Digital Commons Network^™

Testing And Improving The Luminosity Relations For Gamma-Ray Bursts, Andrew Collazzi

LSU Doctoral Dissertations

Gamma Ray Bursts (GRBs) have several luminosity relations where a measurable property of a burst light curve or spectrum is correlated with the burst luminosity. These luminosity relations are calibrated for the fraction of bursts with spectroscopic redshifts and hence the known luminosities. GRBs have thus become known as a type of "standard candle"; where standard candle is meant in the usual sense that their luminosities can be derived from measurable properties of the bursts. GRBs can therefore be used for the same cosmology applications as Type Ia supernovae, including the construction of the Hubble Diagram and measuring massive star …

Formation And Stabilization Of Combustion-Generated Environmentally Persistent Free Radicals On Transition Metal Oxides Supported On Silica, Eric Warren Pimentel Vejerano

LSU Doctoral Dissertations

The formation of environmentally persistent free radicals in combustion system was investigated from chemisorptions of chlorine- and hydroxy-substituted benzenes on transition metal oxide surface under post-combustion conditions. This manuscript reports the formation of EPFRs on silica particles containing 5% Fe(III)2O3, Ni(II)O, and Zn(II)O. The EPFRs are formed by the chemisorption of substituted aromatic molecular adsorbates on the metal cation center followed by electron transfer from the adsorbate to the metal ion at temperatures from 150 to 400 oC. Depending on the nature of the adsorbate and the temperature, two organic EPFRs were formed: a phenoxyl-type radical, which has a lower …

The Effect Of Exopolymers On The Compressibility And Shear Strength Of Kaolinite, Rick Alton Nugent

LSU Doctoral Dissertations

Erosion and subsidence threaten coastal infrastructure and natural habitats throughout the coastal United States, and this threat is especially significant along the Louisiana coastline since wetland clays are generally weak and highly compressible. Hydraulic pumping of dredged sediment is a common method for combating damage caused by erosion and subsidence, but the high water content slurry deposited is very compressible with low shear strength. Although conventional soil amendments are effective for reducing compressibility and increasing shear strength, these stabilizers are often caustic or toxic, making them too risky to use. Exopolymers, however, have the potential to improve sediment stability without …

Redox-Active Liposome Delivery Agents With Highly Controllable Stimuli-Responsive Behavior, Nicole Hollabaugh Carrier

LSU Doctoral Dissertations

Over the last few decades, liposomes have generated a lot of interest as drug delivery vehicles to address the need for providing both increased therapeutic efficacy and decreased systemic exposure, simultaneously. The challenge of increasing drug accumulation at diseased sites, without compromising the integrity and stability of the liposomal carrier during circulation, has been met with two possible solutions: (1) active targeting and (2) active triggering. To achieve selective and site-specific delivery of drugs to tumors, active triggering methods have been developed wherein a responsive element is incorporated into the liposomal bilayer, which causes destabilization of the liposome upon exposure …

Characterization Of Triggerable Quinones For The Development Of Enzyme-Responsive Liposomes, Maria Fabiana Mendoza

LSU Doctoral Dissertations

For decades, there has been a lot of focus on the development of new carriers for drug delivery applications. From all of the carriers, stimuli-responsive liposomes have been studied extensively, but only a handful have been enzyme-responsive liposomes. Therefore, the field of endogenous proteins as activators of liposomes is a fertile field worthy of exploration. The research described in this dissertation involves how structural changes on the quinone moiety altered their electronic properties, as well as their behavior toward the human enzyme NAD(P)H:quinone oxidoreductase type-1 (hNQO1, over expressed in certain tumor tissues), thus yielding a series of triggerable quinones to …

Time Of Day Effects On Language Discourse In Healthy Aging And Dementia, Amanda L. Stead

LSU Doctoral Dissertations

This study’s purpose was to investigate whether language discourse follows a diurnal pattern across one 10-hour day in normal healthy aging individuals (NHA) and individuals with mild to moderate Alzheimer’s disease. Ten healthy older adults; and ten older adults clinically labeled with probable Alzheimer’s disease were recruited for this study. Measurements of procedural language, narrative language, and cognition, the Benton Judgment of Line Orientation (BJLO), were collected across one day at 9:00am, 12:00pm, 3:00 pm, and 6:00pm. Language samples were evaluated for linguistic variables to evaluate the quantity and quality of the discourse samples. Results indicated that the two groups …

