Digital Commons Network^™

Design Of Colloidal Composite Catalysts For Co2 Photoreduction And For Co Oxidation, Bijith D. Mankidy

USF Tampa Graduate Theses and Dissertations

In this doctoral dissertation, novel colloidal routes were used to synthesize nanomaterials with unique features. We have studied the impact of nanoparticle size of catalyst, role of high surface area of a photocatalyst, and the effect of varying elemental composition of co-catalytic nanoparticles in combination with core-shell plasmonic nanoparticles. We have demonstrated how physical and chemical characteristics of nanomaterials with these unique features play a role in catalytic reactions, specifically the oxidation of CO and the photoreduction of CO2. The first objective of this doctoral dissertation involved the preparation of CoO nanoparticles with discrete nanoparticles sizes (1-14 nm) using a …

Parental Leave: Policy And Practice, Amanda Parr

USF Tampa Graduate Theses and Dissertations

Parental leave is a broad term that encompasses maternity and/or paternity leave to care for an infant. Parental leave provides job protection for workers and may be paid or unpaid, with provisions varying throughout the world. Every industrialized nation offers some form of paid parental leave, with the exception of the United States, whose only federal policy regarding parental leave is the Family and Medical Leave Act (FMLA), a law that allows eligible workers to take up to twelve weeks of unpaid, job protected leave for the birth or adoption of a child.

This research project explored how parents understand …

A Preliminary Investigation Of Family Engagement Practices In Schools Implementing Problem-Solving/Response To Intervention (Ps/Rti)., Devon Minch

USF Tampa Graduate Theses and Dissertations

The current study investigated the relationships among level of Problem-Solving/Response to Intervention (PS/RtI) implementation, school factors, educator factors, family factors, and a) educator reports of individual and school-wide practices to engage families, and b) family perceptions of educators' family engagement practices in schools implementing PS/RtI. Survey instruments measuring family engagement in PS/RtI were developed for the current study. Survey data measuring the beliefs about family engagement, perceptions of knowledge and skills for family engagement, and perceptions of family engagement practices were collected from 396 families and 933 educators from 40 schools in a local school district. Findings suggest that PS/RtI …

Enantioselective Brønsted And Lewis Acid-Catalyzed Reaction Methodology: Aziridines As Building Blocks For Catalytic Asymmetric Induction, Shawn E. Larson

USF Tampa Graduate Theses and Dissertations

Chiral molecules as with biological activity are plentiful in nature and the chemical literature; however they represent a smaller portion of the pharmaceutical drug market. As asymmetric methodologies grow more powerful, the tools are becoming available to synthesize chiral molecules in an enantioselective and efficient manner.

Recent breakthroughs in our understanding of phosphoric acid now allow for Lewis acid catalysis via pairing with alkaline earth metals. Using alkaline earth metals with chiral phosphates is an emerging approach to asymmetric methodology, but already has an influential record.

The development of new conditions for the phosphoric acid-catalyzed highly enantioselective ring-opening of meso-aziridines …

Socioscientific Issues: A Path Towards Advanced Scientificliteracy And Improved Conceptual Understanding Of Socially Controversial Scientific Theories, Dean William Pinzino

USF Tampa Graduate Theses and Dissertations

Abstract

This thesis investigates the use of socioscientific issues (SSI) in the high school science classroom as an introduction to argumentation and socioscientific reasoning, with the goal of improving students' scientific literacy (SL). Current research is reviewed that supports the likelihood of students developing a greater conceptual understanding of scientific theories as well as a deeper understanding of the nature of science (NOS), through participation in informal and formal forms of argumentation in the context of SSI. Significant gains in such understanding may improve a student's ability to recognize the rigor, legitimacy, and veracity of scientific claims and better discern …

Water's Dependence On Energy: Analysis Of Embodied Energy In Water And Wastewater Systems, Weiwei Mo

USF Tampa Graduate Theses and Dissertations

Water and wastewater treatment is a critical service provided for protecting human health and the environment. Over the past decade, increasing attention has been placed on energy consumption in water and wastewater systems for the following reasons: (1) Water and energy are two interrelated resources. The nexus between water and energy can intensify the crises of fresh water and fossil fuel shortages; (2) The demand of water/wastewater treatment services is expected to continue to increase with increasing population, economic development and land use change in the foreseeable future; and (3) There is a great potential to mitigate energy use in …

