Digital Commons Network^™

Impacts Of Artificial Reefs On Surrounding Ecosystems, Sarine Manoukian

USF Tampa Graduate Theses and Dissertations

Artificial reefs are becoming a popular biological and management component in shallow water environments characterized by soft seabed, representing both important marine habitats and tools to manage coastal fisheries and resources. An artificial reef in the marine environment acts as an open system with exchange of material and energy, altering the physical and biological characteristics of the surrounding area. Reef stability will depend on the balance of scour, settlement, and burial resulting from ocean conditions over time. Because of the unstable nature of sediments, they require a detailed and systematic investigation.

Acoustic systems like high-frequency multibeam sonar are efficient tools …

Chemical Investigation Of The Antarctic Marine Invertebrates Austrodoris Kerguelenensis & Dendrilla Membranosa And The Antarctic Red Alga Gigartina Skottsbergii, John Alan Maschek

USF Tampa Graduate Theses and Dissertations

The marine realm and, in particular, the Antarctic benthos is largely unexplored and understudied. The chemical investigation reported herein reveals not only the biodiversity, but how that biodiversity manifests remarkable chemical diversity. In our continuing study of the nudibranch Austrodoris kerguelenensis, we have isolated a diverse suite of diterpenoid glyceride esters, palmadorins D - S (2.32 - 2.47), one of which is the first reported halogenated diterpene from a dorid nudibranch. Utilizing genomic data from collaborators, we have investigated the chemical diversity from phylogenetically unique specimens collected in close proximity to one another. Chemical groupings based on comparison of LC/MS …

The Influence Of Meteorological Parameters On Rainfall And Severe Weather In Pinellas County, Fl, Cristina A. Mazza

USF Tampa Graduate Theses and Dissertations

Pinellas County is located on a peninsula in Florida that experiences daily patterns of sea breeze associated rainfall mainly during the summer months of June through August. Previously, rainfall patterns, amounts and timing and severe weather in Pinellas County have not been examined considering dominant wind flow patterns, sea breeze circulations and other atmospheric variables. To improve forecasting of local mesoscale phenomena, this project examined the rainfall patterns, amounts and timing and severe weather occurrences that occur as a result of sea breezes and associated prevailing wind regimes within Pinellas County for the months of June, July and August for …

Seasonal Changes In The Sinking Particulate Flux And In The Nitrogen Cycle Within The Euphotic And Twilight Zones Of The Cariaco Basin, Venezuela, Enrique Montes-Herrera

USF Tampa Graduate Theses and Dissertations

This study explored the effects of seasonal variability on the geochemistry of sinking pthesiss and on the nitrogen cycle of the Cariaco Basin. Pthesis fluxes were measured at the base of the euphotic zone (the depth of 1% of photosynthetically active radiation - PAR) with drifting sediment traps during months of upwelling and non-upwelling regimes from March 2007 to November 2009. Flux estimates were analyzed in the context of seasonal variations in sea surface temperature, primary productivity, and chlorophyll a concentrations using data generated by the CARIACO Time-series Program as well as satellite data. Additionally, nine years (1996-2000 and 2004-2007) …

A Proposed Theoretical Model Of Literacy Learning Using Multisensory Structured Language Instruction (Msli), Judith E. Rusinko

Antioch University Dissertations & Theses

Multisensory Structured Language Instruction has been used for decades by clinicians and practitioners as an intervention for teaching students with dyslexia. Multisensory Structured Language Instruction uses the integration of multiple senses (visual, auditory, and kinesthetic/tactile) simultaneously to teach literacy. Although the anecdotal evidence for Multisensory Structured Language Instruction is strong, there is a lack of empirical evidence to support its effectiveness. In addition, Multisensory Structured Language Instruction includes the foundational skills recommended by the National Reading Panel (2000), but the use of multiple senses to teach these skills has not been thoroughly studied. This theoretical dissertation focused on one element …

The Role Of Nature In John Muir's Conception Of The Good Life, Randy R. Larsen

Antioch University Dissertations & Theses

Aristotle says our best moral guidance comes from considering the lives of exemplary individuals. I explore John Muir, as an exemplar of environmental virtue, and consider the role of Nature in his conception of the good life. I argue his conception consists of a web of virtue including various goods, values, and virtues. I suggest three virtues are cardinal: attentiveness, gratitude and reverence. I explore how Muir cultivated these virtues in Nature.

