Digital Commons Network^™

Simultaneous Determination Of Cu(Ii) And Pd(Ii) As 4-Phenylpiperazinecarbodithioate Complex Using H-Point Standard Addition Method And Derivative Spectrophotometry, Varinder Kaur, Ashok Kumar Malik, Neelam Verma

Turkish Journal of Chemistry

A new, simple, inexpensive, and sensitive method for the simultaneous spectrophotometric determination of Cu(II) and Pd(II) by H-point standard addition method and derivative spectrophotometry is described. 4- Phenylpiperazinecarbodithioate (PPDTC) in an anionic micellar solution of SLS was used as a reagent at pH 4. The experimental parameters, such as pH, type of surfactant, concentration of reagent, and surfactant used, were optimized to minimize the errors. The linear ranges of the method were 0.1-10 and 0.1-11 \mu g mL^{-1} for Cu(II) and Pd(II), respectively. The results of applying H-point standard addition and fourth derivative spectrophotometry showed that Cu(II) and Pd(II) can …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Synthesis, Characterization, Crystal Structures, And Antibacterial Activity Of Some New 1-(3,4,5-Trimethoxybenzoyl)-3-Aryl Thioureasreas, Aamer Saeed, Rasheed Ahmad Khera, Naeem Abbas, Muhammad Latif, Imran Sajid, Ulrich Flörke

Turkish Journal of Chemistry

Synthesis of some novel 1-(3,4,5-trimethoxy)benzoyl-3- arylthiourea derivatives (1a-o) was accomplished in 2 steps. The synthetic route involves the reaction of 1-(3,4,5-trimethoxy)benzoyl chloride with potassium thiocyanate in 1:1 molar ratio in acetone to afford the corresponding isothiocyante followed by treatment with suitably substituted anilines. The structures of the products were established by elemental analyses, IR, ^1H- and ^{13}C-NMR, and mass spectroscopy and for 1b and 1m from single crystal X-ray diffraction data. All of the synthesized compounds (1a-o) were screened for antibacterial activity against gram positive and gram negative bacterial strains and were found to exhibit low activity towards the tested …

Mannich Base Derivatives Of 3-Hydroxy-6- Methyl-4h-Pyran-4-One With Antimicrobial Activity, Demet Us, Barkin Berk, Eni̇se Ece Gürdal, Ni̇han Ayteki̇n, Zühtü Tanil Kocagöz, Berrak Çağlayan, Işil Kurnaz, Di̇lek Demi̇r Erol

Turkish Journal of Chemistry

A series of 3-hydroxy-6-methyl-2-[(substitutedpiperidine-1-yl) methyl]-4H-pyran-4-one structured compounds were synthesized by reacting 5-hydroxy-2-methyl-4H-pyran-4-one with suitable piperidine derivatives using Mannich reaction conditions. Antibacterial activities of the compounds for E. coli ATCC 25922, S. paratyphi ATCC BAA-1250, S. flexneri ATCC 12022, E. gergoviae ATCC 33426, and M. smegmatis ATCC 14468 were assessed in vitro by the broth dilution method for determination of minimum inhibitory concentration (MIC). In addition, their inhibitory effects over DNA gyrase enzyme were evaluated using a DNA gyrase supercoiling assay. All the synthesized compounds showed a MIC value of either 8 or 16 \mu g/mL for M. smegmatis, whereas minimum …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Synthesis And Characterization Of Novel Triazol Compounds Containing A Thiophen Ring As Potential Antifungal Agents And The Structure Of 2-(2-Hydroxy-2-P-Tolyethyl)-5-(Thiophen-2-Ylmethyl)- 4-(4h-1,2,4-Triazol-4-Yl)-2h-1,2,4-Triazol-3(4h)-One, Yasemi̇n Ünver, Esra Düğdü, Kemal Sancak, Mustafa Er, Reşat Ustabaş

