Digital Commons Network^™

Computational Studies On Bimetallic Catalysis And X-Ray Absorption Spectroscopy, Sayakkarage R. G. Fernando

LSU Doctoral Dissertations

Computational studies are very important to gain an insight into reaction mechanisms and in interpreting and understanding complicated experimental observations. This report contains a discussion on computational studies performed on bimetallic catalysis and on X-ray absorption spectroscopy of insulators. The viability of a bimetallic rhodium and cobalt catalysts for industrially important hydroformylation and aldehyde-water shift catalysis (AWS) is discussed. Density functional theory (DFT) studies were used for bimetallic catalysis and time-dependent DFT studies were used for excited state dynamics. These studies were performed using Gaussian 09 package and NWChem. Hydroformylation is experimentally performed in acetone and 30% water/acetone systems and …

Alexander Moyzes And His Piano Sonata In The Context Of Slovak Music Between The Wars, Ivan Koska

LSU Doctoral Dissertations

The purpose of this monograph is to introduce to the English-speaking public the Slovak twentieth-century composer Alexander Moyzes and his Piano Sonata in E Minor, Op. 2 (1942), virtually unknown outside Slovakia. The style of the Sonata represents a retreat from earlier, more experimental positions of its author; this shift can be explained by a closer look at historical and aesthetic circumstances surrounding its composition. The first chapter provides an essential biography of the composer with an emphasis on his life and works between 1925 and 1940. The second chapter compares single movements of the Sonata with earlier manuscripts and …

Boron Functionalization Of Bodipy Dyes, And Their Evaluation As Bioimaging Agents, Alex Long Nguyen

LSU Doctoral Dissertations

BODIPY, also known as “porphyrin’s little sister,” belongs to a class of fluorescent dyes. It contains a dipyrromethene π-system with a disubstituted boron atom. The basic 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) is known for its numerous useful applications in the fields of biology and materials. Modification of this well-known fluorophore has been shown to change its photophysical and chemical properties. There has been great interest in the modification at the boron center in recent years for synthesizing new dyads and cascade-type dyes. This work focuses on functionalization at the boron center with carbon and oxygen nucleophiles for further investigation as bioimaging agents. Chapter …

Mishpacha In The American Diaspora: An Exploratory Study Of Highly-Involved Jewish Families, Trevan Glen Hatch

LSU Doctoral Dissertations

Both family and religion are important to a large majority of the population in the United States. In the last few decades, research on religious families has significantly increased. Empirical research on Jewish families, however, is scant. The purpose of this study is to explore contemporary American Jewish family life in relation to Judaism, both cultural and religious. Specifically, the two primary objectives of this study are 1) to examine how Jewish culture and religion may influence and shape Jewish family life; and 2) to examine how family relationships may influence observance of Jewish cultural or religious traditions. This reciprocal …

Evaluation Of A Modified Monod Model For Predicting Algal Dynamics In Lake Tai, Jian Huang, Qiujin Xu, Xixi Wang, Beidou Xi, Keli Jia, Shouliang Huo, Hongliang Liu, Changyou Li, Bingbing Xu

Civil & Environmental Engineering Faculty Publications

Several modified versions of the Monod model have been proposed to simulate algal dynamics in lakes by keeping the parent model's advantages of simplicity and low data requirement. This study evaluated the performance of a widely-used modified Monod model in predicting algal dynamics at various time scales in Lake Tai, a typical shallow lake in east China, using multiple time series. Chlorophyll-a (Chl-a) concentration was used as a surrogate for algal (CyanoHABs: cyanobacterial harmful algal blooms) growth and the independent variables were total nitrogen (TN), total phosphorus (TP), and either water temperature or air temperature. The evaluation indicated that the …

Vapor Flow Resistance Of Dry Soil Layer To Soil Water Evaporation In Arid Environment: An Overview, Xixi Wang

Civil & Environmental Engineering Faculty Publications

Evaporation from bare sandy soils is the core component of the hydrologic cycle in arid environments, where vertical water movement dominates. Although extensive measurement and modeling studies have been conducted and reported in existing literature, the physics of dry soil and its function in evaporation is still a challenging topic with significant remaining issues. Thus, an overview of the previous findings will be very beneficial for identifying further research needs that aim to advance our understanding of the vapor flow resistance (VFR) effect on soil water evaporation as influenced by characteristics of the dry soil layer (DSL) and evaporation zone …

