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Microwave-Promoted Iminyl Radical Fragmentations And The Total Synthesis Of Yaku'amide A And Its Simplified Analogues, Concordia Lo

Theses and Dissertations

The first project in this dissertation describes the use of microwave-promoted iminyl radical fragmentations to form functionalized nitriles. Nitrogen-centered radical chemistry is a useful tool to construct valuable C-N bonds commonly found in pharmaceuticals and biologically active molecules. Classically, these reactions require the use of toxic initiators and propagators. Iminyl radical chemistry has been gaining momentum as a means of avoiding these harsh conditions. This project utilizes the fragmentation of cyclic iminyl radicals via irradiation of O-phenyl oxime ethers to produce a synthetically useful nitrile tethered to an alkyl radical in the absence of metal catalysts and redox chemistry. The …

Effects Of The Inclusion Of Rice Hull Derived Bio-Oil On Wood Pellet Production, Tyler E. Lowe

Theses and Dissertations

Wood pellet production has become an advancing industry for the sake of reducing greenhouse emissions into the atmosphere especially, in European Union countries. Researchers and industry executives seek new methods and materials to improve the pelletization process. Rice hulls or husks has the potential to aid in wood pelletization as they possess high calorific values. This study focuses on using rice hull derived bio-oil from pyrolysis, which will also decrease ash content, as an additive to aid in the wood pelletization process. Using two groups of rice hull derived bio-oil as an additive in wood pelletization: Group 1 uses heavy …

Disease Biomarker Discovery And Fungal Metabolites Extraction Protocol Optimization Using Gcms Based Metabolomics, Chathuri Udeshika Gamlath Mohottige

Theses and Dissertations

Metabolomics is a powerful science that can be applied for the discovery of disease biomarkers, and investigation of altered metabolomes due to abiotic and biotic perturbations. This dissertation is focused on untargeted metabolomic applications to investigate fungal metabolite alterations associated with pathogenicity, fungal disease propagations, and symbiosis. This dissertation employs qualitative analysis of metabolite mixtures using HS-SPME coupled GC-MS and TMS derivatization followed by GC-MS analytical platforms. In the first study, we discovered a biomarker combination to diagnose fungal soft tissue disease in sweet potato at an early stage of disease propagation. We used an HS-SPME GC-MS untargeted metabolomics workflow …

Women In Science, Technology, Engineering, And Math Professional Night For Youths, Emily N. Henry

Journal of Extension

Extracurricular science, technology, engineering, and math (STEM) activities are an engaging way to introduce historically-minoritized youths to STEM. In this article, I describe one such event, a Women in STEM Professional Night, designed to connect eighth-grade girls with women in STEM careers. This interactive event provides a personalized connection to STEM, helps combat gendered stereotypes, and builds girls’ self-identification with STEM. Best practices include a carefully structured event, inviting a diverse group of women STEM professionals, and intentional preparation of all participants to set expectations. These insights serve as a guide for Extension professionals interested in creating a similar event.

Teaching And Learning During Covid-19 Pandemic: A Qualitative Study On Elementary School Teachers In Indonesia, Kartika Yulianti, Amirul Mukminin

The Qualitative Report

In this study, we explored how teachers in elementary schools in urban and rural areas in Indonesia experienced teaching and learning during school closure or learning from home (LFH) period and examined the barriers that hindered the teaching and learning process in both contexts. We collected data through demographic profiles and semi-structured in-depth interviews with 18 teachers. We organized our analysis around their perspectives on teaching and learning during COVID-19 pandemic that they encountered emerged. Overall, an analysis of the text revealed that major themes related to the critical issues of (1) teaching and learning activities during school closure, (2) …

The NTh-Order Comprehensive Adjoint Sensitivity Analysis Methodology For Response-Coupled Forward/Adjoint Linear Systems (NTh-Casam-L): I. Mathematical Framework, Dan Gabriel Cacuci

