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Multi-Proxy Evidences Of Mid-Pleistocene Dry Climates Observed On Calcretes In Central Turkey, Ceren Küçükuysal, Asuman Günal Türkmenoğlu, Seli̇m Kapur

Turkish Journal of Earth Sciences

Palaeosols are very important in reconstructing palaeoclimate studies, since they are accepted as useful climate markers and as potential providers of proxy data. The study of the palaeosols of the Plio-Pleistocene rock sequences around Ankara revealed evidence for a reconstruction of the Quaternary palaeoclimate of the region. The study area is located in Bala, south-east of Ankara, which contains Middle Pleistocene red palaeosols with powdery to nodular calcrete developments, alternating with channel deposits. During this warm and arid period in the Pleistocene, the limited water available in the soil led to the accumulation of low magnesian carbonates, forming calcretes. The …

Stable Isotope-Based Reconstruction Of Oligo-Miocene Paleoenvironment And Paleohydrology Of Central Anatolian Lake Basins (Turkey), Tina Lüdecke, Tamás Mikes, Fuat Bora Rojay, Michael A. Cosca, Andreas Mulch

Turkish Journal of Earth Sciences

Isotope geochemistry of lacustrine carbonate represents a powerful tool to reconstruct paleoclimatic and paleoenvironmental conditions. Here, we present a comprehensive set of long-term oxygen (delta^{18}O) and carbon (delta^{13}C) stable isotope records from 5 Chattian to Burdigalian lacustrine sequences distributed over the Central Anatolian Plateau. Field relationships combined with stable isotope geochemistry indicate a relatively humid subtropic Late Oligocene climate with an environment characterized by large, temporally open freshwater lakes. Approximately during the middle Aquitanian, a 4%o-5%o increase in lake delta^{18}O values indicates changes in regional climate including more arid conditions and an increasing dominance of closed saline lake conditions in …

Circum-Tethyan Carbonate Platform Evolution During The Palaeogene: The Prebetic Platform As A Test For Climatically Controlled Facies Shifts, Stefan Höntzsch, Christian Scheibner, Johannes P. Brock, Jochen Kuss

Turkish Journal of Earth Sciences

The distribution of selected shallow-benthic biota at circum-Tethyan carbonate platforms demonstrates an excellent proxy for the impact of latitudinally controlled cooling and variations in the trophic resources during the Palaeogene. In this study, we link and compare the spatial distribution and abundance of larger benthic foraminifera and hermatypic corals of Tethyan carbonate successions with new records from the Prebetic platform in SE Spain. The succession of the Prebetic platform is dominated by larger benthic foraminifera and coralline red algae throughout the Eocene, whereas corals were not recorded until the Late Eocene. Similar biotic trends were reported from 10 selected circum-Tethyan …

Impact Of Pb-Zn Mining Activity On Surficial Sediments Of Lake Kalimanci(Fyr Macedonia), Petra Vrhovnik, Nastja Rogan Smuc, Tadej Dolenec, Todor Serafimovski, Matej Dolenec

Turkish Journal of Earth Sciences

The activities of the Sasa mine have led to industrial discharge being released into Lake Kalimanci since the beginning of mining activity in 1954. For this reason, an ecological risk assessment is urgently required. In the present study, surficial lake sediments were analyzed using inductively coupled plasma mass spectrometry (ICP-MS), with all geochemistry data processed using Statistica 8. In order to assess the environmental pollution status, 2 environmental factors were established, while for the determination of chemical fractionation of toxic metals a sequential extraction procedure was carried out. Concentrations of As, Mo, Zn, Ni, Co, Pb, Cd, and Cu in …

Computation Of Grade Values Of Sediment-Hosted Barite Deposits In Northeastern Isparta (Western Turkey), Numan Elmas, Uğur Şahi̇n

Turkish Journal of Earth Sciences

Grade value is a crucial parameter for the mineral industry. Investigation of grade value of mineral resources provides the optimum benefit. In this study, an adaptive neuro-fuzzy inference system (ANFIS) and artificial neural network (ANN) model were applied for the prediction of grade values. The spatial coordinates X, Y, and Z of the study area along with bore hole geochemical data were used as input variables in the model. In order to illustrate the applicability and capability of these methods, the western part of Turkey, between the latitudes 38°01 45 N and 38°09 52 N and between the longitudes 31°23 …

