Digital Commons Network^™

A Practical Photoelectrochemical Cell Using Nonprecious Metal Electrodes, Patrick Enright, Tony Betts, John Cassidy

Articles

Abstract: Photoelectrochemical cells (PECs) can be used to harvest light from the oxidation of dissolved organic matter. Similar to fuel cells but requiring light to operate, PECs contain a light assisted electrode that oxidises electron rich materials (anode); these electrons then flow to a typically Pt cathode where O₂ is normally the electron acceptor. In this work a PEC cell containing inexpensive materials was shown to (a) mineralise typical organic compounds present in waste water and (b) produce electricity from their decomposition. The PEC cell consisted of a TiO₂ coated conducting ink anode exposed to a light source, …

Non Aggregated Colloidal Silver Nanoparticles For Surface Enhanced Resonance Raman Spectroscopy, Aoife Power, John Cassidy, Tony Betts

Articles

Silver nanoparticles with a tuneable l max were produced as colloids by heterogeneous nucleation. The synthesis process is both fast and repeatable, producing stable PVA capped nanoparticles. The colloid’s effectiveness in the SERRS system was investigated using Rhodamine 6G, R6G, Crystal Violet, CV, and Malachite Green, MG, as probe molecules. A clear sensing trend was observed, where the Raman signal emitted was significantly enhanced by the addition of silver nanoparticles. A build up of signal intensity is observed until an optimum ratio is achieved, followed by a decline in signal intensity as the concentration of nanoparticles is further increased. The …

Chromium Salen, Gráinne Hargaden, Pier Giorgio Cozzi

Articles

No abstract provided.

Di-Tert Butyl Chlorosilane, Gráinne Hargaden, Timothy O'Sullivan

Articles

No abstract provided.

On Adjoint Entropy Of Abelian Groups, Brendan Goldsmith, Ketao Gong

Articles

The theory of endomorphism rings of algebraic structures allows, in a natural way, a systematic approach based on the notion of entropy borrowed from dynamical systems. In the present work we introduce a \lq dual\rq \ notion based upon the replacement of the finite groups used in the definition of algebraic entropy, by subgroups of finite index. The basic properties of this new entropy are established and a connection to Hopfian groups is investigated.

Holomorphic Liftings From Infinite Dimensional Spaces, Sean Dineen, Milena Venkova

Articles

We obtain a number of positive solutions to a holomorphic lifting problem on a domain in a locally convex space.

Integrating Formative Feedback Into Individual And Group Assessments In A First Year Organic Chemistry Module, Barry Ryan, Julie Dunne

Conference papers

It is common for science undergraduates, particularly first year students, to remark that they do not receive appropriate support in their transition from second level to third level education; particularly in effective scientific laboratory report writing, new subject area preparedness and technical ‘know-how’ [1]. This is compounded by the insufficient, or inappropriate, feedback offered to students in these problem areas. The pedagogical emphasis often focuses on quantity rather than quality; both in report writing and content delivered. This publication describes an assessment methodology redesign to, firstly, incorporate on-line formative feedback and; secondly, to introduce one-to-one and one-to-group lab report feedback …

A Review Of Situation Identification Techniques In Pervasive Computing, Juan Ye, Simon Dobson, Susan Mckeever

Conference papers

No abstract provided.

Feasibility Study Of Utility-Directed Behaviour For Computer Game Agents, Colm Sloan, John D. Kelleher, Brian Mac Namee

Conference papers

Utility-based control (UBC) hasn’t been widely adopted for commercial game AI. Some of the reasons for this are that UBC is perceived to be: (1) resource intensive, (2) difficult to design complex behaviours with, and (3) difficult to scale for use in complex environments. This paper investigates these perceptions to see if UBC is suitable for controlling the behaviour of non-player characters in commercial games. The investigation compares agents using a UBC system against two control systems that are more frequently used in commercial games: finite state machines (FSMs), considered a simple control system, and goal-oriented action planning (GOAP), considered …

Feeling The Ambiance: Using Smart Ambiance To Increase Contextual Awareness In Game Agents, Colm Sloan, John D. Kelleher, Brian Mac Namee

Conference papers

The behaviour of non-player character game agents can be made more interesting and believable through the use of increased contextual awareness. In this paper, we present smart ambiance which allows information about the am- biance of an environment (determined by the environment itself, objects in the environment and recent events) to be used in agent plan generation. We demonstrate how this leads to contextually in uenced action selection and, in turn, more interesting and believable character behaviour.

