Digital Commons Network^™

Mechanochemistry For Solid-State Syntheses And Catalysis, David Restrepo

Electronic Theses and Dissertations

Traditional methods of synthesizing inorganic materials, such as hydrothermal, sol-gel, calcination and grinding steps, can typically require use of high temperatures, expensive precursors or use of solvents. Because of the energy-intensive nature or environmental impact these techniques, there is a push, especially from an industrial perspective, to move towards greener approaches. Mechanochemistry is a solvent-free alternative technique that can be used to synthesize a variety of materials under ambient conditions. Due to this, there is an increase in attention towards the use of this approach in both solid-state inorganic and organic chemistry. This dissertation reports the mechanochemical synthesis of a …

An Exploratory Study Of Customer Vulnerability: A Cross-Segment Approach, Taryn Aiello

Electronic Theses and Dissertations

The purpose of this study is to explore the concept of customer vulnerability across varying service industries. While the concept of customer vulnerability has been debated in business, marketing, sociology, and psychology scholarly literature, there has been little research conducted that specifically investigates consumers’ perceptions of vulnerability during the service exchange. Specific to this research, customer vulnerability is defined as experiences in which consumers participate in a service exchange with a firm during a time of individual or shared medical, physical, emotional, or spiritual necessity, whether the vulnerability is experienced during the course of the transaction or whether consumers arrive …

An Event-Related Potential Investigation Of Error Monitoring In Adults With A History Of Psychosis, Chi Chan

Electronic Theses and Dissertations

Metacognition, which involves monitoring and controlling of one’s thoughts and actions, is essential for guiding behavior and organization of information. Deficits in self-monitoring have been suggested to lead to psychosis and poor functional outcome. Abnormalities in eventrelated potentials originating from the anterior cingulate cortex (ACC), a brain region associated with error detection, have been consistently reported in individuals with schizophrenia during error monitoring tasks. This study sought to examine whether these abnormalities are present in individuals with a history of psychosis across diagnostic categories and whether they are associated with subjective appraisal of self-performance and personality traits related to psychosis. …

The Latina/O Student's Experience In Social Studies: A Phenomenological Study Of Eighth Grade Students, Christopher Busey

Electronic Theses and Dissertations

The purpose of this research investigation was to explore the experiences of eighth-grade Latina/o students in a large, urban school in the Southeastern United States. Overall, the study uncovered the essence of the Latino/a student experience in social studies and furthermore revealed that social studies is not meeting the needs of Latino students. Using phenomenology as a method of research, two interviews were conducted with twelve research participants who were selected through purposive sampling. In addition to the interviews, students wrote narratives and drew images as a form of data triangulation. The goal was to give students various methods for …

Characterization Of Motility Alterations Caused By The Impairment Of Dynein/Dynactin Motor Protein Complex, Swaran Nandini

Electronic Theses and Dissertations

Transport of intracellular cargo is an important and dynamic process required for cell maintenance and survival. Dynein is the motor protein that carries organelles and vesicles from the cell periphery to the cell center along the microtubule network. Dynactin is a protein that activates dynein for this transport process. Together, dynein and dynactin forms a motor protein complex that is essential for transport processes in all the vertebrate cells. Using fluorescent microscope based live cell imaging techniques and kymograph analyses, I studied dynein/dynactin disruptions on the intracellular transport in two different cell systems. In one set of experiments, effects of …

Solid Phase Extraction Room Temperature Fluorescence Spectroscopy For The Direct Quantification Of Monohydroxy Metabolites Of Polycyclic Aromatic Hydrocarbons In Urine Samples, Korina Jesusa Calimag

Electronic Theses and Dissertations

Polycyclic aromatic hydrocarbons (PAH) are important environmental pollutants generally formed during incomplete combustion of organic matter containing carbon and hydrogen. Introduced into the human body by adsorption through the skin, ingestion or inhalation, the biotransformation processes of PAH lead to the formation of multiple metabolites. Due to the short elimination lifetime from the body, the quantitative determination of monohydroxy-PAH (OH-PAH) in urine samples provides accurate information on recent exposure to environmental PAH. Urine analysis of OH-PAH with established methodology relies on sample clean-up and pre-concentration followed by chromatographic separation and quantification. Although chromatographic techniques provide reliable results in the analysis …

Remediation Of Polychlorinated Biphenyl (Pcb) Contaminated Building Materials Using Non-Metal And Activated Metal Treatment Systems, Tamra Legron-Rodriguez