Antimicrobial Activity And Chemical Composition Of The Essential Oils Of Mosses (Hylocomium Splendens (Hedw.) Schimp. And Leucodon Sciuroides (Hedw.) Schwägr.) Growing In Turkey, Tayyi̇be Beyza Cansu, Büşra Yayli, Turan Özdemi̇r, Nevzat Batan, Şengül Alpay Karaoğlu, Nuretti̇n Yayli

Turkish Journal of Chemistry

In the present work, the volatiles of mosses [Hylocomium splendens (Hedw.) Schimp. (Hylocomiaceae) and Leucodon sciuroides (Hedw.) Schwägr. (Leucodontaceae)] have been investigated by GC-FID and GC/MS. Fifty-eight compounds in the oil of H. splendens, representing 75.4%, and 41 compounds in the oil of L. sciuroides, representing 87.6%, were identified. The major components were found to be \beta-pinene (11.6%) and \alpha-pinene (8.9%) in the oil of H. splendens, and nonanal (26.8%) and heptanal (13.7%) in the oil of L. sciuroides. The essential oil of H. splendens was rich in monoterpenes (30.8%), and aldehydes (49.9%) were the major constituents in the oil …

Synthesis And Characterization Of New Chromogenic Substrates For Exoglycosidases: \Alpha-Glucosidase, \Alpha-Mannosidase, And \Beta-Galactosidase, Dumitru Petru Iga, Richard Schmidt, Silvia Iga, Corina Loredana Hotoleanu, Florentina Duica, Alina Nicolescu, Silvia Stefania Gitman

Turkish Journal of Chemistry

Glycosides of 4-nitrocatechol (1,2-dihydroxy 4-nitrobenzene) with \alpha-D-glucopyranose and \alpha-D-mannopyranose were synthesized by the glycosylation of phenol with peracetylated sugars in the presence of BF_3\cdot OBu_2. The glycoside of 4-nitrocatechol with \beta-D-galactopyranose was prepared by the glycosylation of this phenol as sodium phenoxide with tetra-O-benzoyl-\alpha-D- galactopyranosyl bromide. The structure of the reaction products was confirmed by ^1 H and ^{13}C NMR spectra and by chemical analysis. The latter consisted of acidic hydrolysis, followed by ethyl ether extraction and colorimetric determination of 4-nitrocatechol in the ether phase and application of the anthrone method for the sugar in the water phase. The synthetic …

Anticholinesterase Furocoumarins From Heracleum Platytaenium, A Species Endemic To The Ida Mountains, Demet Di̇ncel, Seda Damla Hatipoğlu, Ahmet Ceyhan Gören, Gülaçti Topçu

Turkish Journal of Chemistry

The petroleum ether extract of Heracleum platytaenium afforded 8 furocoumarins (psoralen, bergapten, xanthotoxin, pimpinellin, isopimpinellin, sphondin, byakangelicin, and heraclenol) and the methanol extract of H. platytaenium gave only 1 glycosylated dihydrofurocoumarin, apterin. In addition, stigmasterol was also obtained from petroleum ether extract. Structure identification of the isolated compounds has been achieved by using spectroscopic methods, namely 1D and 2D NMR experiments and mass spectral analyses. The antioxidant activity of the extracts and pure compounds was investigated by 2 methods, including DPPH free radical scavenging activity and lipid peroxidation inhibitory activity by \beta-carotene-linoleic acid assays. The anticholinesterase activity of petroleum ether …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Optimization Of Synthesizing Glucose 1-Phosphate By Sodium Tripolyphosphate As A Phosphorus Acylating Agent Using Response Surface Methodology, Li 'E Jin, Fenfen Chang, Xiao Juan Wang, Qing Cao

