Digital Commons Network^™

The Role Of Microvascular Complications In The Relationship Between Glycemic Control And Depressive Symptomatology In Patients With Type 1 Diabetes: A Mediational Study, Laura Lynn Mayhew

USF Tampa Graduate Theses and Dissertations

People with diabetes are at double the risk of developing depression. Depression is associated with increased morbidity and mortality in people with diabetes. Levels of A1c have been linked to microvascular complications (e.g., retinopathy, nephropathy, and neuropathy) as well as depression. The interrelationship between A1c, microvascular complications, and depression has not previously been investigated in a comprehensive model, and a better understanding of the nature of these associations is needed. Preliminary analyses test the assumption that A1c mediates the relationship between group assignment in the Diabetes Control and Complications Trial (DCCT) and microvascular complications. The primary purpose of the study …

A Swmm-5 Model Of A Denitrifying Bioretention System To Estimate Nitrogen Removal From Stormwater Runoff, Michelle D. Masi

USF Tampa Graduate Theses and Dissertations

This research estimates nitrogen removal from stormwater runoff using a denitrifying bioretention system using the USEPA Storm Water Management Model Version 5 (SWMM-5). SWMM-5 has been used to help planners make better decisions since its development in 1971. A conventional bioretention system is a type of Low Impact Development (LID) technology, which designed without a media layer specifically for achieving nitrogen removal. More recently studies have showed that high TN removal efficiencies are possible when incorporating a denitrification media layer. These systems are known as denitrifying bioretention systems, or alternative bioretention systems. LID projects are currently being designed and developed …

Natural Product Drug Discovery Against Tropical Diseases, Wai Sheung Ma

USF Tampa Graduate Theses and Dissertations

This dissertation describes the isolation of secondary metabolites from natural origins through a series of chromatographic techniques and spectrometric characterization in the effort of drug discovery. The isolated compounds obtained were used as drug leads against tropical diseases, namely malaria and leishmaniasis. While first chapter offers an introduction on the use of a natural product by itself as an effective therapeutic and its role on inspiring the discovery of new drugs, the later chapters will concentrate on isolation and characterization of bioactive natural products from an Antarctic sponge and mangrove endophytic fungi during the dissertation work.

The second chapter describes …

A House But Not A Home? Measuring "Householdness" In The Daily Lives Of Monticello's "Nail Boys", Shannon Lee Mcvey

USF Tampa Graduate Theses and Dissertations

Monticello, the plantation home of Thomas Jefferson, was also home to more than 100 African American slaves between 1771 and 1826. As many as 40 members of this community lived and worked on Mulberry Row, once a bustling avenue of residential and industrial activity adjacent to the Palladian mansion. Archaeological excavations in 1957 and 1982–-1983 uncovered the remains of Mulberry Row's nailery, where preteen and teenaged enslaved "“nail boys”" manufactured nails for internal use and sale. These excavations revealed surprisingly high amounts of domestic artifacts, particularly ceramics and glass, indicating the young nailers also may have lived inside the nailery. …

Chemical Investigation Of The Antarctic Marine Invertebrates Austrodoris Kerguelenensis & Dendrilla Membranosa And The Antarctic Red Alga Gigartina Skottsbergii, John Alan Maschek

USF Tampa Graduate Theses and Dissertations

The marine realm and, in particular, the Antarctic benthos is largely unexplored and understudied. The chemical investigation reported herein reveals not only the biodiversity, but how that biodiversity manifests remarkable chemical diversity. In our continuing study of the nudibranch Austrodoris kerguelenensis, we have isolated a diverse suite of diterpenoid glyceride esters, palmadorins D - S (2.32 - 2.47), one of which is the first reported halogenated diterpene from a dorid nudibranch. Utilizing genomic data from collaborators, we have investigated the chemical diversity from phylogenetically unique specimens collected in close proximity to one another. Chemical groupings based on comparison of LC/MS …

Cold War Playboys: Models Of Masculinity In The Literature Of Playboy, Taylor Joy Mitchell

USF Tampa Graduate Theses and Dissertations

"Cold War Playboys: Models of Masculinity in the Literature of Playboy" emphasizes the literary voices that emerged in response to the Cold War's redefinitions of space and sexuality and, thus, adds to the growing national discourse of Cold War literary and masculinity studies. I argue that the literature Playboy includes has always been a necessary feature to creating its masculinity model; however, that very literature often destabilizes the magazine's grand narrative because it presents readers with alternative models of masculinity. To make that argument, I presume five things: 1) masculinity, like femininity, is a construct; 2) the mid-century masculinity …