Electronic Theses and Dissertations

PCBs are recalcitrant compounds of no known natural origin that persist in the environment despite their ban by the United States Environmental Protection Agency in 1979 due to negative health effects. Transport of PCBs from elastic sealants into concrete, brick, and granite structures has resulted in the need for a technology capable of removing these PCBs from the materials. This research investigated the use of a nonmetal treatment system (NMTS) and an activated metal treatment system (AMTS) for the remediation and degradation of PCBs from concrete, brick, and granite affixed with PCB-laden caulking. The adsorption of PCBs onto the components …

Capillarity: A Theory Of Mlearning And Its Application In Emerging Markets, David Rogers

Electronic Theses and Dissertations

The theory of capillarity is an organic metaphor invoked to explore the role of network communications as a vehicle for education in a healthy society. Capillarity is offered as a theory in two parts: a mechanism for distribution and a method for engagement. Capillarity seeks to build an architecture that reflects radical humanism's emphasis on access and inclusion as a vehicle for classical humanism's emphasis on the individual expansion of potential and consciousness. The technical instrument whereby this program of humanist education may be deployed is mLearning

Deconstructing Differences In Effectiveness Of Reading Teachers Of Ninth Grade Non-Proficient Readers In One Florida School District, Jason Wysong

Electronic Theses and Dissertations

This study was undertaken to identify specific instructional and professional differences between the most effective and least effective teachers of ninth grade students enrolled in intensive reading courses in one Florida school district. Teachers from eleven schools were invited to complete a survey that included categorical, Likert, and openended response items. Principals and assistant principals at these schools were also invited to complete a similar survey. Teacher respondents were then divided into three effectiveness groups based on the percentage of their students who met 2011-2012 FCAT performance targets established by Florida’s value-added learning growth model. Inferential statistics were used to …

Zora, Genevieve Tyrrell

Electronic Theses and Dissertations

This mixed-media memoir uses a variety of forms from short epigrammatic essays to straightforward stories and graphic narratives to explore the author’s coming-of-age experiences augmented by chronic illness. Trying to succeed in the film industry, romance, and family situations, the young female narrator navigates the often unexpected or disappointing consequences of having an autonomic nervous system disorder. Relationships between conflicting identities emerge—between healthy versus sick self, projected/envisioned versus actual self, and tough versus vulnerable self—as the narrator journeys toward a more complete and accepting self-understanding.

Multicultural Personality And Psychological Functioning, Lauren Trottier

Electronic Theses and Dissertations

As the U.S. becomes increasingly diverse, individuals will need to interact effectively with a wide range of people. The theory of multicultural personality refined by Ponterotto (2010) proposes that some individuals may be better suited than others to adapt to the changing demographic landscape. Individuals with a multicultural personality are theorized to have the ability to interact effectively within a wide range of contexts and draw on diverse experiences and resources to solve everyday problems in multiple ways as well as seek out diversity in their lives. Because of their skills and disposition, Ponterotto (2010) suggests that those with a …

Less Lost: No Touchdown Dance, William Conner

Electronic Theses and Dissertations

Less Lost is a feature-length film by William Chase Conner, made as part of the requirements for earning a Master of Fine Arts in Film & Digital Media from the University of Central Florida.

Immuno-Pcr Detection Of Lyme Borreliosis, Micah Halpern

Electronic Theses and Dissertations

Lyme borreliosis, more commonly referred to as Lyme disease, is the fastest growing zoonotic disease in North America with approximately 30,000 confirmed cases and 300,000 estimated infections per year. In nature, the causative agent of Lyme disease, the bacterium Borrelia burgdorferi, cycles between Ixodes sp. ticks and small mammals. Humans become infected with Lyme disease after being bitten by an infected tick. The primary indicator of a Borrelia burgdorferi infection is a bull’s eye rash typically followed by flu-like symptoms with treatment consisting of a 2-4 week course of antibiotics. If not treated, later stages of the disease can result …

Ozone Photochemistry In An Oil And Natural Gas Extraction Region During Winter: Simulations Of A Snow-Free Season In The Uintah Basin, Utah, P. M. Edwards, C. J. Young, K. Aikin, J. Degouw, W. P. Dubé, F. Geiger, J. Gillman, D. Helmig, J. S. Holloway, J. Kercher, B. Lerner, Randy S. Martin, R. Mclaren, D. D. Parrish, J. Peischl, J. M. Roberts, T. B. Ryerson, J. Thornton, C. Warneke, E. J. Williams, S. S. Brown

