Digital Commons Network^™

Adsorption And Segmental Dynamics Of Acrylate And Methacrylate Polymers Adsorbed On A Silica Surface, Piyawan Krisanangkura

Doctoral Dissertations

"Poly(isopropyl acrylate)-d₇ (PIPA- d₇) was studied using ²H solid-state NMR and modulated differential scanning calorimetry (MDSC). The polymer was deuterated on the methyl groups and side-chain methine. The PIPA- d₇ was adsorbed onto Cab-O-Sil silica. These two types of deuterons each showed their own characteristic deuterium nuclear magnetic resonance (NMR) spectra for bulk PIPA- d₇. The ²H NMR spectra of adsorbed PIPA- d₇ samples showed the presence of heterogeneity of the segmental dynamics. A residual powder pattern was found in the spectra of the surface samples at higher temperatures, indicating that the segments were tightly attached to the silica. The …

Understanding Corrosion Of Ni₃(Si,Nb) Alloys In Hot Sulfuric Acid, Jen-Hsien Hsu

Doctoral Dissertations

"The Sulfur-Iodine thermochemical cycle has been proposed as a method for producing large quantities of hydrogen gas from water. However, the extreme operating environments involved limit the possible materials for construction.

Through proper heat treatment and composition control, the modified patented Ni₃(Si,Nb) alloy keeps high temperature strength to greater than 750⁰C and can be deformed by cold rolling more than 50% using multiple passes and intermediate anneals. The corrosion resistance is reproducible and maintains less than 5 mpy for a broad range of boiling sulfuric acid concentrations, including 70 wt%.

In the boiling 70 wt% sulfuric acid corrosion tests, kinetic …

Synthesis And Characterization Of Metal Decorated Bamboo Structured Carbon Nanotubes For Hydrogen Storage, Sean Charles Mickey

Doctoral Dissertations

"Although hydrogen has been considered as a viable alternative fuel, the storage systems used to contain the hydrogen must be improved for large scale use. A variety of conceivable storage options exist ranging from compressed gas, cryogenic liquid, chemical solid state storage, and adsorptive surfaces. Carbon nanotubes (CNTs) provide a potentially viable option for hydrogen storage applications as a high surface area, lightweight media for adsorptive storage, but do not efficiently store hydrogen at ambient temperatures. Metal hydrides, on the other hand, are able to store large weight percents of hydrogen in a chemical solid state, but generally have unfavorable …

Fluid Flow Related Phenomena And Inclusion Motion In Continuous Casting Strands, Yufeng Wang

Doctoral Dissertations

"To improve the efficiency of the continuous casting process and the quality of its products, this dissertation mainly investigated fluid flow related phenomena and inclusion motion in continuous casting. Mathematical simulation was performed for this purpose. Both a slab caster and a billet caster were investigated. In the study of the slab caster, the application of electromagnetic brake field on the slab mold was evaluated. The results indicated that the magnetic force decelerated the high speed steel jet, stabilized the top fluctuation, and prevented the bias flow inside the mold. The other study of this slab caster involved the fluid …

Intelligent Power System Operation In An Uncertain Environment, Yusuf Yare

Doctoral Dissertations

"This dissertation presents some challenging problems in power system operations. The efficacy of a heuristic method, namely, modified discrete particle swarm optimization (MDPSO) algorithm is illustrated and compared with other methods by solving the reliability based generator maintenance scheduling (GMS) optimization problem of a practical hydrothermal power system. The concept of multiple swarms is incorporated into the MDPSO algorithm to form a robust multiple swarms-modified particle swarm optimization (MS-MDPSO) algorithm and applied to solving the GMS problem on two power systems. Heuristic methods are proposed to circumvent the problems of imposed non-smooth assumptions common with the classical approaches in solving …

Investigating The Source Of Thermal Anomalies In The Northern United Arab Emirates (Uae) Desert Using Geophysical Methods, Khalid Ahmad

Doctoral Dissertations

"We conducted geophysical surveys to investigate the source of thermal anomalies and to delineate any potential water transport pathways from the recharge zones in the Oman Mountains to the location of the temporal thermal anomalies within the desert plain of the United Arab Emirates (UAE). In the visible region of the spectrum of both ASTER and MODIS satellite images, the desert plain of the UAE appears as a bare sandy surface. However, detailed examination of these images in the thermal bands reveal cooler thermal anomalies within the desert plain following major rainfall events. This anomaly has a cooler surface of …

