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การประยุกต์ใช้แผ่นที่ปรับค่าความแข็งด้วยลมเข้ากับมือจับแบบง่าย, เจตนิพิฐ อรุณรัตน์

Chulalongkorn University Theses and Dissertations (Chula ETD)

จากแนวคิดการใช้งานผิวหนังเทียมหรืออุปกรณ์ห่อหุ้มเพื่อเพิ่มความปลอดภัยและประสิทธิภาพในการทำงานของหุ่นยนต์ นำมาสู่การพัฒนาผิวหนังเทียมที่ติดตั้งบริเวณมือจับของหุ่นยนต์ โดยผิวหนังเทียมเหล่านี้จะมีค่าความแข็งที่แตกต่างกันตามการใช้งาน วิทยานิพนธ์เล่มนี้นำเสนอการออกแบบและขึ้นรูปแผ่นที่ปรับค่าความแข็งได้ (VSPs) ด้วยความดันลม ซึ่งทำหน้าที่เสมือนเป็นผิวหนังเทียมของมือจับ จากนั้นนำแผ่นดังกล่าวไปทดลองใช้กับมือจับแข็งเกร็งอย่างง่าย เพื่อหยิบจับวัตถุซึ่งไม่ทราบตำแหน่ง รูปทรงและความแข็งที่แน่ชัดด้วยวิธีการควบคุมอิมพีแดนซ์ VSPs สร้างขึ้นจากวัสดุอ่อนนุ่มประเภทซิลิโคน ซึ่งขึ้นรูปโดยใช้การหล่อและเสริมความแข็งแรงด้วยเส้นใยไฟเบอร์ มีโครงสร้างภายในเป็นทรงกระบอกเรียงตัวขนานกัน สามารถควบคุมค่าความแข็งผ่านการควบคุมค่าความดันโดยใช้ปั๊มเข็มฉีดยาร่วมกับตัวควบคุมแผนเลื่อน จากการทดลองประยุกต์ใช้ VSPs ร่วมกับมือจับแข็งเกร็งพบว่า VSPs ช่วยเพิ่มความปลอดภัยและความยืดหยุ่นในการทำงาน เนื่องจากสามารถปรับค่าความแข็งให้เหมาะสมกับการทำงานนั้น ๆ ได้ โดยการปรับค่าความแข็งเพิ่มจะช่วยลดระยะเวลาในการทำงาน หากลดค่าความแข็งจะช่วยเพิ่มความปลอดภัยและความเสถียรในการทำงานแทน

Expression And Characterization Of Dextransucrase From Leuconostoc Citreum Abk-1, Kakuttapun Bulan

Chulalongkorn University Theses and Dissertations (Chula ETD)

Dextransucrase is an enzyme in the glycoside hydrolase 70 family that catalyze the hydrolysis of sucrose to fructose and glucose, the glucose residues are transferred to synthesize dextran via transglycosylation reaction. Dextransucrase from Leuconostoc citreum ABK-1 (Lcdextransucrase ), which has 99.5% homology with dextransucrase in the NCBI database, was cloned, expressed, and purified. The size of the Lcdextransucrase was predicted by ExPASy and the result showed that its size was 168 kDa with a pI of 5.15. Protein expression was confirmed by western blot analysis. Lcdextransucrase was purified through Ni-sepharose coupled with DEAE anion exchange column chromatography to approximately 80% …

Electroless Cunisn Electrocatalyst Supported On Carbon Fabric For Electrochemical Reduction Of Co2, Atikom Hongmeuan

Chulalongkorn University Theses and Dissertations (Chula ETD)

In the present work, tri-metallic alloy electrocatalysts containing copper (Cu), nickel (Ni), and tin (Sn) supported on Pd-catalyzed carbon fabric substrate were prepared through a simple electroless deposition method. As-deposited Cu-Ni-Sn electrocatalyst was employed in the CO2-ERR in an H-cell type reactor. For the effect of electroless deposition time (15, 30 and 45 mins) on tri-metallic alloy electrocatalyst, the result showed that there is no significant difference for all samples based on the XRD pattern, indicating the deposition time had no effect on the crystalline structure of all catalyst. In addition, the evaluation of the ability of the CO2-ERR on …

