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2023

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Airport Operational Efficiency Evaluation Based On Combined Weighting-Topsis Model, Jie Hu, Fan Bao Dec 2023

Airport Operational Efficiency Evaluation Based On Combined Weighting-Topsis Model, Jie Hu, Fan Bao

Journal of System Simulation

Abstract: In order to improve the scientificity and comprehensiveness of the airport operational efficiency evaluation, a new method based on the combined weighting-TOPSIS model is proposed. From 4 dimensions of stand operational efficiency, passenger boarding efficiency, aircraft taxiing efficiency, and coordination efficiency, a new airport operational efficiency evaluation system consisting of 11 indicators, such as flight approach rate, corridor bridge turnover rate, stand change ratio, etc., are constructed. G1 method and entropy weight method are implemented respectively to calculate the subjective and objective weights of the evaluation indicators, and the combined weights are calculated by minimizing the deviation of subjective …


Research On Network Public Opinion Propagation Model Of Major Epidemics Under Cross-Infection Of Double Emotions, Yaming Zhang, Yanyuan Su, Guiru Zhao, Xiaoyu Guo Dec 2023

Research On Network Public Opinion Propagation Model Of Major Epidemics Under Cross-Infection Of Double Emotions, Yaming Zhang, Yanyuan Su, Guiru Zhao, Xiaoyu Guo

Journal of System Simulation

Abstract: Major epidemics provoke a variety of netizens' emotions. To some degree, the interaction of netizens' intense emotions determine the development direction of public opinion. Considering the complexity and dual emotional contagion, the impact of emotional factors in network public opinion is quantified to three dimensions indicators, emotional enhancement, differences and conversion rates. SIPINR public opinion propagation model is constructed. The equilibrium points and the transmission threshold are estimated and the stability is proved. The law of network public opinion propagation during major epidemics is revealed through numerical simulation. The results show that the dual emotional contagion would lead to …


Automatic Target Recognition Of Substation 3d Scene For Digital Twin, Qian Tu, Jun Li, Dongliang Fan, Qi Kong, Jie Shen Dec 2023

Automatic Target Recognition Of Substation 3d Scene For Digital Twin, Qian Tu, Jun Li, Dongliang Fan, Qi Kong, Jie Shen

Journal of System Simulation

Abstract: In order to improve the accuracy of automatic target recognition and promote the effect on substation operation and maintenance, automatic target recognition of substation 3D scene for digital twin is proposed. The automatic target recognition model for the three dimensional scene of the substation is constructed. The perception module of the model is used to collect the real-time status data of substation, and the communication module is used to transmit the data to digital twin modules. This module, based on the received data information, realizes the deep fusion and panoramic mapping of substation information through the knowledge base constructed …


Simulation On High-Speed Train Carriage Evacuation Considering Passengers Moving To Adjacent Carriages, Zuoan Hu, Tian Zeng, Yidong Wei, Yi Ma Dec 2023

Simulation On High-Speed Train Carriage Evacuation Considering Passengers Moving To Adjacent Carriages, Zuoan Hu, Tian Zeng, Yidong Wei, Yi Ma

Journal of System Simulation

Abstract: To study the influence of passengers moving to adjacent carriages on high-speed train carriages' evacuation, a cellular automata model considering export selection is established. Taking the CR400BF second-class carriage as the research object, some analytical indexes such as evacuation efficiency, number of conflicts and the congestion degree are used to study the effect of passengers moving to adjacent carriages on carriage evacuation, and the passenger seat distribution, the number of passengers transferred from adjacent carriages and the opening door modes of adjacent carriages are discussed. The simulation results show that the discretized seat distribution reduces the times of conflicts …


Application Of Improved Path Tracking Algorithm In Robot Slam, Qian Li, Ye Tao, Hui Li Dec 2023

Application Of Improved Path Tracking Algorithm In Robot Slam, Qian Li, Ye Tao, Hui Li

