Digital Commons Network^™

Characterization Of Small Molecules And Ions By Atmospheric Pressure Ionization-Mass Spectrometry, Maleesha De Silva

Theses and Dissertations

Mass spectrometry (MS) has become a widely used technique for the characterization of a wide range of substances in diverse fields. The selection of appropriate ionization techniques, source parameters, charge carriers based on the analyte’s polarity is essential in MS as only the ions are detected. When using a soft ionization technique, single stage-MS at best provides only chemical composition; thus, tandem MS is needed to determine structural information and dissociation pathways. This dissertation focuses on the characterization of various small molecules and ions using different ionization techniques, charge carriers, and collision-induced dissociation (CID).

In Chapter II, commercially available ionic …

Testing Of Methods For Reducing Motivational Bias In Multi - Criteria Decision Analysis Problems, Chadwick Samuel Kerr

Theses and Dissertations

The idea of multi-criteria decision making has been around for quite a while. All judgement tasks are potential points of bias introduction. Each judgement task was assessed to identify common biases introduced through an extensive literature review for each task and bias. In several other studies, the distinction is made between cognitive and motivational biases. Cognitive biases are widely studied and well known with mitigations that have been validated. Motivational biases are judgements influenced by the decision maker’s desire for a specific outcome, also referred to as intentional bias, that are hard to correct and received very little testing and …

Development Of A Bioinspired Nugalbot For Precision Seeding Of Rice, Harsa Dhani

Theses and Dissertations

Many people around the world live in islands with mountainous lands. These people plant upland rice for their staple food. However, farming in these disadvantageous farms requires high input and gains low yield. One possible solution for improving productivity is by utilizing precision seeding. This study is focused on developing a robot for precision seeding of rice that is suitable for farming in rough terrain. A bioinspired human arm robot for picking seeds and making a hole on the ground was developed in accordance with Aalborg method for bioinspired design. Development of a mobile platform to carry the robot arm …

Design Of Plastic Contaminant Eliminator In Seed Cotton, Joshua H. Tandio

Theses and Dissertations

Plastic contamination in cotton is a problem in cotton industry and researchers have worked on this problem with different approaches. This thesis documents the design of mechanical and electronic real-time systems for detecting and removing plastic contaminants. The mechanical system was designed to expose plastic embedded inside the seed cotton to the sensor and to separate plastic contaminated cotton from the process stream. The detection system consisted of an embedded computer interfaced with a USB camera and Neural Network (NN) software running in it. Two NN models were tested, a transfer learning model and a built-from-scratch original model. The original …

Virtual Reality And Postural Control: The Virtual Moving Room Paradigm, Hannah R. Freeman

Theses and Dissertations

Virtual reality (VR) is becoming increasingly important in balance training. However, the influence of VR generated visual perturbation, through the novel virtual moving room paradigm, is unknown. Thirty healthy individuals had their static balance assessed on a BTrackS balance plate under eight different conditions: baseline eyes open and eyes closed with and without VR, unexpected toward and away moving VR perturbation, and expected toward and away moving VR perturbation. Multiple statistical analyses were conducted, and the results revealed significantly higher postural sway variables in the unexpected moving toward trials compared to the other moving room conditions; significantly higher postural sway …

Soybean (Glycine Max) Response To Multiple, Sublethal Exposures Of 2,4-D And Dicamba From Vegetative Through Reproductive Growth, Graham Robert Oakley

Theses and Dissertations

This study was conducted to determine whether soybean productivity is affected by multiple, sublethal herbicide exposures. The effects of dicamba and 2,4-D on soybean (Glycine max) productivity was investigated at 17 site-years. Relative to a single exposure of dicamba at R1, an additional exposure at either V3 or R3 reduced yield up to 23%. Three or more applications did not further decrease yields relative to an R1&R3 exposure. For 2,4-D, a single application to V3, R1, R3, or R5 soybean did not affect grain yield. However, two exposures of 2,4-D occurring from V3 through R3 reduced yield 5 to 7%. …

Examining The Need For Parental Satisfaction With The Msu Extension Equine Assisted Therapy Program, Ashlyn Ann Kiker

Theses and Dissertations

Animal assisted interventions are becoming more prevalent in our society. Animal interventions have become a popular therapy technique that exist to aid a variety of disabilities. Equine therapeutic riding has become one of the most popular forms of animal assisted therapy for both children and adults. While research shows the importance and benefits of animal assisted therapy for children, there is a lack of research concerning parental satisfaction within therapeutic riding programs.