Effect Of Structure And Plasticizer On The Glass Transition Of Adsorbed Polymer, Boonta Hetayothin

Doctoral Dissertations

"The effect of molecular mass on adsorbed poly(methyl methacrylate) (PMMA) on silica was determined using temperature-modulated differential scanning calorimetry (TMDSC). A two-component model, based on loosely-bound polymer (glass transition temperature, T_g, similar to that of bulk) and tightly-bound polymer (T_g higher than that of bulk) was used to interpret the thermograms. Similar amounts of tightly-bound polymer were found for 450 and 85 kDa PMMA (0.78 mg/m²), while the 32 kDa sample had a smaller amount (0.48mg/m²). A comparison of adsorbed PMMA, poly(vinyl acetate) (PVAc), and poly(methyl acrylate) (PMA) on silica was made using the same technique. The …

Computational Methods For The Discovery And Analysis Of Genes And Other Functional Dna Sequences, Cyriac Kandoth

Doctoral Dissertations

"The need for automating genome analysis is a result of the tremendous amount of genomic data. As of today, a high-throughput DNA sequencing machine can run millions of sequencing reactions in parallel, and it is becoming faster and cheaper to sequence the entire genome of an organism. Public databases containing genomic data are growing exponentially, and hence the rise in demand for intuitive automated methods of DNA analysis and subsequent gene identification. However, the complexity of gene organization makes automation a challenging task, and smart algorithm design and parallelization are necessary to perform accurate analyses in reasonable amounts of time. …

Scaled Experimental Study On Excavation Of Lunar Regolith With Rakes/Rippers And Flat Blade, Masafumi Iai

Doctoral Dissertations

"As humanity's activities expand to the Moon, Mars, and other extra-terrestrial bodies, it will be necessary to use local resources rather than bringing everything from the Earth. This concept is called In-Situ Resource Utilization (ISRU), which starts with excavation and earthmoving. The present study focuses on loosening and moving of the lunar regolith by a ripper (or rake) and a wide blade with consideration of gravel content. After characterizing the lunar regolith and two of its simulants (JSC-1A and FJS-1), the relationship between the excavation energy and different conditions, namely gravel content, relative density, and tine spacing on a rake, …

Synthesis And Characterization Of Conducting Polymer Nanostructures And Their Application In Sensors, Zhe-Fei Li

Doctoral Dissertations

"A one-step synthesis technique has been used to fabricate sensors by growing polyaniline nanofibers and polyaniline/metal nanocomposites in the active area of an interdigitated electrode array. Polyaniline nanofiber sensors can be fabricated by irradiating an aqueous precursor solution containing aniline, HCl, a metal salt, and ammonium persulfate (APS) with a high pressure Hg lamp. The sensors are ready for operation after polymerization is complete, and no additional processing steps are necessary. These sensors showed faster and more intensity response to various organic vapors than conventional bulk polyaniline sensors due to their larger surface area. A chemisorption model and a diffusion …

Educating The United States Supreme Court At Summers' School: A Lesson On The "Special Character Of The Animal", Rafael Gely, Ramona L. Paetzold, Leonard Bierman

Faculty Publications

In this article, we explore the implications that Professor Summers' insights regarding public employment have for the Garcetti and Davenport decisions. In particular, we focus on the extent to which the political nature of public employment affects public employees' rights to freedom of speech as well as matters regarding the representational functions of public employee unions.

