Digital Commons Network^™

Computational Studies On Bimetallic Catalysis And X-Ray Absorption Spectroscopy, Sayakkarage R. G. Fernando

LSU Doctoral Dissertations

Computational studies are very important to gain an insight into reaction mechanisms and in interpreting and understanding complicated experimental observations. This report contains a discussion on computational studies performed on bimetallic catalysis and on X-ray absorption spectroscopy of insulators. The viability of a bimetallic rhodium and cobalt catalysts for industrially important hydroformylation and aldehyde-water shift catalysis (AWS) is discussed. Density functional theory (DFT) studies were used for bimetallic catalysis and time-dependent DFT studies were used for excited state dynamics. These studies were performed using Gaussian 09 package and NWChem. Hydroformylation is experimentally performed in acetone and 30% water/acetone systems and …

Wavelets, Coorbit Theory, And Projective Representations, Amer Hasan Darweesh

LSU Doctoral Dissertations

Banach spaces of functions, or more generally, of distributions are one of the main topics in analysis. In this thesis, we present an abstract framework for construction of invariant Banach function spaces from projective group representations. Coorbit theory gives a unified method to construct invariant Banach function spaces via representations of Lie groups. This theory was introduced by \Fch\, and \Gro\, in \cite{FG,FG1, FG2,FG3} and then extended in \cite{CO2}. We generalize this concept by constructing coorbit spaces using projective representation which is first studied by O. Christensen in \cite{O1}. This allows us to describe wider classes of function spaces as …

Mishpacha In The American Diaspora: An Exploratory Study Of Highly-Involved Jewish Families, Trevan Glen Hatch

LSU Doctoral Dissertations

Both family and religion are important to a large majority of the population in the United States. In the last few decades, research on religious families has significantly increased. Empirical research on Jewish families, however, is scant. The purpose of this study is to explore contemporary American Jewish family life in relation to Judaism, both cultural and religious. Specifically, the two primary objectives of this study are 1) to examine how Jewish culture and religion may influence and shape Jewish family life; and 2) to examine how family relationships may influence observance of Jewish cultural or religious traditions. This reciprocal …

Sensory Perception Of Saltiness And Bitterness In Oil-In-Water Emulsions, Damir Dennis Torrico

LSU Doctoral Dissertations

The objective of this research was to evaluate saltiness and bitterness perception in oil-in-water emulsion systems. For that purpose, three experiments were performed: A sensory threshold study, a descriptive sensory and physical property evaluation, and a psychophysical assessment of taste perception in emulsion systems. Experiment-I: Sensory detection and recognition thresholds of NaCl, caffeine, and KCl in aqueous-solutions vs. oil-in-water emulsions were evaluated. For saltiness recognition thresholds, KCl thresholds were higher compared to those of NaCl. For NaCl and KCl, emulsions did not significantly affect the saltiness recognition threshold compared to that of solutions. The bitterness recognition thresholds of caffeine and …

Boron Functionalization Of Bodipy Dyes, And Their Evaluation As Bioimaging Agents, Alex Long Nguyen

LSU Doctoral Dissertations

BODIPY, also known as “porphyrin’s little sister,” belongs to a class of fluorescent dyes. It contains a dipyrromethene π-system with a disubstituted boron atom. The basic 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) is known for its numerous useful applications in the fields of biology and materials. Modification of this well-known fluorophore has been shown to change its photophysical and chemical properties. There has been great interest in the modification at the boron center in recent years for synthesizing new dyads and cascade-type dyes. This work focuses on functionalization at the boron center with carbon and oxygen nucleophiles for further investigation as bioimaging agents. Chapter …

Real-Time Shadows For Gigapixel Displacement Maps, Kevin Anthony Cherry

LSU Doctoral Dissertations

Shadows portray helpful information in scenes. From a scientific visualization standpoint, they help to add data without unnecessary clutter. In video games they add realism and depth. In common graphics pipelines, due to the independent and parallel rendering of geometric primitives, shadows are difficult to achieve. Objects require knowledge of each other and therefore multiple renders are needed to collect the necessary data. The collection of this data comes with its own set of trade offs. Our research involves adding shadows into a lunar rendering framework developed by Dr. Robert Kooima. The NASA-collected data contains a multi-gigapixel displacement map describing …

Effects Of Mirror Exposure And Brief Mindfulness Interventions In Undergraduate Females With Weight And Shape Concerns, Jessica Abaigeal Esmeier Kinsaul

LSU Doctoral Dissertations

Risk of disordered eating is high amongst college women in the U.S., often resulting in negative outcomes with regard to health, social functioning and psychological well-being. Disordered eating is associated with multiple aspects of emotional processing, such as emotion regulation, negative affect, and avoidance. Emotional processing difficulties can be addressed with both exposure techniques and mindfulness, which involves present moment awareness with an attitude of acceptance and non-judgment. Interventions using mirror exposure (standing before a mirror and systematically describing the body) to treat disordered eating and body image, particularly those utilizing aspects of mindfulness, show promise in terms of improving …

Topological Dynamics On Compact Phase Spaces, Lieth Abdalateef Majed

LSU Doctoral Dissertations

Our main focus will be to investigate the various facets of what are commonly called dynamical systems or flows, which are triples $(S,X,\pi)$, where $X$ is a compact Hausdorff space and $\pi:S \times X \longrightarrow X$ is a separately continuous action of a semigroup $S$ on $X$. Historically, as was introduced by R.Ellis 1960, the enveloping semigroup, which is a closure of the set of continuous functions on a compact space $X$, was discovered to be an important tool to study dynamical systems. Soon, a realization of the existence of a universal compactification of a phase semigroup with an extended …

