Digital Commons Network^™

Synthesis And Investigations Of Type I And Ii Clathrates Of Group 14, Michael Blosser

USF Tampa Graduate Theses and Dissertations

Clathrates are a class of new materials that have an open-framework structure that allows guest atoms or molecules to be enclosed inside of their polyhedral framework. Varying the number, weight, and size of the guest species in a particular framework allows one to alter the physical properties of the clathrate. This relationship enables one to further the fundamental understanding of the physics and chemistry of the clathrate structure and use this knowledge to "tune" certain properties. This "tunability" of inorganic clathrates is of great interest as it allows one to optimize their physical properties; making them promising candidates for a …

Magnetism In Complex Oxides Probed By Magnetocaloric Effect And Transverse Susceptibility, Nicholas Steven Bingham

USF Tampa Graduate Theses and Dissertations

Magnetic oxides exhibit rich complexity in their fundamental physical properties determined by the intricate interplay between structural, electronic and magnetic degrees of freedom. The common themes that are often present in these systems are the phase coexistence, strong magnetostructural coupling, and possible spin frustration induced by lattice geometry. While a complete understanding of the ground state magnetic properties and cooperative phenomena in this class of compounds is key to manipulating their functionality for applications, it remains among the most challenging problems facing condensed-matter physics today. To address these outstanding issues, it is essential to employ experimental methods that allow for …

Effect Of Cement Chemistry And Properties On Activation Energy, Andre J. Bien-Aime

USF Tampa Graduate Theses and Dissertations

The objective of this work is to examine the effect of cement chemistry and physical properties on activation energy. Research efforts indicated that time dependent concrete properties such as strength, heat evolution, and thermal cracking are predictable through the concept of activation energy. Equivalent age concept, which uses the activation energy is key to such predictions. Furthermore, research has shown that Portland cement concrete properties are affected by particles size distribution, Blaine fineness, mineralogy and chemical composition. In this study, four Portland cements were used to evaluate different methods of activation energy determination based on strength and heat of hydration …

Nietzsche And Heidegger On The Cartesian Atomism Of Thought, Steven Burgess

USF Tampa Graduate Theses and Dissertations

My dissertation has two main parts. In the first half, I draw out an underlying presupposition of Descartes' philosophy: what I term "atomism of thought." Descartes employs a radical procedure of doubt in order to show that the first principle of his philosophy, the cogito, is an unshakeable foundation of knowledge. In the dialogue that follows his dissemination of the Meditations, Descartes reveals that a whole set of concepts and rational principles innate in our minds are never doubted. These fundamental units of thought are indivisible, distinct, and isolated, and enable the possibility of any rational demonstration. Atoms of …

Daily Recovery From Work: The Role Of Guilt, Eunae Cho

USF Tampa Graduate Theses and Dissertations

Acknowledging the critical role that occupational factors play in employee health, researchers have tried to understand ways to reduce the harmful effects of work on employee health. As the process by which individuals recharge resources that have been depleted, recovery has been recognized as important due to its potential to mitigate the negative effects of work on employee well-being. Although the recovery literature has continued to grow, many questions remain unanswered. The purpose of the present study was to expand our knowledge of recovery by examining situational (job characteristics) and individual (trait guilt) predictors of recovery and investigating psychological attributes …

Faculty Perceptions Of The Importance Of Internationalizing The General Education Curriculum In The Florida College System, Bonnie M. Clark

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to investigate the attitudes of community college general education faculty members regarding their perceptions of the importance of internationalizing the general education curriculum and to what extent those perceptions are related to their attitudes toward globalization. The study further examined the degree to which faculty members perceive that they are incorporating the teaching of global competencies into their courses. Finally, the study looked at faculty members' perceptions of administrative support - both from the perspective of what they felt their college should be doing to support internationalization and what their college was actually doing …