Journal of System Simulation

Abstract: Mapping is an important part of automated logistics. At present, SLAM is widely used. However, in large-scale scenes, errors are accumulated because robots often repeatedly measure and scan the region edge, which makes it impossible to quickly build a high-precision and complete map. An autonomous mapping method based on auxiliary path tracking is proposed, in which the given initial sketch is grid denoised and the auxiliary path is fitted and improved by multi segment cubic polynomial. The improved pure pursuit algorithm is used to guide the robot to build the map and improve the total distance and time of …


Modeling And Simulation On Production Logistics Of Intelligent Workshop Manufacturing System Based On Efsm, Liuzhen Li, Chao Jin, Tingyu Lin, Yaoqin Zhu Dec 2023

Modeling And Simulation On Production Logistics Of Intelligent Workshop Manufacturing System Based On Efsm, Liuzhen Li, Chao Jin, Tingyu Lin, Yaoqin Zhu

Journal of System Simulation

Abstract: The production logistics mode of manufacturing industry is developing rapidly, on which the modeling and simulation can provide the decision support for the design, analysis and transformation of manufacturing system. A description of the entity elements in intelligent workshop manufacturing system is given according to the classification of "human machine material environment rule". A production and logistics componentized EFSM model is created on the basis of EFSM and componentized modeling ideas. The modeling process for multi-job production in smart shop and the component model instantiation methodology are elaborated. The simulation running through the automatic conversion of EFSM-DEVS model and …


Research On 3d Object Detection Method With Cross-Module Attention, Renjie Xu, Xiaoming Zhang, Chen Wang, Peng Wu Dec 2023

Research On 3d Object Detection Method With Cross-Module Attention, Renjie Xu, Xiaoming Zhang, Chen Wang, Peng Wu

Journal of System Simulation

Abstract: To address the issue of feature loss that occurs during the extraction and transmission of target features in 3D object detection tasks using point cloud data, this study proposes an object detection method based on cross-module attention. This method incorporates a channel attention module and a spatial attention module to enhance the crucial feature information. Through feature transformation, the features from different stages of the attention module are connected to mitigate the loss of features during the extraction and transmission process. To tackle the problem of inadequate detection performance in target detection networks for objects of different scales, a …


Application Of Quantum Algorithms In The Synthesis Of Dynamic Objects, Noilakhon Yakubova Dec 2023

Application Of Quantum Algorithms In The Synthesis Of Dynamic Objects, Noilakhon Yakubova

Chemical Technology, Control and Management

Around the world, the food industry is focusing on achieving energy and resource efficiency. One of the main challenges in the field of process automation is the creation of effective control systems using intelligent technologies to improve the quality of processes and achieve the production of high-quality products with less energy and resources. Therefore, it is necessary to work with a large amount of data. Particular attention is paid to the development of computational algorithms for automated high-speed computational analysis systems for processing this data at high speed. Therefore, the article discusses the use of quantum computing methods in controlling …


System For Advanced Control Of Thermal Parameters Of Glass Furnaces, O'Tkir Xolmanov Dec 2023

System For Advanced Control Of Thermal Parameters Of Glass Furnaces, O'Tkir Xolmanov

Chemical Technology, Control and Management

The results of an analysis of the functioning of glass furnaces for melting semi-white or discolored glass as an object of automatic control and management are presented. Through experimental research, a parametric control scheme for a glass melting furnace was formed and a system for improved control of thermal glass melting processes was synthesized. The proposed system regulates the parameters of a furnace with a horseshoe-shaped flame development. Based on commercially produced instruments and automation equipment that ensure stabilization of thermal conditions of glass melting. The burner block control algorithm provides control over the performance of the gas burner, safety …


What I Think I Learned, Andrew S. Gibbons Iii Dec 2023

What I Think I Learned, Andrew S. Gibbons Iii

Faculty Publications

A retrospective review of fifty years of research and development experience showing the connectedness of the author’s theoretical ideas to practical application. An effort to show designers how over the span of a career new ideas begin as work-related insights and discoveries that by problem solving flow together to create a unique personal view of design and designing. Encouragement for individual designers to be willing to experiment with new ideas that may step beyond received practice and to learn from those experiences, even to the extent of testing and adopting new worldviews that may differ from the general view. Encouragement …


