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Theoretical Studies Of Co Based Catalysts On Co Hydrogenation And Oxidation, Nianthrini Balakrishnan

USF Tampa Graduate Theses and Dissertations

CO hydrogenation and CO oxidation are two important processes addressing the energy and environmental issues of great interest. Both processes are carried out using metallic catalysts. The objective of this dissertation is to study the catalytic processes that govern these two reactions from a molecular perspective using quantum mechanical calculations. Density Functional Theory (DFT) has proven to be a valuable tool to study adsorption, dissociation, chain growth, reaction pathways etc., on well-defined surfaces. DFT was used to study the CO reduction reactions on promoted cobalt catalyst surfaces and CO oxidation mechanisms on cobalt surfaces.

CO hydrogenation via Fischer-Tropsch Synthesis (FTS) …

Evaluation Of A Pilot Land-Based Marine Integrated Aquaculture System, Suzanne Boxman

USF Tampa Graduate Theses and Dissertations

Recirculating aquaculture systems (RAS) produce aquaculture products on land with minimal discharge of waste products and minimal water loss. High costs associated with waste treatment for RAS have triggered the growth of integrated aquaculture systems (IAS) which incorporate macrophytes (aquatic plants) into the treatment train. The objective of this research was to examine a pilot scale inland marine IAS with three different methods for solids treatment: a sand filter followed by a plant bed, only a plant bed, and geotextile bags. Florida Pompano (Trachinotus carolinus) were grown along with Smooth Cordgrass (Spartina alterniflora), Black Needle Rush …

Factors Predicting Pap Smear Adherence In Hiv-Infected Women: Using The Health Belief Model, Crystal L. Chapman Lambert

USF Tampa Graduate Theses and Dissertations

Women infected with the human immunodeficiency virus are at increased risk for developing cervical cancer. Current guidelines reflect that Pap smears should be performed twice during the first year after diagnosis with HIV and annually thereafter. However, women with HIV are not obtaining Pap smears per the current guidelines. The purpose of this study was to evaluate HIV-infected women's attitudes toward cervical cancer and cervical cancer screening. The research design is an exploratory, cross-sectional, quantitative design. The sample of convenience consisted of participants recruited from two ambulatory HIV clinics in Florida. Attitudes were assessed using Champion's Health Belief Model and …

Geometric Optimization Of Retroreflective Raised Pavement Markers, Lukai Guo

USF Tampa Graduate Theses and Dissertations

As the field service life of retroreflective raised pavement marker (RRPM) is much shorter than expected, it is necessary to identify the causes and thus improve the RRPM structural design to mitigate the main failure modes, such as poor retention from pavements, structural damage, and loss of retroreflectivity. One strategy for extending RRPM service life is to enhance RRPM geometric characteristics to decrease critical stresses in markers. The main purpose of this thesis is to analyze the relationship between stresses, failure modes, and RRPM profiles. Based on this research, some measures are suggested in order to avoid corresponding failure modes …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

Refinement, Application, And Evaluation Of Cognitive And Affective Chemistry Measures For College Students, Keily Heredia

USF Tampa Graduate Theses and Dissertations

This work describes three case studies conducted to address two major problems in the area of chemistry education research, the lack of reported psychometrics regarding instrument scores, and the need for well-characterized assessments to evaluate college chemistry curricula.

The first case study describes a psychometric evaluation of the Colorado Learning Attitudes about Science Survey (CLASS), an instrument designed to assess student beliefs about the learning of chemistry. Results from this work suggest that the CLASS instrument provides fertile ground for short instruments with reasonable psychometric properties. Responses to a single scale instrument, created from CLASS, showed that students in an …

Investigation Of Hsf1 Interacting Partners Via A Genome-Wide Yeast Two-Hybrid Screen, Jamie Elizabeth Mendez

USF Tampa Graduate Theses and Dissertations

Heat shock factor 1 (HSF1) is the master transcriptional regulator of the heat shock response (HSR), an evolutionarily conserved cellular stress response. HSF1 promotes the expression of a variety of molecular chaperones that aid in restoring protein homeostasis upon exposure to proteoxic stress. However, all of the proteins responsible for regulating the HSR together with HSF1 are unknown. A genome-wide yeast two hybrid screen was performed to identify new S. cerevisiae Hsf1 protein interacting partners. Two GAL4 DNA binding domain-Hsf1 fusion proteins (baits) were constructed with mutations in the Hsf1 C-terminal activation domain to dampen Hsf1 mediated auto-activation of the …