Spatio-Temporal Patterns Of Water Table And Vegetation Status Of A Deserted Area, Limin Duan, Tingxi Liu, Xixi Wang, Yanyun Luo

Civil & Environmental Engineering Faculty Publications

Understanding groundwater-vegetation interactions is crucial for sustaining fragile environments of desert areas such as the Horqin Sandy Land (HSL) in northern China. This study examined spatio-temporal variations in the water table and the associated vegetation status of a 9.71 km² area that contains meadowland, sandy dunes, and intermediate transitional zones. The depth of the water table and hydrometeorologic parameters were monitored and Landsat Thematic Mapper (TM) and Moderate Resolution Imaging Spectroradiometer (MODIS) data were utilized to assess the vegetation cover. Spatio-temporal variations over the six-year study period were examined and descriptive groundwater-vegetation associations developed by overlaying a water table …

Failure Modes For I-Section Gfrp Beams, Mamadou Konate, Zia Razzaq

Civil & Environmental Engineering Faculty Publications

This paper presents calculations for the failure modes for I-section Glass Fiber Reinforced Polymer (GFRP) beams with single mid-span web brace. Theoretical predictions are made using ASCE-LFRD Pre-Standard for FRP structures. For the member length considered, it is found that for small and medium I-sections the failure mode is governed by lateral-torsional buckling and for bigger I-sections the failure mode is governed by material rupture. The outcome of the predicted lateral-torsional buckling mode is compared with that observed experimentally.

Restricted Salt Diffusion In A Geosynthetic Clay Liner, Michael A. Malusis, Jong Beom Kang, Charles D. Shackelford

Faculty Journal Articles

No abstract provided.

Validating The Client Focused Considering Work Model For People Living With Hiv And Quantifying The Phases Of Change Of Commitment To Work, Liza M. Conyers, K B. Boomer

Faculty Journal Articles

The primary purpose of this study was to validate the client-focused considering work model and to gain a better understanding of the nature of the relationship among the four domains purported to influence the considering work process (medical, psychosocial, financial/legal and vocational). A second goal of the study was to quantify the relationship between these four domains and the phases of considering work (contemplation, preparation, action, resolution). Structural equation modeling was used to analyze data of 1702 diverse (43% Black, 31% White, 19% Latino 7% other) unemployed respondents who were recruited from AIDS Service Organizations (ASO) and networks across the …

I Can Dance: Further Investigations Of The Effect Of Dancing Ability On Mate Value, T. Joel Wade, Erin Weinstein, Nina Dalal, Kelsey J. Salerno

Faculty Journal Articles

The present research examined how being described as a dancer affects Black and White men and women’s assessed mate value in two studies. Study 1 examined evaluations of men by women and study 2 examined evaluations of women by men. Based on prior research examining how dancers are perceived and how body movements affect social perceiver’s evaluations of others, men and women described as dancers were expected to receive better ratings. Additionally, race of the individual being assessed was not expected to have any impact on mate value ratings. The results were consistent with the hypotheses. Men and women described …

How To Flirt Best: The Perceived Effectiveness Of Flirtation Techniques, T. Joel Wade

Faculty Journal Articles

Four studies were implemented in order to ascertain how men and women flirt with potential partners and which flirtatious actions are considered most effective. Study 1 (n = 40) and Study 2 (n = 60) sought to discover the actions that men and women, respectively, engage in to indicate romantic interest to a partner. Study 3 (n = 110) sought to determine which flirtatious acts from women are perceived as most effective by men. Women’s flirtations that suggest sexual access were expected to be rated as most effective. Study 4 (n = 222) sought to determine which flirtatious acts from …

No Evidence That Elevated Co2 Gives Tropical Lianas An Advantage Over Tropical Trees, David C. Marvin, Klaus Winter, Robyn J. Burnham, Stefan A. Schnitzer