I argue Muir sought freedom from a popular conception of the good life, grounded in the gilded age values of money and materialism, and was sensitive to the …

A Qualitative Approach To Spiral Of Silence Research: Self-Censorship Narratives Regarding Environmental And Social Conflict, Christopher John Ryan

Antioch University Dissertations & Theses

The purpose of this research is to seek narratives of self-censorship from in-depth interviews of 19 participants acquired through a purposive (criterion) sampling protocol. The primary research question driving this study is “What types of sanctions contribute to people choosing to self-censor their strongly held beliefs, values, and opinions.” Previous research conducted on the topic of self-censorship (generally under the rubric of the spiral of silence theory) has been predominantly quantitative and consideration of sanctions influencing self-censorship have been limited to fear of social isolation. I suggest that ostensibly important sanction variables have not been utilized within these existing frameworks. …

Restoring Relationships: Indigenous Ways Of Knowing Meet Undergraduate Environmental Studies And Science, Nancy Leigh Rich

Antioch University Dissertations & Theses

As places to engage with changing and complex ideas, institutions of higher education offer a logical site for bringing Indigenous ways of knowing together with environmental studies and science. However, profound differences between Indigenous and Western knowledges, as well as ongoing colonialism, cultural biases of science, and the nature of mainstream academia, have discouraged this endeavor. Recent developments in undergraduate pedagogy now point the way.

Using critical inquiry and qualitative methodology, this comparative study developed recommendations for practice based on current undergraduate teaching practices that bring Indigenous ways of knowing together with environmental studies and science across a diversity of …

Dormant Ethnobotany: A Case Study Of Decline In Regional Plant Knowledge In The Bull Run Mountains Of Virginia, Susan Rene Leopold

Antioch University Dissertations & Theses

This dissertation introduces and applies the concept of dormant ethnobotany, a concept that helps explain the socio-economic, cultural and ecological aspects and implications of the transition away from active use of ethnobotanical knowledge and the factors that may lead to its re-emergence. Dormant ethnobotany is the study of relationships between people and plants that are inactive, but nonetheless still alive in memories, the historic record, and folklore and thereby capable of reemergence in support of the transition to a more sustainable society. The dissertation extends the field of ethnobotany from its current roots in the dynamic ethnobotany of indigenous peoples. …

Stories Of Resistance: Black Women Corporate Executives Opposing Gendered (Everyday) Racism, Cheryl D. Jordan

Antioch University Dissertations & Theses

For this research, I explored contemporary resistance strategies that Black women executives in the corporate world use to oppose negative behaviors by others associated with their race and gender. The dissertation reviews scholarship about the major role the convergence of race and gender play in the day-to-day existence of Black women. Historically, negative images and beliefs have influenced the treatment of Black women in society. These same thoughts and images affect Black women executives in today’s workplace. African-American women continue to see limited advancement to senior levels within the corporate organization, even though diversity programs abound. As leaders in the …

Collaboration And Climate Action At The Local Scale, Linda Lyshall

Antioch University Dissertations & Theses

This dissertation encompasses a case study and a Participatory Action Research project. The case study focuses on climate change mitigation activities within King County, Washington and its 39 cities and towns and discusses progress and challenges related to transportation issues, efficiency measures, and sustainability planning. The findings indicate there is a high level of activity in waste reduction, environmental outreach and education, bicycle and pedestrian promotion, tree canopy protection, sustainability policies, and green building. Other categories, such as energy efficiency, electric vehicle infrastructure, and greenhouse gas emission inventories and goal setting are on the rise. Twelve of the cities were …

[Introduction To] Basic Statistical Tools For Improving Quality, Paul Kvam, Chang W. Kang

Bookshelf

This book is an introductory book on improving the quality of a process or a system, primarily through the technique of statistical process control (SPC). There are numerous technical manuals available for SPC, but this book differs in two ways: (1) the basic tools of SPC are introduced in a no-nonsense, simple, non-math manner, and (2) the methods can be learned and practiced in an uncomplicated fashion using free software (eZ SPC 2.0), which is available to all readers online as a downloadable product. The book explains QC7 Tools, control charts, and statistical analysis including basic design of experiments. Theoretical …

Examining Effects Of Virtual Machine Settings On Voice Over Internet Protocol In A Private Cloud Environment, Yuan Liao