A Webquest For The Instruction Of Appropriate Online Behavior, Susan Heilig

Graduate Research Papers

The requirements of the Children's Internet Protection Act (CIPA) and the expectations of the Iowa Department of Education's (2012) Iowa Core Curriculum 21st Century Skills increase the importance of having an organized collection of resources to teach Internet safety. These requirements and the literature reviewed confirmed the importance of preparing students to use the Internet safely and ethically and be productive digital citizens. While the teachers in the Calamus-Wheatland School District were already instructing students in appropriate online behavior, there wasn't an organized Internet Safety resource that could be used effectively within the time limits of the scheduled computer classes. …

Development Of Improved Models For Gas Sorption Simulation, Keith Mclaughlin

USF Tampa Graduate Theses and Dissertations

Computational chemistry offers one the ability to develop a better understanding of the complex physical and chemical interactions that are fundamental to macro- and mesoscopic processes that are seen in laboratory experiments, industrial processes, and ordinary, everyday life. For many systems, the physics of interest occur at the molecular or atomistic levels, and in these cases, computational modeling and two well refined simulation techniques become invaluable: Monte Carlo (MC) and molecular dynamics (MD). In this work, two well established problems were tackled. First, models and potentials for various gas molecules were produced and refined from first principles. These models, although …

Investigation Of Mercury Use, Release, Deposition, And Exposures In The Tampa Bay Area, Ryan Algernon Michael

USF Tampa Graduate Theses and Dissertations

I investigate the links between mercury use, release, deposition, and population exposure in Tampa Bay, with the focus of identifying levers for reducing population mercury exposures. To achieve this, I investigated the trends in mercury use and release by products and processes in the Tampa Bay area using a Material Flow Analysis. Analysis of USEPA National Emissions Inventory data over time (1999 - 2008) identified relevant air source emission categories, and explored and compared state and regional trends in mercury emissions. To understand source contributions to wet deposited mercury in the Tampa Bay area, I analyzed trends in mercury deposition …

Dead Man's Switch: Disaster Rhetorics In A Posthuman Age, Daniel Patrick Richards

USF Tampa Graduate Theses and Dissertations

When a disaster the magnitude of the Deepwater Horizon blowout and oil spill takes place, is it natural for the news media stories, investigative reports, and public deliberation to focus almost exclusively on finding the person or group responsible for such a horrendous scene. Rhetorically speaking, the discourse surrounding the event can be characterized as a reductive form of praise and blame rhetoric (epideixis). However, these efforts, while well-intentioned, are troublesome because searches for the one technical cause and the sole personal culpability are thwarted by the sheer complexity of the ecological, technological, scientific, institutional, and communicative network required for …

The Extent Of Phosporus Redox Chemistry In West Central Florida Waters, Jacqueline Marie Sampson

USF Tampa Graduate Theses and Dissertations

Phosphorus (P) has long been acknowledged as a vital nutrient for living organisms and is a key factor responsible for the fresh water eutrophication. Our understanding of the phosphorus cycle has been limited by: (1) the common assumption that all P in the environment occurs primarily as phosphates and (2) by the limited analytical methods available to identify P speciation. In an attempt to understand the distribution and chemistry of phosphorus within a freshwater system we must be able to identify individual P species. To this end, we used a coupled High Performance Liquid Chromatograph (HPLC) - Inductively Coupled Plasma …

Associational Resistance And Competition In The Asphondylia - Borrichia - Iva System, Keith Stokes

USF Tampa Graduate Theses and Dissertations

Indirect ecological effects such as associational resistance and resource competition have the potential to affect ecological interactions and influence the structure of ecological communities. Although resource competition is commonly studied, the effects of associational resistance are not as evident if studies are not designed to detect them. Additionally, the relative strengths of different ecological mechanisms ought to be measured in studies, rather than the strength of singular mechanisms. This permits proper attribution of causes and effects in community structure and detection of higher order interactions in a way that naïve reductionism will not.

In a series of experiments, I looked …

Examination Of The Relationship Of Community College Opticianry Student Outcomes With Instructional Delivery Method And Student Age, William Brent Underwood

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to determine whether student outcomes are a function of participation in different modes of delivery in an Opticianry program at the community college level. First, the intent was to determine whether differences in instructional delivery methods and background characteristics impact student performance in an Opticianry program. The three instructional delivery methods were traditional face-to-face instruction, online delivery, and a hybrid format where students take theory courses online and attend face-to-face laboratories on campus. A second objective was to determine the role of background variables such as student age, which was the age when entering …

Nonlinear Techniques For Stochastic Systems Of Differential Equations, Tadesse G. Zerihun

USF Tampa Graduate Theses and Dissertations

Two of the most well-known nonlinear methods for investigating nonlinear dynamic processes in sciences and engineering are nonlinear variation of constants parameters and comparison method. Knowing the existence of solution process, these methods provide a very powerful tools for investigating variety of problems, for example, qualitative and quantitative properties of solutions, finding error estimates between solution processes of stochastic system and the corresponding nominal system, and inputs for the designing engineering and industrial problems. The aim of this work is to systematically develop mathematical tools to undertake the mathematical frame-work to investigate a complex nonlinear nonstationary stochastic systems of differential …

Real Or Personal?: The Area Of Mutual Interest Covenant In The Williston Basin After Golden V. Sm Energy Company, Andrew Scott Graham

North Dakota Law Review

No abstract provided.

