Digital Commons Network^™

The Response Of Plant Community Structure And Productivity To Changes In Hydrology In Alaskan Boreal Peatlands, Amber C. Churchill

Biological Sciences

Northern peatlands have been a long-term sink for atmospheric CO₂, and have had a net cooling effect on global climate for the last 8,000 to 11,000 years. Across Alaska, peatlands face increased effects of climate change through hydrologic disturbance, both drying and flooding, and these conditions alter the ability of peatlands to accumulate carbon. Here, I examined the influence of changing hydrology in a moderate rich fen and a bog located in the discontinuous permafrost zone of interior Alaska. In both sites, I quantified how changing hydrology affected vegetation composition and ecosystem carbon uptake. At the fen, drying via a …

Determination Of Select Metal Ions In Commercially Available Conventional And Organic Baby Foods., Neva S. Winters

Electronic Theses and Dissertations

The goal of this study is to determine whether or not there is an appreciable difference between concentrations of various metal ions present in conventionally grown and processed and organically grown and processed baby foods. Two prominent, commercially available brands were chosen to undergo comparative studies between both their own conventional and organic varieties of second stage green beans and carrots. Samples were tested for cadmium, calcium, iron, lead, nickel, and zinc. Two containers of each variety of baby food were sampled in triplicate, with purchases of foods being made in separate areas to ensure that each set came from …

Student Outcomes And The Implementation Of A Ninth Grade Academy In A Western North Carolina High School., Monet Calloway Samuelson

Electronic Theses and Dissertations

One purpose of this study was to compare outcomes of students who were part of a 9^th grade academy during their freshman year with outcomes of students who were not part of a 9^th grade academy during their freshman year. Student outcomes are defined for this study to include attendance, promotion rate to 10^th grade on time, in-school suspension assignments, Algebra I End-of-Course exam scores, and English I End-of-Course exam scores. The second purpose of this study was to compare outcomes of 10^th grade students who were part of a 9^th grade academy during their …

Correlation Between The Tcap Test And Thinklink Learnings Predictive Assessment Series Test In Reading Math And Science In A Tennessee School System., Jared Edwin Day

Electronic Theses and Dissertations

The purpose of the study was to determine if a correlation existed between the Predictive Assessment Series (PAS) Test, marketed by Discovery Education, and the Tennessee Comprehensive Assessment Program (TCAP) Achievement Test in reading, math, and science for grade 4, grade 6, and grade 8. The study included 4^th-grade, 6^th-grade, and 8^th-grade students during the 2008-2009 school year who had taken the ThinkLink Predictive Assessment Series for reading, math, and science in February 2009 and had taken the TCAP reading, math, and science test in April 2009.

The approach of the study was quantitative …

Use Of Isometric Mid-Thigh Pull To Determine Asymmetrical Strength Differences In Ncaa D-I Athletes., Ethan Monroe Owens

Electronic Theses and Dissertations

The purpose of this study is to investigate the use of isometric mid-thigh pulls to determine lower-limb asymmetrical strength differences in NCAA D-I athletes. Sixty-six subjects (40 males and 26 females) performed 2 maximal effort isometric pulls over two force plates sampling at 1000 Hz each. Peak force was scaled for body weight, and rate of force development was examined from 0-200ms. Results of the study show subjects' produced significantly greater scaled force with the left leg as compared to the right leg; however, no significant differences existed for rate of force development (RFD). Men exhibited significant differences between both …

Modified Organoclay Containing Chelating Ligand For Adsorption Of Heavy Metals In Solution., Mary Akuyea Addy

Electronic Theses and Dissertations

Presence of a chelating ligand in the clay structure significantly improves its ability to immobilize heavy metals from contaminated sludge or wastewater. Two-step modification procedure comprising sequential pillaring and grafting of chelating agent to the modified clay is involved.

