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Articles 25411 - 25440 of 26913
Full-Text Articles in Entire DC Network
Automatic Query Reformulation For Code Search Using Crowdsourced Knowledge, Mohammad M. Rahman, Chanchal K. Roy, David Lo
Automatic Query Reformulation For Code Search Using Crowdsourced Knowledge, Mohammad M. Rahman, Chanchal K. Roy, David Lo
Research Collection School Of Computing and Information Systems
Traditional code search engines (e.g., Krugle) often do not perform well with natural language queries. They mostly apply keyword matching between query and source code. Hence, they need carefully designed queries containing references to relevant APIs for the code search. Unfortunately, preparing an effective search query is not only challenging but also time-consuming for the developers according to existing studies. In this article, we propose a novel query reformulation technique–RACK–that suggests a list of relevant API classes for a natural language query intended for code search. Our technique offers such suggestions by exploiting keyword-API associations from the questions and answers …
Modeling Location-Based Social Network Data With Area Attraction And Neighborhood Competition, Thanh Nam Doan, Ee-Peng Lim
Modeling Location-Based Social Network Data With Area Attraction And Neighborhood Competition, Thanh Nam Doan, Ee-Peng Lim
Research Collection School Of Computing and Information Systems
Modeling user check-in behavior helps us gain useful insights about venues as well as the users visiting them. These insights are important in urban planning and recommender system applications. Since check-in behavior is the result of multiple factors, this paper focuses on studying two venue related factors, namely, area attraction and neighborhood competition. The former refers to the ability of a spatial area covering multiple venues to collectively attract check-ins from users, while the latter represents the extent to which a venue can compete with other venues in the same area for check-ins. We first embark on empirical studies to …
Artificial Intelligence, Machine Learning, And Autonomous Technologies In Mining Industry, Zeshan Hyder, Keng Siau, Fiona Nah
Artificial Intelligence, Machine Learning, And Autonomous Technologies In Mining Industry, Zeshan Hyder, Keng Siau, Fiona Nah
Research Collection School Of Computing and Information Systems
The implementation of artificial intelligence (AI), machine learning, and autonomous technologies in the mining industry started about a decade ago with autonomous trucks. Artificial intelligence, machine learning, and autonomous technologies provide many economic benefits for the mining industry through cost reduction, efficiency, and improving productivity, reducing exposure of workers to hazardous conditions, continuous production, and improved safety. However, the implementation of these technologies has faced economic, financial, technological, workforce, and social challenges. This article discusses the current status of AI, machine learning, and autonomous technologies implementation in the mining industry and highlights potential areas of future application. The article presents …
Optimizing Accounting Decision Making Using Goal Programming, Clarence Goh
Optimizing Accounting Decision Making Using Goal Programming, Clarence Goh
Research Collection School Of Accountancy
Goal programming is a decision‐making technique that seeks to help decision makers make decisions that satisfy competing goals to the best extent possible. This article provides a description of goal programming, demonstrates how it can be implemented on a spreadsheet, and illustrates its use through an example from management accounting.
Solar Tracker Renewable Energy, Stephanie Christie, Annabeth Helmly, Matthew Smith, Katrina Vaughan
Solar Tracker Renewable Energy, Stephanie Christie, Annabeth Helmly, Matthew Smith, Katrina Vaughan
ENgaging Educators in Renewable enerGY (ENERGY): Lesson Plans & Slideshows (2017-2019)
No abstract provided.