Dual Mode Control Of An Inverted Pendulum: Design, Analysis And Experimental Evaluation, Laura Alvarez Hidalgo, Ian Howard Dec 2023

Dual Mode Control Of An Inverted Pendulum: Design, Analysis And Experimental Evaluation, Laura Alvarez Hidalgo, Ian Howard

School of Engineering, Computing and Mathematics

We present an inverted pendulum design using readily available V-slot rail components and 3D printing to construct custom parts. To enable the examination of different pendulum characteristics, we constructed three pendulum poles of different lengths. We implemented a brake mechanism to modify sliding friction resistance and built a paddle that can be attached to the ends of the pendulum poles. A testing rig was also developed to consistently apply disturbances by tapping the pendulum pole, characterizing balancing performance. We perform a comprehensive analysis of the behavior and control of the pendulum. This begins by considering its dynamics, including the nonlinear …


Application Of Multicultural Literature In The Early Childhood Classroom, Deborah Wheeler, Jennifer Hill Dec 2023

Application Of Multicultural Literature In The Early Childhood Classroom, Deborah Wheeler, Jennifer Hill

Journal of English Learner Education

Culture equates to identity; therefore, the implementation of multicultural literature in the early childhood curriculum is an essential method for securing children’s concept of self and cultural identity. This qualitative study explored the implementation of multicultural literature in early childhood classrooms, and the research included questions pertaining to multicultural literature training, instructional methods, and barriers encountered. The purpose of the study was to answer questions regarding teachers use of multicultural literature in the classroom, how often teachers read multicultural literature and how teachers integrated multicultural literature into instruction. An additional question inquired about what multicultural books titles were teachers reading …


Exploring Teacher Leadership’S Effect On Teacher Burnout: Does School Rurality Make A Difference?, Jiangang Xia, Sam Butler Dec 2023

Exploring Teacher Leadership’S Effect On Teacher Burnout: Does School Rurality Make A Difference?, Jiangang Xia, Sam Butler

Department of Teaching, Learning, and Teacher Education: Faculty Publications

In literature, both teacher leadership and teacher burnout have been heavily studied. However, it is unknown to what extent teacher leadership makes a difference in teacher burnout, and whether school rurality makes a difference in between. This study fills the research gaps by conceptualising teacher leadership from both instructional and non-instructional dimensions and applying a quantitative method to large-scale national data. Findings revealed that (a) rural teachers presented higher levels of teacher leadership practices; (b) rural and non-rural teachers presented the same levels of burnout; and (c) both instructional and noninstructional dimensions of teacher leadership practices helped reduce teacher burnout …


A Revision Of Dyscolotaxia Horn, 1890 (Coleoptera: Eucnemidae: Macraulacinae: Macraulacini), With The Description Of Amazotaxia New Genus From South America, Robert L. Otto Dec 2023

A Revision Of Dyscolotaxia Horn, 1890 (Coleoptera: Eucnemidae: Macraulacinae: Macraulacini), With The Description Of Amazotaxia New Genus From South America, Robert L. Otto

Insecta Mundi

Abstract

The Neotropical eucnemid genus, Dyscolotaxia Horn, is revised following the examination of specimens from five collections, examination of the published original description of Plesiofornax tetratoma Chassain, and from images provided by Fernanda Salazar-Buenaño (QCAZI). Dyscolotaxia championi Horn is redescribed with included descriptions of the male genitalia and a female specimen. Three new species of false click beetles (Coleoptera: Eucnemidae) are described from the Neotropical region. These new species are: Dyscolotaxia chiriquiensis (Panama), Dyscolotaxia hispaniolensis (Dominican Republic), and Dyscolotaxia picea (Ecuador). Amazotaxia new genus is described from South America for Plesiofornax tetratoma Chassain, creating Amazotaxia tetratoma (Chassain) new combination. Morphology …