Montmorillonite and kaolin were chosen as typical examples of expandable and non-expandable clays, correspondingly. Modifications with silica and ferric oxide were targeted on development of mesoporous structure. Laboratory tests of the organoclay efficiency for purification of wastewater were conducted with the most promising sample, i.e. organoclay with the highest specific loading of chelating agent. Experiments were conducted with model wastewater containing …

Mesoporous Functionalized Materials For Post-Combustion Carbon Dioxide Capture., Kolade Omoniyi Ojo

Electronic Theses and Dissertations

Novel highly functionalized hybrid organic-inorganic materials were synthesized by polycondensation of bis[3-(trimethoxysilyl)propyl]amine in presence of cationic and anionic surfactants. Reaction media strongly affected gelation time. Thus, in basic media gelation occurred immediately while acid increased gelation time. Material structures were studied by IR spectroscopy, porosimetry, XRD, and SAXS methods. In spite of the absence of an inorganic linker, obtained bridged silsesquioxanes had mesoporous structure. A material prepared in the presence of dodecylamine as a template had higher surface area and narrow pore size distribution while the use of sodium dodecylbenzene sulfate resulted in formation of mesopores with wide size ranges. …

A Study Of The Effects Of Titanium Dioxide Nanoparticles On The Fluorescent Intensity Of Fluorescent Compounds In The Presence Of Known Quenchers., Vivian Dzigbodi Koka

Electronic Theses and Dissertations

Titanium Dioxide is a naturally occurring oxide of titanium. It has a wide range of uses in commercial products for providing whiteness and opacity. It has photocatalytic properties and can also be used to produce electricity in its nanoparticles form. This research is focused on investigating the effect of titanium dioxide nanoparticles in analysis of compounds using luminescence-based techniques. Quenching, which is one of the basic problems of fluorescent measurements, was studied in the presence of molecular oxygen and methyl iodide. The rutile phase of titanium dioxide nanoparticles was synthesized by the acid hydrolysis of titanium isobutoxide at low temperatures …

Reproductive Ecology And Morphometric Subspecies Comparisons Of Dunlin (Calidris Alpina), An Arctic Shorebird, Heather River Gates

Biological Sciences

The Arctic region provides globally important breeding and migratory habitat for abundant wildlife populations including migratory shorebirds. Due to their remote breeding locations, basic information on breeding ecology, annual productivity, and factors that regulate their populations are poorly studied. Wildlife biologists managing migratory bird populations require detailed information on avian breeding biology, in addition to information on migration ecology including connectivity of migratory stopover and wintering locations. To address information gaps in fecundity, I conducted an experimental study investigating the renesting ecology of Dunlin (Calidris alpina arcticola) by removing clutches at two stages of incubation and by following adults marked …

Terrestrial Invertebrate Prey For Juvenile Chinook Salmon: Abundance And Environmental Controls In An Interior Alaska River, Laura Gutierrez

Biological Sciences

Terrestrial prey subsidies can be a key food source for stream fish, but their importance and environmental controls on their abundance have not been widely documented in high latitude ecosystems. This study investigated terrestrial invertebrate prey availability and predation by age-0+ juvenile chinook salmon (Oncorhynchus tshawytscha), overlap between terrestrial infall and drift to diet, and the relationship between diet to stream temperature and discharge in the Chena River, Interior Alaska. Terrestrial infall, drift, and juvenile chinook diet varied widely through the summers (May-September) of 2008 and 2009. Drift was comprised of 33% terrestrial and 67% aquatic invertebrate mass, while juvenile …

Novel Fungal Taxa In An Alaskan Boreal Forest: Phylogenetic Affinities, Ecologies, And Ribosomal Rna Secondary Structures, Daniel Glass

Biological Sciences

Phylogenetic analyses suggest that a novel DNA sequence (NS1) found in a boreal forest soil-clone library belongs to the fungal kingdom but does not fall unambiguously within any known class. In order to determine if NS1 codes for an authentic ribosomal RNA (rRNA) gene-copy, I modeled ribosomal RNA secondary structure for four gene regions. Such analyses have never been used on environmental ribosomal sequences before. It appears that NS1 does code for an authentic gene-copy and is not a biological or lab artifact. I also elucidated the habitat preferences, horizon preferences, and fine-scale spatial structure of NS1 using molecular methods. …

Using Electrochemical Method To Study The Interaction Between Dna And A Compound Known To Have Anticancer Property., Alexander Kamasah

Electronic Theses and Dissertations

The interaction of 4-(1'-[8'-(1''-pyrenyl)naphthyl])-2,6-diaminopyridine bis-glycamide bishydrocholride known to have anticancer properties with deoxyribonucleic acid (DNA) had been studied on a modified gold electrode by self-assembled monolayer using cyclic voltammetry. K₄Fe (CN)₆ was used as a probe to obtain electrochemical information on the electrode surface.