Translation And Adaptation Of The Center For Epidemiologic Studies-Depression (Ces-D) Scale Into Tigrigna Language For Tigrigna Speaking Eritrean Immigrants In The United States, Mulubrhan Fisseha Mogos

USF Tampa Graduate Theses and Dissertations

Depression is one of the oldest known mental health conditions. It is acknowledged to be a global health problem that affects people from any culture or ethnic group. The prevalence of depression widely varied across countries and cultures. The cross-cultural relevance of the concept of depression, its screening or diagnosis, and cultural equivalence of items used to measure symptoms of depression has been area of research interest. Differences in prevalence rates in depression have been suggested as being due to research artifacts, such as use of instrument developed for one culture to another culture. With the current trend of globalization …

Investigation Of The Optimal Dissolved Co2 Concentration And Ph Combination For The Growth Of Nitrifying Bacteria, Raymond Anthony Morris

USF Tampa Graduate Theses and Dissertations

Ammonium (NH₄⁺) is a biological nutrient that is transformed in a wastewater treatment plant (WWTP) in a process called activated sludge. This is accomplished in an aerobic environment using microorganisms and inorganic carbon that convert the ammonium to nitrate (NO₃^-). This process is termed nitrification. Removal of ammonium is necessary due to its oxygen demand and toxicity to the environment.

Nitrification is considered a slow process due to the slow growth rate of the nitrifying bacteria. Ammonia oxidizing bacteria (AOB) first covert the ammonium (NH₄⁺) to nitrite (NO₂^-) …

Crystal Engineering Of Pharmaceutical Cocrystals, Sreya Mukherjee

USF Tampa Graduate Theses and Dissertations

Pharmaceutical cocrystals use principles of crystal engineering for the design of crystalline forms of drugs and can improve their solubility, bioavailability, stability and other important properties without changing the efficacy of the drug. Herein reported are pharmaceutical cocrystals of two API's, caffeine and Pentoxifylline.

Research has indicated that caffeine has the ability to reverse AB; plaque deposition in the brain (believed to be the primary cause of Alzheimer's pathogenesis) and thus revert memory and improve cognitive impairment. But owing to the fast absorption rate and short half life, a controlled release formulation of caffeine would be clinically beneficial. Thus, novel …

Environmental Health In The Latin American And Caribbean Region: Use Of Water Storage Containers, Water Quality, And Community Perception, Erlande Omisca

USF Tampa Graduate Theses and Dissertations

Water quality and availability are important issues in many developing countries where portions of populations still lack access to potable water. Throughout the English-speaking Caribbean and parts of Latin America, households and businesses invest in water supply systems even when they are connected to and pay for water services from a private or state owned provider. Inconsistent supplies of water from the water companies have led many people to invest in storage tanks which, if operated correctly, can provide water throughout the day even when the supply from the main is low or zero. While these individual systems help to …

An Examination Of The Impacts Of Urbanization On Green Space Access And Water Resources: A Developed And Developing World Perspective, Heather E. Wright Wendel

USF Tampa Graduate Theses and Dissertations

This dissertation addresses the impact of urbanization and land use change on the availability and accessibility of two urban amenities that are often inequitably distributed: green space and water features. Diverse methodologies were utilized in order to gain a better understanding of the role of these amenities in improving urban quality of life and integrated water management. Using an interdisciplinary approach, this research provides a unique perspective within both a developed and developing world context by evaluating aspects of urbanization to emphasize more sustainable and integrated approaches to development.

A preliminary analysis highlights potential drivers of green space revitalization in …

Surface Functionalization And Analysis Thereof For An Ovarian Cancer Diagnostic Biosensor, Asad Ali Ahmad

USF Tampa Graduate Theses and Dissertations

Ovarian cancer is the fifth leading cause of cancer death among women in United States and has an alarming 1.4% (1 in 71) lifetime risk. The lack of overt symptoms and the absence of a reliable screening test to detect ovarian cancer result in over 70% of women being diagnosed after the disease has spread beyond the ovary resulting in a poor prognosis. A key characteristic of ovarian cancer is the ability of tumor cells to evade apoptosis, or programmed cell death contributing to the limitless replicative potential, which is a hallmark of all carcinogenesis. There is conclusive evidence that …