Analysis Of Horizontal Axis Wind Turbine Array Optimization, Peter-Claver Nwanze, Keith Bazemore, Jessica Lyons, J. Ann Mitchem
Analysis Of Horizontal Axis Wind Turbine Array Optimization, Peter-Claver Nwanze, Keith Bazemore, Jessica Lyons, J. Ann Mitchem
ENgaging Educators in Renewable enerGY (ENERGY): Lesson Plans & Slideshows (2017-2019)
Wind energy is the fastest growing form of renewable energy, with a multitude of possibilities for expansion. This, as well as other forms of renewable energy, will facilitate understanding of the growing concerns regarding global warming by decreasing our dependence on fossil fuels. Wind energy requires wind speeds of at least six miles per hour; therefore, only certain geographical areas are suitable for the use of this technology. The purpose of this experiment was to determine whether the orientation of an array of wind turbines increases or decreases energy production and efficiency. In this study, various arrays consisting of five …
Explicating Perceived Sustainability-Related Climate: A Situational Motivator Of Pro-Environmental Behavior, Yan Wah Leung, Sonny Rosenthal
Explicating Perceived Sustainability-Related Climate: A Situational Motivator Of Pro-Environmental Behavior, Yan Wah Leung, Sonny Rosenthal
Research Collection College of Integrative Studies
Individuals take cues from their surroundings when deciding whether to perform pro-environmental behaviors. Previous studies have acknowledged the role of structural, policy, and communication efforts to encourage pro-environmental behavior. Such studies demonstrate the importance of evaluating the external contexts when examining behaviors. Yet, there is a lack of explication of what external context is entailed. Expanding the concept of perceived sustainability-related climate (PSRC) used in organizational communication literature, this study proposes two dimensions that shape PSRC in the workplace—structural cues and social cues. The study then generalizes PSRC such that it is applicable in contexts beyond the workplace and proposes …
2019 Spring Commencement, Georgia Southern University
2019 Spring Commencement, Georgia Southern University
Commencement Programs
No abstract provided.
Demography Of Aging, Marc A. Garcia, Catherine García, Kyriakos Markides
Demography Of Aging, Marc A. Garcia, Catherine García, Kyriakos Markides
Department of Sociology: Faculty Publications
From 2010-2015, the annual growth rate of older adults was 3.3 percent globally (United- Nations 2017). As the proportion of the world’s population continues to age, the increasing number of older adults in the population presents significant challenges for policy makers in nearly all sectors of society. According to the United Nations Population Ageing Report 2017, the global population of adults 60 years and older increased more than two-fold from 382 million in 1980 to 962 million in 2017, and the number is expected to reach nearly 2.1 billion by 2050 (United Nations 2018). While population aging affects nearly …
Humans In The Loop: Incorporating Expert And Crowd-Sourced Knowledge For Predictions Using Survey Data, Anna Filippova, Connor Gilroy, Ridhi Kashyap, Antje Kirchner, Allison C. Morgan, Kivan Polimis, Adaner Usmani, Tong Wang
Humans In The Loop: Incorporating Expert And Crowd-Sourced Knowledge For Predictions Using Survey Data, Anna Filippova, Connor Gilroy, Ridhi Kashyap, Antje Kirchner, Allison C. Morgan, Kivan Polimis, Adaner Usmani, Tong Wang
Department of Sociology: Faculty Publications
Survey data sets are often wider than they are long. This high ratio of variables to observations raises concerns about overfitting during prediction, making informed variable selection important. Recent applications in computer science have sought to incorporate human knowledge into machine-learning methods to address these problems. The authors implement such a “human-in-the-loop” approach in the Fragile Families Challenge. The authors use surveys to elicit knowledge from experts and laypeople about the importance of different variables to different outcomes. This strategy offers the option to subset the data before prediction or to incorporate human knowledge as scores in prediction models, or …
Curriculum Integration: Twenty Questions- With Answers, Gert Nesin, John Lounsbury
Curriculum Integration: Twenty Questions- With Answers, Gert Nesin, John Lounsbury
Becoming: Journal of the Georgia Association for Middle Level Education
This is a digital edition of the book Curriculum Integration: Twenty Questions- With Answers, first published in 1999 by the Georgia Middle School Association.
