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2011

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The Investigation Of Antimicrobial Activity Of Thyme And Oregano Essential Oils, Bülent Çeti̇n, Songül Çakmakçi, Ramazan Çakmakçi Jan 2011

The Investigation Of Antimicrobial Activity Of Thyme And Oregano Essential Oils, Bülent Çeti̇n, Songül Çakmakçi, Ramazan Çakmakçi

Turkish Journal of Agriculture and Forestry

The aim of this study is to investigate in-vitro antimicrobial effects of the essential oils from oregano (Origanum acutidens and Origanum rotundifolium) and thyme (Thymus sipyleus subsp. sipyleus var. rosulans). The chemical composition and antimicrobial attributes of the essential oils obtained from the aerial parts of the plants, of which there were 3 Lamiaceae species, have been studied. A total of 43 microorganisms, including 26 bacteria, 14 fungi, and 3 yeasts species, have been studied by using disc-diffusion (DD) and minimal inhibition concentration (MIC) methods. Mean inhibition zones and MIC values of bacterial strains varied from 8 and 72 mm …


Clonal Propagation And Cryogenic Storage Of Virus-Free Grapevine (Vitis Vinifera L.) Via Meristem Culture, Mohamad Shatnawi, Ghandi Anfoka, Rida Shibli, Mohammed Al-Mazra'awi, Wesam Shahrour, Areej Arebiat Jan 2011

Clonal Propagation And Cryogenic Storage Of Virus-Free Grapevine (Vitis Vinifera L.) Via Meristem Culture, Mohamad Shatnawi, Ghandi Anfoka, Rida Shibli, Mohammed Al-Mazra'awi, Wesam Shahrour, Areej Arebiat

Turkish Journal of Agriculture and Forestry

A protocol for production of virus-free Vitis vinifera using meristem culture was developed. Meristems (0.1-0.2 mm) of V. vinifera infected with grapevine fanleaf virus and grape leafroll associated viruses were excised from 1-year-old growing vines. Shoot tips were cultured on half-strength Murashige and Skoog (MS) medium, supplemented with 0.02 mg L^{-1} of benzylaminopurine (BAP) and 0.01 mg L^{-1} of naphthalene acetic acid (NAA). BAP and kinetin resulted in differences in the number of new shoots per explant, shoot height, and number of new leaves per explant. BAP at 0.8 mg L^{-1} gave the highest in vitro multiplication rate, with 5.25 …


Cover And Contents Jan 2011

Cover And Contents

Turkish Journal of Agriculture and Forestry

No abstract provided.


Interactions Between Rural Migration And Land Use Change In The Forest Villages In The Gökçay Watershed, Ceyhun Göl, Sezgi̇n Özden, Hüseyi̇n Yilmaz Jan 2011

Interactions Between Rural Migration And Land Use Change In The Forest Villages In The Gökçay Watershed, Ceyhun Göl, Sezgi̇n Özden, Hüseyi̇n Yilmaz

Turkish Journal of Agriculture and Forestry

This study was carried out to analyze the spatial and temporal pattern of land use/land cover change (from 1955 to 2008) and migration movement (from 1935 to 2007) in the Gökçay River Watershed. To assess this period, the necessary data were obtained from forest stand maps (1955 and 2008) and evaluated by using Geographic Information Systems. Maps of the study area dated 1955 and 2008 have been analyzed, and land use type and change on the land pattern have been investigated. The data reveal that the percentage of forest area, which was 47% in 1955, rose to 50% in 2008; …


Effect Of Acid Scarification And Cold Moist Stratification On The Germination Of Cercis Siliquastrum L. Seeds, Elias Pipinis, Elias Milios, Pavlos Smiris, Christos Gioumousidis Jan 2011

Effect Of Acid Scarification And Cold Moist Stratification On The Germination Of Cercis Siliquastrum L. Seeds, Elias Pipinis, Elias Milios, Pavlos Smiris, Christos Gioumousidis