Turkish Journal of Chemistry

A series of new 4-(3,5-disubstitue-4H-1,2,4-triazol-4-yl)- 5-(thiophen-2-yl-methyl)-2H-1,2,4-triazol-3(4H)-ones (3a-c) were obtained by reaction N'-1-ethoxy-2-thiophen-2-yl-ethylydene hydrazino carboxylic acid ethyl ester (1) and 4-amino-4H-1,2,4-triazoles (2). 4-(3,5-disubstitue-4H-1,2,4-triazol-4-yl)-2-(2-oxo-2-arylethyl)-5- (thiophen-2-yl-methyl)-2H-1,2,4-triazol-3(4H)-ones (4a-e) and ethyl 2-(4-(3,5-disubstitue-4H-1,2,4-triazol-4-yl)-5-oxo-3-(thiophen-2-ylmethyl)- 4,5-dihydro-1,2,4-triazol-1-yl)acetates (6a-c) were obtained by reaction of compounds 3 and bromoacetophenon derivatives and bromo ethylacetate, respectively. Compounds 5a-e were synthesized from the reaction of corresponding compounds 4a-e with NaBH_4. Compounds 7a-c were obtained by the reaction compounds 6 and LiAlH_4. Seventeen new compounds were synthesized and characterized by elemental analyses, IR, ^1H-NMR, and ^{13}C-NMR spectral data. The structure of compound 5d was inferred through IR, ^1H-, ^{13}C-NMR, elemental analyses, and X-ray spectral techniques. …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Quantum Chemical Studies On Tautomerism And Basicity Behavior Of Some 1,2,4-Triazole Derivatives, Cemi̇l Öğreti̇r, Yadi̇gar Gülseven Sidir, İsa Sidir, Erol Taşal

Turkish Journal of Chemistry

The acidity constants, relative stabilities, and tautomeric equilibrium constants of some 1,2,4-triazole derivatives were determined using the density functional theory (DFT) with the B3LYP method and 6-311G(d,p) basis set. The integral equation formalism version of the polarizable continuum model (IEFPCM) was used in the calculations of the aqueous phase. The calculated tautomeric equilibrium and relative stabilities values revealed that the 4H-1,2,4 triazole form for all studied molecules was favored over the 1H-1,2,4 triazole form. Protonation processes indicated the predominance of the 1H-1,2,4 triazole form over the 2H-1,2,4 triazole form. The correlation attempt between the experimental and the calculated acidity constants, …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Tsunami Hazard And Total Risk In The Caribbean Basin, X. William Proenza, George A. Maul

Ocean Engineering and Marine Sciences Faculty Publications

Deadly western North Atlantic Ocean tsunami events in the last centuries have occurred along the east coast of Canada, the United States, most Caribbean islands, and the North Atlantic Coast of South America. The catastrophic Indian Ocean tsunami of 2004 reminded natural hazards managers that tsunami risk is endemic to all oceans. Total Risk is defined as hazard (frequency of tsunami events) times measures of elements at risk (human exposure) times measures of vulnerability (preparedness) in a given epoch (Nott, 2006). While the tsunami hazard in the Caribbean (averaging 19 ± 22 years between deadly events) is lower than Pacific …

Roles Of Src Family Kinase Signaling During Fertilization And The First Cell Cycle In The Marine Protostome Worm Cerebratulus, Stephen A. Stricker, David J. Carroll, Wai L. Tsui

Ocean Engineering and Marine Sciences Faculty Publications

For eggs to generate a calcium response during fertilization, the sperm of many deuterostome animals must first activate a group of egg kinases, called Src family kinases (SFKs). However, whether SFK activation is also required for fertilization-induced calcium signals in eggs of protostomes remains unknown. Thus, in this study, unfertilized oocytes of the marine protostome worm Cerebratulus were treated with either PP2 to inhibit SFKs or with U73122 to block phospholipase C activity downstream of SFK. Compared with control fertilizations, the inhibitors significantly reduced post-insemination levels of polar body formation and cleavage, but apparently did so via different mechanisms, based …