Turkish Journal of Chemistry

With glucose as the starting material, sodium tripolyphosphate as the phosphorus acylating agent, and urea as the catalyst, glucose 1-phosphate was synthesized and its properties were analyzed. The synthesis conditions were selected according to the phosphorus content and optimized through the response surface methodology (RSM), based on a 3-level, 3-variable Box--Behnken experimental design. The results showed that the phosphorus content of glucose 1-phosphate was 8.12% using a reaction temperature of 70 °C, a molar ratio of glucose to sodium tripolyphosphate of 1.54:1, and catalyst amount of 3.7 g. It coincided well with the experimental value (8.34%). The structure of the …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Biodegradability Of Degradable Mulching Film In A Laboratory-Controlled Composting Test, Xuemei Zhang, Yaxi Huang, Deqiang Li, Zicheng Wen, Baoxun Sui, Zhiyong Liu

Turkish Journal of Chemistry

A series of degradable films was prepared, and 2 formulas of polyethylene (PE) films with the highest degradable performance were experimentally determined. These films contained 3.43% and 0.44% stearate, and were denoted as PE-3 and PE-4, respectively. Their biodegradability was studied in a laboratory-controlled composting test using ordinary PE film (OPEF) as a control. Contrast composting experiments indicated that the biodegradability of untreated samples was very low, and that the biodegradation rates of PE films after natural aging were significantly higher. FT-IR analysis showed that OPEF changed little after the composting experiment, and that PE-3 and PE-4 showed a carbonyl …

Synthesis Of New N-[3-(Benzo[D]Thiazol-2-Yl)-4-Methylthiazol-2(3h)-Ylidene] Substituted Benzamides, Aamer Saeed, Hummera Rafique

Turkish Journal of Chemistry

A series of novel N-[3-(2-benzo[d]thiazol-2-yl)-4-methylthiazol-2(3H)-ylidene] substituted benzamides (2a--k) were efficiently synthesized by heterocyclization of the corresponding 1-(benzo[d]thiazol-2-yl)-3-aroylthioureas (1a--k). The cyclization was achieved by the reaction of \alpha-bromoacteone produced in situ using bromine in dry acetone in the presence of triethylamine.

Expression Of Cyclin D1, P27, P21, Bcl-2, And P53 In Laryngeal Squamous Cell Carcinoma And An Investigation Of The Correlation With Conventional Prognostic Factors, Gülçi̇n Şi̇mşek, Ünsal Han, Bi̇nnur Önal, Fatma Fulya Köybaşioğlu, İstemi̇han Akin, Muharrem Dağli

Turkish Journal of Medical Sciences

Because it is a multistep process, in carcinogenesis it is necessary to determine key genes such as cyclin D1, p27, p21, bcl-2, and p53 that are responsible for uncontrolled proliferation and other mechanisms. The aim of this study was to examine the correlation between the anomalous accumulation of these proteins and the prognosis of laryngeal carcinomas. Materials and methods: In our study, cyclin D1, p27, p21, bcl-2, and p53 expressions were analyzed immunohistochemically in laryngeal squamous cell carcinomas, and the findings were compared with conventional prognostic parameters such as patient age, sex, tumor localization and diameter, tumor differentiation, lymph node …

Leptin Regulation Of Pubertal Maturation In Intact And Pinealectomized Female Rats, Emi̇ne Kaçar, Si̇ğnem Eyuboğlu Di̇nç, Bayram Yilmaz, Haluk Keleşti̇mur

Turkish Journal of Medical Sciences

To explore the roles of leptin and melatonin in early pubertal maturation. Materials and methods: Wistar female rats were used as experimental animals. Leptin was subcutaneously infused for 28 days through osmotic minipumps starting from postnatal day 15 (preweaning). Pinealectomy was performed on postnatal day 21 (weaning), and the animals were decapitated when estrus was detected by vaginal smearing. Results: Chronic preweaning, by peripheral infusion of leptin through subcutaneous routes, advanced the onset of puberty in leptin-treated sham and pinealectomized groups as determined by vaginal opening, while causing no significant change in serum estradiol levels and uterus weight. Mean body …

A Potential Association Between The Number Of Ca Repeats In The Promoter Region Of The Adamts9 Gene With Lymphatic Metastasis Of Breast Cancer, Mi̇kdat Bozer, Fatma Aşik, Muradi̇ye Acar, Hacer Haltaş, Si̇bel Yeni̇dünya, Meti̇n Canbal, Vehap Topçu, Muhammet Ramazan Yi̇ği̇toğlu, Mehmet Gündüz, Esra Gündüz, Satoshi Hirohata, Kadi̇r Demi̇rcan