Turkish Journal of Agriculture and Forestry

Dormancy in Cercis siliquastrum seeds is due to the hard, impermeable seed coat and inhibition by endosperm. The effects of acid scarification, cold moist stratification, and the combination of both on breaking dormancy and enhancing seed germination were evaluated. Seeds were scarified with concentrated (95%-97%) sulfuric acid for various times (0, 20, 40, and 60 min), followed by cold moist stratification for 0, 1, 2, 3, or 4 months. Unscarified seeds did not germinate whether they were stratified (up until 4 months) or not. Similarly, seeds that were scarified (20, 40, and 60 min) and then stratified for 0 or …


Total Carbon Stocks And Carbon Accumulation In Living Tree Biomass In Forest Ecosystems Of Turkey, Doğanay Tolunay Jan 2011

Total Carbon Stocks And Carbon Accumulation In Living Tree Biomass In Forest Ecosystems Of Turkey, Doğanay Tolunay

Turkish Journal of Agriculture and Forestry

In this study, the carbon stocks of forests of Turkey were examined by taking the national forest inventory completed in 2004 as a basis. Furthermore, the annual accumulations of carbon in the above- and below-ground biomass of Turkey were also investigated according to the gain-loss methods of "Agriculture, Forestry and Other Land Use" (AFOLU), published in 2006. The results of estimates showed that the total stock in all carbon pools (above- and below-ground, dead wood, litter, and soil) in the forests of Turkey was 2251.26 Tg C in 2004. Of that total carbon stock, 74.78% was in soil, 21.32% in …


Rooting Behaviour, Polyphenol Oxidase Activity, And Biochemical Changes In Grape Rootstocks At Different Growth Stages, Ramhari G. Somkuwar, Devanand D. Bondage, Manisha S. Surange, Sahadeo D. Ramteke Jan 2011

Rooting Behaviour, Polyphenol Oxidase Activity, And Biochemical Changes In Grape Rootstocks At Different Growth Stages, Ramhari G. Somkuwar, Devanand D. Bondage, Manisha S. Surange, Sahadeo D. Ramteke

Turkish Journal of Agriculture and Forestry

Four grape rootstocks belonging to different Vitis species were planted in September. Rooting behaviour, polyphenol oxidase (PPO; EC 1.14.18.1) activity and biochemical parameters were studied at different growth stages after planting the cuttings in polythene bags. Significant differences were recorded for rooting success among the different rootstocks, with the maximum sprouting percentage determined in the Freedom rootstock. The highest variation in PPO activity was also recorded in Freedom. High PPO activity was recorded in rootstock 140 Ru, while the highest root length was recorded in Dog Ridge. In the rootstock 110 R, the PPO activity was the lowest during the …


Effect Of Different Irrigation Water Salinities On Some Yield And Quality Components Of Two Field-Grown Cucurbit Species, Li Zong, Anna Tedeschi, Xian Xue, Tao Wang, Massimo Menenti, Cuihua Huang Jan 2011

Effect Of Different Irrigation Water Salinities On Some Yield And Quality Components Of Two Field-Grown Cucurbit Species, Li Zong, Anna Tedeschi, Xian Xue, Tao Wang, Massimo Menenti, Cuihua Huang

Turkish Journal of Agriculture and Forestry

Using irrigation water with a salinity level of 0.8, 2, and 5 g L^{-1}, the impact of saline water irrigation on the yield and quality of 2 Chinese Cucurbit species, melon (Cucumis melo cv. Huanghe) and watermelon (Citrullus lanatus. convar megulaspemus) were studied in Minqin Oasis, northwestern China. Our results show that melon yields decreased as water salinity increased, just as concentrations of glutamic acid content rose, although the concentration of most amino acids did not differ significantly. In contrast, watermelon yields decreased significantly as water salinity rose, and fruit number, fruit firmness, fruit crude protein, and essential amino acid …


Cover And Contents Jan 2011

Cover And Contents

Turkish Journal of Agriculture and Forestry

No abstract provided.