Contextualizing Hiv/Aids Prevention And Treatment Programs In Zanzibar, Tanzania, Naheed Ahmed

USF Tampa Graduate Theses and Dissertations

International aid organizations and wealthy nations have contributed billions to combat the spread and treatment of HIV/AIDS in sub-Saharan Africa; however, these programs have been critiqued for not addressing the socioeconomic and cultural context of the epidemic, instead relying upon generalized approaches. The prevalence rate in Zanzibar, Tanzania is low in the general population, but high among vulnerable segments of Zanzibari society, resulting in interventions focusing on particular groups (e.g. sex workers, drug users, and men who have sex with men). Through interviews with government agencies, non-profit organizations, medical professionals, vulnerable populations, and HIV/AIDS patients, this paper examines how local …

Sol-Gel Resorcinarene Sorbent For Capillary Microextraction Coupled To Gas Chromatography, Abdullah Awadh Alhendal

USF Tampa Graduate Theses and Dissertations

For the first time, octahydroxyl methylresorcinarene with four hexyl groups on the lower rim was utilized in the in-situ preparation of a silica-based sol-gel organicinorganic hybrid coating for sample preconcentration by capillary microextraction (CME). Tetraethoxysilane (TEOS) was chosen as a sol-gel precursor to create a crosslinked sol-gel network via acid-catalyzed hydrolytic polycondensation reactions. Sol-gel chemistry helped in the in situ preparation of resorcinarene-containing extraction phase in the form of a surface coating. It also provided an effective means to chemically bind the coating to the inner surface of fused silica capillary via condensation of the hydroxyl groups in the sol-gel …

A Case Study Of Adolescent Females' Perceptions Of Identity In An After-School Book Club, Holly Atkins

USF Tampa Graduate Theses and Dissertations

Reading is a perennial educational hot topic - but now extends for beyond early literacy to the secondary level. Reading researchers are growing in our knowledge of how to reach and teach struggling adolescent readers yet too often success in literacy is measured solely by performance on standardized tests. Literacy is seen on one hand as a one-dimensional set of skills students need to possess to be successful in school and their future workplaces. A more expansive view of the importance of literacy and what it means to adolescent females' growth as individuals and members of communities is needed.

This …

Identification And Characterization Of The Human Herpesviruses 6a And 6b Genome Integration Into Telomeres Of Human Chromosomes During Latency, Jesse Herbert Arbuckle

USF Tampa Graduate Theses and Dissertations

While the latent genome of most Herpesviruses persists as a nuclear circular episome, previous research has suggested that Human Herpesvirus 6 (HHV-6) may integrate into host cell chromosomes, and be vertically transmitted in the germ-line. Because the HHV-6 genome encodes a perfect TTAGGG telomere repeat array at the right end direct repeat (DR_R) and an imperfect TTAGGG repeat at the end of the left end direct repeat (DR_L), we established a hypothesis that during latency, the HHV-6A and HHV-6B genome integrates into the telomeres of human chromosomes through homologous recombination with the n(TTAGGG) viral repeats, and …

The Relationships Between Frontal Alpha Asymmetry, Mood, And Emotional Memory, Ross Avila

USF Tampa Graduate Theses and Dissertations

Frontal alpha asymmetry is often used as a metric to compare activation between homologous frontal brain sites. A positive asymmetry refers to greater activation in the left hemisphere than in the right hemisphere, while the opposite is true of negative asymmetries. Two expansive but largely separate bodies of research have examined the relationships between (1) frontal asymmetry scores and mood, and (2) mood and emotional memory performance. Specifically, one body of research has found that positive moods are associated with positive asymmetries while negative moods are associated with negative asymmetries. A second body of literature has examined the effects of …

Giving Meaning To Grief: The Role Of Rituals And Stories In Coping With Sudden Family Loss, Julia Janelle Barnhill

USF Tampa Graduate Theses and Dissertations

In this dissertation, I seek to better understand the sensemaking process among surviving family members after a tragic loss of a teenage or young adult child. Using social constructionism (Gergen, 1991) as a theoretical framework, I focused on how meanings of loss are constructed through the use of language and other symbols. I specifically looked at the role of family stories and rituals in making sense of the sudden loss as well as how a survivor's role as a sibling or parent may impact the grieving process. The participants in my research were all members of families in which a …

Synthesis And Characterization Of Self-Healing Poly (Carbonate Urethane) Carbon-Nanotube Composites, Roger Wesley Bass

USF Tampa Graduate Theses and Dissertations

Synthesis of high molar mass polycarbonate polyurethanes using a novel polyol is described. The resulting elastomers demonstrate excellent mechanical properties as well as the capability to re-heal after rupture without the addition of additives or imbedded healing agents. The self-healing functionality is shown to greatly improve with the addition of up to 1% single and multi-walled carbon nanotubes. The interface of the carbon nanotubes and self-healing polymer are probed using Raman techniques and provide an insight into how the self-healing actions are improved with the addition of carbon nanotubes.