All-Inclusive List of Electronic Theses and Dissertations

The virtualization of computing resources, as represented by the sustained growth of cloud computing, continues to thrive. Information Technology departments are building their private clouds due to the perception of significant cost savings by managing all physical computing resources from a single point and assigning them to applications or services as needed while remaining in control of their systems and information. As part of this trend, real time communication applications including IP telephony can be integrated with other software applications into one platform and deployed in private clouds to reduce capital expenditure and lower overall costs of daily based maintenance …

Diversity And Inclusion In The Information Technology Industry: Relating Perceptions And Expectations To Demographic Dimensions, Suanu Bliss Wikina

All-Inclusive List of Electronic Theses and Dissertations

The American society, especially the workplace, is becoming increasingly diverse in terms of race/ethnicity, culture, national origin, sexual orientation, familial status, age, religion, disability, and educational attainment (where there are people from different backgrounds and cultures the potential for suspicion and prejudices occur). This study examines diversity and inclusion in the information technology sector and assesses whether differences in group members perceptions and expectations are influenced by gender, race/ethnicity, position, and educational status. This study adopts a descriptive, quantitative approach utilizing a survey in the form of a questionnaire constructed using the Web-based survey software SurveyMonkey. This researcher designed a …

An Open Framework For Low-Latency Communications Across The Smart Grid Network, John Andrew Sturm

All-Inclusive List of Electronic Theses and Dissertations

The recent White House (2011) policy paper for the Smart Grid that was released on June 13, 2011, A Policy Framework for the 21st Century Grid: Enabling Our Secure Energy Future, defines four major problems to be solved and the one that is addressed in this dissertation is Securing the Grid. Securing the Grid is referred to as one of the four pillars to be built on an open technology framework. The problem of securing the grid is further defined that cybersecurity practices must provide the special, low-latency communications needed for real-time automation control (White House, 2011, p. 49). The …

A Sense Of Place: Branding The Richardson Olmsted Complex Through Architectural Motif, Lisa Mauro

Theses

(keywords: Henry Hobson Richardson, Frederick Law Olmsted, Thomas Kirkbride, Romanesque architecture, Buffalo State Asylum for the Insane, 19th century English design reformers, Richardsonian Romanesque, motif, psychology of pattern, pattern design, architectural ornament, place-branding, Buffalo, NY) Motif design and repeat patterns have been used to decorate, communicate and imbue surface with meaning across cultures and eras. It is also evident that pattern satisfies a fundamental psychological need in humans for order and beauty. Motifs are a well-suited graphic design basis from which to create an effective branding strategy with potential to communicate with a subliminal power and in a way that …

Use Of Sarima Models To Assess Data-Poor Fisheries: A Case Study With A Sciaenid Fishery Off Portugal, Nuno Prista, Norou Diawara, Maria J. Costa, Cynthia M. Jones

OES Faculty Publications

Research on assessment and monitoring methods has primarily focused on fisheries with long multivariate data sets. Less research exists on methods applicable to data-poor fisheries with univariate data sets with a small sample size. In this study, we examine the capabilities of seasonal autoregressive integrated moving average (SARIMA) models to fit, forecast, and monitor the landings of such data-poor fisheries. We use a European fishery on meagre (Sciaenidae: Argyrosomus regius), where only a short time series of landings was available to model (n=60 months), as our case-study. We show that despite the limited sample size, a SARIMA model could …

Anaerobic Oxidation Of Methane And The Stoichiometry Of Remineralization Processes In Continental Margin Sediments, David J. Burdige, Tomoko Kamada

OES Faculty Publications

In many coastal and continental margin sediments, pore-water property-property plots yield values of r_c:s, the stoichiometric ratio of dissolved inorganic carbon (DIC) produced to sulfate reduced, that are lower than the commonly assumed value of 2. Remineralization of organic matter more reduced than CH₂O can cause such observations, as can DIC loss due to authigenic carbonate precipitation. However, through studies of Santa Monica Basin sediments, we have observed that these observations could also be related to the occurrence of anaerobic oxidation of methane (AOM) in sediments. Specifically, using a reactive transport sediment model, we have shown …

Structural Studies Of Complex Compounds Of 6,6'-Diacetyl-2,2'-Bipyridine Dioxime With Copper(I/Ii), Platinum(Ii), And Palladium(Ii) Metal Ions, Abdurrahman Şengül, Hakan Ağaç, Burak Çoban, Erol Eroğlu