A Study On Lane-Change Recognition Using Support Vector Machine, Weiping Deng

USF Tampa Graduate Theses and Dissertations

This research focuses primary on recognition of lane-change behaviors using support vector machines (SVMs). Previous research and statistical results show that the vast majority of motor vehicle accidents are caused by driver behavior and errors. Therefore, the interpretation and evaluation of driver behavior is important for road safety analysis and improvement. The main limit to understanding driver behavior is the data availability. In particular, a full-scale lane-change data set is difficult to collect in a real traffic environment because of the safety and cost issues. Considering the data demands of the recognition model development and the obstacles of field data …

Hydrogen Storage In Hypercrosslinked Polystyrene And Li-Mg-N-H Complex Hydride, Dervis Emre Demirocak

USF Tampa Graduate Theses and Dissertations

In this dissertation, hydrogen storage enhancement in hypercrosslinked polystyrene, effects of single walled carbon nanotubes (SWCNTs) supported ruthenium (Ru) catalyst on the kinetics and ammonia suppression in the LiNH2-MgH2 complex hydride system and the accuracy of hydrogen storage measurements are investigated in detail.

High surface area physisorption materials are of interest for room temperature hydrogen storage enhancement by spillover. Six different commercially available hypercrosslinked polystyrenes are screened by considering the specific surface area, average pore size, pore volume, and adsorption enthalpy. MN270 is selected mainly due to its high surface area and narrow pores for investigation of the spillover enhancement …

Modeling State Transitions With Automata, Egor Dolzhenko

USF Tampa Graduate Theses and Dissertations

Models based on various types of automata are ubiquitous in modern science. These models allow reasoning about deep theoretical questions and provide a basis for the development of efficient algorithms to solve related computational problems. This work discusses several types of automata used in such models, including cellular automata and mandatory results automata.

The first part of this work is dedicated to cellular automata. These automata form an important class of discrete dynamical systems widely used to model physical, biological, and chemical processes. Here we discuss a way to study the dynamics of one-dimensional cellular automata through the theory of …

The Underrepresentation Of African American Women Faculty: A Phenomenological Study Exploring The Experiences Of Mcknight Doctoral Fellow Alumna Serving In The Professoriate, Dionne Jones Ferguson

USF Tampa Graduate Theses and Dissertations

While African American women have been participating in higher education for more than a century, they remain significantly underrepresented among college and university professors in America. This study was pursued in an attempt to address the underrepresentation of African American women faculty at public and private universities within the State of Florida. More importantly, the study aimed to examine the role of the McKnight Doctoral Fellowship program (MDFP) in assisting McKnight Doctoral Fellow alumna in doctoral degree attainment, preparing them for the professoriate and contributing toward their professional success. A phenomenological methodological approach was used for this study, which was …

A Study Of Permutation Polynomials Over Finite Fields, Neranga Fernando

USF Tampa Graduate Theses and Dissertations

Let p be a prime and q = p^k. The polynomial g_n,q isin F_p[x] defined by the functional equation Sigma_{a isin Fq} (x+a)ⁿ = g_n,q(x^q- x) gives rise to many permutation polynomials over finite fields. We are interested in triples (n,e;q) for which g_n,q is a permutation polynomial of F_q^e. In Chapters 2, 3, and 4 of this dissertation, we present many new families of permutation polynomials in the form of g_n,q. The permutation behavior of g_n,q is becoming increasingly more …

The Effects Of Temporal Preparation On Reaction Time, Glen Robert Forester

USF Tampa Graduate Theses and Dissertations

When responding to external stimuli, preparation reduces Reaction Time (RT). One form of preparation known as temporal preparation results from advance knowledge about when a stimulus will appear. We used Event Related Potentials to investigate how increasing temporal preparation decreases RT during a speeded, choice RT task by manipulating temporal preparation within subjects. In order to determine which cognitive processes are speeded, the latencies of the Lateralized Readiness Potential (LRP) and P300 were examined across two levels of temporal preparation. In line with previous research the stimulus locked LRP, but not the response locked LRP, was speeded when temporal preparation …