Biological Properties Of Marigold Flower Extract And Its Microcapsule, Nilar Oo

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focuses on the optimization of ultrasound-assisted extraction (UAE) conditions of marigold flower extract (MFE) using response surface methodology (RSM) and to produce microcapsule using spray drying with different wall materials and ratios. The extraction factors including temperature (30-50 ℃), time (5 -15 min), and ethanol concentration (60 - 100% v/v) were investigated. The optimum condition was investigated according to the maximum concentration of total phenolic, total flavonoid, total carotenoid, and antioxidant activity determined by 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical and ferric reducing antioxidant power (FRAP) assay. The optimized extraction conditions were temperature (40 ℃), time (15 min), and ethanol …

Health Risk Assessment For Heavy Metals In Chao Phraya River Basin, Natthanicha Nateekhuncharoen

Chulalongkorn University Theses and Dissertations (Chula ETD)

Heavy metal contamination has become a serious concern due to its toxicity not only on ecosystems but also directly on human health. The Chao Phraya River Basin is the main area important for commerce, industries, and residence in Thailand. This study aimed to evaluate the impact on human health due to heavy metal contamination and identify the relationship between land use and heavy metal contamination in the Chao Phraya River. Pearson correlation was applied to analyze the relationship between heavy metal concentration and water parameters. The results indicated that during 2009-2013, Fe concentration positively correlated to turbidity (0.640), total phosphate …

The Role Of Neutrophils Against Pythium Insidiosum, Apichaya Sriwarom

Chulalongkorn University Theses and Dissertations (Chula ETD)

Pythium insidiosum (P. insidiosum) is an oomycetes fungus-like microorganism causing pythiosis infection in humans. The zoospores (infective stage) of this pathogen contaminate aquatic environments such as moist soil and swampy area, which is a natural habitiat. Humans are infected with P. insidiosum via cutaneous route which is the main entry of the zoospores. Recent studies have shown that patients with pythiosis shows high morbidity and mortality rates particularly those with hematologic diseases. As neutrophils are the first line of immune defense during fungal infections, this study therefore investigated the activity of neutrophils in response to P. insidiosum. The neutrophil killing …

Alteration Of Extracellular Matrix Components In Anterior Pituitary Gland Of Neonatal Rats Induced By Maternal Bisphenol A (Bpa) Diet During Pregnancy, Bumpenporn Sanannam

Chulalongkorn University Theses and Dissertations (Chula ETD)

Bisphenol A (BPA) is a well-known endocrine-disrupting chemical that is widely used in the resin and plastic manufacturing sectors. Prenatal exposure to this chemical results in changes of pituitary hormone-producing cells. However, there have been no reports of the alterations of extracellular matrix (ECM) which play a role in controlling cell activities in the pituitary gland. In the present study, a daily oral dose of 5,000 µg/kg BW of BPA was administered to pregnant rats. ECM-producing cells, i.e., pericytes and folliculostelate cells, ECM products, and ECM regulators were investigated in the neonatal anterior pituitary at day 1 at the histology …

A Retrospective Study In Comparison Of Skeletal Stability And Pharyngeal Airway Changes In Mandibular Prognathism After Correction With Mandibular Setback Surgery Using Two Different Types Of Osteofixation Materials, Phu Hnin Thet

Chulalongkorn University Theses and Dissertations (Chula ETD)

Objectives: This study compared the skeletal stability and pharyngeal airway changes after mandibular setback procedure using the titanium and resorbable plate and screws fixation. Materials and Methods: 28 patients with mandibular prognathism being treated with bilateral sagittal split ramus osteotomy (BSSRO) were randomly selected from titanium and resorbable fixations. Analyses of lateral cephalometric x-rays were performed according to preoperative (T0), 1st week post-surgery (T1), 3-6 months post-surgery (T2) and 1-year post-surgery (T3). The horizontal measurement (BX), vertical measurement (BY), and angle measurement (SNB and Mandibular Plane Angle; MPA) were studied for skeletal stability. The pharyngeal airway changes were observed by …

สงครามโลกครั้งที่ 1 กับการระบุตัวตนของสยามในสังคมระหว่างประเทศ, ศิวพล ชมภูพันธุ์

Chulalongkorn University Theses and Dissertations (Chula ETD)