Production Of Cellulase By Pleurotus Ostreatus And Pleurotus Sajor-Caju In Solid State Fermentation Of Lignocellulosic Biomass, Md Ibrahim Khalil, Mia Mahmudul Hoque, Mafroz Ahmed Basunia, Nadia Alam, Md Asaduzzaman Khan Jan 2011

Production Of Cellulase By Pleurotus Ostreatus And Pleurotus Sajor-Caju In Solid State Fermentation Of Lignocellulosic Biomass, Md Ibrahim Khalil, Mia Mahmudul Hoque, Mafroz Ahmed Basunia, Nadia Alam, Md Asaduzzaman Khan

Turkish Journal of Agriculture and Forestry

Bioconversion of cellulosic components into fermentable sugars has currently been accomplished with the help of the microbial enzyme, cellulase. In this study, Pleurotus ostreatus (Jacquin ex Fr.) Kummer and Pleurotus sajor-caju (Fr.) Singer were tested for cellulase production by solid state fermentation (SSF) using saw dust, sugarcane bagasse, and paddy straw as substrate. To enhance production, the substrates were pretreated with 1% and 4% NaOH solutions. Supernatants of extracted enzyme solutions were used to estimate reducing sugar and soluble protein, as well as enzyme activities. Maximum production of reducing sugar and soluble protein were recorded in 12 and 10 day …


Stability Properties Of Certain Durum Wheat Genotypes For Major Quality Characteristics, Mehmet Ali̇ Saki̇n, Oral Düzdemi̇r, Abdulvahi̇t Sayaslan, Ferhat Yüksel Jan 2011

Stability Properties Of Certain Durum Wheat Genotypes For Major Quality Characteristics, Mehmet Ali̇ Saki̇n, Oral Düzdemi̇r, Abdulvahi̇t Sayaslan, Ferhat Yüksel

Turkish Journal of Agriculture and Forestry

Many ecological regions of Turkey are suitable for the production of durum wheat, and therefore the yield and quality of this wheat should be improved. In this study, stability properties associated with the pasta quality of 25 durum wheat (Triticum durum Desf.) genotypes grown in 3 different locations (Tokat-Kazova, Diyarbakır, and Sivas-Ulaş) for 2 years (2005-2006, 2006-2007) were investigated. Durum wheat genotypes were composed of 12 registered varieties and 13 advanced experimental lines. Field trials were conducted in a randomized complete block design with 3 replications. Protein content, gluten index, sedimentation and specific sedimentation volumes, yellow pigment content, and lipoxygenase …


Effect Of Mini-Plug Container Depth On Root And Shoot Growth Of Four Forest Tree Species During Early Developmental Stages, Panagiota Kostopoulou, Kalliopi Radoglou, Olympia Dini-Papanastasi, Christina Adamidou Jan 2011

Effect Of Mini-Plug Container Depth On Root And Shoot Growth Of Four Forest Tree Species During Early Developmental Stages, Panagiota Kostopoulou, Kalliopi Radoglou, Olympia Dini-Papanastasi, Christina Adamidou

Turkish Journal of Agriculture and Forestry

The container type used in nursery culture is among the most important determinants of containerised seedling quality. The objective of the present study was to analyse root and shoot growth, root growth potential, and photochemical efficiency of seedlings of Picea abies, Robinia pseudoacacia, Pinus brutia, and Pinus nigra cultivated for 5 weeks in mini-plugs of 2 different cavity depths (37 and 60 mm). The results showed that precultivation of P. nigra and, to a lesser extent, of R. pseudoacacia in deeper mini-plug containers improved seedling morphological attributes and quality, but shallow containers produced better quality seedlings of P. abies. In …


Micropropagation Of Olive Tree Olea Europaea L. 'Oueslati', Anissa Chaari Rkhis, Mohamed Maalej, Noureddine Drira, Alvaro Standardi Jan 2011

Micropropagation Of Olive Tree Olea Europaea L. 'Oueslati', Anissa Chaari Rkhis, Mohamed Maalej, Noureddine Drira, Alvaro Standardi

Turkish Journal of Agriculture and Forestry

The present study was undertaken to contribute to the continuous search for efficient in vitro protocols for the micropropagation of olive trees, with special focus on the Oueslati cultivar. It investigates the main factors involved in the micropropagation process, namely medium composition, growth regulators, rooting, and acclimatization conditions. It demonstrates that under particular conditions, the Oueslati cultivar displays a high capacity to proliferate. During the multiplication phase, the multiplication medium, which is a modification of Rugini medium with zeatin (1 and 2 mg L^{-1}), yielded the highest multiplication rates, with an average of more than 9. Furthermore, almost 91% of …