Pine Creek Conservation Area: 2013 Mapping And Monitoring Report, Eric M. Nielsen, Matthew D. Noone, James S. Kagan, Matthew T. Lee

Institute for Natural Resources Publications

Pine Creek Conservation Area (PCCA), just northeast of the John Day River in Wheeler County, Oregon, was acquired in 1999-2001 by the Confederate Tribes of Warm Springs with support from the Bonneville Power Administration (BPA), to mitigate for wildlife losses created by the large, hydropower Columbia River Dams, particularly the Bonneville, Dalles and John Day Dams. Many thousands of acres of grassland, shrub steppe and riparian habitats were lost due to inundation, and the objectives of the acquisition included restoration of similar habitats. As part of an interagency agreement created in 2002, the Oregon Natural Heritage Information Center established a …

Development Of Dynamic Thermal Performance Metrics For Eco-Roof Systems, Seth Sinclair Moody

Dissertations and Theses

In order to obtain credit for an eco-roof in building energy load calculations the steady state and time-varying thermal properties (thermal mass with evapotranspiration) must be fully understood. The following study presents results of experimentation and modeling in an effort to develop dynamic thermal mass performance metrics for eco-roof systems. The work is focused on understanding the thermal parameters (foliage & soil) of an eco-roof, further validation of the EnergyPlus Green Roof Module and development of a standardized metric for assessing the time-varying thermal benefits of eco-roof systems that can be applied across building types and climate zones. Eco-roof foliage, …

Challenges And Rewards Of Single Crystal Flux Growth: Physical Properties Of Structurally Related Ln-Ru-Al Intermetallics, Gregory Morrison

LSU Doctoral Dissertations

The availability of single crystals is vital for understanding the intrinsic properties of crystalline materials. The flux growth method is a versatile technique which may be used to grow single crystals. However, their synthesis can often be challenging, especially when a competing phase is very robust. Herein, we study the growth competition between structurally related compounds in the Ln-Ru-Al phase space. We demonstrate the benefits of single crystals and suggest methods to grow competing phases. CeRu2Al10 has garnered interest due to its higher ordering temperate than expected from de Gennes scaling and its metal-to-insulator transition at the same temperature. Here, …

A Revised View Of The Judicial Hunch, Linda L. Berger

Scholarly Works

Judicial intuition is misunderstood. Labeled as cognitive bias, it is held responsible for stereotypes of character and credibility. Framed as mental shortcut, it is blamed for overconfident and mistaken predictions. Depicted as flashes of insight, it takes credit for unearned wisdom. The true value of judicial intuition falls somewhere in between. When judges are making judgments about people (he looks trustworthy) or the future (she will be the better parent), the critics are correct: intuition based on past experience may close minds. Once a judge recognizes a familiar pattern in a few details, she may fail to see the whole …

Analysis Of Protein Aggregates And Synthetic Nanoparticles Using Capillary Electrophoresis With Light Scattering And Fluorescence Detection, Suresh Chandra Regmi

LSU Doctoral Dissertations

The goal of the research presented in this dissertation is to develop capillary electrophoresis (CE) based analysis techniques for the characterization of individual particles including amyloid beta (Aâ) peptide aggregates and to apply these methods to study the aggregation of Aâ peptides. Protein self-assembly into ordered aggregates is a common and important process in normal biological function, but this process is also involved in several diseases. Amyloid beta peptide aggregation is linked to Alzheimer’s disease. Thioflavin T (ThT) has been used as a fluorescent probe for the detection of Aâ aggregation. Based on previous observations of false positive fluorescent signals …

Treatment Effects Of Attention Process Training For An Individual With Idiopathic Parkinson's Disease, Kristen Michelle Ferguson