Graphene Casimir Interactions And Some Possible Applications, Anh Duc Phan

USF Tampa Graduate Theses and Dissertations

Scientific development requires profound understandings of micromechanical and nanomechanical systems (MEMS/NEMS) due to their applications not only in the technological world, but also for scientific understanding. At the micro- or nano-scale, when two objects are brought close together, the existence of stiction or adhesion is inevitable and plays an important role in the behavior operation of these systems. Such effects are due to surface dispersion forces, such as the van der Waals or Casimir interactions. The scientific understanding of these forces is particularly important for low-dimensional materials. In addition, the discovery of materials, such as graphitic systems has provided opportunities …

Spatial And Temporal Variability Of Remotely Sensed Ocean Color Parameters In Coral Reef Regions, Daniel Brooks Otis

USF Tampa Graduate Theses and Dissertations

The variability of water-column absorption due to colored dissolved organic matter (CDOM) and phytoplankton in coral reef regions is the focus of this study. Hydrographic and CDOM absorption measurements made on the Bahamas Banks and in Exuma Sound during the spring of 1999 and 2000 showed that values of salinity and CDOM absorption at 440nm were higher on the banks (37.18 psu, 0.06 m^-1), compared to Exuma Sound (37.04 psu, 0.03 m^-1). Spatial patterns of CDOM absorption in Exuma Sound revealed that plumes of CDOM-rich water flow into Exuma Sound from the surrounding banks. To examine absorption variability in reef …

Multi-Time Scales Stochastic Dynamic Processes: Modeling, Methods, Algorithms, Analysis, And Applications, Jean-Claude Pedjeu

USF Tampa Graduate Theses and Dissertations

By introducing a concept of dynamic process operating under multi-time scales in sciences and engineering, a mathematical model is formulated and it leads to a system of multi-time scale stochastic differential equations. The classical Picard-Lindel\"{o}f successive approximations scheme is expended to the model validation problem, namely, existence and uniqueness of solution process. Naturally, this generates to a problem of finding closed form solutions of both linear and nonlinear multi-time scale stochastic differential equations. To illustrate the scope of ideas and presented results, multi-time scale stochastic models for ecological and epidemiological processes in population dynamic are exhibited. Without loss in generality, …

Responses To Chemical Exposure By Foraminifera: Distinguishing Dormancy From Mortality, Benjamin James Ross

USF Tampa Graduate Theses and Dissertations

The Deepwater Horizon blowout in 2010 released an estimated 4.9 million barrels of crude oil into the Gulf of Mexico in the 83 days between the initial explosion and the capping of the well. Response included extensive use of Corexit© oil dispersant. Although South Florida was spared exposure by currents, this event highlights the need for effective bioassay organisms for coral reefs. Amphistegina spp. are benthic foraminifers that host diatom symbionts in a relationship similar to that of coral and their zooxanthellae. Amphistegina spp. occur abundantly in reef communities nearly worldwide, are easily collected and maintained in culture, and are …

Development Of A Bio-Molecular Fluorescent Probe Used In Kinetic Target-Guided Synthesis For The Identification Of Inhibitors Of Enzymatic And Protein-Protein Interaction Targets, Katya Pavlova Nacheva

USF Tampa Graduate Theses and Dissertations

Abstract

Fluorescent molecules used as detection probes and sensors provide vital information about the chemical events in living cells. Despite the large variety of available fluorescent dyes, new improved fluorogenic systems are of continued interest. The Diaryl-substituted Maleimides (DMs) exhibit excellent photophysical properties but have remained unexplored in bioscience applications. Herein we present the identification and full spectroscopic characterization of 3,4-bis(2,4-difluorophenyl)-maleimide and its first reported use as a donor component in Forster resonance energy transfer (FRET) systems. The FRET technique is often used to visualize proteins and to investigate protein-protein interactions in vitro as well as in vivo. The analysis …

Perceived Barriers For Implementing Primary Sexually Transmitted Infection Prevention, Rachel Monique Stewart-Campbell