L2 Investment In The Transnational Context: A Case Study Of Prc Scholar Students In Singapore, Chang Liu, Guangxiang Liu Dec 2023

L2 Investment In The Transnational Context: A Case Study Of Prc Scholar Students In Singapore, Chang Liu, Guangxiang Liu

Journal of English and Applied Linguistics

Despite growing research on mainland Chinese international students’ intercultural language learning and adjustment experiences in Anglophone countries, few studies have delved into these students’ socially constructed language learning practices as an essential component of their study-abroad journey, especially in Singapore which shares linguistic and cultural affinities with China. As such, building on Darvin and Norton’s (2015) theory of investment at the intersection of identity, capital, and ideology, this case study focuses on Chinese foreign talent students in Singapore and aims to understand how they invest in learning English as an additional language (L2) and assert their legitimate place in the …


Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel Dec 2023

Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel

Turkish Journal of Chemistry

This study aimed to investigate the photocatalytic and photodynamic actions of a 2,6-diiodinated-BODIPY (2,6-diI2-Bod) photosensitizer (PS) covalently linked to TiO2 nanoparticles (NPs). The TiO2 NPs were synthesized utilizing the hydrothermal technique, yielding an average particle size of 4–5 nm as ascertained by transmission electron microscopy and 6.4 nm as determined by dynamic light scattering measurements. The integration of the nonsoluble Bod PS to TiO2 NPs provided increased dispersibility in physiological media, making it more applicable to photodynamic therapy applications. Bod-TiO2 NPs exhibited moderate efficiency of 56.9% in singlet oxygen generation. Additionally, the photocatalytic behavior of the TiO2 NPs was evaluated …


Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n Dec 2023

Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n

Turkish Journal of Chemistry

In this study, a new method for synthesizing diepoxides is proposed. Tetrahydroindene 1 was brominated with NBS in the presence of LiClO4 and acetic acid, resulting in the formation of dibromodiacetate derivatives 2 and 3. Treatment of compounds 2 and 3 with NaOH in methanol produced a mixture of diepoxides 4 and 5. Additionally, direct bromination of tetrahydro-1H-indene yielded tetrabromo octahydroindene isomers 6 and 7. The structures of the compounds were characterized using spectroscopic techniques such as 1H NMR, 13C NMR, APT, COSY, and XRD. The new method provides an easy and selective route to access epoxides for the synthesis …


#Metoo & The Courts: The Impact Of Social Movements On Federal Judicial Decisionmaking, Carol T. Li, Matthew E.K. Hall, Veronica Root Martinez Dec 2023

#Metoo & The Courts: The Impact Of Social Movements On Federal Judicial Decisionmaking, Carol T. Li, Matthew E.K. Hall, Veronica Root Martinez

Washington and Lee Law Review Online

In late 2017, the #MeToo movement swept through the United States as individuals from all backgrounds and walks of life revealed their experiences with sexual abuse and sexual harassment. After the #MeToo movement, many scholars, advocates, and policymakers posited that the watershed moment would prompt changes in the ways in which sexual harassment cases were handled. This Article examines the impact the #MeToo movement has had on judicial decisionmaking. Our hypothesis is that the #MeToo movement’s increase in public awareness and political attention to experiences of sexual misconduct should lead to more pro-claimant voting in federal courts at the district …


An Evaluation Of Online Training Effectiveness And Pre-Service And In-Service Teacher Satisfaction: A Case Study From Nigeria, Laila Mohebi, Alanood Alshamsi, Mariam Alhammadi, Fatima Almohsen Dec 2023

An Evaluation Of Online Training Effectiveness And Pre-Service And In-Service Teacher Satisfaction: A Case Study From Nigeria, Laila Mohebi, Alanood Alshamsi, Mariam Alhammadi, Fatima Almohsen