A bare gold (Au) electrode was modified with cysteamine and our results showed no change in the limiting steady state current as compared to the bare Au electrode. There was a reduction in the steady state current after the modification of the gold electrode with DNA. Immobilization of the DNA modified gold electrode …

Synthesis Of Resveratrol Ester Derivatives Using Selective Enzymatic Hydrolysis., Marian Osei-Mensah

Electronic Theses and Dissertations

Resveratrol, a naturally derived stilbene, is an interesting compound mostly talked about recently because for its anti-cancer properties. Unfortunately it has some shortcomings due to its low bioavailability and low solubility in water. For this reason, my research is to overcome resveratrol's drawbacks by improving its bioavailability and hydrophilicity. My research is focused on syntheses of novel derivatives of resveratrol such as 3, 5-di-O-isobutyroyl resveratrol and 3, 5-di-O-hexanoyl resveratrol using lipase catalyzed hydrolysis. Therefore, the tri-acylated resveratrols 3, 5, 4'-tri-O-isobutyroyl resveratrol and 3, 5,4'-tri-O-hexanoyl resveratrol were first synthesized.

3,5,4'-tri-O-isobutyroyl resveratrol and 3,5,4'-tri-O-hexanoyl resveratrol were then hydrolyzed using lipase (C. …

Statistical Spectral Parameter Estimation Of Acoustic Signals With Applications To Byzantine Music, Kyriakos Michael Tsiappoutas

LSU New Orleans Theses and Dissertations

Digitized acoustical signals of Byzantine music performed by Iakovos Nafpliotis are used to extract the fundamental frequency of each note of the diatonic scale. These empirical results are then contrasted to the theoretical suggestions and previous empirical findings. Several parametric and non-parametric spectral parameter estimation methods are implemented. These include: (1) Phase vocoder method, (2) McAulay-Quatieri method, (3) Levinson-Durbin algorithm,(4) YIN, (5) Quinn & Fernandes Estimator, (6) Pisarenko Frequency Estimator, (7) MUltiple SIgnal Characterization (MUSIC) algorithm, (8) Periodogram method, (9) Quinn & Fernandes Filtered Periodogram, (10) Rife & Vincent Estimator, and (11) the Fourier transform. Algorithm performance was very precise. …

Measuring Early Numeracy Of Kindergarten Students In A Group Setting, Stacy A. Winck

LSU New Orleans Theses and Dissertations

Early identification practices in assessment are crucial to preventing academic failure as well as identifying students at-risk for later learning disabilities. The PAM Early Numeracy Screening is a set of subscales designed to measure early numeracy in kindergarten students in a group setting. Given that the existing early numeracy measures are individually administered, the purpose of the current study was to explore the psychometric properties of the PAM Early Numeracy Screening. Correlational analysis was the primary research design used to investigate the evidence of reliability, criterion-related validity, and construct validity of the PAM Early Numeracy Screening. Criterion measures …

Synthesis And Antifungal Evaluation Of Spirostane Saponins, Sunil Upadhyay

LSU New Orleans Theses and Dissertations

Methods for the preparation of novel antifungal saponins have been investigated in

order to further explore their medicinal utility and provide the opportunity to synthesize

their derivatives.

Through this work, several partially protected stereoisomers of Cholestane,

Androstane and Spirostane have been prepared which could be used for the synthesis of

various saponin derivatives in order to discover novel saponin based antifungal agent.

Various mono and disaccharide derivatives of these steroids have been synthesized and

evaluated for their antifungal activity against four pathogenic fungal strains. Among the

various derivatives maltose derivatives were found to have the best antifungal activity.