Guided Modes And Resonant Transmission In Periodic Structures, Hairui Tu

LSU Doctoral Dissertations

We analyze resonant scattering phenomena of scalar fields in periodic slab and pillar structures that are related to the interaction between guided modes of the structure and plane waves emanating from the exterior. The mechanism for the resonance is the nonrobust nature of the guided modes with respect to perturbations of the wavenumber, which reflects the fact that the frequency of the mode is embedded in the continuous spectrum of the pseudo-periodic Helmholtz equation. We extend previous complex perturbation analysis of transmission anomalies to structures whose coefficients are only required to be measurable and bounded from above and below, and …

In The Ruins Of Zine Pedagogy: A Narrative Study Of Teaching With Zines, Karin H. Degravelles

LSU Doctoral Dissertations

This study considers the educational significance of zines—small circulation, self-published magazines—by asking how educators who teach with zines encounter and negotiate zine pedagogy. Though the literature on zines and teaching describes many potential benefits, it also describes contradictions and failures, with some researchers even going so far as to claim that “zines do not belong in classrooms” (Guzzetti, Elliott, & Welsch, 2010, p. 71). Through this dissertation, I investigate and complicate these claims by examining the stories and perspectives of teacher/zinesters—educators who teach or have taught with zines in a classroom setting. The project is situated within theories of the …

Symmetric Spaces, Se-Jong Kim

LSU Doctoral Dissertations

We first review the basic theory of a general class of symmetric spaces with canonical reflections, midpoints, and displacement groups. We introduce a notion of gyrogroups established by A. A. Ungar and define gyrovector spaces slightly different from Ungar's setting. We see the categorical equivalence of symmetric spaces and gyrovector spaces with respect to their corresponding operations. In a smooth manifold with spray we define weighted means using the exponential map and develop the Lie-Trotter formula with respect to midpoint operation. Via the idea that we associate a spray with a Loos symmetric space, we construct an analytic scalar multiplication …

Fate Of Mississippi River Diverted Nitrate On Vegetated And Non-Vegetated Coastal Marshes Of Breton Sound Estuary, Christine M. Vanzomeren

LSU Master's Theses

The Caernarvon Diversion meters Mississippi River water into coastal marshes of Breton Sound. Elevated levels of nitrogen in river water have sparked concerns that nutrient loading may affect marsh resilience and belowground biomass, as evidence from several marsh fertilization studies. These concerns resulted from observation that fresh and brackish Breton Sound marshes suffered extensive damage from Hurricane Katrina. The goal of this study is to determine the fate of nitrate (the dominant inorganic nitrogen form in the Mississippi River) in Breton Sound Estuary marshes. We hypothesized that most nitrate would be removed by denitrification and that nitrate loading would not …

Temporal Changes In Quality Of Life And Environment In New Orleans After Hurricane Katrina, Danielle Johanna Larock

LSU Master's Theses

Understanding and assessing the spatial and temporal changes of quality of life and environment of a community is critical to its sustainable development, especially after a disaster strikes. This study explores an approach that integrates remote sensing with socioeconomic data to assess the temporal changes in quality of life and environment (QOL) using Orleans Parish as an example. Hurricane Katrina, which struck New Orleans in 2005, has had vast implications economically, socially, and environmentally for this city and the surrounding area. Empirically quantifying these concepts will help to rebuild the city more sustainably. This study investigated change in environmental quality …

Advanced Management Of The Mexican Rice Borer (Eoreuma Loftini) In Sugarcane, Blake Emerson Wilson

LSU Master's Theses

Insecticide, greenhouse and varietal resistance experiments were conducted in Texas to develop management tactics for the Mexican rice borer, Eoreuma loftini (Dyar), sugarcane. A 3-treatment, large plot aerial application study was set up in 5 commercial sugarcane fields (35-84 acres) to evaluate the utilization of pheromone traps to improve chemical control strategies for E. loftini during 2009 and 2010 growing seasons. A threshold of 20-25 moths/trap/wk was used as an indicator to initiate monitoring for E. loftini larval infestations. Larval infestations were directly related to the no. of moths/trap/wk (R2=0.71). Reductions in borer injury and adult emergence (60% and 40% …