Faculty Publications

This work presents the mathematical framework of the n^th-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Response-Coupled Forward/Adjoint Linear Systems (abbreviated as “n^th-CASAM-L”), which is conceived for obtaining the exact expressions of arbitrarily-high-order (n^th-order) sensitivities of a generic system response with respect to all of the parameters (including boundary and initial conditions) underlying the respective forward/adjoint systems. Since many of the most important responses for linear systems involve the solutions of both the forward and the adjoint linear models that correspond to the respective physical system, the sensitivity analysis of such responses makes it necessary …

Basis For Changes In The Disease Burden Estimates Related To Vitamin A And Zinc Deficiencies In The 2017 And 2019 Global Burden Of Disease Studies, Sonja Y. Hess, Alexander C. Mclain, Haley Lescinsky, Kenneth H. Brown, Ashkan Afshin, Reed Atkin, Saskia Jm Osendarp

Faculty Publications

Background:

The Global Burden of Disease (GBD) Study provides estimates of death and disability from eighty-seven risk factors, including some micronutrient deficiencies. Objectives:

To review methodological changes that led to large differences in the disease burden estimates for vitamin A and Zn deficiencies between the GBD 2017 and 2019 Studies. Methods:

GBD publications were reviewed; additional information was provided by GBD researchers. Results:

Vitamin A deficiency prevalence is based on plasma retinol concentration, whereas the estimate for Zn deficiency prevalence uses dietary adequacy as a proxy. The estimated global prevalence of vitamin A deficiency for children aged 1–4 years in …

Statistical Development Of The Neutrosophic Lognormal Model With Application To Environmental Data, Zahid Khan, Adnan Amin, Sajjad Ahmad Khan, Muhammad Gulistan

Neutrosophic Sets and Systems

No abstract provided.

Corn Oil-Based Highly Flame Retardant Rigid Polyurethane Foams For Industrial Application, Muhammad Rizwan Sulaiman

Electronic Theses & Dissertations

The synthesis of flame retardant polyurethane (PU) foam was carried out using two different flame retardants, such as triethyl phosphate (TEP) and triphenyl phosphate (TPP). The thermal and mechanical characteristics of the foam were analyzed. The obtained TGA results confirmed that the flame retardant acts in the gaseous form to stop the fire. All the prepared samples displayed excellent closed cell content, which was above 90 %. The burning time were reduced from 80 s to 7.5 s with the weight loss 3.2% of for sample E-12 (19.29 % TEP) and from 80 s to 11 s with the weight …

A Workers' Paradise: Re-Integrating Newfoundland Into Colonial American History, Elena Hynes

Electronic Theses & Dissertations

The island of Newfoundland is conspicuous in colonial British and North American histories, most particularly and paradoxically, in its absence, a state of affairs which this study aims to help address. Multiple factors, including a paucity of documentary sources and various historiographic trends, have traditionally contributed to Newfoundland’s marginalization within colonial historical narratives. However, developments in recent years have made Newfoundland’s potential integration into the broader colonial dialogue more feasible including the advent of the Atlantic perspective, the expansion of available sources, and the work of multiple regional historians who have challenged enduring historiographic trends characterizing Newfoundland colonial settlements as …

Quantitative Stem: A Method For Measuring Temperature And Thickness Effects On Thermal Diffuse Scattering Using Stem/Eels, And For Testing Electron Scattering Models, Paul S. Minson

Theses and Dissertations

In the last two decades, advances in the dark field detectors and microscopes of scanning transmission electron microscopy (STEM) have inspired a resurgence of interest in quantitative STEM analysis. One promising avenue is the use of STEM as a nanothermometric probe. In this application, thermal diffuse scattering, captured by a CCD camera or an annular dark field detector, acts as an indirect measurement of the specimen temperature. One challenge with taking such a measurement is achieving adequate sensitivity to quantify a change in scattered electron signal on the order of 1% or less of the full electron beam. Another difficulty …

Field Investigations And Numerical Modeling Of Earthquake And Tsunami Risk At Four Vulnerable Sites In Indonesia, Claire E. Ashcraft

Theses and Dissertations

Maps and models of seismic and tsunami risk are constructed from a variety of measurements taken in Indonesia, which have the potential to reduce loss of life and infrastructure. The first study uses the multichannel analysis of surface waves (MASW) method to calculate the time-averaged shear wave velocity to 30 m depth (Vs30). These measurements were taken at 58 sites in the city of Pacitan, Java and on the islands of Lombok, Ambon, and the Banda Islands. Vs30 calculations are compared with local geologic maps to extrapolate site class for locations not measured directly. Site class maps are then compared …