วิทยานิพนธ์นี้ศึกษาสงครามโลกครั้งที่ 1 กับการระบุตัวตนของสยามในสังคมระหว่างประเทศผ่านกรอบแนวคิดเรื่องสังคมระหว่างประเทศของสำนักอังกฤษและแนวคิดเรื่องการระบุตัวตนของชาติ จากการศึกษาพบว่า สงครามโลกครั้งที่ 1 เป็นจุดสัมฤทธิผลสูงสุดในกระบวนการระบุตัวตนของสยามในสังคมระหว่างประเทศอันเป็นผลมาจากการแสดงบทบาทระหว่างประเทศของการเป็นรัฐสมัยใหม่ อีกทั้งยังเป็นการแสดงผลของการผสมผสานความรู้ความเข้าใจเกี่ยวกับการทำงานของสถาบันระหว่างประเทศให้เป็นที่ประจักษ์แก่นานาอารยประเทศ ในอีกด้านหนึ่ง การระบุตัวตนของสยามจากสงครามโลกครั้งที่ 1 ได้ถูกนำมาใช้เป็นโอกาสในการเมืองภายในด้วยการเสริมสร้างความสำคัญให้แก่ระบอบราชาธิปไตยและการยกพระราชสถานะของพระบาทสมเด็จพระมงกุฎเกล้าเจ้าอยู่หัวให้สูงเด่นยิ่งขึ้น

Earliness, Yield, And Fruit Quality Characteristics In Low Chill Peach-Nectarines: A Comparison Of Protected And Open Area Cultivation, Oğuzhan Çalişkan, Safder Bayazit, Kazi̇m Gündüz, Derya Kiliç, Sultan Göktaş

Turkish Journal of Agriculture and Forestry

This study was carried out to determine the effects of protected cultivation on the earliness, yield, and fruit quality characteristics of some lowchill peach-nectarine cultivars grown in the eastern Mediterranean region of Turkey. Phenological observations, yield parameters, and fruit quality characteristics were investigated. The chilling durations as CH (chilling hours), CU (chilling unit), and heat accumulations were determined. The `Astoria? cultivar reached the highest cumulative yield of 29.11 kg/tree and 38.72 t/ha, and fruit size was 131.89 g and 61.74 mm in protected cultivation. The CH and CU values under protected cultivation were 28% and 40% lower than in open …

Recently Developed Carbohydrate Based Gelators And Their Applications, Joedian Morris, Jonathan Bietsch, Kristen Bashaw, Guijun Wang

Chemistry & Biochemistry Faculty Publications

Carbohydrate based low molecular weight gelators have been an intense subject of study over the past decade. The self-assembling systems built from natural products have high significance as biocompatible materials and renewable resources. The versatile structures available from naturally existing monosaccharides have enriched the molecular libraries that can be used for the construction of gelators. The bottom-up strategy in designing low molecular weight gelators (LMWGs) for a variety of applications has been adopted by many researchers. Rational design, along with some serendipitous discoveries, has resulted in multiple classes of molecular gelators. This review covers the literature from 2017-2020 on monosaccharide …

Energy Renewal: Isothermal Utilization Of Environmental Heat Energy With Asymmetric Structures, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

Through the research presented herein, it is quite clear that there are two thermodynamically distinct types (A and B) of energetic processes naturally occurring on Earth. Type A, such as glycolysis and the tricarboxylic acid cycle, apparently follows the second law well; Type B, as exemplified by the thermotrophic function with transmembrane electrostatically localized protons presented here, does not necessarily have to be constrained by the second law, owing to its special asymmetric function. This study now, for the first time, numerically shows that transmembrane electrostatic proton localization (Type-B process) represents a negative entropy event with a local protonic entropy …

Synthesis Of Carbohydrate Based Macrolactones And Their Applications As Receptors For Ion Recognition And Catalysis, Surya B. Adhikari, Anji Chen, Guijun Wang