Synthesis of polycarbonate polyurethanes and carbon nanotube composites using a novel …

The Virtuoso Human: A Virtue Ethics Model Based On Care, Frederick Joseph Bennett

USF Tampa Graduate Theses and Dissertations

The goal of this thesis is to develop the foundation and structure for a virtue ethics theory grounded in a specific notion of care. While there has been a recent revival of interest in virtue ethics theory, the theory has its roots in Aristotle's work as well in the medieval writings of Thomas Aquinas. Aquinas worked out many of Aristotle's ideas in much more detail. However, while Aquinas offers a very rich and compelling ethical theory, it is problematic because it is very tightly wrapped in his theology. A key component in Aquinas's theory is charity. Charity is one of …

Influence Of Temperature On Yolk Resorption By Centropomus Undecimalis Larvae, Claudia Catalina Baron-Aguilar

USF Tampa Graduate Theses and Dissertations

In an effort to determine the optimal temperature for rearing Centropomus undecimalis larvae during the yolk resorption period, larval development was measured under four different temperature regimes (23, 25, 28 and 31 °C). The eggs were incubated at 28 °C until hatching, which occurred at about 17 hours post-fertilization. After hatching, temperatures were adjusted to the respective treatment levels. Measurements were collected from 25 individual larvae across rearing temperatures at the following pre-determined time intervals: at hatching, 24 hours post hatch (hph), 48 hph, and 72 hph. Morphometric measurements were obtained from photomicrographs, including yolk sac length and height, oil …

Development Of An Elisa For Eastern Equine Encephalitis Virus That Can Differentiate Infected From Vaccinated Horses, Andrea Bingham

USF Tampa Graduate Theses and Dissertations

Eastern Equine Encephalitis virus (EEEV) causes a fatal mosquito-borne virus that is vaccine preventable for horses. The conventional serological tests measure antibodies to the structural proteins of EEEV which are also found in the vaccine. This makes it difficult to differentiate infected and vaccinated animals (DIVA). Detection of antibodies to non-structural proteins (NSPs) is a theoretical strategy that would allow you to survey natural infections among vaccinated populations. This test would also allow for more accurate representations of the natural infection rate, vaccination rate, and help identify vaccine failures. The potential uses of the NSPs of Eastern Equine Encephalitis virus …

Assessment Of A Countywide Stormwater Pond Improvement Project: Impacts Of The Hillsborough County Adopt-A-Pond Program, Anthony Thomas Betts

USF Tampa Graduate Theses and Dissertations

Comparative research was conducted to assess the environmental impacts of the Adopt-a-Pond program, which operates throughout Hillsborough County, Florida. The Adopt-a-Pond program was established in 1992 and designed to address nonpoint pollution through outreach and stormwater pond enhancement. However, the program had never been thoroughly and scientifically evaluated. Therefore, assessments of water quality and vegetative characteristics were made at ninety Adopt-a-Pond participants and eleven control ponds to explore the potential impacts of the program on measurable environmental parameters. Statistical analysis of the results failed to demonstrate any statistically significant environmental improvements associated with the Adopt-a-Pond program, and measures of program …

_Alien_ Thoughts: Spectatorial Pleasure And Mind Reading In Ridley Scott's Horror Film, Cecilia Madeline Bolich

USF Tampa Graduate Theses and Dissertations

Pleasure experienced in an unpleasant film genre, like horror, has prompted numerous discussions in film studies. Noted scholars like Carol J. Clover and Noël Carroll have rationalized spectatorial enjoyment of a genre that capitalizes on human anxieties and complicates cultural categories. Clover admits that horror initially satisfies sadistic tendencies in young male viewers but then pushes them to cross gender lines and identify with the strong female heroine who defeats the film's threat. Carroll provides a basic explanation, citing spectators' cognitive curiosity as the source of pleasure. Both scholars are right to consider emotional, psychological, and cognitive experiences felt by …