Potential Of Steinernema Feltiae (Rhabditida: Steinernematidae) As A Biological Control Agent Against The Cabbage Maggot Delia Radicum (Diptera: Anthomyiidae) In Oilseed Rape, İsmai̇l Alper Susurluk Jan 2011

Potential Of Steinernema Feltiae (Rhabditida: Steinernematidae) As A Biological Control Agent Against The Cabbage Maggot Delia Radicum (Diptera: Anthomyiidae) In Oilseed Rape, İsmai̇l Alper Susurluk

Turkish Journal of Agriculture and Forestry

Entomopathogenic nematodes (EPNs) in families Heterorhabditidae and Steinernematidae have considerable potential as biological control agents against soil-inhabiting insect pests. In the present study, the potential of Steinernema feltiae as a biological control agent against cabbage maggot (CM) Delia radicum (Diptera: Anthomyiidae), persistence of the nematode in areas infested by CM larvae, and foraging behavior of the nematode toward CM and/or oilseed rape roots were examined in the laboratory. The results of the laboratory experiment showed that more than 80% control was achieved against the last instars of D. radicum. Steinernema feltiae persisted in the soil in high numbers for 12 …


Isolation And Characterization Of Native Bacillus Thuringiensis Isolates From Syrian Soil And Testing Of Their Insecticidal Activities Against Some Insect Pests, Hassan Ammouneh, Muhand Harba, Emad Idris, Hayat Makee Jan 2011

Isolation And Characterization Of Native Bacillus Thuringiensis Isolates From Syrian Soil And Testing Of Their Insecticidal Activities Against Some Insect Pests, Hassan Ammouneh, Muhand Harba, Emad Idris, Hayat Makee

Turkish Journal of Agriculture and Forestry

Bacillus thuringiensis was detected in 12.5% of soil samples collected from different regions in Syria and 25 B. thuringiensis isolates were found to be highly toxic to larvae of Ephestia kuehniella Zeller, Phthorimaea operculella Zeller, and Cydia pomonella L. (Lepidoptera), but not to the larvae of Culex quinquefasciatus (Diptera). Light microscopy investigation showed the presence of bipyramidal and cuboidal parasporal bodies produced by these isolates. The existence of different cry genes in the tested isolates was studied using a PCR strategy with a set of general primers recognizing some of the cry genes reported in the relevant literature. Primers corresponding …


Agroecological Land Use Potential Of Amik Plain, Turkey, Şeref Kiliç Jan 2011

Agroecological Land Use Potential Of Amik Plain, Turkey, Şeref Kiliç

Turkish Journal of Agriculture and Forestry

The loss of agricultural land due to the development of other land uses has increasingly become an issue of local, regional, and national concern in Turkey. This study was aimed at evaluating land use potential and suitability of 174 land mapping units of 72,544 ha in Amik Plain (Hatay, Turkey) for 21 different land use types. For this purpose, land suitability evaluation was carried out using soil and land data and a PC-compatible ILSEN software package program developed by the SENOL land evaluation system. Our study showed that out of 39 potential groups, 26 combined land uses and land covers …


Cover And Contents Jan 2011

Cover And Contents

Turkish Journal of Agriculture and Forestry

No abstract provided.


Biological Control Of Chestnut Canker, Caused By Cryphonectria Parasitica, By Antagonistic Organisms And Hypovirulent Isolates, Seçi̇l Akilli, Yakup Zekai̇ Katircioğlu, Sali̇h Maden Jan 2011

Biological Control Of Chestnut Canker, Caused By Cryphonectria Parasitica, By Antagonistic Organisms And Hypovirulent Isolates, Seçi̇l Akilli, Yakup Zekai̇ Katircioğlu, Sali̇h Maden