Biological Sciences Faculty Research and Publications

Recent studies indicate that lianas are increasing in size and abundance relative to trees in neotropical forests. As a result, forest dynamics and carbon balance may be altered through liana‐induced suppression of tree growth and increases in tree mortality. Increasing atmospheric CO₂ is hypothesized to be responsible for the increase in neotropical lianas, yet no study has directly compared the relative response of tropical lianas and trees to elevated CO₂. We explicitly tested whether tropical lianas had a larger response to elevated CO₂ than co‐occurring tropical trees and whether seasonal drought alters the response of either …

Revenue Sharing And Within-Team Payroll Inequality In Major League Baseball, Nicholas A. Jolly

Economics Faculty Research and Publications

Using data from the 2000 to 2012 Major League Baseball seasons, this article investigates how changes to revenue sharing in the 2007 collective bargaining agreement altered within-team payroll inequality. Results indicate that inequality within teams decreased after the 2007 bargaining agreement. This reduced inequity is concentrated among those teams that were already experiencing relatively higher levels of inequality. This indicates that changes to revenue sharing should help increase competitive balance within the league. Additionally, the reduction in inequality occurs only among hitters and not pitchers. These results highlight how collective bargaining can have heterogeneous effects on groups of workers despite …

Curbing Corruption, Financial Development And Income Inequality, Sourav Batabyal, Abdur Chowdhury

Economics Faculty Research and Publications

In recent years, many of the Commonwealth countries have experienced a reduction in income inequalities due to the development of financial markets and intermediaries. At the same time, widespread corruption among public officials, civil servants, or politicians from these countries have been well documented. A key public policy question is whether the return to financial sector development at the level of massive corruption, exacerbate income inequality, offsetting the benefits of financial development. Using a panel data of 30 Commonwealth countries over the period of 1995–2008, it is found that the high rates of corruption in the Commonwealth countries are crowding …

Trade Liberalization And Trade Performance Of Environmental Goods: Evidence From Asia-Pacific Economic Cooperation Members, Qi He, Hong Fang, Miao Wang, Bo Peng

Economics Faculty Research and Publications

In this article, we study the impact of trade liberalization, including reductions in both tariff and nontariff trade barriers, on environmental goods (EGs) exports. Using bilateral trade data from 20 Asia-Pacific Economic Cooperation members, we find that tariff reduction in an exporting country has a larger positive impact on its exports of EGs than tariff reduction in an importing country. Our results also show that a lower nontariff barrier in an importing country increases its imports of EGs. A considerable amount of heterogeneity also exists in subsample results based on countries’ income levels.

Agency And The Process Aspect Of Capability Development: Individual Capabilities, Collective Capabilities, And Collective Intentions, John B. Davis

Economics Faculty Research and Publications

This paper addresses the process aspect of capability development in connection with the debate in the capability approach over the relationship between individual and collective capabilities by combining Sen’s ‘privateness’ interpretation of different aspects of the self and Granovetter’s social embeddedness framework. It interprets Sen’s commitment aspect of the self in collective intentionality terms, uses this to explain his view of ‘identification with’ social groups, and then uses social identity theory’s distinction between relational and categorical social group identities to explain a general relationship between individual and collective capabilities. The paper applies this analysis to three broad domains of social …

The Impact Of Output And Exchange Rate Volatility On Fixed Private Investment: Evidence From Selected G7 Countries, Abdur Chowdhury, Mark Wheeler

Economics Faculty Research and Publications

This study examines the impact of shocks to exchange rate and output uncertainty (volatility) on real private fixed investment (FI) in Canada, Germany, the United Kingdom and the United States. The analysis is conducted using vector autoregressive models that contain the price level, real output, the volatility of real output, the real exchange rate, the volatility of the real exchange rate, an interest rate and FI. The results yield important public policy implications with regard to the impact of output volatility of FI. Our analysis indicates that volatility shocks, measured as output volatility or exchange rate volatility, do not have …

Theorizing The Social Provisioning Process Under Capitalism: Developing A Veblenian Theory Of Care For The Twenty-First Century, Andrew Cumbers, John B. Davis, Robert Mcmaster