This study tested a newly developed instrument for measuring parental satisfaction for therapeutic riding programs. The Parent/Caregiver Evaluation Tool (Kerr, 2021) was administered to parents/caregivers whose children participated …

The Development Of An Immersive Virtual Exploratory Engine (Ivee) For Immersive Analytics, Sofia Karam

Theses and Dissertations

Due to increasing data complexity, researchers are struggling to visually explore data using traditional methods. Research has shown that a variety of analytics-related tasks can be enhanced using new emerging technologies (e.g., virtual reality [VR] and augmented reality [AR]). This paper provides a detailed design approach for developing an immersive virtual engine system for conducting exploratory and descriptive data analytics. This system is called the Immersive Virtual Exploratory Engine (IVEE), is a VR system that allows users to experience full intractability with its graphical elements and examines various datasets within the same immersive environment. Basic plots—such as histograms, line plots, …

Detecting Malware In Memory With Memory Object Relationships, Demarcus M. Thomas Sr.

Theses and Dissertations

Malware is a growing concern that not only affects large businesses but the basic consumer as well. As a result, there is a need to develop tools that can identify the malicious activities of malware authors. A useful technique to achieve this is memory forensics. Memory forensics is the study of volatile data and its structures in Random Access Memory (RAM). It can be utilized to pinpoint what actions have occurred on a computer system.

This dissertation utilizes memory forensics to extract relationships between objects and supervised machine learning as a novel method for identifying malicious processes in a system …

Verification Of Acoustic Dissipation In Two-Phase Dilute Dispersed Flow Models In Computational Fluid Dynamics, Brennan Reeder

Theses and Dissertations

With existing numerical models for fluid particle systems in CHEM, the acoustic-particle interactions associated with two-phase dilute dispersed flow can be captured and the particle model can be validated using experimental and analytical data and verified using numerical techniques. The experimental and analytical data come from Zink and Delsasso and provides data for particles of diameters 5 to 15 microns for frequencies between 500Hz to 13600Hz. In the particle number density measurements by Zink and Delsasso there was a 10% estimated error range. Using the fourth order skew symmetric flux in CHEM and the built in Eulerian and Lagrangian particle …

Impacts Of Sea-Level Rise On Urban Properties In Tampa Due To Climate Change, Weiwei Xie

Theses and Dissertations

The fast urbanization produces a large and growing population in coastal areas. However, the rise of sea level, one of the most significant impacts of global warming, makes coastal communities much more vulnerable to flooding than before. This Master’s thesis study investigates sea-level rise impacts on parcel-level property in the specific coastal city of Tampa, Florida, USA. An improved sea-level rise model based on satellite altimeter data is first used to predict future sea levels. Based on high-resolution LiDAR digital elevation data and property map, flooded properties are identified to evaluate property damage cost. This empirical analysis provides an in-depth …

Predictive Computational Materials Modeling With Machine Learning: Creating The Next Generation Of Atomistic Potential Using Neural Networks, Mashroor Shafat Nitol

Theses and Dissertations

Machine learning techniques using artificial neural networks (ANNs) have proven to be effective tools to rapidly mimic first principles calculations. These tools are capable of sub meV/atom accuracy while operating with linear scaling with respect to the system size. Here novel interatomic potentials are constructed based on the rapid artificial neural network (RANN) formalism. This approach generates precise force fields for various metals that have historically been difficult to describe at the atomic scale. These force fields can be utilized in molecular dynamics simulations to provide new physical insights. The RANN formalism, which is incorporated into a LAMMPS molecular dynamics …