Turkish Journal of Medical Sciences

We investigated the effect of the number of cytosine-adenine (CA) repeats in the ADAMTS9 promoter region on breast cancer lymphatic metastasis. Materials and methods: Thirty-one postoperative breast cancer patients were selected and examined retrospectively. The patients were classified into 2 groups: metastatic or nonmetastatic. Thirty healthy women were selected as the control group, and their peripheral blood was obtained. Following DNA isolation from the cancer tissue specimens and peripheral blood, the promoter region of the ADAMTS9 gene was directly sequenced and the number of CA repeats was determined. Results: The number of CA repeats ranged between 19 and 21 in …

Medical Issue Or Policy? A Framing Analysis Of The Medical Marijuana Issue In U.S. Newspapers, Christopher Lee Kaiser

LSU Master's Theses

This study conducted a framing analysis of the medical marijuana issue in United States print media. In addition, this analysis investigated whether the medical marijuana issue was portrayed as a policy issue or a medical issue, and based the inquiry in public opinion and health communication literature. This analysis extracted a sample (N=240) from newspaper stories that reported the issue within the past five years in states that have enacted medical marijuana legislation. The framing analysis measured the occurrence of frames in three different categories: gain vs. loss, types of frames, and policy vs. medical. Furthermore, this analysis determined if …

Fish And Macroinvertebrate Assemblage Composition And Diversity At Revetted Banks In The Pearl River And The Response Of These Assemblages To A Paper Mill Effluent Spill, Jose Alexander Vazquez

LSU Master's Theses

The armoring of river banks with riprap can have detrimental effects on lotic ecosystems due to the subsequent alteration of hydrologic regimes; however, evidence suggests that riprap can also increase aquatic diversity in degraded systems. The goal of my study was to determine what impacts riprapped banks have on fish and macroinvertebrate assemblages in the Pearl River, which has a history of anthropogenic degradation. I collected fishes with an electrofishing boat from armored and natural banks at five regions during fall 2011, winter 2012, and summer 2012. I also collected macroinvertebrates with introduced substrates in fall 2011. Richness was analyzed …

Does Flexible Grouping Increase Retention Levels To Improve Test Scores More Than Traditional Lecture In The Science Classroom, Brian Joseph Carter

LSU Master's Theses

The purpose of my research was to analyze the effect flexible grouping had on science retention scores. Education faces so many challenges today. The old way of teaching, traditional lecture is being challenged. For centuries, traditional lecture was the primary way of teaching and most colleges still use this teaching method. In this thesis traditional lecture and flexible grouping are compared. Through the use of pretests and posttests in my traditional and honors chemistry classes, I tested both strategies. Presentation of seven chapters were used for data collection and through the research, several things were discovered. In this study, honor …

Differential Effect Of 14 Free Fatty Acids In The Expression Of Inflammation Biomarkers On Human Coronary Arterial Cells, Adriana Soto Rodriguez Gil

LSU Master's Theses

Cardiovascular disease is the leading cause of death in the US, and circulating free fatty acids (FFAs) are known risk factors associated with cardiovascular inflammation. The influence of 14 dietary FFAs (including saturated, mono-, poly-unsaturated and trans), on the expression of inflammatory markers in human coronary arterial smooth muscle (HACSM) and endothelial (HCAEC) cells using a cell culture model was investigated. HACSM and HCAEC cell cultures were incubated with 200 μM of each FFA for 8 or 24 h respectively at 37 °C in a 5% CO2 humidified incubator. Inflammatory biomarkers were assessed by ELISA or Western Blot in the …

The Sisters' Experience Of Having A Sibling With An Autism Spectrum Disorder, Melissa L. Mcvicker

Antioch University Dissertations & Theses

This dissertation consists of two articles. This first article is a literature review identifying studies of autism spectrum disorders and sibling relationships published in the past 10 years. This search strategy identified 16 articles for inclusion in this review and conveyed the following main outcomes: a) parental factors influence sibling relationship and typically developing child, b) behavioral interactions/problems affect the quality of the sibling relationship, c) genetic factors have varying impact on diagnosis, and d) effects/outcomes for typically developing sibling are both positive and negative. This review supported the call for a better understanding of the family factors on the …

The Effects Of Weight Bias In Physical Education And The Impact Of Intervention Methods, Chris Ehlert

Graduate Research Papers

The purpose of this review was to examine the effects of weight bias in physical education programs and discuss interventions that may help to eliminate any negative consequences.