Economics Faculty Research and Publications

Thorstein Veblen highlighted a number of human instincts, one of which was the “parental bent.” In contrast to the other “positive” instincts, the parental bent is specifically other-regarding in that Veblen described it in terms of utilizing knowledge for the betterment of society. Veblen’s “parental bent” stresses the social embeddedness of humanity and the human instinct to care. Our ability to care is partially predicated on our social roles and the values embedded within those roles. Critically, this is influenced by the configuration of institutions within a society. Care is grossly under-valued. By drawing upon recent contributions to care in …

Factoring Emerging Markets Into The Relationship Between Global Liquidity And Commodities, Steven Landgraf, Abdur Chowdhury

Economics Faculty Research and Publications

Purpose – What caused the mid-2000s world commodity price “bubble” and the recent commodity price growth? Some have suggested that rapid global industrial growth over the past decade is the key driver of price growth. Others have argued that high commodity prices are a result of excessively loose monetary policy. The purpose of this paper is to extend the current research in this area by incorporating emerging economies, the BRIC (Brazil, Russia, India, and China) nations specifically, into global measures.

Design/methodology/approach – The paper uses a vector error correction (VEC) model and computes variance decomposition and impulse response functions (IRFs). …

Judging Statutes, Peter L. Strauss

Faculty Scholarship

Chief Judge Robert Katzmann has written a compelling short book about statutory interpretation. It could set the framework for a two- or three-hour legislation class, supplemented by cases and other readings of the instructor's choosing. Or it might more simply be used as an independent reading assignment as law school begins, to apprise 21st-century law students just how important the interpretation of statutes will prove to be in the profession they are entering, and how unsettled are the judiciary's means of dealing with them. It should be required reading for all who teach in the field.

The Constitutional Duty To Supervise, Gillian E. Metzger

Faculty Scholarship

The IRS targets Tea Party organizations' applications for nonprofit tax-exempt status for special scrutiny. Newly opened online federal health exchanges fail to function. Officials at some Veterans Administration hospitals engage in widespread falsification of wait times. A key theme linking these examples is that they all involve managerial and supervisory failure. This should come as no surprise. Supervision and other systemic features of government administration have long been fundamental in shaping how an agency operates, and their importance is only more acute today. New approaches to program implementation and regulation mean that a broader array of actors is wielding broader …

Evidence For Respiratory Neuromodulator Interdependence After Cholinergic Disruption In The Ventral Respiratory Column, Clarissa Muere, Suzanne Neumueller, Justin Robert Miller, Samantha Olesiak, Matthew Hodges, Lawrence Pan, Hubert Forster

Physical Therapy Faculty Research and Publications

Reverse dialysis of the muscarinic receptor antagonist, atropine (ATR, 50 mM), into the pre-Bötzinger Complex region of the ventral respiratory column (VRC) of awake and sleeping goats increases breathing frequency and serotonin (5-HT), substance P (SP), glycine, and GABA concentrations in the effluent dialysate. Herein, we report data from goats in which we reverse dialyzed 5 mM ATR or specific antagonists of M2 or M3 muscarinic receptors into the VRC. The effects on frequency of all three antagonists were not significantly different from time control studies. 5 mM ATR and the M3 antagonist increased SP sevenfold less than 50 mM …

Modeling, Dynamics And Control Of Spacecraft Relative Motion In A Perturbed Keplerian Orbit, Mohamed Okasha, Brett Newman

Mechanical & Aerospace Engineering Faculty Publications

The dynamics of relative motion in a perturbed orbital environment are exploited based on Gauss' and Cowell's variational equations. The inertial coordinate frame and relative coordinate frame (Hill frame) are used, and a linear high fidelity model is developed to describe the relative motion. This model takes into account the primary gravitational and atmospheric drag perturbations. Then, this model is used in the design of a navigation, guidance, and control system of a chaser vehicle to approach towards and to depart from a target vehicle in proximity operations. Relative navigation uses an extended Kalman filter based on this relative model …

Nanomechanical And Morphological Characterization Of Tungsten Trioxide (Wo3) Thin Films Grown By Atomic Layer Deposition, M. A. Mamun, K. Zhang, H. Baumgart, A. A. Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