Deep Multi-Modal U-Net Fusion Methodology Of Infrared And Ultrasonic Images For Porosity Detection In Additive Manufacturing, Christian E. Zamiela

Theses and Dissertations

We developed a deep fusion methodology of non-destructive (NDT) in-situ infrared and ex- situ ultrasonic images for localization of porosity detection without compromising the integrity of printed components that aims to improve the Laser-based additive manufacturing (LBAM) process. A core challenge with LBAM is that lack of fusion between successive layers of printed metal can lead to porosity and abnormalities in the printed component. We developed a sensor fusion U-Net methodology that fills the gap in fusing in-situ thermal images with ex-situ ultrasonic images by employing a U-Net Convolutional Neural Network (CNN) for feature extraction and two-dimensional object localization. We …

Modulation Of Effector Gene Expression In The Blood-Feeding Arthropods Cimex Lectularius Linnaeus, (Hemiptera: Cimicidae) And Aedes Albopictus Skuse, (Diptera: Culicidae), Travis C. Van Warmerdam

Theses and Dissertations

Hematophagy, or blood-feeding behavior, has independently evolved multiple times in the class Insecta and results in the transmission of vector-borne parasites, bacteria and viruses causing 17% of all infectious diseases and over 700,000 human deaths annually. One of the major challenges in studying the discrete mechanisms involved in host-response to hematophagy or the host seeking behavior of hematophagous insects, is the vast amount of signaling processes and genes that are inextricably tied to these interactions. These experiments used the clustered regularly interspersed short palindromic repeat (CRISPR)/CRISPR-associated (Cas) and dsRNA knock-down technologies to examine mechanisms of immunological reactivity and host-seeking behavior. …

Evaluation Of Hyperspectral Band Selection Techniques For Real-Time Applications, Samantha Butler

Theses and Dissertations

Processing hyperspectral image data can be computationally expensive and difficult to employ for real-time applications due to its extensive spatial and spectral information. Further, applications in which computational resources may be limited can be hindered by the volume of data that is common with airborne hyperspectral image data. This paper proposes utilizing band selection to down-select the number of spectral bands to consider for a given classification task such that classification can be done at the edge. Specifically, we consider the following state of the art band selection techniques: Fast Volume-Gradient-based Band Selection (VGBS), Improved Sparse Subspace Clustering (ISSC), Maximum-Variance …

Discrete Processing In Visual Perception, Marshall L. Green

Theses and Dissertations

Two very different classes of theoretical models have been proposed to explain visual perception. One class of models assume that there is a point at which we become consciously aware of a stimulus, known as a threshold. This threshold is the foundation of discrete process models all of which describe an all-or-none transition between the mental state of perceiving a stimulus and the state of not perceiving a stimulus. In contrast, the other class of models assume that mental states change continuously. These continuous models are founded in signal detection theory and the more contemporary models in Bayesian inference frameworks. …

Development Of A Three Degree-Of-Freedom Control Simulation For A Group 3 Large Unmanned Aircraft System, Majka Anna Wilczynski

Theses and Dissertations

Aircraft modeling and simulation has become increasingly important in the aviation world. Simulations allow for safer and more economical training prior to flight testing. In this project, a three degree-of-freedom control simulation coded in a MATLAB environment is used to assess and simulate the dynamic stability of group three unmanned aircraft system. By calculating, evaluating, and simulating the static and dynamic stability derivatives of the aircraft, this project will allow for the estimation of the handling qualities of an unmanned aircraft system. This can help mitigate risks that come along with altering the mass and aerodynamic properties of an aircraft, …

Implementing Food Science-Based Instruction In Career Technical Education Courses, Jasmine D. Hendrix