Mixing Temperature, Binder Content, And Dust Content Effects On Stone Matrix Asphalt, Abhinash Subedi

Theses and Dissertations

This study focuses on the effects of mixing temperature, binder content, and dust content on the performance of Stone Matrix Asphalt (SMA). Mixes produced at different mixing temperatures and with or without added polymer modified binder (P_b) and/or bag house dust (BHD) were evaluated. Two different types of specimens: laboratory mixed laboratory compacted, and plant mixed laboratory compacted were evaluated by Cantabro Mass Loss (CML) testing in an unaged condition or after a laboratory conditioning protocol (CP) was applied. Additional P_b and BHD were added to plant produced mixes in the laboratory before mixing. Results showed that …

School Transportation Protocol And Procedures Related To Students’ Safety And Discipline: Reflective Experiences Of School Bus Drivers And School Administrators, David Luke

Theses and Dissertations

This dissertation deals with the protocol and procedures related to students’ safety and discipline while on a school bus as experienced by school bus drivers’ and school administrators’ experiences as a guide for changes to the existing programs. The following was the overarching research question that guided the study: How do school bus drivers and school administrators describe their reflective experiences related to bus driver training and protocol and procedures associated with student safety and discipline?

A qualitative research design was selected for the study. A case study approach was used to collect and analyze data for the study.

Participants …

Torque Vectoring To Maximize Straight-Line Efficiency In An All-Electric Vehicle With Independent Rear Motor Control, William Blake Brown

Theses and Dissertations

BEVs are a critical pathway towards achieving energy independence and meeting greenhouse and pollutant gas reduction goals in the current and future transportation sector [1]. Automotive manufacturers are increasingly investing in the refinement of electric vehicles as they are becoming an increasingly popular response to the global need for reduced transportation emissions. Therefore, there is a desire to extract the most fuel economy from a vehicle as possible. Some areas that manufacturers spend much effort on include minimizing the vehicle’s mass, body drag coefficient, and drag within the powertrain. When these values are defined or unchangeable, interest is driven to …

Macronutrient Intake: A Multi-Sport Study Of Female Division I Collegiate Athletes, Ffion Price

Theses and Dissertations

Background: Macronutrients play a critical role within collegiate athletes’ performance and health, with carbohydrates providing most of the energy needs for most athletes. There is little research examining the macronutrient intake of healthy collegiate female athletes across sports. The aim of the present study was to compare macronutrient intakes of female collegiate athletes within different sports and compare their intakes to recommendations. Methods: An observational study was conducted to determine whether a sample of female collegiate athletes (n=26) consumed the IOC nutritional recommendations. Sports included within the study were soccer, basketball, volleyball, and cross-country. Athletes were asked to complete a …

Synthesis And Characterization Of A Ccc-Nhc Manganese Complex And Its Catalytic Activity In Alpha-Alkylation Reactions Of Ketones Using Alcohols – Acceptorless Dehydrogenative Coupling Reaction, Thi Bao Tran Nguyen

Theses and Dissertations

N-heterocyclic carbenes are essential for the synthesis and stabilization of various metal complexes due to the tendency to act as sigma-donor of sp2 hybridized lone pair in carbene into sigma-accepting orbital of metals. Meanwhile, the electronic and steric properties of pincer complexes can be fine-tuned by modifying three sites bonded to the metals. Utilizing advantages of both NHCs and the pincer structures, NHCs-based pincer complexes have become increasingly developed in recent years. After the discovery of zirconium and rhodium complexes with CCC-NHC backbones reported in 2005, Hollis’s group has been interested in applying the CCC-NHC pincer precursor for other transition …

The NTh-Order Comprehensive Adjoint Sensitivity Analysis Methodology For Response-Coupled Forward/Adjoint Linear Systems (NTh-Casam-L): I. Mathematical Framework, Dan Gabriel Cacuci