Automated Quantification Of Biological Microstructures Using Unbiased Stereology, Om Pavithra Bonam

USF Tampa Graduate Theses and Dissertations

Research in many fields of life and biomedical sciences depends on the microscopic image analysis of biological images. Quantitative analysis of these images is often time-consuming, tedious, and may be prone to subjective bias from the observer and inter /intra observer variations. Systems for automatic analysis developed in the past decade determine various parameters associated with biological tissue, such as the number of cells, object volume and length of fibers to avoid problems with manual collection of microscopic data. Specifically, automatic analysis of biological microstructures using unbiased stereology, a set of approaches designed to avoid all known sources of systematic …

Placing Reedy Creek Improvement District In Central Florida: A Case Study In Uneven Geographical Development, Kristine Bezdecny

USF Tampa Graduate Theses and Dissertations

This study is primarily about the theory of uneven geographical development. In an era when it is proclaimed that, through globalization, the world has become flat, the unevenness of economic and social development is often overlooked or suppressed. As the nexus between global and local processes, the urban space often becomes the site of conflict between those defining the hegemonic narrative of the space, from a global and flat perspective; and those experiencing heterogenous local narratives, whose uneven positions are reinforced by this hegemonic narrative.

This study explores the conditions of uneven geographical development in the urban space of central …

Urban Greenways: The Case For The Selmon Greenway, Alana Brasier

USF Tampa Graduate Theses and Dissertations

Across the country and world, cities are building urban greenways to achieve environmental, economic, and social objectives. Greenways are recreational trails that provide functions beyond recreation, such as stormwater management, economic development, community development, and aesthetic improvements. A plan to build an urban greenway in downtown Tampa is underway. The greenway is proposed to be built underneath and adjacent to the Selmon Expressway, in conjunction with a widening and redecking project. A feasibility study was performed and approved by the Hillsborough County Metropolitan Planning Organization; now the biggest hurdle standing in the way of the Selmon Greenway is finding funding. …

Initial Ablation Of The Laurentide Ice Sheet Based On Gulf Of Mexico Sediments, Elizabeth A. Brown

USF Tampa Graduate Theses and Dissertations

The objective of this project is to reconstruct a picture of initial Laurentide Ice Sheet retreat at the end of the Last Glacial Maximum (LGM) using geochemical proxies in Gulf of Mexico sediments, and place the reconstruction into global perspective. The project asks two questions. (1) Can a time frame be established for initial retreat of the Laurentide Ice Sheet? (2) If so, how does the timing compare to that of other large ice sheets and mountain glaciers in both hemispheres?

Sediment core MD02-2550 from the anoxic Orca Basin offers excellent preservation and a high sediment accumulation rate. Twelve accelerator …

An Examination Of The Impact Of Preconception Health On Adverse Pregnancy Outcomes Through The Theoretical Lens Of Reciprocal Determinism, Mary Elizabeth Buie

USF Tampa Graduate Theses and Dissertations

Statement of Purpose

The purpose of this study is to examine the impact of preconception health on adverse pregnancy outcomes through the theoretical lens of reciprocal determinism. Thus, this study aims to develop a preconception health conceptual framework that accounts for the interactive relationships among behavior, the environment, and the person.

Rationale for the Study

Women may not recognize a pregnancy until the first or second missed menstrual cycle, a full four to eight weeks or more after conception. Once a woman realizes the possibility of a pregnancy, it takes further time to confirm the pregnancy with a home pregnancy …

A Structural Equation Analysis Of Family Accommodation In Pediatric Obsessive-Compulsive Disorder, Nicole Elise Caporino

USF Tampa Graduate Theses and Dissertations

Family accommodation of symptoms conflicts with the primary goals of cognitive-behavioral therapy for pediatric obsessive-compulsive disorder (OCD) and can be an obstacle to positive outcomes. This study examined a structural equation model of parent and child variables related to family accommodation using a sample of 65 parent-child dyads recruited from a university-based clinic. Additionally, parents' motivations for engaging in accommodation were explored. Results generally supported the hypothesized model. Family accommodation mediated the relationship between OCD symptom severity and parent-rated functional impairment, child internalizing problems mediated the relationship between parent anxiety and family accommodation, and parent empathy and consideration of future …