Chemistry & Biochemistry Faculty Publications

Glycomacrolactones exhibit many interesting biological properties, and they are also important in molecular recognitions and for supramolecular chemistry. Therefore, it is important to be able to access glycomacrocycles with different sizes and functionality. A new series of carbohydrate-based macrocycles containing triazole and lactone moieties have been designed and synthesized. The synthesis features an intramolecular nucleophilic substitution reaction for the macrocyclization step. In this article, the effect of some common sulfonate leaving groups is evaluated for macrolactonization. Using tosylate gave good selectivity for monolactonization products with good yields. Fourteen different macrocycles have been synthesized and characterized, of which eleven macrocycles are …

Photodynamic Therapy Of Inorganic Complexes For The Treatment Of Cancer, Chloe B. Smith, Lindsay C. Days, Duaa R. Alajroush, Khadija Faye, Yara Khodour, Stephen J. Beebe, Alvin Holder

Chemistry & Biochemistry Faculty Publications

Photodynamic therapy (PDT) is a medicinal tool that uses a photosensitiser and a light source to treat several conditions, including cancer. PDT uses reactive oxygen species (ROS) such as cytotoxic singlet oxygen ¹O₂ to induce cell death in cancer cells. Chemotherapy has historically utilized the cytotoxic effects of many metals, especially transition-metal complexes. However, chemotherapy is a systemic treatment so all cells in a patient's body are exposed to the same cytotoxic effects. Transition metal complexes have also shown high cytotoxicity as PDT agents. PDT is a potential localized method for treating several cancer types by using inorganic …

The Role Of Oxygen In Stimulating Methane Production In Wetlands, Jared L. Wilmoth, Jeffra K. Schaefer, Danielle R. Schlesinger, Spencer W. Roth, Patrick G. Hatcher, Julie K. Shoemaker, Xinning Zhang

Chemistry & Biochemistry Faculty Publications

Methane (CH₄), a potent greenhouse gas, is the second most important greenhouse gas contributor to climate change after carbon dioxide (CO₂). The biological emissions of CH₄ from wetlands are a major uncertainty in CH₄ budgets. Microbial methanogenesis by Archaea is an anaerobic process accounting for most biological CH₄ production in nature, yet recent observations indicate that large emissions can originate from oxygenated or frequently oxygenated wetland soil layers. To determine how oxygen (O₂) can stimulate CH₄ emissions, we used incubations of Sphagnum peat to demonstrate that the temporary exposure of …

Genome-Wide Characterization Of Lateral Organ Boundaries Domain Genes In Sunflower (Helianthus Annuus L.), Saleh M. Aljurbua

Masters Theses

Lateral Organ Boundaries (LBD) gene family encodes transcription factors found only in plants with essential roles in growth, development, and response to biotic and abiotic factors. The sunflower (Helianthus annuus L., Asteraceae family) LBD genes were studied using different in silico and phylogenetic approaches including four major steps: gene identification, phylogenic analysis, structural analysis, and expression analysis. Sixty-four sunflower LBD genes (HaLBDs) were identified using query search of all Arabidopsis LBD genes against sunflower genome (version r1.2) followed by LBD domain sequence verification. A phylogenetic tree was reconstructed using MEGA-X program. The identified genes were phylogenetically classified into two main …

Identifying Scotomata In Hazard Identification Caused By Ignorance And Overconfidence, Allen Johanson

Masters Theses

The manufacturing and construction industries are two of the most dangerous professions, and employees are frequently exposed to hazards and hazardous conditions which can lead to serious injury or even death. An observed phenomenon, frequently called the Dunning-Kruger Effect states that unskilled people are often unaware of their shortcomings and those with the higher-level skills often underestimate their abilities. This study examines employees’ training, years of experience, and performance to gauge any correlations among these variables in the area of hazard awareness. The goal of this study is to help individuals to recognize blind spots in their knowledge to identify …

Effects Of Emerging Contaminants On Centrarchidae And Catostomidae In Midwestern Rivers: A Multiple Biomarker Approach, Camden Garret Nix

Masters Theses

Natural habitats of fish are gradually declining due to land use and pollution caused by industrial wastes, intensive agriculture and contamination from sewage systems. The United States has 14,780 wastewater treatment facilities that discharge effluent into navigable waters, and in some cases these discharge waters represent a considerable proportion of the water system flow. These activities make it critical to discern the effects of pollutants that are entering our waterways at a consistent rate, such as 17β-estradiol (E2) and nickel, on aquatic organisms. To determine the effects of 17β-estradiol on endocrine disruption in fish, Bluegill Sunfish (Lepomis macrochirus) …