ISBN-13: 978-0967508108
ISBN-10: 096750810X
Partnering For Engineering Teacher Education, Lara K. Smetana, Cynthia Nelson, Patricia Whitehouse, Kim Koin
Partnering For Engineering Teacher Education, Lara K. Smetana, Cynthia Nelson, Patricia Whitehouse, Kim Koin
Education: School of Education Faculty Publications and Other Works
The aim of this article is to describe a specific approach to preparing elementary teacher candidates to teach engineering through a field-based undergraduate course that incorporates various engineering experiences. First, candidates visit a children’s museum to engage in engineering challenges and reflect on their experiences as learners as well as teachers. The majority of course sessions occur on-site in a neighborhood elementary school with a dedicated engineering lab space and teacher, where candidates help facilitate small group work to develop their own understandings about engineering and instructional practices specific to science and engineering. Candidates also have the option to attend …
'As You Were': Military-Bureaucratic Control And The Employment Relationship In The British Armed Forces, Margaret Prior
'As You Were': Military-Bureaucratic Control And The Employment Relationship In The British Armed Forces, Margaret Prior
Plymouth Business School Theses
Service in the British armed forces has not previously been considered a subject for employment and industrial relations research, but military personnel are in an employment relationship and thus worthy of such study. Drawing on an extensive literature review, documentary analysis and a qualitative survey and interviews with ex-service personnel, this study adopts a critical realist philosophy and retroduction to examine how the military employment relationship is regulated, experienced and contested, with particular reference to discipline and voice. It also compares military service with civilian employment, noting that the two, once similar, have diverged. The study uncovers a complex web …
Fathers At Work: Challenges And Stereotypes Facing Fathers With Caregiving Responsibilities In Employment, Jasmine Kelland
Fathers At Work: Challenges And Stereotypes Facing Fathers With Caregiving Responsibilities In Employment, Jasmine Kelland
Plymouth Business School Theses
This study explores how caregiving fathers are perceived in contemporary employment to establish if this contributes to an understanding of the dominance of fathers in the role of ‘breadwinner’. Much existing research in this area is based in the US, largely utilising students as participants, and has limited applicability to contemporary UK fatherhood. This study employs a mixed methods design underpinned by a social constructivist standpoint, with managers and working parents as participants. Understanding regarding the perceptions of caregiving fathers is sought through exploring how such fathers are rated when they apply for work utilising online vignettes, vignette based focus …
Complementary Currencies: A Systems Theory Approach To Monetary Macroeconomics, Neil Smith
Complementary Currencies: A Systems Theory Approach To Monetary Macroeconomics, Neil Smith
Plymouth Business School Theses
It was commonplace in history for several types of currencies to circulate side-by-side within a country, often by design, and the notion that this may enable improved socioeconomic outcomes has been proposed in narratives across various disciplines. However, orthodox macroeconomic theory presupposes that national economies operate optimally when a single monetary unit is employed: general equilibrium optimisation modelling is applied where coordination is assumed and a single money acts only as numéraire. This thesis adopts a broader Political Economy perspective to develop a general theory macroeconomic model to elucidate the arguments for monetary plurality in a regional context. Cross-disciplinary literature …
Hydrogen Storage In Formic Acid As A Renewable Energy Source Using Heterogeneous Catalysis, Obaid Aldosari
Hydrogen Storage In Formic Acid As A Renewable Energy Source Using Heterogeneous Catalysis, Obaid Aldosari