Evaluation Of The Pencil Beam Algorithm And Pencil Beam Redefinition Algorithm For Bolus Electron Conformal Therapy Dose Computation, James Kavanaugh

LSU Master's Theses

Purpose: This study aimed (1) to demonstrate the ability of mixed beam (MB) therapy, intensity modulated x-ray therapy (IMXT) optimized on top of a bolus electron conformal therapy (ECT) plan, to deliver a uniform dose to the planning target volume (PTV) in a homogenous phantom and (2) to evaluate the accuracy of the pencil beam algorithm (PBA) and pencil beam redefinition algorithm (PBRA) in calculating the dose distributions for the bolus ECT and MB plans. Methods: PTVs and critical structures from parotid and post-mastectomy chest wall patients were modeled in a 27cm ö polystyrene phantom. Bolus ECT treatment plans using …

Into The Vault Of The Saints: The Exterior Crypts Of Saint-Denis In Paris And Saint-Germain In Auxerre, Matthew Ryan Reed

LSU Master's Theses

Historians have held the Carolingian rule of Western Europe as a brief strike of light against the dark backdrop of the Medieval period. In this period two structures emerged for the first time in church architecture: the westwork and the exterior crypt. These two structures did not follow models found in Early Christian architecture: they accommodated functions specific to developments and needs that emerged in the context of the Carolingian Empire. Although both hold many opportunities for scholarship, the exterior crypt offers significant insights into developments at the heart of Carolingian liturgy, society, and architectural design. Two of these exterior …

Parallel Surrogate Detection In Large-Scale Simulations, Lei Jiang

LSU Master's Theses

Simulation has become a useful approach in scientific computing and engineering for its ability to model real natural or human systems. In particular, for complex systems such as hurricanes, wildfire disasters, and real-time road traffic, simulation methods are able to provide researchers, engineers and decision makers predicted values in order to help them to take appropriate actions. For large-scale problems, the simulations usually take a lot of time on supercomputers, thus making real-time predictions more difficult. Approximation models that mimic the behavior of simulation models but are computationally cheaper, namely "surrogate models", are desired in such scenarios. In the thesis, …

Demography, Paleopathology, And Health Status Of The Moche Remains In Huambacho, Peru: A Comprehensive Osteological Analysis, Emily Grace

LSU Master's Theses

The Moche civilization, which thrived in northern Peru from AD 100-800, influenced a vast area that extended to the southernmost monumental site of Pañamarca. Huambacho, an archaeological site in the Nepeña Valley, which dates to the Early Horizon (600-200 cal BC), has yielded multiple Moche graves uncovered by the Proyecto Huambacho (2003-2004). The graves provide the first evidence of Moche presence outside of the neighboring Pañamarca monumental complex. This research entailed the osteological analysis of eleven individuals from nine Moche grave contexts at Huambacho, including the analysis of demographic features, pathology, trauma, and antemortem cultural modifications. Methodology included the visual …

Building Information Management (Bim) Implementation In Naval Construction, Raymond Rohena

LSU Master's Theses

Traditional two-dimensional (2D) delivery systems in the construction industry can hinder the way information is communicated between owners, architects, and contractors. This hindrance exists in all phases of a project, from design and construction to the operation and maintenance of the completed facility. Building Information Management (BIM) is an emerging information technology that promotes a collaborative process for the Architectural, Engineering, Construction and Facilities Management (AECFM) industry; it can aid the exchange of information and provide improved project data accessibility to all stakeholders of a construction project. The Naval Facilities Engineering Command (NAVFAC), in conjunction with the facility management (FM) …

Enumerate / Construct, Andrew Gilliatt

LSU Master's Theses

I am fascinated how we define and personalize ourselves through the objects we own and accumulate. It is my goal to make a collection of utilitarian pottery forms that through the use of color, form, and pattern, are cohesive in their variety, and are accessible as objects for daily use.