Effects Of Wastewater Effluent On Fish Fin Morphology Of Larval Fathead Minnows (Pimephales Promelas) And Swimming Performance Of Smallmouth Buffalo (Ictiobus Bubalus), Seth Michael Bogue

Masters Theses

The Sangamon River flows across central Illinois and is mostly free flowing except in the city of Decatur where it is impounded to form Lake Decatur. The Sanitary District of Decatur (SDD) is located approximately three miles downstream of the Lake Decatur dam. For a significant portion of the year, the stretch of the Sangamon River downstream of SDD is dominated by effluent due to limited discharge from the Lake Decatur dam. This has resulted in heavy nutrient loading, most notably phosphorus, and elevated levels of nickel and other compounds in the downstream section of the river. Smallmouth buffalo ( …

Genetic Relatedness Can Alter The Strength Of Plant-Soil Feedbacks, Kelly M. Clark

Masters Theses

Intraspecific variation may play a key role in understanding the relationships between plants and their interactions with soil microbial communities. The effects that soil-microbes have on individuals can venerate variation across individuals in their responsiveness. I explored how relatedness alters plant-soil feedbacks in established Solidago altissima clones grown in a common garden. Seedlings of known parentage were inoculated with soils from the maternal, paternal, or unrelated clones and compared to autoclaved control inocula. I found that the soil inocula generated from S. altissima had an overall negative effect of seedling biomass. Furthermore, seedlings inoculated with maternal or paternal soils experienced …

A Novel Palladium Bodipy Photocatalyst For Sonogashira Carbon-Carbon Cross-Coupling, Prahadeesh Nagaretnam

Masters Theses

No abstract provided.

The Effects Of Imf's Lending And Conditionalities On Economic Growth: Case Of Sadc Countries, Lutete Celina Carlos

Masters Theses

I examine the impact of IMF credit use and its conditions on economic growth performance in 12 South African countries over a period of 1999-2019. The work adopts an empirical and quantitative approach to analyzing the relationship between the GDP per Capita, the use of IMF Credit, Government Final Consumption Expenditure, Net Domestic Credit and Current Account balance. These variables are the most recommended in the IMF conditionalities during the lending arrangements with SADC members. The study uses Fixed-effect approach to evaluate how the use of IMF program and the conditions imposed directly affects economic growth. A dummy variable is …

Scientific Development Vs. Political Strategy: Nasa’S Commitment To Science Following The First Moon Landing, Sean Van Buskirk

Masters Theses

This work looks at the scientific program of NASA during the Space Race. (1961- 1975) During this period of the Cold War, NASA shifted it role from a political asset of the United States strategy to an agency of scientific discovery. This was not a smooth transition due to political opinions on the wastefulness and role of NASA. Many politicians, citizens and even scientists had doubts about the scientific potential of NASA’s manned missions to the Moon. Despite the power politics, the administrators at NASA were able to break out of the political arena and create a balanced program where …

Synthesis, Characterization And Photophysical Properties Of Ytterbium Complexes Of Functionalized Porphyrins And Porpholactone, Beibei Liu

Masters Theses

The unique structure and superior properties of lanthanide porphyrins enable them to be used in a broad variety of applications, especially in medical diagnosis fields. This research focuses on modifying the porphyrin ligands in various places, resulting in broader absorption in the red region and strong emission in the near-infrared region for these ytterbium(III) porphyrin complexes. The design, synthesis and characterization for DMPH₂-BDP, DMPH₂-COOH, TPLH₂ ligands and YbDMP-BDP, YbDMP-COOH complexes are described. The photophysical properties of these ligands and complexes including their absorbance, fluorescence and quantum yields are also presented. Both the synthesized ligands and …

The Gene Expression Patterns Of Phanerochaete Chrysosporium And Trametes Versicolor On Diverse Lignocellulosic Feedstocks, Noor Osama Alabbasi