Turkish Journal of Agriculture and Forestry

Biological control of chestnut blight was investigated by using 3 hypovirulent isolates of Cryphonectria parasitica, 5 Trichoderma sp., 4 Penicillium sp., and 4 Bacillus sp. isolates. Hypovirulent isolates and antagonistic organisms were obtained from samples collected from the Black Sea region of Turkey, in 2008 and 2009. Effectiveness of the hypovirulent isolates and antagonistic microorganisms was tested on 3-year-old chestnut saplings. In the tests, bark disks of 6 mm were removed from the stem bases and culture disks of the virulent isolate of C. parasitica were first placed into the hole and then the hypovirulent isolate or the antagonistic fungi. …


Molecular Cloning And Functional Characterization Of A Na+/H+ Antiporter Gene From Halophyte Spartina Anglica, Tao Lan, Yuanlin Duan, Bin Wang, Yuanchang Zhou, Weiren Wu Jan 2011

Molecular Cloning And Functional Characterization Of A Na+/H+ Antiporter Gene From Halophyte Spartina Anglica, Tao Lan, Yuanlin Duan, Bin Wang, Yuanchang Zhou, Weiren Wu

Turkish Journal of Agriculture and Forestry

Na^+/H^+ antiporters have been suggested to play important roles in salt tolerance in plants. English cordgrass (Spartina anglica) is a gramineous halophyte with very strong salt tolerance. It possesses salt glands in its stems and leaves, through which excess salt can be excreted. In this study, a vacuolar Na^+/H^+ antiporter homologous gene (temporarily named SaNHX1) was isolated from Spartina anglica by RT-PCR and rapid amplification of cDNA ends (RACE). Southern blot analysis suggested that there might be 2 or 3 copies of the vacuolar Na^+/H^+ antiporter genes in the English cordgrass genome. Northern blot analysis showed that the expression of …


Soil Formation Overlying Volcanic Materials At Mount Erenler, Konya, Turkey, Sidika Özcan, Hasan Hüseyi̇n Özayteki̇n Jan 2011

Soil Formation Overlying Volcanic Materials At Mount Erenler, Konya, Turkey, Sidika Özcan, Hasan Hüseyi̇n Özayteki̇n

Turkish Journal of Agriculture and Forestry

Studies of soils developed on volcanic materials are insufficient in Turkey in light of the wide distribution of these soils. The objectives of the present work were to assess the influence of climate and other soil-forming factors on physical, chemical, and mineralogical characteristics and pedological processes in the soil genesis and soil classification of 4 volcanic soil profiles derived from andesitic parent material, and to determine whether they meet the requirements for classification as Andisols. Collected from a semiarid climate in Konya, Turkey, these soils are characterized as medium- and fine-textured with low organic matter content, low cation exchange capacity, …


Cover And Contents Jan 2011

Cover And Contents

Turkish Journal of Agriculture and Forestry

No abstract provided.


Estimation Of Single Leaf Chlorophyll Content In Sugar Beet Using Machine Vision, Parviz Ahmadi Moghaddam, Mohammadali Haddad Derafshi, Vine Shirzad Jan 2011

Estimation Of Single Leaf Chlorophyll Content In Sugar Beet Using Machine Vision, Parviz Ahmadi Moghaddam, Mohammadali Haddad Derafshi, Vine Shirzad

Turkish Journal of Agriculture and Forestry

Estimating crop nitrogen status accurately during side-dressing operations is essential for effective management of site-specific nitrogen applications. Variable rate technology (VRT) is one of the major operations in precision agriculture to reduce environmental risks and increase fertilizer use efficiency. In the present study, color image analysis was performed to estimate sugar beet leaf chlorophyll status. The experiment was carried out in a phytotron and nitrogen was applied at 6 levels to the sugar beet grown in pots. Chlorophyll level of the leaves was measured by a SPAD-502 chlorophyll meter. To estimate chlorophyll status, a neural-network model was developed based on …


Control Of Trialeurodes Vaporariorum (Westwood) Adults On Glasshouse-Grown Cucumbers In Four Different Growth Substrates: An Efficacy Comparison Of Foliar Application Of Steinernema Feltiae (Filipjev) And Spraying With Thiamethoxamn, Ziga Laznik, Dragan Znidarcic, Stanislav Trdan Jan 2011