Turkish Journal of Chemistry

The tetradentate ligand 6,6'-diacetyl-2,2'-bipyridine dioxime (L) was obtained in high yield by the condensation reaction of 6,6'-diacetyl-2,2'-bipyridine with hydroxyl amine in alkaline solution. Density functional calculations and 3D modeling of the structure at the B3LYP/6-31G(d) level of theory for L revealed that the energy difference between the global trans conformer (trans-L), which possesses the C_{2h} point group, and the distorted cis conformer (cis-L) was 5.214 kcal/mol. Synthesis and characterization of the metal complexes with Cu(I), Cu(II), Pt(II), and Pd(II) metal ions were reported. L acted as a N_4-donor ligand to coordinate to the metal centers via N atoms of the …

Synthesis And Characterisation Of Tris(2,4-Dinitrophenoxo)Monooxovanadium(V) And Its Complex Salts, Neeraj Sharma, Reena Sharma, Meena Kumari, Subhash Chaudhry

Turkish Journal of Chemistry

The monooxovanadium(V) complex of composition [VO(OC_6H_3(NO_2)_2-2,4)_3] (I) was synthesized by the reaction of VOCl_3 with Me_3SiOC_6H_3(NO_2)_2-2,4 in toluene and characterised by elemental analyses, molar conductance, and IR, ^1H- and ^{13}C-NMR, and mass spectral studies. The reactions of (I) with alkali metal 2,4-dinitrophenoxides [MOC_6H_3(NO_2)_2-2,4] (M = Li, Na, K) yield complex salts of composition M[VO(OC_6H_3(NO_2)_2-2,4]_4 authenticated by physicochemical and IR spectral studies. Thermal behaviour of complexes was studied by TG and DTA techniques. The molecular modelling calculations of the parent complex and its complex salts were performed to visualise the probable geometry around vanadium metal, which, coupled with spectroscopic evidence, suggests …

A Study Of Behavior Of Some 5-Substituted- 4-Phenyl-1,2,4-Triazoline-3-Thiones In Sulfuric Acid Solution Using Characteristic Vector Analysis, Vesna Dimova

Turkish Journal of Chemistry

The protonation process of 1,2,4-triazoline-3-thiones (T3T) was studied in aqueous sulfuric acid using the UV method. Characteristic vector analysis (CVA) was used to reconstruct the experimentally obtained UV spectra, to overcome difficulties in calculating the protonation constants of T3T, and to separate the effect of protonation from the generalized medium effect. pK_{TH}+ values were calculated using the Hammett acidity function method, the Bunnett and Olsen method, and the excess acidity function method. The obtained values for m, \phi and m* were close to those characteristic for similar thio compounds, indicating that the protonation site in the molecule of T3T is …

A Simple And Rapid Spectrophotometric Determination Of Trace Level Simple And Rapid Spectrophotometric Determination Of Trace Level Chromium Using Bis (Salicylaldehyde) Orthophenylenediamine In Nonionic Micellar Media, Rubina Soomro, Jamaluddin Ahmed, Najma Memon

Turkish Journal of Chemistry

Bis(salicylaldehyde)orthophenylenediamine (BSOPD) has been proposed as new analytical reagent for the direct spectrophotometric determination of chromium. It reacts with chromium(VI) in slightly acidic (0.1 -- 0.3 M H_2SO_4) micellar medium to form a yellow - orange chelate with a molar ratio 2:3. The most remarkable point of this method is that the molar absorptivities of the Cr^{VI} -- BSOPD complex formed in the presence of nonionic TritonX -- 100 surfactant are almost 10 times higher than the value observed in aqueous solution. This results in enhancing the sensitivity and selectivity of the method. The reaction is instantaneous and the maximum …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Synthesis And Biological Activity Of 5-Substituted-2-Amino-1,3,4-Oxadiazole Derivatives, Sanjeev Kumar

Turkish Journal of Chemistry

Electrical energy offers numerous benefits for performing synthesis, including increased reaction rates, enhanced yields, and cleaner chemistries. 5-Substituted-2-amino-1,3,4-oxadiazoles were synthesized directly from the semicarbazone at a platinum electrode under controlled potential electrolysis in an undivided cell assembly in acetonitrile. The compounds were screened for antibacterial and antifungal activity against Staphylococcus aureus, Klebsiella pneumoniae, Pellicularia salmonicolor, and Macrophomina phaseolina.