Turkish Journal of Chemistry
One of the most vital chemicals, which is not only found naturally but can also be synthesized in the laboratory, is formic acid (FA). FA is a key byproduct of several second-generation biorefinery processes as well, and it is used in several pharmaceutical and industrial applications. Recently, another significant use of FA that is taking the lead is as a form of fuel. This could either involve reformation, as a possible form of chemical hydrogen storage, or be done without reformation in the form of FA fuel cells, in particular because FA fuel cells are much more effective than other …
Amperometric Urea Biosensor Based On Immobilized Urease On Polypyrrole And Macroporous Polypyrrole Modified Pt Electrode, Maliheh Hosseinian, Ghasem Najafpour, Ahmad Rahimpour
Amperometric Urea Biosensor Based On Immobilized Urease On Polypyrrole And Macroporous Polypyrrole Modified Pt Electrode, Maliheh Hosseinian, Ghasem Najafpour, Ahmad Rahimpour
Turkish Journal of Chemistry
Biosensing of urea by a biosensor as a direct detection method at ambient temperature and pressure instead of chromatography leads to a significant reduction in processing costs. Amperometric biosensors based on urease immobilization on macroporous polypyrrole (MPPy) and pyrrole on the surface of a Pt electrode were developed. Applying cyclic voltammetry (CV), we demonstrated the synthesis of MPPy using monodispersed polystyrene spheres (460 nm) as a template. CV and chronoamperometric studies were conducted to evaluate the electrochemical current of the modified electrodes. For the electrode with polypyrrole (PPy), the biosensor response was linear in the range of 1.67--8.32 mM (R$^{2}$ …
Antioxidant Properties Of Water-Soluble Phthalocyanines Containing Quinoline 5-Sulfonic Acid Groups, Armağan Günsel, Esma Hande Alici, Ahmet Turgut Bi̇lgi̇çli̇, Gülnur Arabaci, Meryem Ni̇lüfer Yaraşir
Antioxidant Properties Of Water-Soluble Phthalocyanines Containing Quinoline 5-Sulfonic Acid Groups, Armağan Günsel, Esma Hande Alici, Ahmet Turgut Bi̇lgi̇çli̇, Gülnur Arabaci, Meryem Ni̇lüfer Yaraşir
Turkish Journal of Chemistry
In the present study, the antioxidant properties of peripherally and nonperipherally water-soluble tetra (quinoline 5-sulfonic acid) substituted metal-free (1,2), Zn(II) (3, 4), Co(II) (5, 6), and Mn(III)Cl (7, 8) phthalocyanine (Pc) derivatives were reported. In order to determine the antioxidant properties of the Pc compounds, three different commonly known antioxidant methods were used: DPPH ($\alpha $,$\alpha $-diphenyl-$\beta $-picrylhydrazyl) radical scavenging, ferrous ion chelating, and reducing power assays. Compound \textbf{6} showed the best DPPH activity among the other tested compounds except for the standards. The ferrous ion chelating IC$_{50\, }$value of compound 7 was nearly as good as that of the …
Detection Of Lard Contamination In Five Different Edible Oils By Ft-Ir Spectroscopy Using A Partial Least Squares Calibration Model, Fazeelah Munir, Syed Ghulam Musharraf, Syed Tufail Hussain Sherazi, Muhammad Imran Malik, Muhmmad Iqbal Bhanger
Detection Of Lard Contamination In Five Different Edible Oils By Ft-Ir Spectroscopy Using A Partial Least Squares Calibration Model, Fazeelah Munir, Syed Ghulam Musharraf, Syed Tufail Hussain Sherazi, Muhammad Imran Malik, Muhmmad Iqbal Bhanger
Turkish Journal of Chemistry
Lard is defined as animal fat acquired from the adipose tissue of pigs and is not permitted for human consumption or external use by certain religions such as Islam and Judaism. Due to its low-cost availability for commercial use, it is often mixed with other vegetable oils mistakenly or deliberately and causes loss of consumer trust; hence, its detection in food products is essential. Consumers tend to know the authenticity of commercially available edible oils. However, edible oils are subjected to adulteration risks with lard, which breaches consumer rights. In the present study, we designed a transmission Fourier transform infrared …