All Works

This study evaluates the perceptions of 122 pre-service and in-service Nigerian teachers on adopting an online training module during the COVID-19 pandemic, a period marked by significant educational challenges and shifts. Employing a qualitative approach through open-ended online questions, it delves into the factors critical to enhancing online training effectiveness. Key findings highlight the importance of training in imparting theoretical knowledge and practical skills, the quality and relevance of content, interactivity, practical examples, and appropriate video length. These align with existing literature, underscoring the effectiveness of online training in challenging times. Significantly, nearly all participants expressed satisfaction with the training. …


Corporate Finance, Kenneth S. Bigel Dec 2023

Corporate Finance, Kenneth S. Bigel

Open Touro Created

2023

Corporate Finance is a comprehensive guide covering the three fundamental topics in Corporate Finance, including Capital Budgeting under Certainty, Capital Structure Theory, and Short-term Financial Management and Operating Leverage. In-depth explanations of topics and terms are provided as well as key illustration in the manner of problem sets and solutions, tables, and diagrams. Review problems are also included so that students can conduct self-assessments. This text will be continually updated in order to provide novel information and enhance students’ experiences.


Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu Dec 2023

Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu

Turkish Journal of Chemistry

In this paper, a novel Fenton reaction system which was called MHACF-MIL-100(Fe) was constructed. In this system, based on active hydrogen-accelerated FeIII reduction, the hydroxyl radical was continuously produced with a trace amount of total iron. The MIL-100(Fe) modified with the nano-Pd0 particle could be used to activate the H2. Under normal temperature and pressure, the target organic pollutants, such as sulfamethazine and 4-chloro phenol, could be degraded fast. In the condition of initial aqueous solution pH 3, 2 g L–1 dosage of MIL-100(Fe) catalyst loaded with nano-Pd0, Pd/MIL-100(Fe), 20 mM 30 wt% hydrogen peroxide, 25 μM ferrous chloride and …


Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin Dec 2023

Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin

Turkish Journal of Chemistry

In the present work novel conductive organic-inorganic nanocomposites were produced by grafting of pyrrole monomer onto silanized Laponite RD utilizing emulsion graft polymerization. Influence of some important factors like concentration of monomer, initiator and surfactant were investigated on grafting efficiency. Grafting of polypyrrole chains onto modified Laponite RD was verified by Fourier transform infrared spectroscopy (FT-IR). Scanning electron microscope (SEM) revealed the spherical particles of nanocomposite with average diameter of 271.5 nm. XRD pattern showed that molecular framework of pure polypyrrole almost remains same in nanocomposite. Surface area and pore volume of Laponite RD, measured by Brunauer-Emmett-Teller (BET) analysis, was …


Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh Dec 2023

Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh

Turkish Journal of Chemistry

Veratrum spp. have traditionally been used in folk medicine to treat various pathologies. In this study, nine compounds, comprising one simple phenolic compound (1), three stilbenoids (2–4), and five flavonoids (5–9), were isolated from the aerial parts of Veratrum versicolor f. viride Nakai. The structures of these compounds were elucidated by spectroscopic analyses and comparison with reported data. Together, all reported compounds were isolated from V. versicolor f. viride for the first time in the study. Among them, two flavone aglycone tricetins (7 and 9) have never been isolated from the genus Veratrum or the family Melanthiaceae. The ethanol extract …


Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya Dec 2023

Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya

Turkish Journal of Chemistry

A weak acidic complex ester (CE) in solid form was prepared by a condensation reaction between very weak boric acid (BA: H3BO3) and (D)-mannitol (MA: C6H14O6) by the molar ratio of BA/MA = 2. A boron carbide (B4C) precursor was obtained from heating of the CE at 400 °C for 4 h. The precursor was pyrolyzed under argon flow in the interval of 1300–1550 °C for 4 h and at 1400 °C for 1–4 h, respectively. The materials were examined using several techniques such as X-ray diffraction analysis, thermal analysis, scanning electron microscopy, particle size distribution, and nitrogen adsorption/desorption. The …


Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren Dec 2023

Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren

Turkish Journal of Chemistry

In this study, silane and quaternary ammonium functional methacrylate monomers were synthesized and used to construct a copolymer using an emulsion polymerization technique to control the reaction rate. The copolymer was then designed using different ratios of silane and quaternary ammonium groups to investigate the relationship between the structure and properties. The presence of the ethoxy silane group in the copolymer series provided covalent bonding through the silanol group onto cotton fabric. The presence of cationic groups also helped to cover the fabric surface. After coating the cotton textile fabric, the resistance of the dye on the fabric surface to …


Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang Dec 2023

Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang

Turkish Journal of Chemistry

In this study, mixed matrix membranes (MMMs) composed of poly(vinyl alcohol) (PVA) and porous ZSM-5 zeolite are thoroughly investigated for concentrating alcohols of ethanol and n-propanol via dewatering pervaporation. The effects of the zeolite content (10–30 wt.%), feed composition (5–30 wt.% water), and feed temperature (50–90 °C) on the pervaporation flux/separation factor and component permeance/selectivity of these MMMs are examined in detail. These MMMs achieve higher separation efficiency and pervaporation flux than their pure PVA counterparts as expected, even if the dehydration results strongly depend on the pervaporation conditions. The disparity in pervaporation performances acquired for different alcohol solutions may …


Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat Dec 2023

Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat

Turkish Journal of Chemistry

The transport properties of Co2+ ions from the aqueous donor phase to aqueous acceptor phase with the recently developed multidroplet liquid membrane (MDLM) extraction system were studied. This system serves as a continuous process for the transportation of ions and requires fewer reagents for starting and conducting the procedure. Moreover, the procedure results in fewer waste chemicals and mixtures in comparison to traditional extraction methods. During extraction, bis(2-ethylhexyl) phosphate (D2EHPA) was used as a carrier material and 5% potassium thiocyanate (KSCN) solution was used to obtain a colored complex for UV-Vis detection. By means of several experiments, the optimum D2EHPA …


Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül Dec 2023

Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül

Turkish Journal of Chemistry

Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …


Photophysical, Thermal, And Dft Studies On A Tetraaryl-Azadipyrromethene Ligand And Its Zinc(Ii) Complex, Gökhan Sevi̇nç Dec 2023

Photophysical, Thermal, And Dft Studies On A Tetraaryl-Azadipyrromethene Ligand And Its Zinc(Ii) Complex, Gökhan Sevi̇nç

Turkish Journal of Chemistry

An azadipyrromethene ligand (H1) and homoleptic zinc(II) (H1-Zn) complex were synthesized. The resulting structures were elucidated by NMR, FTIR, and HRMS techniques. The photophysical properties and effects of complexing the zinc(II) atom to azadipyrromethene ligands in solution were studied by means of UV-Vis absorption and fluorescence spectroscopy. Experimental findings were elucidated using density functional theory computations and interfragment charge transfer (IFCT) and electron-hole analyses. The fluorescence features were found to be negligible. The ligand molecule decayed at a rate of 3% while the complex decayed at 2% upon photoirradiation based on photostability experiments. The singlet oxygen quantum yields of the …


Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t Dec 2023

Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t

Turkish Journal of Chemistry

Cr(VI), which has toxic effects, is a heavy metal and it must be removed from the environment due to the various damages it causes. In this study, the removal of Cr(VI) pollutants from aqueous solutions with Fe3O4-based materials using a batch adsorption technique was investigated. Magnetically modified graphene nanoplatelet (GNP)-based nanocomposites were prepared and their structures were characterized by FTIR, XRD, SEM, BET, and TGA techniques. The effects of various physicochemical parameters such as adsorbent dose, contact time, initial Cr(VI) solution concentration, pH, and the presence of coexisting ions (NaCl) on the adsorption process were investigated. Accordingly, the optimum conditions …