USF Tampa Graduate Theses and Dissertations

Adolescents continue to be at increased risk for contracting sexually transmitted infections (STI's). This research study describes the perception of barriers that providers in the Tampa Bay area encounter when implementing primary STI prevention programs for adolescents within the community context. This study used semi structured interviews to explore perceived barriers for implementing primary such programs for adolescents in the Tampa Bay area programs. Participants reported faith based institutions/churches and schools as common sectors for presenting a variety of barriers for implementing their program. Perceptions of barriers were described as, the need to tailor program messages and presentations based on …

Dolphin Sound Production And Distribution On The West Florida Shelf, Peter Simard

USF Tampa Graduate Theses and Dissertations

This dissertation is an investigation of dolphin sound production and distribution off west central Florida. Although a wealth of information exists on the production of common sounds (whistles, echolocation) made by captive, trained dolphins, far less is known about free-ranging dolphin sound production and of unusual sounds. In addition, while inshore dolphin populations or communities are the subjects of research projects in many locations, dolphins in offshore waters are less commonly studied. The objectives of this dissertation were to contribute information on free-ranging dolphin sounds and continental shelf dolphin distribution.

While echolocation has been rigorously studied in captive, trained dolphins, …

Improvisational Music Performance: On-Stage Communication Of Power Relationships, David A. Steinweg

USF Tampa Graduate Theses and Dissertations

This project explores how musical improvisational processes come into being through interacting discursive power relationships that are embodied and enacted through performance. By utilizing the concepts of framing and performativity I am able to show how discursive power constitutes the performance of improvisational music. To exemplify this theory, the project presents a case study examining a Grateful Dead cover band named Uncle John's Band that performs at Skipper's Smokehouse in Tampa, FL. Using an ethnographic methodology, the project articulates the dominant discursive power relationships that constitute Uncle John's Band's improvisational performances. The dominant discursive power relationships revolve around the lived …

Optical Detection And Classification Of Phytoplankton Taxa Through Spectral Analysis, Daniel Tyler Sensi

USF Tampa Graduate Theses and Dissertations

Phytoplankton serve as the bottom of the marine food web and therefore play an essential role in marine ecosystems. On the other hand, coastal phytoplankton communities can adversely affect the marine ecosystem and humans. A variety of techniques have been developed to measure and study phytoplankton, including in situ methods (e.g., flow cytometry) and laboratory methods (e.g., microscopic taxonomy). These provide accurate measurements of phytoplankton taxa and concentrations, yet they are limited in space and time, and synoptic information is difficult to obtain with these techniques.

Optical remote sensing may provide complementary information for its synoptic nature, as demonstrated by …

Environmental Change And Place-Based Identities: Sponge Fishing In Tarpon Springs, Florida, Michael Suver

USF Tampa Graduate Theses and Dissertations

Abstract

As the environmental consequences of urbanization and climate change become apparent in coastal communities, it has become important to understand how residents of these communities experience and approach their changing environments. This becomes especially significant in places where nature-based livelihoods constitute a major part of the economy. This thesis focuses on the city of Tarpon Springs, located along the Gulf of Mexico in Florida, where sea sponge fishing is an important contributor to the local economy while also being central to place-based tourist and ethnic identities. It seeks to understand how environmental changes in the sea sponge economy will …

Design Of Novel Inhibitors For Infectious Diseases Using Structure-Based Drug Design: Virtual Screening, Homology Modeling And Molecular Dynamics, Divya Ramamoorthy

USF Tampa Graduate Theses and Dissertations

The main aim of the study in this thesis was to use structure-based protocols to design new drugs for enzymes, DXS and DXR in the non mevalonate pathway. Another aim of this study was to identify the dimer interface in E.coli FabH as an allosteric binding site for designing new class of anti-infective drugs. We have attempted to identify potential inhibitors for DXS by docking the NCI Diversity set compounds, compound libraries available from GSK-MMV and St. Jude's Children's research center. FabH dimer interface has been identified as a potential target using SiteMap, Alanine mutagenesis and docking studies.