Theses and Dissertations

Students are exposed to food concepts in agriculture-based career technical education (CTE) courses which provide a gateway for students to become more aware of food science career pathways. Professional development for Mississippi (MS) CTE teachers is needed to effectively implement food science-based instruction since there is not a food science curriculum framework adopted in MS. The objective of this study was to assess a food science professional development training for MS CTE teachers that would increase their self-perceived knowledge of food science, self-perceived ability to conduct food science skills, and their self-efficacy to implement food science-based instruction. Thirty-one teachers participated …

A Longitudinal Analysis Of Pathways To Computing Careers: Defining Broadening Participation In Computing (Bpc) Success With A Rearview Lens, Mercy Jaiyeola

Theses and Dissertations

Efforts to increase the participation of groups historically underrepresented in computing studies, and in the computing workforce, are well documented. It is a national effort with funding from a variety of sources being allocated to research in broadening participation in computing (BPC). Many of the BPC efforts are funded by the National Science Foundation (NSF) but as existing literature shows, the growth in representation of traditionally underrepresented minorities and women is not commensurate to the efforts and resources that have been directed toward this aim.

Instead of attempting to tackle the barriers to increasing representation, this dissertation research tackles the …

3d Shape Estimation Of Negative Obstacles Using Lidar Point Cloud Data, Viswadeep Lebakula

Theses and Dissertations

Obstacle detection and avoidance plays a crucial role in the autonomous navigation of unmanned ground vehicles (UGV). Information about the obstacles decreases as the distance between the UGV and obstacles increases. However, this information decreases much more rapidly for negative obstacles than for positive obstacles. UGV navigation becomes more challenging in off-road environments due to the higher probability of finding negative obstacles (e.g., potholes, ditches, trenches, etc.) compared with on-road environments. One approach to solve this problem is to avoid the candidate path with a negative obstacle, but in off-road environments avoiding negative obstacles in all situations is not possible. …

Nuclear Transparency From Quasi-Elastic $^{12}C(E,E'P)$ Scattering Reaction Up To $Q^2=14.2 ~(Gev/C)^{2}$ In Hall C At Jefferson Lab, Deepak Kumar Bhetuwal

Theses and Dissertations

Color Transparency $(CT)$ is a unique prediction of Quantum Chromodynamics $(QCD)$ where the final (and/or initial) state interactions of hadrons with the nuclear medium are suppressed for exclusive processes at high momentum transfers. While this phenomenon has been observed for mesons, there has never been a conclusive observation for baryons. A clear signal of $CT$ for baryons would be the first evidence of baryons fluctuating to a small size in the nucleus, and the onset would show the transition from nucleon-meson picture to quark-gluon degrees of freedom. The experiment $E1206107$, searching for the onset of $CT$ in protons was completed …

The Effects Of Prior Exposure To Agriculture On College Students’ Food Purchasing Decisions, Leah E. Gann

Theses and Dissertations

This text examines the possible impacts of prior exposure to agriculture, and how this relates to college students’ food purchasing decisions. This study will assess if college students had prior exposure to agriculture before attending college, and what type of exposure this was, as well as assess how this prior exposure may alter purchasing decisions made by students who attend Mississippi State University. To collect this data, this study used a qualitative survey method to question students enrolled in the College of Agriculture and Life Sciences at Mississippi State University and determine if there is a significant relationship between prior …

Modeling The Ballistic Limit Of Fragment Simulating Projectiles Impacting A36 Mild Steel Spaced Armor Configurations, Daniel H. Rios-Estremera

Theses and Dissertations

Terminal ballistics study multivariate behavior and aftermath of projectile and target interactions. Tests and models are often based on monolithic armors, however, layered and spaced armors are common in real world applications. Such configurations add complexities that require research to understand their effects on terminal ballistics. The ballistic limit velocity (V50) represents the speed where armor perforation probability is 50%. It is used for quantitative comparison of protection capabilities for different armors. This research studied the V50 of spaced and layered A36 steel armors against fragment simulating projectiles (FSPs). Four methods for estimating armor V50 were evaluated and compared to …

A Dual Perspective Towards Building Resilience In Manufacturing Organizations, Steven A. Fazio