LSU Master's Theses

Purpose: The purpose of this study was to determine the treatment efficacy of the Attention Process Training (APT; Sohlberg & Mateer, 2005), a therapeutic protocol designed for individuals who have sustained a traumatic brain injury (TBI), on a person with Parkinson’s disease to determine if improvement of various attention processes and memory recall could be improved. Methods: We designed a phase I, multiple baseline A1-B-A2-A3, single-subject study with one participant diagnosed with idiopathic PD and self-reported attention impairments. We used Attention Process Training (APT) protocol (Sohlberg & Mateer, 2005) to train attention process 120-minutes per session, one time per week …

Using Writing Assignments In High School Geometry To Improve Students' Proof Writing Ability, Amanda Choppin Mcallister

LSU Master's Theses

The Common Core State Standards encourage the use of writing in mathematics classrooms. This study was designed to create a template for high school teachers to use in a geometry class to improve students’ proof writing ability. The students enrolled in the class were asked to complete journal and expository writing assignments throughout the course. The assignments were scored with a rubric. To assess if growth was made in proof writing, the students were all given a test four times throughout the school year. All four tests were assessed using the same rubric. We provide evidence that the template was …

Monitoring The Survival Of Hatchery-Produced Spat And Larvae On Louisiana Public Oyster Reefs, Erin R. Leonhardt

LSU Master's Theses

Alternative or supplemental management activities may be necessary to restore and enhance oyster production on Louisiana public oyster reefs. The production of wild oysters is variable due to anthropogenic and environmental factors that affect recruitment, growth and survival. The availability and structure of cultch material for larval recruitment and survival is particularly important to maintain oyster production. Beginning in 2011, the Sea Grant Oyster Hatchery on Grand Isle, LA and the Louisiana Department of Wildlife and Fisheries (LDWF) collaborated to test the survival of hatchery-produced spat and hatchery-produced larvae deployed on public oyster grounds and cultch plant sites. In 2011, …

The Extraterritoriality Of Data Privacy Laws -- An Explosive Issue Yet To Detonate, Fred H. Cate, Christopher Kuner, Christopher Millard, Dan Jerker B. Svantesson

Articles by Maurer Faculty

No abstract provided.

The Effects Of Implementing The Cooperative Learning Structure, Numbered Heads Together, In Chemistry Classes At A Rural, Low Performing High School, Daniel Paul Baker

LSU Master's Theses

Due to the positive academic results in numerous studies on cooperative learning and the need and desire to improve academic results in East Feliciana High School Chemistry classes, the implementation of a cooperative learning structure called “numbered heads together” was studied during the spring 2013 semester at this rural, low performing high school. Numbered heads together was utilized during three units of a Chemistry class with 24 students and three units of an AP Chemistry with 11 students after completion of two units taught without the use of any type of cooperative learning structure. Using pre- and post-tests, learning gain …

Notice And Consent In A World Of Big Data, Fred H. Cate, Viktor Mayer-Schönberger

Articles by Maurer Faculty

• Nowadays individuals are often presented with long and complex privacy notices routinely written by lawyers for lawyers, and are then requested to either ‘consent’ or abandon the use of the desired service.
• The over-use of notice and consent presents increasing challenges in an age of ‘Big Data’.
• These phenomena are receiving attention particularly in the context of the current review of the OECD Privacy Guidelines.
• In 2012 Microsoft sponsored an initiative designed to engage leading regulators, industry executives, public interest advocates, and academic experts in frank discussions about the role of individual control and notice and consent in data protection …

Evaluating High School Students' Constitutional And Civic Literacy: A Case Study Of The Washington, D.C. Chapter Of The Marshall-Brennan Constitutional Literacy Project, Maryam Ahranjani, Caleb Medearis, Jeff Shook