Synthesis And Antiinflammatory Activity Of Novel 2,5-Disubstituted Thiophene Derivatives, Sahar Badr

Turkish Journal of Chemistry

New series of 2,5-disubstituted thiophenes were synthesized. Thiosemicarbazones 1a-b were reacted with various reagents, such as diethyl-2-bromomalonate, ethyl-2-chloroacetoacetate, thioglycolic acid, 4-substituted phenacyl bromides, and acetic anhydride, to afford heterocyclic substituted thiophene derivatives 2a-b, 3a-b, 4a-b, 5a-b, 6a-b, and 7a-b, respectively. Moreover, cyclization of the key intermediate 1b with chloroacetic acid yielded thiazolidine 9, which on reaction with appropriate aromatic aldehydes afforded the corresponding arylidene derivatives 10a-f. Finally, reaction of N^\-arylidene cyanoacetohydrazide 11 with sulfur and phenylisothiocyanate yielded thiazoline derivative 12, which on treatment with triethylorthoformate and acetic anhydride afforded thiazolo[4,5-d]pyrimidinone derivative 13. Some of the newly synthesized compounds showed promising …

Reaction Dynamics Of Br + Hd: Quantum Wave Packet On Three Potential Energy Surfaces, Qing Song, Wei-Long Quan, Tian-Jun Feng

Turkish Journal of Chemistry

The initial state-resolved reaction probabilities, reaction cross-sections, and rate constants of the reaction Br + HD are computed on 3 potential energy surfaces (denoted as e-LEPS, MB2, and MB3, respectively) by carrying out quantum time-dependent wave packet calculations. The results show that the reactivity of Br + HD on MB3 is much stronger than that on e-LEPS and somewhat weaker than that on MB2. Both of the vibrational and the rotational excitation of reagent HD enhance the reaction, which depends on the PESs and the strongest enhancement effects are on e-LEPS.

Synthesis And Characterization Of Novel Benzovesamicol Analogs, Thaer Assaad

Turkish Journal of Chemistry

Three new racemic vesamicol analogs were successfully prepared in good yields and high purity. All compounds were characterized by both IR and NMR spectroscopy. Compounds (\pm)-5 and (\pm)-6 showed a moderate lipophilicity compared with reference compounds IBVM and DRC140, respectively. However, the lipophilicity of DRC140 and (\pm)-9 showed very similar behaviors.

Stability Study Of Passive Film On Copper Surface As A Function Of Anodic Potential, Amtul Naseer, Athar Yaseen Khan

Turkish Journal of Chemistry

Results for passive film formation and breakdown on copper disk electrodes in buffer solutions, pH 9.2 and 8.5, were reported earlier. The present studies were carried out in a buffer solution, pH 8.0, and together these studies make good material for understanding the effect of pH changes on film texture as a function of potential. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to examine passive film and the variations it went through upon being treated potentiostatically in the range of -0.3 to 0.9 V. On the basis of equivalent circuits used for modeling impedance data in this …

Tridentate Ligands Derived From L-Tert-Leucine For The Cu(Ii) Mediated Asymmetric Henry Reaction, Nesli̇han Korkmaz, Demet Astley, Stephen Thomas Astley

Turkish Journal of Chemistry

Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired \beta-nitroalcohols were obtained.

Synthesis, Characterization, And Biological Activity Studies Of (E)-N'-((Thiophen-2-Yl)Methylene)Benzofuran-2-Carbohydrazide And Its Metal(Ii) Complexes, Madappa B. Halli, Vijayalaxmi B. Patil, Sumathi R. Bevinamarada

Turkish Journal of Chemistry

Metal complexes of the type MLX_2, where M = Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II), and X = Cl and L = TMBC, Schiff base derived from the condensation of benzofuran-2-carbohydrazide with thiophene-2-aldehyde were synthesized. The structure of the complexes was proposed in light of analytical, IR, UV-Vis, ^1H-NMR, FAB-MS, ESR spectral data, and magnetic studies. The complexes were soluble in DMF and DMSO. The measured molar conductance values indicated that the complexes were nonelectrolytic in nature. On the basis of these studies, 6 coordinated octahedral polymeric structures were assigned to the Co(II), Ni(II), and Cu(II) complexes, and 4 …