Investigating Intrinsic And Extrinsic Variables During Simulated Internet Search, Molly M. Liechty, Poornima Madhaven

Psychology Faculty Publications

Using an eye tracker we examined decision-making processes during an internet search task. Twenty experienced homebuyers and twenty-five undergraduates from Old Dominion University viewed homes on a simulated real estate website. Several of the homes included physical properties that had the potential to negatively impact individual perceptions. These negative externalities were either easy to change (Level 1) or impossible to change (Level 2). Eye movements were analyzed to examine the relationship between participants' "stated preferences"[verbalized preferences], "revealed preferences" [actual decisions[, and experience. Dwell times, fixation durations/counts, and saccade counts/amplitudes were analyzed. Results revealed that experienced homebuyers demonstrated a more refined …

Density And Temperature Scaling Of Disorder-Induced Heating In Ultracold Plasmas, Scott D. Bergeson, A. Denning, M. Lyon, F. Robicheaux

Faculty Publications

We report measurements and simulations of disorder-induced heating in ultracold neutral plasmas. Fluorescence from plasma ions is excited using a detuned probe laser beam while the plasma relaxes from its initially disordered nonequilibrium state. This method probes the wings of the ion velocity distribution. The simulations yield information on time-evolving plasma parameters that are difficult to measure directly and make it possible to connect the fluorescence signal to the rms velocity distribution. The disorder-induced heating signal can be used to estimate the electron and ion temperatures ~100 ns after the plasma is created. This is particularly interesting for plasmas in …

Natural Product Drug Discovery Against Tropical Diseases, Wai Sheung Ma

USF Tampa Graduate Theses and Dissertations

This dissertation describes the isolation of secondary metabolites from natural origins through a series of chromatographic techniques and spectrometric characterization in the effort of drug discovery. The isolated compounds obtained were used as drug leads against tropical diseases, namely malaria and leishmaniasis. While first chapter offers an introduction on the use of a natural product by itself as an effective therapeutic and its role on inspiring the discovery of new drugs, the later chapters will concentrate on isolation and characterization of bioactive natural products from an Antarctic sponge and mangrove endophytic fungi during the dissertation work.

The second chapter describes …

Numeracy, Cancer Risk Perceptions, And Self-Protective Behaviors Among U.S. Adults, Teri Malo

USF Tampa Graduate Theses and Dissertations

Individuals have become more involved in health-related decisions, in part due to an unprecedented access to information that can be used to enhance both physical and mental health. Much of this health-related information is presented in a numerical format; unfortunately, research suggests many Americans may not possess the literacy skills necessary to comprehend numerical health-related information. More research needs to be conducted to examine numeracy and its role in cancer risk perceptions, and how those risk perceptions relate to cancer self-protective behaviors. The purpose of the current study was to: (a) examine socio-demographic variables associated with numeracy, (b) determine which …

Automorphism Groups Of Quandles, Jennifer Macquarrie

USF Tampa Graduate Theses and Dissertations

This thesis arose from a desire to better understand the structures of automorphism groups and inner automorphism groups of quandles. We compute and give the structure of the automorphism groups of all dihedral quandles. In their paper Matrices and Finite Quandles, Ho and Nelson found all quandles (up to isomorphism) of orders 3, 4, and 5 and determined their automorphism groups. Here we find the automorphism groups of all quandles of orders 6 and 7. There are, up to isomoprhism, 73 quandles of order 6 and 289 quandles of order 7.

Impacts Of Artificial Reefs On Surrounding Ecosystems, Sarine Manoukian

USF Tampa Graduate Theses and Dissertations

Artificial reefs are becoming a popular biological and management component in shallow water environments characterized by soft seabed, representing both important marine habitats and tools to manage coastal fisheries and resources. An artificial reef in the marine environment acts as an open system with exchange of material and energy, altering the physical and biological characteristics of the surrounding area. Reef stability will depend on the balance of scour, settlement, and burial resulting from ocean conditions over time. Because of the unstable nature of sediments, they require a detailed and systematic investigation.

Acoustic systems like high-frequency multibeam sonar are efficient tools …

Chemical Investigation Of The Antarctic Marine Invertebrates Austrodoris Kerguelenensis & Dendrilla Membranosa And The Antarctic Red Alga Gigartina Skottsbergii, John Alan Maschek

USF Tampa Graduate Theses and Dissertations

The marine realm and, in particular, the Antarctic benthos is largely unexplored and understudied. The chemical investigation reported herein reveals not only the biodiversity, but how that biodiversity manifests remarkable chemical diversity. In our continuing study of the nudibranch Austrodoris kerguelenensis, we have isolated a diverse suite of diterpenoid glyceride esters, palmadorins D - S (2.32 - 2.47), one of which is the first reported halogenated diterpene from a dorid nudibranch. Utilizing genomic data from collaborators, we have investigated the chemical diversity from phylogenetically unique specimens collected in close proximity to one another. Chemical groupings based on comparison of LC/MS …