Student Reward Programs In Collegiate Athletics, Danielle N. Bakken

Graduate Research Papers

Incentive marketing is becoming increasingly popular among many brands, companies, and even sports teams. Incentive marketing uses motivational campaigns to promote the consumption or sale of merchandise or services. It encourages consumers to become repeat buyers and/or to become more loyal toward a specific product, brand, or company. An aspect of incentive marketing that is emerging within the sports industry is reward programs; specifically with students of universities or colleges. The goals of student reward programs include increasing awareness and attendance of all athletic events on campus, as well as the possibility of students remaining loyal and purchasing season tickets …

Alignment Of A 9th Grade Earth Science Curriculum With The Iowa Core, Courtney Elizabeth Giesel

Graduate Research Papers

In 1990, education was brought to the forefront of federal law with the reauthorization of the Elementary and Secondary Education Act (ESEA). The Act was continued during the Bush administration under the name No Child Left Behind (NCLB) (P.L, 2002). These laws became the framework for guiding state education policy (Massell, 2008). Education began experiencing growing pains as lawmakers decided there needed to be better continuity within the American education system, hence the birth of standards-based education.

High School Physics: Virtual Circuit Construction Vs. Real Circuit Equipment, Charlie Leslie Gardner Jr.

Graduate Research Papers

It is amazing to think about the transition of the computer's importance and the abundance of computers within schools. In the last couple of decades, the main purpose has shifted from teaching basic clerical work, to everyday use. It has gone from schools with a single computer room full of bulky desktops, to multiple computer labs, mobile laptop carts, and even personal laptops. Today, advances in technology are taken for granted as we continuously find ourselves surrounded by it. In 2000, there were approximately 1000 American schools using a 1:1 model, which totaled 150,000 laptops (Johnstone, 2003; Dunleavy, Dextert, & …

Student Centered Instruction & Incorporation Of Information, Communications And Technology (Ict) Into The Life Science Curriculum, Cathy Hones

Graduate Research Papers

My job as a high school teacher is a continual quest for helping my students explore and learn about the biological world. However, I also would like them to be self-motivated learners who develop 21st Century Skills to help them succeed as they move on to future learning, working and living experiences. I would like to use ICT (Information, Communications & Technology) tools such as Google Apps and Moodie along with other Web 2.0 tools and incorporate them into my life science curricula in order to meet the following three goals:

The first goal is to take advantage of the …

Problem Based Learning Lesson For The Next Generation Science Standards: Earth And Space, Amy Ann Tursi

Graduate Research Papers

No abstract provided.

Developing The Nature Of Science Skills In At-Risk High School Students: Students “Doing” Science Using Historical Perspectives And Inquiry, Glenn Dewayne Varner

Graduate Research Papers

No abstract provided.

A Comparison Of Obesity Patterns Between University Students From The United States And Gulf Arab Countries, Ali Alsultan

Graduate Research Papers

No abstract provided.

Desulfotomaculum Dissimilatory Reduction Of Iron (Iii), Jim Elric

Dissertations and Theses @ UNI

Excess plant nutrient, often from agricultural runoff, can cause uncontrolled algal growth that leads to eutrophic conditions in a water body. Desulfotomaculum sp. reduction of ferric ions to ferrous ions can aid in reduction of excess phosphate in a water body. This bacterium may use iron mine tailings as an inexpensive source of iron ions that can aid in elimination of excess nutrient load such as phosphates. As part of a remediation plan Desulfotomaculum sp. reduction of ferric ions can help restore and maintain a healthy aquatic ecosystem. The biochemical pathway of iron reduction by Desulfotomaculum sp. is unclear and …