Synthesis Of Smz Derivatives And Investigation Of Effects On Germination, Root, And Plant Growth Of \Textit{Arabidopsis Thaliana} L., Tuğba Güngör, Ferah Cömert Önder, Fati̇h Sezer, Aslihan Özbi̇len, Kemal Meli̇h Taşkin, Mehmet Ay
Synthesis Of Smz Derivatives And Investigation Of Effects On Germination, Root, And Plant Growth Of \Textit{Arabidopsis Thaliana} L., Tuğba Güngör, Ferah Cömert Önder, Fati̇h Sezer, Aslihan Özbi̇len, Kemal Meli̇h Taşkin, Mehmet Ay
Turkish Journal of Chemistry
A series of sulfonamide derivatives were synthesized by reactions with various functional groups containing benzenesulfonyl chlorides and aniline derivatives under different substitution reaction conditions. The structures of SMZ derivatives were confirmed with melting point, FT-IR, $^{1}$H NMR, $^{13}$C NMR, and LC-MS/MS techniques. In order to investigate the cytotoxic effects of these derivatives, we used a model plant species. The synthesized compounds (S1-S5) and sulfamethazine (SMZ) as a positive control were applied to Arabidopsis thaliana seeds. Our results indicated that S3 and S4 induced shorter roots and lower wet weight in plants. Plants treated with S2 and S5 showed no growth …
Novel Voltammetric Investigation Of Dipyridamole At A Disposable Pencil Graphite Electrode, Iulia Gabriela David, Lorelei Iordache, Dana Elena Popa, Mihaela Buleandra, Victor David, Emilia-Elena Iorgulescu
Novel Voltammetric Investigation Of Dipyridamole At A Disposable Pencil Graphite Electrode, Iulia Gabriela David, Lorelei Iordache, Dana Elena Popa, Mihaela Buleandra, Victor David, Emilia-Elena Iorgulescu
Turkish Journal of Chemistry
The present paper describes the voltammetric analysis of dipyridamole (DIP) at a cheap, disposable pencil graphite electrode (PGE). The working conditions were optimized with regard to the electrode material and the supporting electrolyte. Cyclic voltammetric investigations emphasized that DIP is irreversibly oxidized at the PGE. The electrode process is pH-dependent and controlled by both diffusion and adsorption. For DIP quantitative determination a differential pulse voltammetric (DPV) method in phosphate buffer solution pH 7.00 was developed. DIP's oxidation peak current varied linearly with the analyte concentration, presenting two linear ranges, namely 5.00 $\times $ 10$^{-7}$-2.50 $\times $ 10$^{-5}$ M and 2.50 …
$N$-Acylazole Mediated Stereoselective And Regioselective Synthesis Of $N$-Substituted Azole Acrylonitriles, Osman Aydin, Şule Kökten, Hakan Ünver, İlhami̇ Çeli̇k
$N$-Acylazole Mediated Stereoselective And Regioselective Synthesis Of $N$-Substituted Azole Acrylonitriles, Osman Aydin, Şule Kökten, Hakan Ünver, İlhami̇ Çeli̇k
Turkish Journal of Chemistry
Regio- and stereoselective synthesis of $N$-substituted azole acrylonitriles has been achieved smoothly in $N,N$-dimethylformamide (DMF) in the presence of potassium carbonate (K$_{2}$CO$_{3})$ as a base catalyst. $N$-Substituted azole acrylonitriles were obtained in moderate to good yields (39%-87%) with a one-pot reaction between readily available $N$-acetylazoles and Baylis-Hillman nitriles. The structural determinations were accomplished by NOESY $^{1}$H NMR and X-ray crystallography.
On The Azo Dyes Derived From Benzoic And Cinnamic Acids Used As Photosensitizers In Dye-Sensitized Solar Cells, Luka Matovic, Nikola Tasic, Nemanja Trisovic, Jelena Ladarevic, Vesna Vitnik, Zeljko Vitnik, Branimir Grgur, Dusan Mijin
On The Azo Dyes Derived From Benzoic And Cinnamic Acids Used As Photosensitizers In Dye-Sensitized Solar Cells, Luka Matovic, Nikola Tasic, Nemanja Trisovic, Jelena Ladarevic, Vesna Vitnik, Zeljko Vitnik, Branimir Grgur, Dusan Mijin
Turkish Journal of Chemistry
In order to get a better insight into the relationship between molecular structure and photovoltaic performance, six monoazo dye molecules containing benzoic and cinnamic acid moieties were synthesized and their photovoltaic properties were studied. Three of them have not been previously used in solar cells. Spectroscopic measurements of the investigated compounds coupled with theoretical calculations were performed. Short-circuit current density, open-circuit voltage, and fill-factor were determined. It was found that a larger amount of short-circuit current density will be generated if the HOMO--LUMO energy gap is lower, determined by the stability of the molecule and the electronic effect of the …