Masters Theses

Plant biomass is considered to be an important future starting material for fuels and chemicals, thereby decreasing our reliance on fossil fuels. While direct combustion continues to be a source of fuel, the generation of liquid fuels from plant biomass for transportation has proven to be challenging. Among the limiting factors for conversion of this material to biofuels is the recalcitrant nature of lignocellulose, the primary component of non-starch plant biomass. A strategy to overcome this dilemma is to directly or indirectly use the enzymes from white-rot fungi, which have evolved a unique ability to deconstruct lignocellulose. However, the biochemical …

Opioid System's Involvement In Ketamine's Antidepressant-Like Effects, Fan Zhang

Theses and Dissertations

Depression is one of the most debilitating disorders in the world. The currently available medications typically have a 2-4 week delay in their therapeutic effects and are ineffective for about 40% of patients. In 2000, a subanesthetic dose (0.5 mg/kg i.e.) of the dissociative anesthetic ketamine was reported to have both rapid and robust antidepressant effects in in treatment-resistant depressed patients. However, the mechanisms responsible for ketamine’s antidepressant effects remain unclear. In 2018, a clinical study reported that pretreatment with the nonselective opioid antagonist naltrexone attenuated the rapid antidepressant effect of ketamine in depressed patients. The current study investigated the …

Role Of P53 Deficient Clonogenic Endothelial Cells In The Pathogenesis Of Pulmonary Hypertension, Aneel Roy Bhagwani

Theses and Dissertations

Pulmonary Artery Hypertension (PAH) is a progressive disorder of the small vessels of the pulmonary vasculature. It is characterized by occlusive vascular remodeling leading to right heart failure and ultimately death. PAH pathogenesis involves a multifactorial etiology leading to formation of occlusive lesions in small (preacinary) pulmonary arteries. These lesions contain hyper-proliferative, apoptosis resistant endothelial cells (ECs), smooth muscle cells and fibroblasts. ECs play a major role in the development of PAH. These ECs in vascular lesions are primitive and express progenitor cell markers, including CD117 (c-kit).

We have isolated clonally expanded, c-kit+ ECs from the lungs of Green Fluorescent …

Mathematical Modeling Of Lung Inflammation: Macrophage Polarization And Ventilator-Induced Lung Injury With Methods For Predicting Outcome, Sarah B. Minucci

Theses and Dissertations

Lung insults, such as respiratory infections and lung injuries, can damage the pulmonary epithelium, with the most severe cases needing mechanical ventilation for effective breathing and survival. Furthermore, despite the benefits of mechanical ventilators, prolonged or misuse of ventilators may lead to ventilation-associated/ventilation-induced lung injury (VILI). Damaged epithelial cells within the alveoli trigger a local immune response. A key immune cell is the macrophage, which can differentiate into a spectrum of phenotypes ranging from pro- to anti-inflammatory. To gain a greater understanding of the mechanisms of the immune response in the lungs and possible outcomes, we developed several mathematical models …

Influence Of Metal Sleeves In The Accuracy Of Dental Implant Placement Using Guided Implant Surgery, Coleman Adams

Theses and Dissertations

The fabrication of implant surgical guides through stereolithographic 3D printing has become a staple in dental implant guided surgery over the last couple decades. These surgical guides have typically utilized metal sleeves to assist in guidance of the drills during osteotome preparation. The metal sleeves can be costly and potentially cause deviations if improperly placed during post-processing of the guide. This research explored a novel method for the utilization of sleeve-free surgical guides by comparing the dimensional and angulational deviations between the implant guides with and without a metal sleeve. To achieve this goal, two separate aims were pursued. Our …

Humanizing Architecture: A Polymorphic Space, Nada Abbara

Theses and Dissertations

The built environments in which our communities thrive constitute an integral part of human experience and evolution. Yet, many places are detached from the way we experience them due to mass-production, which often produces standardized environments, and due to the tendency of modern architecture to delineate spaces as static objects rather than dynamic interactions. Thus, there is an emerging need to humanize architecture through an interdisciplinary approach that engages nature’s behavioral patterns. The project proposes a transformable polyhedral structure that interacts with human emotion through a three-dimensional morphing space that contracts and expands. This spatial interaction is achieved through a …