Dry Reforming Of Methane On Rhodium And Nickel Substituted Pyrochlore Catalysts, Sarthak Gaur

LSU Master's Theses

Dry reforming of methane (DRM) has been widely investigated, with most studies showing rapid deactivation due to carbon deposition. This suggests a need to develop catalysts that limit carbon formation while avoiding structural changes at the elevated temperatures typical of this reaction. Here, we report CO2 reforming of methane on four pyrochlore catalysts. First, Rh was partially substituted for Zr in lanthanum zirconate (La2Zr2O7) to give La2Zr2-xRhxO7.5 (LRZ, x=0.112, 2 wt% Rh) pyrochlore. A second pyrochlore catalyst was synthesized in which Ca was further substituted into the La-site to give La1.95Ca0.05Zr2-xRhxO7 (LCRZ, x=0.055, 1 wt% Rh). A third catalyst was …

Soft Sediment Relay Zones: A High Resolution Seismic Survey Livingston Parish, Louisiana, Erin T. Elliott

LSU Master's Theses

The southern coast of the United States, bordering the Gulf of Mexico, is home to several down-to-the-south, listric, normal fault systems striking parallel to the coast. One of these, the Baton Rouge–Tepetate Fault System located in southern Louisiana, consists of a series of near-surface, reactivated growth faults and relay ramps– a broad area of ductile strain, with contemporaneous sedimentation. Evidence of recent fault and relay ramp movement is seen in surficial fault line scarps and offset roads. This thesis utilizes two near-surface (<500 >m), high-resolution (10 - 300 Hz), continuous seismic reflection profiles (360 m and 480 m long, 3 …

Secure Distributed Detection In Bandwidth-Constrained Wireless Sensor Networks, Reza Soosahabi

LSU Master's Theses

Utilizing wireless sensor network (WSN) is a novel idea in a variety of applications. However, the limited resources allocated to the sensor nodes make the design of WSNs a challenging problem. We consider the problem of hypothesis testing in a bandwidth-constrained, low-power wireless sensor network operating over insecure links. Sensors quantize their observations and transmit their decisions to an intended (ally) fusion center (AFC) which combines the received messages to detect the state of an unknown hypothesis.

In many applications the sensor messages are vulnerable to unauthorized eavesdropping. The scarce bandwidth and processing power for the sensors rule out the …

Social Vulnerability In Louisiana's Upper Industrial Corridor: Spatial Distribution And Linkages With Cumulative Pollution - A Zip Code Level Analysis, María Belén Toscano

LSU Master's Theses

Louisiana’s industrial corridor, the stretch of the lower Mississippi River from New Orleans to Baton Rouge, is one of the areas with the highest concentration of petrochemical facilities and chemical plants in the United States, as well as one of the most heavily polluted. In particular, the present study examined the associations of social vulnerability and potential exposure to environmental pollution in the upper section of the industrial corridor, the Baton Rouge Metropolitan Statistical Area (MSA). The study was based on the methodology developed by Cutter et al. (2003) to construct an empirically derived index to measure social vulnerability to …

Spray Drying Technology For The Production And Processing Of Microencapsulated Omega-3 Fish Oil With Egg Powder, Kevin Estuardo Mis Solval

LSU Master's Theses

Protein with essential amino acids is required for recovering, repairing, and building muscles after intensive exercise. A powder produced with egg white (EW) (high quality protein) and fish oil (menhaden (Brevoortia patronus) (MO) oil or salmon oil (SO)) with high DHA and EPA content should be particularly beneficial for athletes. The objective of this study was to develop microencapsulated omega-3 fatty acids fortified EW powders. Two stable emulsions were prepared with 3.43% (MO) or (SO), 56.21% EW, and 40.36% water (E-MO-EW and E-SO-EW). An EW with water solution (without fish oil) (E-EW) was prepared as a control. Two emulsions (E-MO-EW; …

La Ola Verde: Female, Hispanic Consumers And The Green Movement, Stefanie Ann Ramirez

LSU Master's Theses

Due to their impact on the environment, apparel companies have gradually begun to change manufacturing and production processes and provide consumers with environmentally responsible apparel product options. Among these consumers are Hispanics, a consumer group which research has shown to have a strong purchasing power and astounding population increase. Between 2000 and 2010, the total population in the United States increased by 23.7million people, with Hispanics accounting for over 50% of that total increase (Humes, Jones, & Ramirez, 2011). It is estimated that by 2125 Hispanics will account for 50% of the total U.S. population (Day, 1996). Additionally, between 1990 …