The Influence Of Meteorological Parameters On Rainfall And Severe Weather In Pinellas County, Fl, Cristina A. Mazza

USF Tampa Graduate Theses and Dissertations

Pinellas County is located on a peninsula in Florida that experiences daily patterns of sea breeze associated rainfall mainly during the summer months of June through August. Previously, rainfall patterns, amounts and timing and severe weather in Pinellas County have not been examined considering dominant wind flow patterns, sea breeze circulations and other atmospheric variables. To improve forecasting of local mesoscale phenomena, this project examined the rainfall patterns, amounts and timing and severe weather occurrences that occur as a result of sea breezes and associated prevailing wind regimes within Pinellas County for the months of June, July and August for …

Seasonal Changes In The Sinking Particulate Flux And In The Nitrogen Cycle Within The Euphotic And Twilight Zones Of The Cariaco Basin, Venezuela, Enrique Montes-Herrera

USF Tampa Graduate Theses and Dissertations

This study explored the effects of seasonal variability on the geochemistry of sinking pthesiss and on the nitrogen cycle of the Cariaco Basin. Pthesis fluxes were measured at the base of the euphotic zone (the depth of 1% of photosynthetically active radiation - PAR) with drifting sediment traps during months of upwelling and non-upwelling regimes from March 2007 to November 2009. Flux estimates were analyzed in the context of seasonal variations in sea surface temperature, primary productivity, and chlorophyll a concentrations using data generated by the CARIACO Time-series Program as well as satellite data. Additionally, nine years (1996-2000 and 2004-2007) …

A Proposed Theoretical Model Of Literacy Learning Using Multisensory Structured Language Instruction (Msli), Judith E. Rusinko

Antioch University Dissertations & Theses

Multisensory Structured Language Instruction has been used for decades by clinicians and practitioners as an intervention for teaching students with dyslexia. Multisensory Structured Language Instruction uses the integration of multiple senses (visual, auditory, and kinesthetic/tactile) simultaneously to teach literacy. Although the anecdotal evidence for Multisensory Structured Language Instruction is strong, there is a lack of empirical evidence to support its effectiveness. In addition, Multisensory Structured Language Instruction includes the foundational skills recommended by the National Reading Panel (2000), but the use of multiple senses to teach these skills has not been thoroughly studied. This theoretical dissertation focused on one element …

The Role Of Nature In John Muir's Conception Of The Good Life, Randy R. Larsen

Antioch University Dissertations & Theses

Aristotle says our best moral guidance comes from considering the lives of exemplary individuals. I explore John Muir, as an exemplar of environmental virtue, and consider the role of Nature in his conception of the good life. I argue his conception consists of a web of virtue including various goods, values, and virtues. I suggest three virtues are cardinal: attentiveness, gratitude and reverence. I explore how Muir cultivated these virtues in Nature.

I argue Muir sought freedom from a popular conception of the good life, grounded in the gilded age values of money and materialism, and was sensitive to the …

A Qualitative Approach To Spiral Of Silence Research: Self-Censorship Narratives Regarding Environmental And Social Conflict, Christopher John Ryan

Antioch University Dissertations & Theses

The purpose of this research is to seek narratives of self-censorship from in-depth interviews of 19 participants acquired through a purposive (criterion) sampling protocol. The primary research question driving this study is “What types of sanctions contribute to people choosing to self-censor their strongly held beliefs, values, and opinions.” Previous research conducted on the topic of self-censorship (generally under the rubric of the spiral of silence theory) has been predominantly quantitative and consideration of sanctions influencing self-censorship have been limited to fear of social isolation. I suggest that ostensibly important sanction variables have not been utilized within these existing frameworks. …

Restoring Relationships: Indigenous Ways Of Knowing Meet Undergraduate Environmental Studies And Science, Nancy Leigh Rich

Antioch University Dissertations & Theses

As places to engage with changing and complex ideas, institutions of higher education offer a logical site for bringing Indigenous ways of knowing together with environmental studies and science. However, profound differences between Indigenous and Western knowledges, as well as ongoing colonialism, cultural biases of science, and the nature of mainstream academia, have discouraged this endeavor. Recent developments in undergraduate pedagogy now point the way.