Emerging Technology Supply Chain Model For Additive Manufacturing, David M. Dietrich

Doctoral Dissertations

"This research concerns developing an emerging manufacturing technology, additive manufacturing (AM), into a mature and flexible, cost-effective supply chain for aerospace production. The field of additive manufacturing is an approach to low volume manufacturing of plastic or metal parts using three dimensional Computer Aided Design data. As an emerging technology, AM's supply chain is not established compared to conventional aerospace manufacturing technologies, such as injection molding or composite manufacturing. Technical and business challenges limit the robustness of the additive manufacturing system for aerospace applications. The overall intent of this research is to: first, provide an introduction to two main polymer …

A Decision-Theoretic Rule Of Reason For Minimum Resale Price Maintenance, Thom Lambert

Faculty Publications

This article evaluates these approaches from the perspective of decision theory and, finding each lacking, proposes an alternative approach to structuring the rule of reason governing RPM. Part II sets forth the decision-theoretic perspective, which seeks to maximize the net benefits of liability rules by minimizing the sum of decision and error costs. Part III then evaluates, from the standpoint of decision theory, the proposed approaches to evaluating instances of RPM. Part IV proposes an alternative evaluative approach that is more consistent with decision theory’s insights.

Introduction To The South Dakota Law Review's 2010 Symposium Issue, Marci A. Hamilton

South Dakota Law Review

No abstract provided.

The Spread Of The Parthenogenetic Marbled Crayfish, Marmorkrebs (Procambarus Sp.), In The North American Pet Trade, Zen Faulkes

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Biology)

The parthenogenetic marbled crayfish Marmorkrebs was discovered in the pet trade in Europe in the 1990s. Since then, its distribution through the pet trade has spread from Europe to other continents, including North America. North American pet owners were surveyed online with the aims of trying to track when Marmorkrebs entered the North American pet trade, the ways in which it spread through the pet trade, and how widely distributed Marmorkrebs are throughout the continent. Marmorkrebs have been in the North American pet trade since at least 2004, with the number of people increasing every year. While many Marmorkrebs are …

Review Of Licensing Digital Content: A Practical Guide For Librarians, 2d.Ed., Glenda A. Thornton

Michael Schwartz Library Publications

Review of Licensing Digital Content: A Practical Guide for Librarians, 2d.ed.

Review Of Planning New And Remodeled Archival Facilities, Glenda A. Thornton

Michael Schwartz Library Publications

Review of Planning New and Remodeled Archival Facilities

Review Of Electronic Records In The Manuscript Repository, Kiffany Francis

Michael Schwartz Library Publications

Review of Electronic Records in the Manuscript Repository

Ageism And Psychological Well-Being In Older Adults, Jenny Denver

LSU Doctoral Dissertations

Despite being faced with difficulties such as declining physical health and negative stereotypes, older adults are often able to maintain a positive sense of well-being in the face of such challenges (Mroczek & Kolarz, 1998). This finding is known as the paradox of well-being. The present study examined this phenomenon as it relates to the experience of ageism, reactions to aging as interpreted through identity process theory, and psychological well-being. The study is an exploratory examination of these factors in a sample of 137 community-dwelling older adults. It was hypothesized that 1) a greater experience of ageism would be associated …

Exercise-Induced Alterations In Melanocortin Receptor Expression And Inflammation, Tara Michelle Henagan

LSU Doctoral Dissertations

Inflammatory cytokines play a significant role in the pathogenesis of obesity-related diseases and have been implicated as integral factors in both early and late phases of atherosclerosis. Lifestyle modifications such as increasing physical activity and making dietary changes to induce weight loss are part of the primary prescription for the treatment of metabolic syndrome. Additionally, physical activity has been implicated as a potentially effective regimen for the control of inflammation, yet little is known about the anti-inflammatory mechanistic alterations induced by physical activity.

Exercise training causes acute changes in inflammation immediately post exercise, evidenced by upregulation of inflammatory cytokines and …

Biopharmaceuticals: An Overview, Bhupinder Singh Sekhon

The Thai Journal of Pharmaceutical Sciences

Biopharmaceuticals drugs structurally mimics compounds found within the body and are produced using biotechnologies. These have the potential to cure diseases rather than merely treat symptoms, and have fewer side effects because of their specificity, fo...

Conjugation Of Some Nsaids With 5-Phenyl-2-Aminothiazole For Reduced Ulcerogenicity, Abhilasha Verma, Nirupam Das, Meenakshi Dhanawat, Sushant K. Shrivastava

The Thai Journal of Pharmaceutical Sciences

Analgesic drugs containing free acidic group were reacted with N, N' carbonyldiimidazole to prepare the acylimidazole derivatives. They were further reacted with 5-phenyl-2-amino thiazole nucleus to obtain the corresponding amides. All the compounds were...