Amino-Functionalized Mesostructured Cellular Foam Silica: A Highly Efficient And Recyclable Catalyst In The Knoevenagel Condensation Reaction, Dong Hao, Hongyuan Yang, Tengfei Zhang, Qing Liu
Amino-Functionalized Mesostructured Cellular Foam Silica: A Highly Efficient And Recyclable Catalyst In The Knoevenagel Condensation Reaction, Dong Hao, Hongyuan Yang, Tengfei Zhang, Qing Liu
Turkish Journal of Chemistry
Mesostructured cellular foam silica was functionalized by an amino group (MCF-NH$_{2})$ using the postsynthesis grafting method and utilized as a recyclable catalyst for the Knoevenagel reaction to afford $\alpha $, $\beta $-unsaturated compounds. The catalyst was systematically characterized by various analyses such as nitrogen adsorption, X-ray diffraction, Fourier transform infrared spectrophotometry, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and Hammett indicator method. The results showed that MCF-NH$_{2}$ catalyst was successfully prepared with a high surface area of 215 m$^{2}$ g$^{-1}$ and a large pore volume of 1.37 cm$^{3}$ g$^{-1}$. Compared with the nonfunctionalized MCF sample, the window and cell …
A Novel Silver(I)-Selective Pvc Membrane Sensor And Its Potentiometric Applications, Ömer Işildak, Ni̇hal Deli̇gönül, Oğuz Özbek
A Novel Silver(I)-Selective Pvc Membrane Sensor And Its Potentiometric Applications, Ömer Işildak, Ni̇hal Deli̇gönül, Oğuz Özbek
Turkish Journal of Chemistry
Silver(I)-selective sensors were prepared from a solid-state contact polyvinyl chloride (PVC) membrane. ($Z)$-2-(2-((3-(2-hydroxyphenyl)-5-(p-tolyl)-1$H$-pyrrol-2-yl)imino)-5-(p-tolyl)-2$H$-pyrrol-3-yl)phenol was synthesized as an ionophore molecule and embedded in the silver(I)-selective PVC membrane composition. The optimum membrane composition was determined as 2.5% ionophore, 61.7% bis-(2-ethylhexyl)sebacate, 1.0% potassium tetrakis (p-chlorophenyl) borate, and 34.8% PVC. The developed sensor exhibited a linear potential change $E$ = 67.42 (-log [Ag$^{+}$]) $+$ 1152.9 and $R^{2}$ = 0.9960) in the varying concentration range of 1.0 $\times $ 10$^{-1}$ to 1.0 $\times $ 10$^{-5}$ mol L$^{-1}$ silver ions. This sensor shows a detection limit of 7.3 $\times $ 10$^{-7}$ mol L$^{-1}$. The proposed sensor …
Determination Of N-Acetylcysteine In The Presence Of Ciprofloxacin Or Levofloxacin In Microparticulate Dry Powder Inhalers, Yağmur Akdağ Çayli, Selma Şahi̇n, Emi̇rhan Nemutlu, Levent Öner
Determination Of N-Acetylcysteine In The Presence Of Ciprofloxacin Or Levofloxacin In Microparticulate Dry Powder Inhalers, Yağmur Akdağ Çayli, Selma Şahi̇n, Emi̇rhan Nemutlu, Levent Öner
Turkish Journal of Chemistry
A fast and easy method was validated for simultaneous determination of ciprofloxacin hydrochloride monohydrate (CP), levofloxacin hemihydrate (LV), and N-acetylcysteine (NAC) in samples. The analysis was performed on a C$_{18}$ column (250 x 4.6 mm, 5 μm) (Inertsil ODS-3V) using an isocratic elution method with a mobile phase composed of 25 mM KH$_{2}$PO$_{4}$ (pH 3.0) and methanol (72:28, v/v) at a flow rate of 1 mL/min. UV detection was performed at 214 nm for NAC and 293 nm for CP and LV. The method was validated for linearity, accuracy, precision (repeatability and reproducibility), specificity, sensitivity, and stability. The calibration study …
Qualitative And Quantitative Determination Of The Effective Components Of The Plants In Different Herbal Slimming Products In Turkey By Hplc, Benan Dursunoğlu, Hafi̇ze Yuca, Sefa Gözcü, Bi̇lal Yilmaz, Zühal Güvenalp
Qualitative And Quantitative Determination Of The Effective Components Of The Plants In Different Herbal Slimming Products In Turkey By Hplc, Benan Dursunoğlu, Hafi̇ze Yuca, Sefa Gözcü, Bi̇lal Yilmaz, Zühal Güvenalp
Turkish Journal of Chemistry