This study investigates the nanomechanical properties and surface morphology of tungsten oxide WO₃thin films deposited on p-type Si(100) substrates using atomic layer deposition (ALD) technology with 2000 ALD deposition cycles at a growth temperature of 300°C and annealed at different temperatures. The samples were further furnace annealed at 500, 600 and 700°C for 60 min. The influence of the deposition process on the structure and properties of the WO₃ films is discussed, presented and correlated to the characteristic features of the ALD technique. The results depict significant difference in the hardness and modulus measurements between the as …

Numerical Geometry Of Map And Model Assessment, Willy Wriggers, Jing He

Mechanical & Aerospace Engineering Faculty Publications

We are describing best practices and assessment strategies for the atomic interpretation of cryo-electron microscopy (cryo-EM) maps. Multiscale numerical geometry strategies in the Situs package and in secondary structure detection software are currently evolving due to the recent increases in cryo-EM resolution. Criteria that aim to predict the accuracy of fitted atomic models at low (worse than 8 angstrom) and medium (4-8 angstrom) resolutions remain challenging. However, a high level of confidence in atomic models can be achieved by combining such criteria. The observed errors are due to map-model discrepancies and due to the effect of imperfect global docking strategies. …

Endgame For Polio Eradication? Options For Overcoming Social And Political Factors In The Progress To Eradicating Polio., Pavan Ganapathiraju, Christiaan B Morssink, James D. Plumb

College of Population Health Faculty Papers

In 1988, the Global Polio Eradication Initiative (GPEI) was launched with the goal of eradicating polio by the year 2000. After 25 years, several dynamics still challenge this large public health campaign with new cases of polio being reported annually. We examine the roots of this initiative to eradicate polio, its scope, the successes and setbacks during the last 25 years and reflect on the current state of affairs. We examine the social and political factors that are barriers to polio eradication. Options are discussed for solving the current impasse of polio eradication: using force, respecting individual freedoms and gaining …

Coordination And Sustainability Of River Observing Activities In The Arctic, James W. Mcclelland, Suzanne E. Tank, Robert G. M. Spencer, Alexander I. Shiklomanov

Faculty Publications

To understand and respond to changes in the world’s northern regions, we need a coordinated system of long-term Arctic observations. River networks naturally integrate across landscapes and link the terrestrial and ocean domains. Changes in river discharge reflect changes in the terrestrial water balance, whereas changes in water chemistry are linked to changes in biogeochemical processes and water flow paths. Sustained measurements of river water discharge and water chemistry are therefore essential components of an Arctic observing network. As we strive to establish and sustain long-term observations in the Arctic, these two measurements must be coupled. Although river discharge and …

Causes And Consequences Of Ecosystem Service Regionalization In A Coastal Suburban Watershed, Wilfred M. Wollheim, M. B. Green, B. A. Pellerin, Nathaniel B. Morse, Charles S. Hopkinson

Faculty Publications

The demand for ecosystem services and the ability of natural ecosystems to provide those services evolve over time as population, land use, and management practices change. Regionalization of ecosystem service activity, or the expansion of the area providing ecosystem services to a population, is a common response in densely populated coastal regions, with important consequences for watershed water and nitrogen (N) fluxes to the coastal zone. We link biophysical and historical information to explore the causes and consequences of change in ecosystem service activity—focusing on water provisioning and N regulation—from 1850 to 2010 in a coastal suburban watershed, the Ipswich …

Enriching Christian Hospitality At Malaby's Crossroads Missionary Baptist Church In Knightdale, North Carolina, Barbara Starr Barner

Doctor of Ministry Projects

Hospitality is the welcoming of strangers, family, and friends. In the early biblical and historical traditions, hospitality focused on welcoming the alien and extending resources to them. Hospitality, however, need not be limited to the basic physical needs of the stranger, but spiritual needs are to be addressed as well. In the reflection of Jesus’ work on the cross, Christian hospitality should be the intentional, responsible, and caring act of welcoming or visiting strangers, enemies, the distressed, downtrodden, without regard for reciprocation. The goal of this project was to enhance Malaby’s Christian hospitality culture and take our personal interactions to …