Control Of Trialeurodes Vaporariorum (Westwood) Adults On Glasshouse-Grown Cucumbers In Four Different Growth Substrates: An Efficacy Comparison Of Foliar Application Of Steinernema Feltiae (Filipjev) And Spraying With Thiamethoxamn, Ziga Laznik, Dragan Znidarcic, Stanislav Trdan

Turkish Journal of Agriculture and Forestry

In a glasshouse experiment, the effectiveness of the entomopathogenic nematode (EPN) Steinernema feltiae (Filipjev) (Rhabditida: Steinernematidae) was compared with thiamethoxam for the control of adults of the greenhouse whitefly (GWF), Trialeurodes vaporariorum (Westwood) (Homoptera: Aleyrodidae), on slicer cucumbers. In a period from mid June to the end of August (2007 and 2008), cucumbers were grown in 4 different growth substrates: expanded perlite, expanded vermiculite, light expanded clay, and peat. A suspension of the nematode (2500 infective juveniles mL^{-1}) was applied to cucumbers 5 times in 2007 and twice in 2008, whilst an insecticide thiametoxam at the recommended dose (0.7 g …


Cover And Contents Jan 2011

Cover And Contents

Turkish Journal of Agriculture and Forestry

No abstract provided.


Analysis Of A Differential Equation Model Of Hiv Infection Of Cd4^+ T-Cells With Saturated Reverse Function, Xiangyun Shi, Gang Li, Xueyong Zhou, Xinyu Song Jan 2011

Analysis Of A Differential Equation Model Of Hiv Infection Of Cd4^+ T-Cells With Saturated Reverse Function, Xiangyun Shi, Gang Li, Xueyong Zhou, Xinyu Song

Turkish Journal of Mathematics

In this paper, an ordinary differential equation model of HIV infection of CD4^+ T-cells with saturated reverse function is studied. We prove that if the basic reproduction number R_0


Azocalixarenes.7: Synthesis And Study Of The Absorption Properties Of Novel Mono-Azo Substituted Chromogenic Calix[4]Arenes, Hasaletti̇n Deli̇göz, Özlem Özen Karakuş Jan 2011

Azocalixarenes.7: Synthesis And Study Of The Absorption Properties Of Novel Mono-Azo Substituted Chromogenic Calix[4]Arenes, Hasaletti̇n Deli̇göz, Özlem Özen Karakuş

Turkish Journal of Chemistry

Eight new mono-azo substituted chromogenic calix[4]arenes (1-8) were synthesized by diazo-coupling reactions in which 25,26,27-tribenzoyloxy-28-hydroxy-5,11,17-tri-(tert-butyl)calix[4]arene and diazonium salts (2-, 3-, and 4-nitroaniline; 4-phenyl azoaniline; 3- and 4-chloroaniline; or 2- and 4-methylaniline) formed the corresponding mono-azo substituted derivatives in high yields. The mono-azo substituted calix[4]arenes were characterized by UV-Vis, FT-IR, and ^1H-NMR spectroscopic techniques. Elemental analysis was also carried out. In addition, the effects of varying pH levels and solvents upon the absorption ability of azocalix[4]arenes substituted with electron-donating and electron-withdrawing groups at their o-, m-, and p- positions were studied. The results proved that the absorption maxima of the prepared …


Antimicrobial Activity And Volatile Constituents Of The Flower, Leaf, And Stem Of Paeonia Daurica Grown In Turkey, Gonca Tosun, Nuran Kahri̇man, Canan Albay, Şengül Alpay Karaoğlu, Nuretti̇n Yayli Jan 2011

Antimicrobial Activity And Volatile Constituents Of The Flower, Leaf, And Stem Of Paeonia Daurica Grown In Turkey, Gonca Tosun, Nuran Kahri̇man, Canan Albay, Şengül Alpay Karaoğlu, Nuretti̇n Yayli

Turkish Journal of Chemistry

The volatile constituents of the essential oils from the flower, leaf, and stem of Paeonia daurica Andrews were analyzed by GC and GC-MS. A total of 74 compounds were identified, constituting over 95.0%, 80.8%, and 98.2% of the oil composition of the flower, leaf, and stem of P. daurica, respectively. Aldehydes were shown to be the main group of constituents of the flower and stem parts, at 39.1% and 79.8%, respectively. However, the major group in the leaf oil was found to be oxygenated monoterpenes (43.5%). Salicylaldehyde (20.7% and 79.5%) was the major component of the flower and stem oils …