A Window Of Opportunity: Assessing Behavioural Scoring, Kenneth Kennedy, Brian Mac Namee, Sarah Jane Delany, Michael O'Sullivan, Neil Watson

Articles

After credit has been granted, lenders use behavioural scoring to assess the likelihood of default occurring during some specific outcome period. This assessment is based on customers’ repayment performance over a given fixed period. Often the outcome period and fixed performance period are arbitrarily selected, causing instability in making predictions. Behavioural scoring has failed to receive the same attention from researchers as application scoring. The bias for application scoring research can be attributed, in part, to the large volume of data required for behavioural scoring studies. Furthermore, the commercial sensitivities associated with such a large pool of customer data often …

A Matlab Primer In Four Hours With Practical Examples, Jerome Casey

Instructional Guides

No abstract provided.

The Integration Of Sustainable Development Competencies In Irish Engineering Education: Findings Of A Curriculum Content Investigation Of Four Engineering Programmes, Iacovos Nicolaou, Eddie Conlon

Conference papers

This paper presents the initial findings of an investigation of the Sustainable Development (SD) content in five professional engineering degree programmes in a large Irish Institute of Technology.

A comprehensive investigation of the modules content was conducted to see to what extent the learning outcomes for SD as set out in the Barcelona Declaration and SD competencies were covered by the modules. It was found that 40% of the 137 modules included SD learning outcomes and/or addressed SD competencies. The modules have a focus on environmental issues and tend to address only one of the three dimensions, environmental, social and …

Vibrational Spectroscopy In Sensing Radiobiological Effects: Analyses Of Targeted And Non-Targeted Effects In Human Keratinocytes, Aidan Meade, Orla L. Howe, Valerie Unterreiner, Ganesh Sockalingum, Hugh Byrne, Fiona Lyng

Articles

Modern models of radiobiological effects include mechanisms of damage initiation, sensing and repair, for those cells that directly absorb ionizing radiation as well as those that experience molecular signals from directly irradiated cells. In the former case, the effects are termed targeted effects while, in the latter, non-targeted effects. It has emerged that phenomena occur at low doses below 1Gy in directly irradiated cells which are associated with cell-cycle dependent mechanisms of DNA damage sensing and repair. Likewise in non-targeted bystander irradiated cells the effect saturates at 0.5Gy. Both effects at these doses challenge the limits of detection of vibrational …

Seaweed-Based Functional Foods, Nissreen Abu-Ghannam, Sabrina Cox

Books/Book Chapters/ Proceedings

Functional foods are foods that provide health benefits in addition to basic nutrition. They are categorized through identification, characterization, and evaluation of the health-promoting properties they present. New high-value nutrition and wellness products, manufactured by reformulation of existing products through development of nutraceutical or functional foods, present an exciting opportunity for the food industry worldwide. Many bioactive constituents to which a beneficial physiological function has been directly or indirectly attributed, originating mainly from plant extracts, have been incorporated in already existing food products or have been commercialized in the form of pharmaceutical products such as pills, capsules, solutions, and gels …

Improving Performance By Re-Rating In The Dynamic Estimation Of Rater Reliability, Alexey Tarasov, Sarah Jane Delany, Brian Macnamee

Conference papers

Nowadays crowdsourcing is widely used in supervised machine learning to facilitate the collection of ratings for unlabelled training sets. In order to get good quality results it is worth rejecting results from noisy/unreliable raters, as soon as they are discovered. Many techniques for filtering unreliable raters rely on the presentation of training instances to the raters identified as most accurate to date. Early in the process, the true rater reliabilities are not known and unreliable raters may be used as a result. This paper explores improving the quality of ratings for train- ing instances by performing re-rating. The re-rating relies …

A Brief Motivational Intervention For Heavy Alcohol Use In Dental Practice Settings: Rationale And Development, James A. Neff, Scott T. Walters, Abby L. Braitman, Michelle L. Kelley, Michele L. Darby, Margaret F. Lemaster

Psychology Faculty Publications

Although brief alcohol interventions have proven effective in a variety of health care settings, the present article describes the development of the first brief intervention for heavy drinkers in dental practice. Elements of motivational interviewing and personalized normative feedback were incorporated in a 3- to 5-minute intervention delivered by dental hygienists. The intervention is guided by a one-page feedback report providing personalized normative feedback regarding the patient's current oral health practices, their drinking in comparison to others, and oral cancer risk associated with current smoking and drinking. Future publications will present data regarding intervention effectiveness from an ongoing randomized trial.