Civil and Environmental Engineering Faculty Publications

The Uintah Basin in northeastern Utah, a region of intense oil and gas extraction, experienced ozone (O3) concentrations above levels harmful to human health for multiple days during the winters of 2009–2010 and 2010–2011. These wintertime O3 pollution episodes occur during cold, stable periods when the ground is snow-covered, and have been linked to emissions from the oil and gas extraction process. The Uintah Basin Winter Ozone Study (UBWOS) was a field intensive in early 2012, whose goal was to address current uncertainties in the chemical and physical processes that drive wintertime O3 production in regions of oil and gas …

Estimation Of Performance Indices For The Planning Of Sustainable Transportation Systems, Alexander Paz, Pankaj Maheshwari

Electrical & Computer Engineering Faculty Research

In the context of sustainable transportation systems, previous studies have either focused only on the transportation systemor have not used a methodology that enables the treatment of incomplete, vague, and qualitative information associated with the available data. This study proposes a system of systems (SOS) and a fuzzy logic modeling approach. The SOS includes the Transportation, Activity, and Environment systems. The fuzzy logic modeling approach enables the treatment of the vagueness associated with some of the relevant data. Performance Indices (PIs) are computed for each system using a number of performance measures. The PIs illustrate the aggregated performance of each …

Barry Rosen V. Ebay, United States District Court For The Central District Of California

Historical and Topical Legal Documents

No abstract provided.

Nasser V. Whitepages, United States District Court For The Western District Of Virginia

Historical and Topical Legal Documents

No abstract provided.

2253 Apparel V. Target, United States District Court For The Central District Of California

Historical and Topical Legal Documents

No abstract provided.

Treaties In Force: A List Of Treaties And Other International Agreements Of The United States In Force On January 1, 2013, United States Department Of State

Historical and Topical Legal Documents

No abstract provided.

Acetyl Radical In Tobacco Smoke: Detection, Quantification And Simulation, Na Hu

Dissertations, Master's Theses and Master's Reports - Open

Free radicals are present in cigarette smoke and can have a negative effect on human health by attacking lipids, nucleic acids, proteins and other biologically important species. However, because of the complexity of the tobacco smoke system and the dynamic nature of radicals, little is known about the identity of the radicals, and debate continues on the mechanisms by which those radicals are produced. In this study, acetyl radicals were trapped from the gas phase using 3-amino-2, 2, 5, 5- tetramethyl-proxyl (3AP) on solid support to form stable 3AP adducts for later analysis by high performance liquid chromatography (HPLC), mass …

Induction Of Microalgal Lipids For Biodiesel Production In Tandem With Sequestration Of High Carbon Dioxide Concentration, Wilbel J. Brewer

Dissertations, Master's Theses and Master's Reports - Open

There is no doubt that sufficient energy supply is indispensable for the fulfillment of our fossil fuel crises in a stainable fashion. There have been many attempts in deriving biodiesel fuel from different bioenergy crops including corn, canola, soybean, palm, sugar cane and vegetable oil. However, there are some significant challenges, including depleting feedstock supplies, land use change impacts and food use competition, which lead to high prices and inability to completely displace fossil fuel ^[1-2]. In recent years, use of microalgae as an alternative biodiesel feedstock has gained renewed interest as these fuels are becoming increasingly economically viable, …

Strategic Optimization Techniques For Frtu Deployment And Chip Physical Design, Chen Liao

Dissertations, Master's Theses and Master's Reports - Open

Combinatorial optimization is a complex engineering subject. Although formulation often depends on the nature of problems that differs from their setup, design, constraints, and implications, establishing a unifying framework is essential. This dissertation investigates the unique features of three important optimization problems that can span from small-scale design automation to large-scale power system planning: (1) Feeder remote terminal unit (FRTU) planning strategy by considering the cybersecurity of secondary distribution network in electrical distribution grid, (2) physical-level synthesis for microfluidic lab-on-a-chip, and (3) discrete gate sizing in very-large-scale integration (VLSI) circuit.