Determination Of Stability Constants Of 5-(2-Hydroxybenzylidene)-2-Thioxodihydropyrimidine-4,6(1h,5h)-Dione With Copper(Ii) And Mercury(Ii) Ions, Morteza Bahram, Nader Noroozi Pesyan, Abdolhossein Naseri, Masomeh Tasbihforosh Jan 2011

Determination Of Stability Constants Of 5-(2-Hydroxybenzylidene)-2-Thioxodihydropyrimidine-4,6(1h,5h)-Dione With Copper(Ii) And Mercury(Ii) Ions, Morteza Bahram, Nader Noroozi Pesyan, Abdolhossein Naseri, Masomeh Tasbihforosh

Turkish Journal of Chemistry

In this work, a hard model chemometric method was used to determine the stability constants of copper(II) and mercury(II) complexes with the newly synthesized ligand 5-(2-hydroxybenzylidene)- 2-thioxodihydropyrimidine-4,6(1H,5H)-dione in acetonitrile by UV-Vis spectrophotometry. The ligand forms stable complexes with both metal cations. The protonation constants of the ligand were also measured in an ethanol-water (1:1) mixture.


Synthesis And Antimicrobial Activity Of Methoxy Azachalcones And N-Alkyl Substituted Methoxy Azachalconium Bromides, Canan Albay, Nuran Kahri̇man, Nagi̇han Yilmaz İskender, Şengül Alpay Karaoğlu, Nuretti̇n Yayli Jan 2011

Synthesis And Antimicrobial Activity Of Methoxy Azachalcones And N-Alkyl Substituted Methoxy Azachalconium Bromides, Canan Albay, Nuran Kahri̇man, Nagi̇han Yilmaz İskender, Şengül Alpay Karaoğlu, Nuretti̇n Yayli

Turkish Journal of Chemistry

In this study, 18 new N-octyl, N-decyl, and N-dodecyl substituted o-, m-, and p-methoxy (E)-3- and 4-azachalcones, {4- or 3-[(1E)-3-(4-, 3-, or 2-methoxyphenyl)-3-oxoprop-1-en-1-yl]-1-alkyl (C_{8,10,12}) pyridinium bromides} (1a-6a, 1b-1b, and 1c-6c), and 4 new o-, and m-methoxy (E)-3- and 4-azachalcones (2, 3, 5, and 6) were synthesized and tested for antimicrobial activities against Escherichia coli, Yersinia pseudotuberculosis, Enterobacter aerogenes, Pseudomonas aeruginosa, Staphylococcus aureus, Enterococcus faecalis, Bacillus cereus, and Candida albicans. N-Alkyl substituted azachalconium bromides showed good antimicrobial activity against all tested microorganisms with minimal inhibitory concentration (MIC) values in the range of 0.42-58.7 \mu g/mL in most cases. Nonalkylated compounds 1-9 …


Microwave Synthesis Of Some New Antimicrobial And Antiproliferative Butenamides And Pyrrolidine-2,5-Diones, Shadia Mahmoud Abdallah, Halima Aly Hefny Jan 2011

Microwave Synthesis Of Some New Antimicrobial And Antiproliferative Butenamides And Pyrrolidine-2,5-Diones, Shadia Mahmoud Abdallah, Halima Aly Hefny

Turkish Journal of Chemistry

Microwave irradiation, comparable to conventional thermal heating, proves to be a convenient method in assisting the synthesis of some butenamides, pyrrolidine-2,5-diones, and their benzenesulfonamido derivatives, which are known to have biological activities and wide medical and industrial applications. Both procedures were used to compare their efficiency in synthesizing butenamides and pyrrolidine-2,5-diones (2-25), which have important and wide applications, from condensation of \alpha,\beta-unsaturated anhydride (1) with the corresponding amines. Some of the products showed biological or cytotoxic (antiproliferative) activity.