Faculty Publications

This work presents the mathematical framework of the n^th-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Response-Coupled Forward/Adjoint Linear Systems (abbreviated as “n^th-CASAM-L”), which is conceived for obtaining the exact expressions of arbitrarily-high-order (n^th-order) sensitivities of a generic system response with respect to all of the parameters (including boundary and initial conditions) underlying the respective forward/adjoint systems. Since many of the most important responses for linear systems involve the solutions of both the forward and the adjoint linear models that correspond to the respective physical system, the sensitivity analysis of such responses makes it necessary …

Epa Region 8 Qa Document Review Crosswalk, Trec Inc., A Woodard And Curran Company, Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Predation Efficiency Of Lionfish (Pterois Volitans And P. Miles) In Differing Levels Of Habitat Complexity, Abigail Ehlers Kimbrel

All HCAS Student Capstones, Theses, and Dissertations

The invasion of the Indo-Pacific lionfish (Pterois sp.) into the Atlantic and Caribbean has received attention around the globe. Venomous spines, over-sized fanlike pectoral fins, slow movement, and novel feeding strategies have allowed lionfish to become effective apex- predators. Recent research has determined that lionfish use inshore mangrove habitats as foraging grounds, which are also used as nursery habitats for juvenile fish, thus reducing recruitment of native fish populations. The purpose of this study was three-fold: (1) determine the predation efficiency of lionfish in differing mangrove habitat complexities, (2) examine the influence of temperature and behavior of prey commonly found …

Characterization Of Fish Assemblages On An Upper Mesophotic Reef In South Florida Using A Commercial Grade Mini Rov, Sydney L. Panzarino

All HCAS Student Capstones, Theses, and Dissertations

Mesophotic coral ecosystems, or MCEs, are coral ecosystems at approximately 30-150m depths and represent the transitional zone where benthic organisms rely less on photosynthesis and more on filter-feeding or other feeding habits in order to sustain themselves. Fish assemblages in MCE’s have been poorly studied and may possibly provide a connection to shallow water reefs (SWR’s). Mesophotic reef fish communities from 32-37 m depths were assessed using video footage recorded by a remotely operated vehicle (ROV). Video transects were performed at three locations: unburied areas north and south of Port Everglades, as well as an area which experienced burial from …

Student Teachers' Usage And Access Of Electronic Resources In The National Digital Library Of India (Ndli) During The Covid-19 Outbreak, Deivam Muniyandi

Library Philosophy and Practice (e-journal)

. The Indian Institute of Technology (IIT) in Kharagpur created the National Digital Library of India (NDLI). It is a single-window portal that accumulates and collates information from prestigious Indian and international educational institutions, as well as other relevant sources. It is free and accessible to the public. The objective of the study was to find out the student teachers' usage and access of the NDLI during the Covid-19 outbreak. The online survey method was employed for the study. The investigator designed the questionnaire in Google Forms. The researcher sent the questionnaire about the National Digital Library of India via …

Is Activation Of Gdnf/Ret Signaling The Answer For Successful Treatment Of Parkinson's Disease? A Discussion Of Data From The Culture Dish To The Clinic, James A. Conway, Edgar R. Kramer

Peninsula Medical School

The neurotrophic signaling of glial cell line-derived neurotrophic factor (GDNF) with its canonical receptor, the receptor tyrosine kinase RET, coupled together with the GDNF family receptor alpha 1 is important for dopaminergic neuron survival and physiology in cell culture experiments and animal models. This prompted the idea to try GDNF/RET signaling as a therapeutic approach to treat Parkinson's disease with the hallmark of dopaminergic cell death in the substantia nigra of the midbrain. Despite several clinical trials with GDNF in Parkinson's disease patients, which mainly focused on optimizing the GDNF delivery technique, benefits were only seen in a few patients. …

Heat Transfer In The Seabed Boundary Layer, S. Michele, R. Stuhlmeier, A. G.L. Borthwick

School of Engineering, Computing and Mathematics

We present a theoretical model of the temperature distribution in the boundary layer region close to the seabed. Using a perturbation expansion, multiple scales and similarity variables, we show how free-surface waves enhance heat transfer between seawater and a seabed with a solid, horizontal, smooth surface. Maximum heat exchange occurs at a fixed frequency depending on ocean depth, and does not increase monotonically with the length and phase speed of propagating free-surface waves. Close agreement is found between predictions by the analytical model and a finite-difference scheme. It is found that free-surface waves can substantially affect the spatial evolution of …

Error Correction In Quantum Cryptography, Mohamed Salah El Ashmawy

Archived Theses and Dissertations

No abstract provided.