Using critical inquiry and qualitative methodology, this comparative study developed recommendations for practice based on current undergraduate teaching practices that bring Indigenous ways of knowing together with environmental studies and science across a diversity of …

Dormant Ethnobotany: A Case Study Of Decline In Regional Plant Knowledge In The Bull Run Mountains Of Virginia, Susan Rene Leopold

Antioch University Dissertations & Theses

This dissertation introduces and applies the concept of dormant ethnobotany, a concept that helps explain the socio-economic, cultural and ecological aspects and implications of the transition away from active use of ethnobotanical knowledge and the factors that may lead to its re-emergence. Dormant ethnobotany is the study of relationships between people and plants that are inactive, but nonetheless still alive in memories, the historic record, and folklore and thereby capable of reemergence in support of the transition to a more sustainable society. The dissertation extends the field of ethnobotany from its current roots in the dynamic ethnobotany of indigenous peoples. …

Stories Of Resistance: Black Women Corporate Executives Opposing Gendered (Everyday) Racism, Cheryl D. Jordan

Antioch University Dissertations & Theses

For this research, I explored contemporary resistance strategies that Black women executives in the corporate world use to oppose negative behaviors by others associated with their race and gender. The dissertation reviews scholarship about the major role the convergence of race and gender play in the day-to-day existence of Black women. Historically, negative images and beliefs have influenced the treatment of Black women in society. These same thoughts and images affect Black women executives in today’s workplace. African-American women continue to see limited advancement to senior levels within the corporate organization, even though diversity programs abound. As leaders in the …

Collaboration And Climate Action At The Local Scale, Linda Lyshall

Antioch University Dissertations & Theses

This dissertation encompasses a case study and a Participatory Action Research project. The case study focuses on climate change mitigation activities within King County, Washington and its 39 cities and towns and discusses progress and challenges related to transportation issues, efficiency measures, and sustainability planning. The findings indicate there is a high level of activity in waste reduction, environmental outreach and education, bicycle and pedestrian promotion, tree canopy protection, sustainability policies, and green building. Other categories, such as energy efficiency, electric vehicle infrastructure, and greenhouse gas emission inventories and goal setting are on the rise. Twelve of the cities were …

[Introduction To] Basic Statistical Tools For Improving Quality, Paul Kvam, Chang W. Kang

Bookshelf

This book is an introductory book on improving the quality of a process or a system, primarily through the technique of statistical process control (SPC). There are numerous technical manuals available for SPC, but this book differs in two ways: (1) the basic tools of SPC are introduced in a no-nonsense, simple, non-math manner, and (2) the methods can be learned and practiced in an uncomplicated fashion using free software (eZ SPC 2.0), which is available to all readers online as a downloadable product. The book explains QC7 Tools, control charts, and statistical analysis including basic design of experiments. Theoretical …

Examining Effects Of Virtual Machine Settings On Voice Over Internet Protocol In A Private Cloud Environment, Yuan Liao

All-Inclusive List of Electronic Theses and Dissertations

The virtualization of computing resources, as represented by the sustained growth of cloud computing, continues to thrive. Information Technology departments are building their private clouds due to the perception of significant cost savings by managing all physical computing resources from a single point and assigning them to applications or services as needed while remaining in control of their systems and information. As part of this trend, real time communication applications including IP telephony can be integrated with other software applications into one platform and deployed in private clouds to reduce capital expenditure and lower overall costs of daily based maintenance …

Diversity And Inclusion In The Information Technology Industry: Relating Perceptions And Expectations To Demographic Dimensions, Suanu Bliss Wikina

All-Inclusive List of Electronic Theses and Dissertations

The American society, especially the workplace, is becoming increasingly diverse in terms of race/ethnicity, culture, national origin, sexual orientation, familial status, age, religion, disability, and educational attainment (where there are people from different backgrounds and cultures the potential for suspicion and prejudices occur). This study examines diversity and inclusion in the information technology sector and assesses whether differences in group members perceptions and expectations are influenced by gender, race/ethnicity, position, and educational status. This study adopts a descriptive, quantitative approach utilizing a survey in the form of a questionnaire constructed using the Web-based survey software SurveyMonkey. This researcher designed a …

An Open Framework For Low-Latency Communications Across The Smart Grid Network, John Andrew Sturm

All-Inclusive List of Electronic Theses and Dissertations

The recent White House (2011) policy paper for the Smart Grid that was released on June 13, 2011, A Policy Framework for the 21st Century Grid: Enabling Our Secure Energy Future, defines four major problems to be solved and the one that is addressed in this dissertation is Securing the Grid. Securing the Grid is referred to as one of the four pillars to be built on an open technology framework. The problem of securing the grid is further defined that cybersecurity practices must provide the special, low-latency communications needed for real-time automation control (White House, 2011, p. 49). The …