However there …

Synthesis Of N-(Substituted Phenyl) Acetamides., Landon Zink

Undergraduate Honors Theses

No abstract.

Fluid Characterization And Phase Behavior Studies Of Oil From The Frozen Reservoir Of Umiat Oil Field, Alaska, Chinmay Shukla

Engineering

Umiat oil field is the largest oil accumulation in National Petroleum Reserve (NPRA) No. 4 of Alaska. Shallow reservoir depths, low reservoir pressures, and low temperatures with most of the oil-producing zone in a continuous layer of permafrost are unique characteristics that make Umiat reservoir unconventional and difficult to produce. However, unavailability of fluid characterization and phase behavior data needed for reservoir simulation studies pose challenges in developing an effective production strategy. Given the conspicuous lack of complete fluid data on Umiat oils and the unavailability of live oil samples from Umiat, an experimental study was undertaken to characterize and …

College Readiness Of African-American Student Athletes, Carol Bos, Grace Chaidez, Andrew Nunn-Miller, Daisy Rodriguez

Program Design and Evaluation

Research project of The Larry English Foundation- Leading Education to Athletes for their Dreams, focusing on African-American student-athletes.

Illinois State University, One Hundred And Fifty-Second Annual Commencement, December 17, 2011, Illinois State University

Commencement Programs

Normal, Illinois
Illinois State University
One Hundred and Fifty-Second Annual Commencement
December 17, 2011

Self-Assemblies Driven By The Hydrophobic Effect, Haiying Gan

LSU New Orleans Theses and Dissertations

Water is a simple molecule but is an essential part of life. One key aspect of the properties of water is the hydrophobic effect, and whilst there is an appreciation of this phenomenon at the macro-scale (raindrops falling off leaves) and the micro-scale (the structure of cellular systems), a complete understanding at the molecular level still eludes science. Addressing this issue, our studies involve synthetic supramolecular compounds that assemble in water via the hydrophobic effect.

First of all, a novel water-soluble deep-cavity cavitand was synthesized. It possesses four endo methyl groups on top rim of the cavitand, eight water-solubilizing carboxylic …

Synthesis And Biological Evaluation Of Aeruginosin Based Compounds And Self-Assembly Of Glucosamine Based Compounds, Navneet Goyal

LSU New Orleans Theses and Dissertations

Aeruginosins are a family of marine natural products containing mostly non-proteogenic amino acids. These compounds contain a common 2-carboxy-6-hydroxy-octaindole (Choi) rigid bicyclic structure. Many aeruginosins are inhibitors for enzymes involved in the blood coagulation cascade, such as thrombin and Factor VIIa. In order to understand the structure activity relationship (SAR) of the aeruginosins and to discover novel anticoagulants with potentially improved inhibitory and pharmacokinetic properties, in the first part of my thesis I have discussed, synthesis of a series of novel analogs of aeruginosin 298-A, in which the Choi will be replaced with L-proline and oxygenated Choi analogs, and the …

Use Of Hurst And Renyi Analysis To Detect And Characterize Pacific Decadal Oscillation Impacts On Climate Variability In Alaska, Jean K. Talbot

Atmospheric Sciences

While climate systems are known be nonlinear, most statistical tools used to study climate are linear. Two nonlinear analyses are introduced for indicating predictability in climate studies: Hurst analysis and Renyi analysis, the advantages of which are illustrated by applying both to characterize Alaska climate time series 'dynamics' or temporal evolution. These methods are also applied to reanalysis and model data to compare with the observational analysis. Hurst analysis is used to calculate long term predictability in data on a scale of five to 15 years; Renyi analysis is used to quantify the degree of order on a time scale …

A Dynamical Study Of The Evolution Of Pressure Waves Propagating Through A Semi-Infinite Region Of Homogeneous Gas Combustion Subject To A Time-Harmonic Signal At The Boundary, John Eslick