Spiritual Struggle And Spiritual Growth Of Bereft College Students In A Christian Evangelical University, Melinda G. Rhodes, Andrea C. Walker Ph.D.

Salubritas: International Journal of Spirit-Empowered Counseling

This article examines spiritual struggle in bereft Christian evangelical students and how struggle might potentiate spiritual growth. The death loss of a close person can result in shattered assumptions about the world that trigger spiritual questions and struggle and spiritual struggle can be a catalyst for growth. To our knowledge, spiritual growth has not been measured utilizing the actual voices of those struggling with the loss, nor has it been measured in Christian evangelical populations who may find it more threatening to yield to spiritual questioning. The Spirit-centered Change Model guides our conceptualization of spiritual growth from a Christian evangelical …

Expanding God's Redemptive Fractal: Spirit-Centered Counseling And The Transformative Wisdom Of Jesus, Bill Buker

Salubritas: International Journal of Spirit-Empowered Counseling

Using the image of a fractal, a Spirit-centered approach to counseling is proposed that conceptualizes the Spirit’s activity as seeking to replicate the patterns of God’s redemptive story throughout creation by facilitating deep second-order change. Involving an epistemological shift from ways of knowing shaped by the conventional wisdom of culture to a renewed mind grounded in the transformative wisdom of Jesus, this deep change is explored from the perspectives of science and Scripture. Integrating findings from systems theory with the ministry and message of Jesus, this approach to counseling emphasizes relational premises and values believed to be characteristic of the …

The Spirit, Change, And Healing: Toward A Spirit-Centered Model Of Counseling, Edward E. Decker Jr., Bill Buker, Jeffrey S. Lamp

Salubritas: International Journal of Spirit-Empowered Counseling

Spirit-centered counseling is an approach to counseling that makes full use of Spirit-centered spirituality as well as techniques and interventions used within Spirit-centered faith groups. An emphasis is always on the importance of being aware of, and experiencing, the Spirit and utilizing this awareness within the counseling endeavor. Three orienting assumptions are delineated to provide direction for the specific practices and methods of Spirit-centered counseling that prepare the way for Spirit-directed changes. Of special importance are the pneumatological imagination, Holy Spirit empowerment, and the development of a trialogical encounter, within which the counselor and the person seeking counseling experience the …

Full Issue Salubritas 1 (2021), Editors Salubritas

Salubritas: International Journal of Spirit-Empowered Counseling

Inaugural issue of Salubritas: International Journal of Spirit-empowered Counseling

Book Reviews, Florida Historical Society

Florida Historical Quarterly

LAND INTO WATER--WATER INTO LAND: A HISTORY OF WATER MANAGEMENT IN FLORIDA, by Nelson M. Blake, reviewed by George E. Buker; A REVOLUTIONARY PEOPLE AT WAR: THE CONTINENTAL ARMY AND AMERICAN CHARACTER, 1775-1783, by Charles Royster, reviewed by Gerard W. Gawalt; THE BEGINNINGS OF NATIONAL POLITICS: AN INTERPRETIVE HISTORY OF THE CONTINENTAL CONGRESS, by Jack N. Rakove, reviewed by Robert A. Rutland; THE MADISONS: A BIOGRAPHY, by Virginia Moore, reviewed by John Hebron Moore; THE MAKING OF TOCQUEVILLE’S DEMOCRACY IN AMERICA, by James T. Schleifer, reviewed by Herbert Aptheker; CHATTEL SLAVERY AND WAGE SLAVERY: THE ANGLO-AMERICAN CONTEXT, 1830-1860, by Marcus …