A Next, Big Step For The West: Using Model Legislation To Create A Water-Climate Element In Local Comprehensive Plans, Michelle Bryan

Faculty Law Review Articles

The West is witnessing early, important efforts to join water supply and land use planning, and the reality of climate change makes this convergence all the more critical. Local comprehensive planning presents itself as an existing and indispensable tool for unifying important planning efforts in the areas of land use, water, and climate change. As the primary regulators of land use, local governments are at the front line of regulating a myriad of environmental concerns. They are also integral partners in planning and implementing water-related initiatives alongside tribal, state, federal, and private partners. The West’s potential for broad-based action is …

Fractured Fairytales: The Failed Social License For Unconventional Oil And Gas Development, Evan J. House

Wyoming Law Review

No abstract provided.

Higher Education, Citizens Engagement And Economic Development Work At The Grassroots: A Case Study Of Dayton, Southwest Ohio, Olatokunbo A. Awoshakin

Antioch University Dissertations & Theses

This qualitative case study focused on the efforts of the Southwestern Ohio Council for Higher Education (SOCHE) to work with citizens and use existing community assets along with Dr. Richard Florida's 4T model to spur economic growth in the area of Dayton, Ohio. This study provides a unique opportunity to closely examine how innovative approaches and nontraditional alliances might fare in the face of a declining economic growth with a view toward creating an environment that can support sustainable economic development. Multiple interview data, archival documents, and participatory observation were utilized during the study. Analysis of transcripts from structured interviews …

The Sisters' Experience Of Having A Sibling With An Autism Spectrum Disorder, Melissa L. Mcvicker

Antioch University Dissertations & Theses

This dissertation consists of two articles. This first article is a literature review identifying studies of autism spectrum disorders and sibling relationships published in the past 10 years. This search strategy identified 16 articles for inclusion in this review and conveyed the following main outcomes: a) parental factors influence sibling relationship and typically developing child, b) behavioral interactions/problems affect the quality of the sibling relationship, c) genetic factors have varying impact on diagnosis, and d) effects/outcomes for typically developing sibling are both positive and negative. This review supported the call for a better understanding of the family factors on the …

What Are The Key Competencies, Qualities, And Attributes Of The African American Municipal Police Chief?, Patrick Oliver

Antioch University Dissertations & Theses

The purpose of this dissertation was to identify and understand the dimensions of leadership of those African Americans, who are effective as the chief executive officer (CEO) of a municipal law enforcement agency, and thereby to educate and inform both those aspiring to be police chiefs and those presently serving as police chiefs, particularly African Americans. Four content areas were examined to gain a better understanding of the research question: (1) Police executive leadership literature; (2) African American leadership; (3) The trait theory of leadership; (4) emotional intelligence. Study participants were all African American police chiefs with the expertise and …

Applying A Leadership Framework To Historically Black Colleges And Universities (Hbcus) Post Fordice, Armenta Hinton

Antioch University Dissertations & Theses

Historically Black Colleges and Universities (HBCUs) have a list of outstanding accomplishments that span over a century; however, this segment of higher education continues to be underfunded and remains in a position of justifying its existence in a postracial America. The issues facing HBCUs are significant. Race-based legislation has created a dual system of American higher education that adversely affects these minority serving institutions, impacting the quality of education they dispense and producing potentially negative effects on vulnerable and under-served collegians. Supreme Court Justice Thomas’s opinion in the U.S. v. Fordice (1992) case opposed the creation of HBCUs as “enclaves …

The Role Of Agency In Community Health Outcomes: Local Health Departments And Childhood Immunization Coverage Rates, James Anthony Ransom

Antioch University Dissertations & Theses

Organizational culture is defined as a system of shared meaning held by members of an organization that distinguishes it from other organizations. How organizational culture is experienced in the public sector, particularly local health departments (LHDs), is not well understood. The purpose of this study was to determine whether LHD organizational culture impacts childhood immunization coverage rates. I used a modified organizational culture survey tool, the Organizational Management Survey, to quantify organizational culture and determine whether an LHD's organizational culture helps explain variations in childhood immunization coverage rates. In addition, qualitative data from an earlier study of LHD immunization staff …