First, an optimization technique by cross entropy is proposed to …

Factors Affecting Diporeia Growth Rates In Lake Superior, Miles J. Corcoran

Dissertations, Master's Theses and Master's Reports - Open

An ability to predict population dynamics of the amphipod Diporeia is important in understanding how energy pathways in the Lake Superior food web might be altered by disturbances to the ecosystem. Estimating growth rates for this prominent prey item for fish requires information on the physiological effects of changes to its environment. These effects have been investigated for Diporeia in other Great Lakes, but little is known about Lake Superior populations. The primary objective of this study is to obtain quantitative data for rates of Diporeia respiration and consumption that can be incorporated into a bioenergetics model for Lake Superior. …

Selective Mercury Sequestration From A Silver/Mercury Cyanide Solution, Kristen L. Gabby

Dissertations, Master's Theses and Master's Reports - Open

Silver and mercury are both dissolved in cyanide leaching and the mercury co-precipitates with silver during metal recovery. Mercury must then be removed from the silver/mercury amalgam by vaporizing the mercury in a retort, leading to environmental and health hazards. The need for retorting silver can be greatly reduced if mercury is selectively removed from leaching solutions.

Theoretical calculations were carried out based on the thermodynamics of the Ag/Hg/CN- system in order to determine possible approaches to either preventing mercury dissolution, or selectively precipitating it without silver loss. Preliminary experiments were then carried out based on these calculations to determine …

Electrospun Quaternized Chitosan Fibers For Virus Removal From Drinking Water, Xue Mi

Dissertations, Master's Theses and Master's Reports - Open

Membrane filtration has become an accepted technology for the removal of pathogens from drinking water. Viruses, known to contaminate water supplies, are too small to be removed by a size-exclusion mechanism without a large energy penalty. Thus, functionalized electrospun membranes that can adsorb viruses have drawn our interest. We chose a quaternized chitosan derivative (HTCC) which carries a positively-charged quaternary amine, known to bind negatively-charged virus particles, as a functionalized membrane material. The technique of electrospinning was utilized to produce nanofiber mats with large pore diameters to increase water flux and decrease membrane fouling. In this study, stable, functionalized, electrospun …

Innovative Human-Computer Interactions To Support Cognitive Collaborative Geospatial Environments, Kevin Takala

Dissertations, Master's Theses and Master's Reports - Open

In the current world geospatial information is being demanded in almost real time, which requires the speed at which this data is processed and made available to the user to be at an all-time high. In order to keep up with this ever increasing speed, analysts must find ways to increase their productivity. At the same time the demand for new analysts is high, and current methods of training are long and can be costly. Through the use of human computer interactions and basic networking systems, this paper explores new ways to increase efficiency in data processing and analyst training.

Perspectives On Ict Adoption In Ugandan Schools, Anthony G. Markon

Dissertations, Master's Theses and Master's Reports - Open

This report discusses steps for the integration and adoption of information and communication technologies (ICT) in Uganda schools. Barriers of ICT adoption for teachers were determined through surveys at three schools in Eastern Uganda. Teachers identified lack of familiarity of ICT resources and lack of ICT skills as the two greatest barriers to ICT integration. Administrators and staffs were also interviewed to determine current resources. Through observations, interviews and collected data the report addresses two major ideas, promoting utilization of ICT resources and development of sustainable ICT programs. Promotion of utilization not only relies on overcoming the major barriers listed, …

The Effect Of Eastern Kentucky Coal Fires On Local Air Quality And Personal Health, Eric C. Abbott

Dissertations, Master's Theses and Master's Reports - Open

The purpose of this project was to investigate student learning in the areas of earth science and environmental responsibility using the subject of coal fires. Eastern Kentucky, where this study was performed, has several coal fires burning that affect the local air quality and may also affect the health of people living near them. This study was conducted during the regular education of 9th grade Earth Science classroom in Russell Independent Schools, located in Russell, Kentucky. Students conducted internet research, read current articles on the subject of coal fire emissions and effect on local ecology, and demonstrated what they learned …

The Effects Of Black Locust (Robinia Pseudoacacia L.) On Understory Vegetation And Soils In A Northern Hardwood Forest, Keri A. Deneau

Dissertations, Master's Theses and Master's Reports - Open

No abstract provided.

Sustainable Energy Production In The United States: Life Cycle Assessment Of Biofuels And Bioenergy, Jiqing Fan

Dissertations, Master's Theses and Master's Reports - Open

The United States of America is making great efforts to transform the renewable and abundant biomass resources into cost-competitive, high-performance biofuels, bioproducts, and biopower. This is the key to increase domestic production of transportation fuels and renewable energy, and reduce greenhouse gas and other pollutant emissions.

This dissertation focuses specifically on assessing the life cycle environmental impacts of biofuels and bioenergy produced from renewable feedstocks, such as lignocellulosic biomass, renewable oils and fats. The first part of the dissertation presents the life cycle greenhouse gas (GHG) emissions and energy demands of renewable diesel (RD) and hydroprocessed jet fuels (HRJ). The …