LSU New Orleans Theses and Dissertations

In this dissertation, the evolution of a pressure wave driven by a harmonic signal on the boundary during gas combustion is studied. The problem is modeled by a nonlinear, hyperbolic partial differential equation. Steady-state behavior is investigated using the perturbation method to ensure that enough time has passed for any transient effects to have dissipated. The zeroth, first and second-order perturbation solutions are obtained and their moduli are plotted against frequency. It is seen that the first and second-order corrections have unique maxima that shift to the right as the frequency decreases and to the left as the frequency increases. …

Evaluation Of Pgaa Data For Provenance Of Lithic Artifacts, Otis N. Crandell

Studia UBB Geologia

The objectives of the study were to determine whether Prompt Gamma Activation Analyses (PGAA) could be successfully used to trace the source(s) of various Neolithic artifacts made of microcrystaline quartz. Two macroscopically identical sources of jasper from central and western Romania were analyzed by PGAA along with five Neolithic artifacts from the Limba site (Alba County). Due to the limited number of trace elements, which can be measured by PGAA, this method when used alone might produce inconclusive results for discriminating between jaspers from different sources. The interpretation of the data may be used for general assessments of provenance involving …

2011 Winter Boise State University Commencement Program, Boise State University Commencement Committee

Commencement Programs

No abstract provided.

Reactions With Platinum (Ll) Complexes And Selenium-Containing Amino Acids, Stephanie Robey

Mahurin Honors College Capstone Experience/Thesis Projects

We have reacted [Pt(Me₄en)(D₂O)₂]²⁺ [Me₄En=N,N,N’N’-tetramethylethylenediamine] with Selenomethionine (SeMet), Methionine (Met), and Methylselenocysteine (MeSeCys). When MeSeCys was reacted with [Pt(Me₄en)(D₂O)₂]²⁺, we observed both stereoisomers of Se,N chelates, as well as [Pt(Me₄en)(MeSeCys)Cl]⁺ from ­¹­H NMR Spectroscopy; the latter formed due to the presence of Cl^- in the solution. Both isomers of the chelate seemed to form proportionally to one another, not favoring a specific stereoisomer. Eventually the [Pt(Me₄en)(MeSeCys)Cl]⁺ products became Se,N chelates. We incubated SeMet with …

The Vulnerability Assessment And Penetration Testing Of Two Networks, Steven L. Simpson

Regis University Student Publications (comprehensive collection)

Vulnerability assessments and penetration testing are two approaches available for use by internet security practitioners to determine the security posture of information networks. By assessing network vulnerabilities and attempting to exploit found vulnerabilities through penetration testing security professionals are able to evaluate the effectiveness of their network defenses by identifying defense weaknesses, affirming the defense mechanisms in place, or some combination of the two. This project is a discussion of the methods and tools used during the vulnerability assessment and penetration testing, and the respective test results of two varied and unique networks. The assessment and testing of the first …

Nonparametric Copula Density Estimation In Sensor Networks, Leming Qu, Hao Chen, Yicheng Tu

Mathematics Faculty Publications and Presentations

Statistical and machine learning is a fundamental task in sensor networks. Real world data almost always exhibit dependence among different features. Copulas are full measures of statistical dependence among random variables. Estimating the underlying copula density function from distributed data is an important aspect of statistical learning in sensor networks. With limited communication capacities or privacy concerns, centralization of the data is often impossible. By only collecting the ranks of the data observed by different sensors, we estimate and evaluate the copula density on an equally spaced grid after binning the standardized ranks at the fusion center. Without assuming any …

Quantitative Field Testing Rotylenchulus Reniformis Dna From Metagenomic Samples Isolated Directly From Soil., Kurt Showmaker, Gary W. Lawrence, Shien Lu, Clarissa Balbalian, Vincent P. Klink

CALS Publications

A quantitative PCR procedure targeting the ?-tubulin gene determined the number of Rotylenchulus reniformis Linford & Oliveira 1940 in metagenomic DNA samples isolated from soil. Of note, this outcome was in the presence of other soil-dwelling plant parasitic nematodes including its sister genus Helicotylenchus Steiner, 1945. The methodology provides a framework for molecular diagnostics of nematodes from metagenomic DNA isolated directly from soil.