The first …

Assessing The Reuse Potential Of Wastewater For Irrigation: The Removal Of Helminth Eggs From A Uasb Reactor And Stabilization Ponds In Bolivia, Matthew Eric Verbyla

USF Tampa Graduate Theses and Dissertations

Extreme hunger, malnutrition, and the lack of access to sanitation are among the most pressing development challenges, but the world is not on track to meet the targets that have been established by the Millennium Development Goals. The integration of wastewater treatment and food production systems allows for the recovery of resources from wastewater, and can provide an important solution to meet the sanitation needs of growing urban populations and provide periurban farmers with a consistent supply of water and nutrients. Stabilization ponds have been long considered to be an appropriate technology for wastewater reuse systems in developing countries, but …

Remote Sensing Of Whitings In The Bahamas, Ryan Allen Lloyd

USF Tampa Graduate Theses and Dissertations

Whitings on both the Great Bahama Bank (GBB) and Little Bahama Bank (LBB) were evaluated using data collected from 2000-2010 by the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments onboard the Terra and Aqua satellites. A semi-objective method was developed to classify whiting patches from other look-alike features using the recently developed Floating Algae Index (FAI) algorithm, an empirical cloud masking algorithm, and a gradient analysis from the 250-m resolution MODIS data. A total of 1,500 images with minimal cloud cover was used to calculate long-term and seasonal trends as well as an average daily coverage for both banks. Annual and …

Ontogeny And Littoral Structure Of Lakes Created On Phosphate Mined Lands Of Central Florida, Chrysoula Mitraki

USF Tampa Graduate Theses and Dissertations

Created lakes are an end product of phosphate mining in Florida. Beginning in 1975, Florida reclamation rules set criteria for phosphate created lakes aiming to approximate the structure of natural lakes, and emphasizing extensive littoral zones with both emergent and submersed vegetation.

Lake development relative to lake age and design were examined for 22 phosphate lakes representing a 40-year age trajectory, utilizing water quality and benthic invertebrate communities from littoral and deep-water locations (Chapter 1). The relative importance of morphometry and lake age in the development of littoral plant communities was examined using multiple vegetation surveys throughout the year, in …

Study On The Microstructure Of African Wild Silk Cocoon Shells And Fibers, Addis Teshome, Fritz Vollrath, Suresh K. Raina, J. M. Kabaru, J. Onyari

All Peer-Reviewed Publications

Silk fibers and cocoon shells from four African wild silkmoths Gonometa postica, Anaphe panda, Argema mimosae and Epiphora bauhiniae-were studied to gain insight into the structure-property-function relations and potential commercial application. The surface and cross-section of cocoon shells and fibers revealed the presence of prominent structural variations. Cocoon shells were multilayered and porous structures constructed from highly cross-linked fibers that are densely packed within the sericin/gum. Fibers had fibrillar sub-structures running along the fiber axis and with greater number and size of voids. The ecological significance and implication of these structures for further application are discussed. © 2011.

Impaired Cleanance And Enhanced Pulmonary Inflammatory/Fibrotic Response To Carbon Nanotubes In Myeloperoxidase-Deficient Mice, Anna A. Shvedova, Alexandr A. Kapralov, Wei Hong Feng, Elena R. Kisin, Ashley R. Murray, Robert R. Mercer, Claudette M. St. Croix, Megan A. Lang, Simon C. Watkins, Nagarjun V. Konduru, Brett L. Allen, Jennifer Conroy, Gregg P. Kotchey, Bashir M. Mohamed, Aidan Meade, Yuri Volkov, Alexander Star, Bengt Fadeel, Valerian E. Kagan

Articles

Advancement of biomedical applications of carbonaceous nanomaterials is hampered by their biopersistence and pro-inflammatory action in vivo. Here, we used myeloperoxidase knockout B6.129X1-MPO (MPO k/o) mice and showed that oxidation and clearance of single walled carbon nanotubes (SWCNT) from the lungs of these animals after pharyngeal aspiration was markedly less effective whereas the inflammatory response was more robust than in wild-type C57Bl/6 mice. Our results provide direct evidence for the participation of MPO – one of the key-orchestrators of inflammatory response – in the in vivo pulmonary oxidative biodegradation of SWCNT and suggest new ways to control the biopersistence …

Effects Of Four Commercially Available Fxa Proteins On The Fluorogenic Anti-Fxa Assay When Monitoring Unfractionated Heparin, Vanessa Castro-Lopez, Brian Murray, Leanne F. Harris, James S. O'Donnell, Anthony J. Killard