Investing In The Civic Economy: Social Capital And Choice Neighborhoods, Mary Ellen Brown

LSU Doctoral Dissertations

Concentrated poverty in inner-city neighborhoods in the United States generates social disorganization and isolation, limiting residents’ access to opportunities for upward mobility. Place-based concentration effects can be detrimental to individual health outcomes and overall community health. Communities require assets and resources across multiple types of capital, and in particular social capital, in order to foster a thriving civic economy. The purpose of this research was to provide a foundation through the study of social capital for pursuing strategic actions to foster a thriving civic economy for residents in a low-wealth neighborhood in Shreveport, Louisiana, that was also the focus of …

A Spatial Analysis Of Obesity And Its Associations With The Built And Natural Environment, Physical Inactivity, And Socioeconomic And Demographic Conditions In The United States Of America, Mustafa Erdem

LSU Doctoral Dissertations

Obesity has strong genetic determinants but the genetic composition of the population does not change rapidly. Thus in this study, the major changes in non-genetic factors such as the development of obesogenic environments and shifting socioeconomic status and lifestyle of individuals are hypothesized to increase the risk of obesity. As the prevalence of obesity continue to increase worldwide with substantial attention in the US, a clearer understanding of how spatial associations between obesity and confounding factors are interrelated is crucial to better tackle the issue of obesity. This study employs the ‘global’ and ‘local’ Exploratory Spatial Data Analysis (ESDA) methods …

Classification In The Presence Of Ordered Classes And Weighted Evaluative Attributes, Forrest Justin Osterman

LSU Doctoral Dissertations

We are interested in an important family of problems in the interface of the Multi-Attribute Decision-Making and Data Mining fields. This is a special case of the general classification problem, in which records describing entities of interest have been expressed in terms of a number of evaluative attributes. These attributes are associated with weights of importance, and both the data and the classes are ordinal. Our goal is to use historical records and the corresponding decisions to best estimate the class values of new data points in a way consistent with prior classification decisions, without knowledge of the weights of …

Surface Structure/Property Relationship For (001) Surface Of Magnetite, Fangyang Liu

LSU Doctoral Dissertations

Magnetite (Fe3O4), a well-known magnetic material, is still attracting intense study because of its great application in catalyst and technology development. These useful properties are related to the coexistence and coupling of several degrees of freedom, including charge, lattice, orbital and spin. The interaction between Fe3O4 and hydrogen is one of the most important issues, which guides the development of catalytic efficiency and material practicality. In this work, natural single crystal Fe3O4 (001) surfaces are studied with a variety of techniques. It is discovered that the Fe3O4 (001) surface structure and properties are dependent on the surface preparation methods. Conventional …

Visual Representations Of Gender In Engineering Trade Journals Of Professional Societies During 1998-2012: A Content Analysis Of Hierarchy And Stereotypes, Tracy Ettel Morris

LSU Doctoral Dissertations

Recruiting and retaining women in engineering have stagnated since the mid-1990's partially due to the marginalization of women in education and the workforce. This research analyzed the quality and quantity of representation of women and men in visual images of professional science and engineering trade journals to illuminate the marginalizing climate of engineering. A mixed methods approach using visual content analysis was performed for a 15-year period during 1998-2012 of three different trade journals of professional societies representing various disciplines of engineering: the first has a low percentage of women, the second has a higher percentage of women, and the …

Partial Cosine-Funk Transforms At Poles Of The Cosine-Λ Transform On Grassmann Manifolds, Christopher Adam Cross

LSU Doctoral Dissertations

The cosine-λ transform, denoted C^λ, is a family of integral transforms we can define on the sphere and on the Grassmannian manifolds of p-dimensional subspaces in Kⁿ where K is R, C or the skew field H of quaternions. We treat the Grassmannians as the symmetric spaces SO(n)/S(O(p) × O(q)), SU(n)/S(U(p) × U(q)) and Sp(n)/(Sp(p) × Sp(q)) and we work by analogy with the case of the cosine-λ transform on the sphere, which is also a symmetric space.

The family C^λ extends meromorphically in λ to the complex plane with poles at (among other values) λ …

Sourcing And Framing Analysis Of Source Messages In The Coverage Of Armed Conflicts By American And British Foreign Reporters, Ellada Gamreklidze

LSU Doctoral Dissertations

This dissertation contributes to closing several gaps in mass communication scholarship as well as indicates new avenues for further research in the area of sourcing and framing. This study explored whether reliance on official sources in foreign reporting of international crises is as heavy as the hypothesis predicts, and, by studying messages delivered by official sources in this coverage, revealed how those messages were framed. The results showed that officials were dominant sources of information in all the three media outlets studied. The results also supported the argument that the same indexing mechanisms are at force in foreign reporting and …

Effects Of Inbreeding On Endangered Red Wolves (Canis Rufus), Kristin E. Brzeski

LSU Doctoral Dissertations

Inbreeding depression, the reduction in offspring fitness caused by mating among close relatives, is widespread in small populations and a major concern in conservation biology because it can affect population persistence. The negative effects of inbreeding results in the evolution of inbreeding avoidance behaviors; within small populations, such behaviors may encourage individuals to select mates outside of their respective species. Mate choice may also be facilitated by variation at major histocompatibility complex (MHC) genes, a gene group critical for immune response and disease resistance. Given broad impacts of inbreeding and MHC variation on fitness and behavior, evaluating their effects is …