Anticonvulsant Activity Of Methanolic Extract Of Clerodendron Infortunatum Linn, In Swiss Albino Mice, Sudipta Das, Pallab K., Goutam Pramanik, Siva P. Panda, Samit Bera

The Thai Journal of Pharmaceutical Sciences

The present study was designed to investigate the anticonvulsant and sleep potentiation effect of methanolic extract of C lerodendron info rtun atum Linn. (MECI) leaves in Swiss albino mice. The anticonvulsant effect of the MECI (250, 500 mg/kg body weig...

Use Of Charge Transfer Complexation Reaction For The Spectrophotometric Determination Of Bupropion In Pharmaceuticals And Spiked Human Urine, Kanakapura Basavaiah, Sameer A. M.

The Thai Journal of Pharmaceutical Sciences

This is the first report on use of two visible spectrophotometric methods for the determination of bupropion hydrochloride (BUPH) in pharmaceuticals and spiked human urine. Bupropion is a second-generation antidepressant agent which is also used in the m...

Inhibitory Effect Of 2,5-Bis(4-Hydroxy-3-Methoxybenzylidene) Cyclopentanone On Mast Cell Histamine Mediated-Rat Paw Edema, Agung Endro Nugroho, Sardjiman, Kazutaka Maeyama

The Thai Journal of Pharmaceutical Sciences

2,5-Bis(4-hydroxy-3-methoxybenzylidene)cyclopentanone, known as pentagamavunon-0 (PGV-0), is a benzylidene cyclopentanone analog of curcumin. This compound posses stronger pharmacological activities such as anti-inflammatory, antioxidative and antibacter...

Sensitive Ultraviolet Spectrophotometric Determination Of Quetiapine Fumarate In Pharmaceuticals, K. Basavaiah, N. Rajendraprasad, P.J. Ramesh, K.B. Vinay

The Thai Journal of Pharmaceutical Sciences

Quetiapine fumarate (QTF) is a psychotropic agent belonging to the chemical class of benzisoxazole derivatives indicated for the treatment of schizophrenia. It is a selective monoaminergic antagonist with high affinity for the serotonin type 2 (5HT2), an...

Improvement In The Dissolution Of Poorly Water Soluble Drug Using Media Milling Technique, Dhaval J. Patel, Jayvadan K., Vikram M. Pandya

The Thai Journal of Pharmaceutical Sciences

The rate of dissolution is rapidly becoming the leading hurdle in formulation development of poorly water-soluble drugs. In the present work, media milling was employed to formulate nanoparticles of a poorly water-soluble anti-ulcer drug, famotidine (FAM...

Bs 503 Introduction To Biblical Studies: Inductive Bible Study, Joseph R. Dongell

Syllabi

A. Required 1. Bibliography: Bauer, David R. An Annotated Guide to Biblical Resources for Ministry. Peabody, MA: Hendrickson, 2003. 1-56563-723-2 [Available new from Amazon, $15.75] 2. Ryken, Leland, James C. Wilhoit and Tremper Longman, eds. Dictionary of Biblical Imagery. Downers Grove, IL: InterVarsity Press, 1998. 0-8308-1451-5 $50.00

Spontaneous Hemoperitoneum Following Colonoscopy, Christine Whylings Do, Gavin C. Barr Jr., Md, Kathleen Kane Md

Department of Emergency Medicine

No abstract provided.

Examining Resistance, Accommodation And The Pursuit Of Aspiration In The Indian It‐Bpo Space: Reflections On Two Case Studies, M. N. Ravishankar, Laurie Cohen, Amal El-Sawad

All Works

This article is based on case studies of two organisations: an India-based information technology (IT) services company and a financial services company located in the UK and India. Although they operate in different sectors and have some notable contrasts, both can be seen as typifying aspects of India's new economy. Our article explores the lived experience of working in this economy—a perspective that has been relatively neglected in the extant literature. Drawing on Homi Bhabha's notions of ambivalence and mimicry, and V. S. Naipaul's powerful illustrations of these concepts in his fiction and non-fiction works, we report on how respondents …