Scholarly Works

The United States maintains a reputation as a vibrant, participatory democracy. Yet, paradoxically, formal civics education has essentially disappeared from America's public high schools, particularly urban public schools serving low-income and minority students. The Marshall-Brennan Constitutional Literacy Project, which is offered at almost zero cost to public schools and districts, developed as a response to the need for civics education in high schools and as a way to train future lawyers in public speaking, leadership, and counseling. To support the growth of the Marshall-Brennan project all over the country, the authors of this Essay came together to study the Marshall-Brennan …

Interpreting Individual Classifications Of Hierarchical Networks, Will Landecker, Michael David Thomure, Luis M.A. Bettencourt, Melanie Mitchell, Garrett T. Kenyon, Steven P. Brumby

Computer Science Faculty Publications and Presentations

Hierarchical networks are known to achieve high classification accuracy on difficult machine-learning tasks. For many applications, a clear explanation of why the data was classified a certain way is just as important as the classification itself. However, the complexity of hierarchical networks makes them ill-suited for existing explanation methods. We propose a new method, contribution propagation, that gives per-instance explanations of a trained network's classifications. We give theoretical foundations for the proposed method, and evaluate its correctness empirically. Finally, we use the resulting explanations to reveal unexpected behavior of networks that achieve high accuracy on visual object-recognition tasks using well-known …

Forecasting Microprocessor Technology In The Multicore Era Using Tfdea, Saranya Durairajan, Maria Ibarra Prado, Noshad Rahimi, Shabnam Razeghian Jahromi

Engineering and Technology Management Faculty Publications and Presentations

Technological advancements in the microprocessor industry are benchmarked and gauged against a set of diverse criteria, specific to the fabrication process, usage as well as achieved performance. Changing trends in the appeal factor as well as wide variety of growing application of microprocessors in different industries also have a defining impact in the advancement of the technological features in future. This study improves the previous investigation in forecasting microprocessors? technology and uses Technology Forecasting using Data Envelopment Analysis (TFDEA) methodology for an enhanced model. The study takes advantage of the recent microprocessor dataset including multi core processors, from a variety …

Forecasting Hybrid Electric Vehicles Using Tfdea, Shabnam Razeghian Jahromi, Anca-Alexandra Tudori, Timothy R. Anderson

Engineering and Technology Management Faculty Publications and Presentations

The Toyota Prius was introduced in Japan fifteen years ago and over 60 additional hybrid electric vehicles automobiles and redesigns have been brought to the market around the world since that time. There is major interest in future of the electric cars as using ?the alternative fuel? can significantly decrease the environmental and fuel dependency concerns. This work has used data envelopment analysis to forecast the future of hybrid electric cars. It is based on a previous research on the same subject with an improvement in input-output model that has enhanced the outcomes to a great extent. The former study …

Bayesian Estimation For Tracking Of Spiraling Reentry Vehicles, Juan Esteban Tapiero Bernal

Master's Theses (2009 -)

This thesis presents a development of a physics-based dynamics model of a spiraling atmospheric reentry vehicle. An analysis of the trajectory characteristics, using elements from differential geometry lead to a relationship of the state of the vehicle to the spiraling of motion. The Bayesian estimation framework for nonlinear systems is introduced showing the theoretical basis of the estimation techniques. Two estimation algorithms, extended Kalman filter and particle filter are presented, their mathematical formulation and implementation characteristics.

Different trajectories that can be represented by the model are introduced and analyzed, showing the spiraling behavior that can be described by the model. …

Language, Politics, And History: An Introductory Essay, José Del Valle

Publications and Research

This book chapter examines different articulations of language and history and introduces a new configuration that focuses on the political dimension of language.

Comment On "Density And Physical Current Density Functional Theory", Xiao-Yin Pan, Viraht Sahni

Publications and Research

In this letter to the editor, the authors comment on an earlier article they had published, "Density and Physical Current Density Functional Theory" (Pan, X.-Y. and Sahni, V. (2010), Density and physical current density functional theory. Int. J. Quantum Chem., 110: 2833–2843. doi: 10.1002/qua.22862).