Articles

Four commercially available Factor Xa (FXa) reagents were evaluated in a fluorogenic anti-FXa assay. The four reagents - of which three were of human origin and the fourth was bovine - were compared in terms of the resulting assay dynamic ranges, lag times, CV and R2 values, sum of squares as well as their sensitivity to unfractionated heparin (UFH) within the therapeutic range of 0-1.2 U mL-1. Based on a balance of performance characteristics, an optimum reagent was selected which had the best combination of all parameters. The best performing serine endopeptidase in the fluorogenic anti-FXa assay was found to …

Tactics In Philanthropy: The Case Of The Moving Spotlight, Dan M. Martin

The Foundation Review

· In recent years, strategy has been a muchdiscussed topic in philanthropy, while tactics have received little attention.

· The experience of the MacArthur Foundation’s environmental program and its Moving Spotlight approach provide examples of the importance of tactical decisions.

· Tactical decisions such as the timing of grants, foundation staffing levels, and the timing of evaluations all contribute to grantees’ ability to achieve outcomes.

· Structure and flexibility can be complementary approaches to grantmaking if the tactics are well thought out.

Table Of Contents

Georgia Law Review

No abstract provided.

Recipes Of Resolve: Food And Meaning In Post-Diluvian New Orleans, Jessica Claire Menck

Antioch University Dissertations & Theses

In 2005 the city of New Orleans experienced catastrophic flooding as a result of the failure of the federal levee system following Hurricane Katrina. This was an immediate disaster that evolved into a longer-term crisis as the city, state, and national government struggled to respond to the event. This study focuses on one part of managing crisis: meaning making. Specifically, the study investigates meaning making within the food community of New Orleans, asking the questions: is food a way for individuals and groups to make meaning following critical change events such as the failure of the federal levee system in …

Homeless Mothers As Parent Leaders, Dorothy Ann Milligan

Antioch University Dissertations & Theses

Presents a qualitative study examining the general conditions that lead to single mother homelessness and the impact of being homeless on their ability to parent effectively, based on interviews with mothers who are clients of First Place, a Seattle, Washington, social service agency. The purpose of the study is to identify different paths of life stabilizing strategies and parenting of women who have been in touch with the same agency. The research attempts to determine how the mothers achieved stability amid daily stress through examination of how the stories reflect decisions, initiatives, and commitments that helped them reach a level …

Women's Leadership In Philanthropy: An Analysis Of Six Giving Circles, Deborah A. Witte

Antioch University Dissertations & Theses

Women have played an essential role in the development of philanthropy in the United States. While their giving behavior and financial contributions have been studied extensively, other aspects of their philanthropy-namely leadership-have not been documented as completely. The giving circle-a new trend within philanthropy where groups of individuals pool their money, and through educating themselves about issues in their community, decide together where to award their funds-provides an ideal case for this study, as the majority of giving circle members are women. In order to gain a better understanding of women's leadership, focus groups were conducted with more than 35 …

Facilitating Emergence: Complex, Adaptive Systems Theory And The Shape Of Change, Peter Martin Dickens

Antioch University Dissertations & Theses

This study used Principal Component Analysis to examine factors that facilitate emergent change in an organization. As organizational life becomes more complex, today’s dominant management paradigms no longer suffice. This is particularly true in a health care setting where multiple sources of disease interacting with each other meet with often-competing organizational priorities and accountabilities in a highly complex world. This study identifies new ways of approaching complexity by embracing the capacity of complex systems to find their own form of order and coherence. Based on a review of the literature, interviews with hospital CEOs, and my organization development practice experience …

Millennial Integration: Challenges Millennials Face In The Workplace And What They Can Do About Them, Chip Espinoza

Antioch University Dissertations & Theses

There is a monumental changing of the guard that is currently taking place in organizations due to demographic metabolism. One of the largest birth cohorts or generations in history (Baby Boomer) is beginning to retire while their predecessor (Builder) is almost completely out of the workforce. Gen X is hitting stride and on the cusp of inheriting the proverbial organizational mantle. The three aforementioned age cohorts have learned to play in the organizational sandbox together. However, a new age cohort (Millennial, a.k.a. Gen Y), equal or greater in size to the Baby Boomer cohort started entering the playground approximately ten …