown in popularity in recent years. Conventional solar panels cannot provide enough energy to meet consumer demand. Therefore, more solar panels are needed to meet consumer demand. The Internet of Things (IoT) Solar Tracker maximises solar energy collecting by connecting the physical and digital worlds. This study integrates IoT to improve solar tracker performance. Blynk uses the NodeMCU ESP8266 control unit to monitor voltage, current, and power usage. This research uses the Arduino IDE, a photoresistor sensor, and a current sensor, INA219. This work advances solar energy efficiency. By comparing solar panel electrical qualities in different environments, …

Improved Design For Horizontal Axis Wind Turbine Blades With Winglets, Hamza Ben Ahmadi, Yousef Abdulbari Atfah, Catherine Kamal Samy, Lujain Subhi, Haya Fares Turkmani, Sharul Sham Dol

Platform: A Journal of Engineering

The horizontal axis wind turbine blades are modified to enhance the turbine's aerodynamic performance. The performance of the modified geometry was evaluated by comparing the lift, drag and torque findings to the same propeller with a straight leading edge. The symmetrical airfoil of NACA 0012 was chosen for the turbine blade profiles. The computational fluid dynamics (CFD) simulation was performed using the shear stress transport (SST) k-ω turbulence model to capture the vortical structures for the inlet wind speed of 20 m/s. From the simulation results, it has been shown that the four blades with winglets at 15° angle of …

Performance Analysis Of Solar Water Heater: A Case Study In Al Seeb, Oman, Zainab Albalushi, Girma T. Chala, Sreejaya K.V.

Platform: A Journal of Engineering

The 2040 vision of the Sultanate of Oman has given remarkable attention to providing green energy supplies to different sectors in the country. The solar water heater system is projected to boost Oman's renewable energy utilisation and help achieve the country’s energy sustainability. Due to extreme weather conditions, electric water heaters consume most of the electricity, mainly during the winter. In this study, the evacuated tube solar water heater was installed, and the system's performance at different inclination angles and weather conditions was investigated. The experiment was conducted during various weather conditions and at three different inclination angles, such as …

A Comparative Analysis Of Cryogenic, Adsorption And Amine-Based Absorption Techniques For Co₂ Capture, Siti Nuraishah Zuraidi, Hazlina Husin

Platform: A Journal of Engineering

Cryogenic carbon capture (CCC), adsorption-based CO2 capture and amine-based absorption are the key carbon capture and storage (CCS) technologies discussed in this review paper. This paper analysed these techniques' fundamental mechanisms, advantages, disadvantages and developments. This paper revealed the promising role of adsorption-based CO2 capture utilising solid adsorbents, emphasises the potential of cryogenic carbon capture for capturing and storing CO2, and examines widely used amine-based absorption technology. The comparison of these technologies provides insight into their efficiency, sustainability, and commercialisation potential in achieving a low-carbon future.

Influence Of Ph On The Wettability Of Carbonate Rocks For Carbon Dioxide Sequestration In Deep Saline Aquifer, Khaw Chi Foong, Sia Chee Wee, M Aslam Md Yusof

Platform: A Journal of Engineering

The escalating carbon dioxide (CO2) emissions have precipitated climate change, underscoring the urgent need for innovative solutions. Carbon Capture and Storage (CCS) represents a groundbreaking technology to mitigate carbon emissions by capturing CO2 and depositing it deep within reservoirs. This study focuses on the storage aspect of CCS by scrutinising reservoir properties. A pivotal factor influencing the geological storage of CO2 is the wettability of the rock/CO2/brine system, which is intricately linked to the contact angle. However, previous research has indicated that pH can significantly influence the wettability of this system. Acetic acid, a prevalent organic acid in the petroleum …

#Metoo & The Courts: The Impact Of Social Movements On Federal Judicial Decisionmaking, Carol T. Li, Matthew E.K. Hall, Veronica Root Martinez

Washington and Lee Law Review Online

In late 2017, the #MeToo movement swept through the United States as individuals from all backgrounds and walks of life revealed their experiences with sexual abuse and sexual harassment. After the #MeToo movement, many scholars, advocates, and policymakers posited that the watershed moment would prompt changes in the ways in which sexual harassment cases were handled. This Article examines the impact the #MeToo movement has had on judicial decisionmaking. Our hypothesis is that the #MeToo movement’s increase in public awareness and political attention to experiences of sexual misconduct should lead to more pro-claimant voting in federal courts at the district …