The Lower Ninth Ward: Resistance, Recovery, And Renewal, Alexandra Giancarlo

LSU Master's Theses

After Hurricane Katrina of 2005, New Orleans’s Lower Ninth Ward became an icon for the failure of recovery efforts and the persistence of inequality and poverty in American society. However, for as long as this community has been marginalized it has been creating advocacy organizations and counter-narratives that battled discrimination and imbued its cultural practices with meaning. Residents often speak of a profound sense of community attachment, a commitment to educational prospects, and a deep historic and cultural identity. Historically, this area has been home to various social and legal campaigns, mirroring the contemporary protests that arose when residents encountered …

Mechanical Evaluation Of Aluminum Oxide Roughened Screws In Equine Third Metacarpal Bone, Petrisor Baia

LSU Master's Theses

ABSTRACT Objectives – To compare the osseointegration of roughened and electropolished 5.5 mm cortical screws used to secure a 4.5 mm broad dynamic compression plate (DCP) in equine third metacarpal (MC3) bones. Study Design – In vivo study Animals – 5 Adult thoroughbred horses (2-7 years old). Methods – For each horse one MC3 was randomly assigned to secure a 4.5 mm broad DCP with 4aluminum oxide (Al2O3) roughened screws on the dorsal mid diaphysis. Four regular electropolished screws used to secure a similar plate on the contralateral limb served as control. They were removed at 12 weeks and the …

Fostering Compliance In Preschool-Aged Children Using Least-To-Most Assistive Prompt Hierarchy, Courtney Powers

LSU Master's Theses

Previous research has shown that prompting can increase child compliance to adult directives (Tarbox, Wallace, Penrod, & Tarbox, 2007; Wilder & Atwell, 2006; Wilder, Atwell, & Wine, 2006). The purpose of this study was to train teachers to use prompting to increase child compliance to teacher directives. This study builds on the current literature by using least-to-most prompting (Horner & Keilitz, 1975) within the naturally occurring context of the preschool classroom. The participants consisted of 3 preschool teachers who interacted with a target child in an early childhood classroom. Child compliance was measured during free choice center time. Results were …

Efficient Replica-Exchange Across Distributed Production Infrastructure, Abhinav S. Thota

LSU Master's Theses

Replica-Exchange (RE) methods represent a class of algorithms that involve a large number of loosely-coupled ensembles and are used to understand physical phenomena -- ranging from protein folding dynamics to binding affinity calculations. We develop a framework for RE that supports different replica pairing and coordination mechanisms, that can use a wide range of production cyberinfrastructure concurrently. Additionally, our framework uses a flexible pilot-job implementation, which enables effective resource allocation for multiple replicas. We characterize the performance of two different RE algorithms - synchronous and asynchronous - at unprecedented scales on production distributed infrastructure (Teragrid and LONI). The synchronous RE …

Foldable Substrates For Micro-Ultrasonic Transducers, Karthik Balasubramanian

LSU Master's Theses

Ultrasound has broad range of applications from underwater examination, nondestructive testing of materials and medical diagnosis and treatment. The ultrasonic transducer plays an vital role in determining the resolution, sensitivity, as well as other diagnostic capabilities of an ultrasonic imaging system. Current piezoelectric transducer which dominates the medical field has limited applications compared to the capacitive ultrasonic transducer. The capacitive transducer is easy to fabricate compared to the piezoelectric transducer. In this work, the fabrication of a foldable substrate for a capacitive ultrasonic transducer has been discussed. The foldable substrate was fabricated using an ultrathin silicon wafer which is 50 …

Characterization Of Biocompatible Parylene-C Coating For Biomems Applications, Quoc Phuc Nguyen

LSU Master's Theses

This thesis characterizes parylene-C films with respect to biological micro-electro-mechanical system (BioMEMS) applications. BioMEMS devices have fueled the growth and research in the area of detecting, analyzing and identifying pathogens rapidly with precision in the bio-medical applications, thereby positively impacting millions of lives and made it extremely popular among researchers. These devices are fabricated using state-of-the-art techniques usually involving more than one material which typically has different biocompatibility and is not acceptable for various BioMEMS and biomedical applications; therefore, a special biocompatible coating is required. The parylene polymer is an example of such a coating as it is known for …