Theses and Dissertations

Modern manufacturing organizations exist in the most complex and competitive environment the world has ever known. This environment consists of demanding customers, enabling, but resource intensive Industry 4.0 technology, dynamic regulations, geopolitical perturbations, and innovative, ever-expanding global competition. Successful manufacturing organizations must excel in this environment while facing emergent disruptions generated as biproducts of complex man-made and natural systems. The research presented in this thesis provides a novel two-sided approach to the creation of resilience in the modern manufacturing organization. First, the systems engineering method is demonstrated as the qualitative framework for building literature-derived organizational resilience factors into organizational structures …

Leveraging Choice Modeling Technique For Enhancing The Cyber Resilience Of The Smart Grid, Kesava Karishma Devi Dadi

Theses and Dissertations

This research focuses on the cyber-attack of the smart grid and its retrieval to a normal state by estimating the smart grid's resilience. This study developed a theoretical model to estimate the resilience of the smart grid using choice modeling. A utility function is formulated based on various factors and sub-factors of resilience to estimate the resilience of the smart grid. Choice modeling is applied to estimate the model parameters in various fields such as marketing, energy, transportation, and health and to predict the outcome.

1,2-Diazetidine As A New Amidomethylative Reagent To Control The Selectivity For The Synthesis Of N-Heterocycles And Ru(Ii)-Catalyzed Enantioselective Hydroarylation To Form Chromane Derivatives, Chaminda Lakmal Hetti Handi

Theses and Dissertations

1,2-Diazetidine is a four-membered ring heterocyclic compound which has two adjacent nitrogen atoms. However, the syntheses of C-unsubstituted 1,2-diazetidines are rarely reported in the literature. C-unsubstituted 1,2-diazetidines were synthesized through an operationally simple intermolecular vicinal disubstitution reaction between 1,2-dibromoethane and hydrazine with N-arylsulfonyl as the protecting group. Several different types of C-unsubstituted 1,2-diazetidines derivatives were synthesized with either two of the same or two different N-arylsulfonyl groups. The electronic and steric properties were analyzed using Raman spectroscopy and computational calculations. Then, several synthetic applications were demonstrated with 1,2-ditosyl-1,2-diazetidine (DTD). As a synthetic application, a nucleophilic ring-opening reaction of the diazetidine …

Hydrology And Water Quality Analysis In The Big Black River Watershed, Mississippi, Moniba Shabbir

Theses and Dissertations

Evaluating hydrology and water quality for the Big Black River Watershed in Mississippi was accomplished by using the Better Assessment Science Integrating Point and Nonpoint Source (BASINS 4.5), Loading Simulation Program in C++ (LSPC), and Water Quality Analysis Simulation Program (WASP) models. The watershed model calibration was originally accomplished by using historical data collected from U.S. Geological Survey (USGS). The watershed model was calibrated using data from 2000 through 2018 in order to quantify stream flow and point source discharges under a variety of hydrologic conditions. The model predicted response of hydrology was consistent with the observed data range. The …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Assessing The Potential For Lightning-Induced Damage In Commercial Broiler Houses In Mississippi And Alabama, Matthew R. Rowland

Theses and Dissertations

Modern broiler houses are expensive to build, maintain, and insure. Protecting them from extreme weather events is a major concern to producers, integrators, and insurance companies. Lightning strikes can cause catastrophic fires and electrical damage and can lead to costly bird losses. A greater understanding of the impact of lightning on the commercial broiler industries of MS and AL is needed. The objectives of this research were collection of baseline resistance data for broiler houses and equipment in both states, and mapping lightning strike densities across MS and AL, evaluating annual, monthly, seasonal, and diurnal patterns. 63.5% of surveyed broiler …

Methods For Inference And Analysis Of Gene Networks From Rna Sequencing Data, Himangi Srivastava

Theses and Dissertations

RNA (Ribonuceic Acid) sequencing technology is a powerful technology used to give re- searchers essential information about the functionality of genes. The transcriptomic study and downstream analysis highlight the functioning of the genes associated with a specific biological process/treatment. In practice, differentially expressed genes associated with a particular treatment or genotype are subjected to downstream analysis to find some critical set of genes. This critical set of genes/ genes pathways infers the effect of the treatment in a cell or tissue. This disserta- tion describes the multiple stages framework of finding these critical sets of genes using different analysis methodologies …