Obesity is a serious disease that can be due to genetic and environmental reasons and is defined by the World Health Organization as abnormal or excessive fat accumulation that may impair health. There is an increasing trend towards herbal slimming products in obesity treatment. The quality control analysis of these products is important for public health. In this study, new, simple, and sensitive high performance liquid chromatography methods were developed for qualitative and quantitative determination of arbutin, hydroquinone, ursolic acid, chlorogenic acid, epigallocatechin gallate, epigallocatechin, epicatechin gallate, and catechin in eleven herbal slimming products in Turkey containing Camellia sinensis, Ilex …
Enhanced Uptake Capacities And Isosteric Heats Of Co$_{2}$ And Ch$_{4}$ Adsorption On Spent Coffee Ground Activated Carbons Loaded With Metal Ions, Çi̇sem Kirbiyik, Burak Zafer Büyükbekar, Mahmut Kuş, Mustafa Ersöz
Enhanced Uptake Capacities And Isosteric Heats Of Co$_{2}$ And Ch$_{4}$ Adsorption On Spent Coffee Ground Activated Carbons Loaded With Metal Ions, Çi̇sem Kirbiyik, Burak Zafer Büyükbekar, Mahmut Kuş, Mustafa Ersöz
Turkish Journal of Chemistry
Low-cost activated carbon (AC) samples obtained from waste coffee grounds were used for CO$_{2}$ and CH$_{4}$ adsorption. ACs were prepared by chemical activation and carbonized at three different temperatures. AC carbonized at 800 $^{\circ}$C showed a relatively high surface area (582.92 m$^{2}$ g$^{-1})$ and high adsorption capacities of 2.6 mmol g$^{-1}$ and 1.1 mmol g$^{-1}$ at 25 $^{\circ}$C for CO$_{2}$ and CH$_{4}$, respectively. Adsorbent samples were prepared by loading of Fe$^{3+}$ metal ions onto ACs and their adsorption capacities were compared with those of nonloaded ACs. As expected, the loading of Fe$^{3+}$ metal ions increased the adsorption capacities at all …
Alpha-Pyrone Glycosides From Scutellaria Salviifolia Benth, Zeynep Doğan, Kan'ichiro Ishiuchi, Toshiaki Makino, İclal Saraçoğlu
Alpha-Pyrone Glycosides From Scutellaria Salviifolia Benth, Zeynep Doğan, Kan'ichiro Ishiuchi, Toshiaki Makino, İclal Saraçoğlu
Turkish Journal of Chemistry
Scutellaria salviifolia Benth. is an endemic species growing in Turkey that belongs to the family Lamiaceae. As a result of a phytochemical study on the aerial parts of S. salviifolia Benth., two new and 10 known compounds were isolated from the aqueous fraction of methanolic extract. The new compounds are methyl-$\alpha $-pyrone glucosides, 3,4-dihydroxy-6-methylpyran-2-one 3-$O$-$\beta $-glucopyranoside (=scusalvioside A, 1), and 3,4-dihydroxy-6-methylpyran-2-one 3-$O$-$\beta $-(6$'$-$O$-$E$-caffeoyl) glucopyranoside (=scusalvioside B, 2) with new skeletal structures. Along with them, 3 phloroglucinol glucosides [phlorin (3), tadehaginoside (4), and 6$^{\prime \prime} $-$O$-$Z$-$p$-coumaroyl phloroglucinol-1-$O$-$\beta $-glucopyranoside (5)], 6 flavonoids [apigenin (6), apigenin 5-$O$-$\beta $-glucopyranoside (7), isoschaftoside (8), luteolin 7-$O$-$\beta …
Synthesis, Characterization, And Nonlinear Optical Properties Of Some New Series Of S-(5-Aryl-1,3,4-Oxadiazol-2-Yl) 2-Chloroethanethioate Derivatives, Zahra Dono Ghezelbash, Hamideh Motiei, Miri Mahmoody, Karim Akbari Delmaghani
Synthesis, Characterization, And Nonlinear Optical Properties Of Some New Series Of S-(5-Aryl-1,3,4-Oxadiazol-2-Yl) 2-Chloroethanethioate Derivatives, Zahra Dono Ghezelbash, Hamideh Motiei, Miri Mahmoody, Karim Akbari Delmaghani
Turkish Journal of Chemistry
In the present investigation, some novel S-(5-aryl-1,3,4-oxadiazol-2-yl)2-chloroethanethioate (3a-3e) derivatives were synthesized and their impact on optical properties was studied. They have also been characterized by elemental analysis and various spectroscopic methods including FTIR, $^{1}$H NMR, $^{13}$C NMR, and UV-Vis techniques. The nonlinear refractive indexes of 3a-3e were also measured in dichloromethane via Z-scan method using a continuous wave diode-pumped laser at 532 nm wavelength. The nonlinear refractive coefficient of compounds was obtained from ${10}^{11}\, \, {m}^{{2}}{/W}$ order. Regarding the appropriate nonlinearity of these compounds, they could be considered good candidates for biooptical and photonic applications. All the synthesized compounds (3a-3e) …