A Preliminary Study: Body Dysmorphic Disorder In Division I Women’S Collegiate Soccer Players, Tammy D. Jones

Department of Educational Administration: Dissertations, Theses, and Student Research

The prevalence of Body Dysmorphic Disorder (BDD) among collegiate athletes has not been clearly determined. The purpose of this study was to determine if there are symptoms of body dysmorphic disorder found in Division I women’s soccer players. The researcher hypothesized that there would be some symptoms found within the participants of sport and that there was a need to research this area further.

The study consisted of four participants who participated in semi-structured interviews. The subjects were asked a series of questions from the Yale-Brown Obsessive Compulsive Scale Modified for Body Dysmorphic Disorder (BDD-YBOCS) to determine if they indicated …

Generalized Fourier-Feynman Transforms, Convolution Products, And First Variations On Function Space, Seung Jun Chang, Jae Gil Choi, David Skough

Department of Mathematics: Faculty Publications

In this paper we examine the various relationships that exist among the first variation, the convolution product and the Fourier-Feynman transform for functionals of the form F(x) = f((α₁, x), . . . , (α_n, x)) with x in a very general function space C_a,b[0,T].

Dean Emeritus Patrick J. Rohan, Michael A. Simons, Mario E. Cuomo, Edward D. Cavanagh, Vincent C. Alexander

St. John's Law Review

(Excerpt)

Patrick J. Rohan’s connection to St. John’s reaches back more than half a century. He graduated from St. John’s University in 1954 and from the School of Law in 1956. Two years later, he joined the Law School faculty, where he served for fifty-two years until his retirement in June 2009. He died just a few months later, on November 26, 2009. The School of Law community mourns the passing of this man of St. John’s—Dean Emeritus, Professor of Law, alumnus, supporter, and friend.

Constitutional Accommodation Of The Rights Of Ethnic And Religious Minorities In Plural Democracies: Lessons And Cautionary Tales From South-East Asia, Li-Ann Thio

Pace International Law Review

No abstract provided.

What Do You Think Should Happen? Public Participation In Transitional Justice, Anna Triponel, Stephen Pearson

Pace International Law Review

No abstract provided.

‘Food For Life’: Looking Beyond The Horizon, Charles A. Francis, John W. Doran

Department of Agronomy and Horticulture: Faculty Publications

Our real challenge appears to be anticipating what the major challenges and constraints will be to food production and distribution a decade or more into the future. This could be called ‘Beyond the Horizon’ thinking. Today there is little disagreement over the massive depletion on a global scale of two essential inputs to agriculture: fossil fuels and fresh water. We also recognize that phosphorus is found in concentrated form in only a few deposits in nature, and that agriculture is rapidly using this limited resource and dispersing it through harvested products and soil loss from fields in forms that make …

Dryland Performance Of Sweet Sorghum And Grain Crops For Biofuel In Nebraska, Charles S. Wortmann, Adam Liska, Richard B. Ferguson, Drew J. Lyon, R. N. Klein, Ismail M. Dweikat

Department of Agronomy and Horticulture: Faculty Publications

Sweet sorghum [SS; Sorghum bicolor (L.) Moench] is a potential biofuel crop for the Great Plains. Sweet sorghum was compared with corn [Zea mays (L.)] and grain sorghum for potential ethanol yield, energy use effi ciency, and greenhouse gas (GHG) emissions at seven dryland site-years in Nebraska. Seasonal rainfall ranged from approximately 340 to 660 mm. Soils were deep with medium texture at all site-years. Th e eff ects of seeding rate, N rate, and cultivar on SS performance were evaluated. Sweet sorghum sugar yield was not aff ected by seeding rate and N application at six of seven …

Emissions Savings In The Corn-Ethanol Life Cycle From Feeding Coproducts To Livestock, Virgil R. Bremer, Adam Liska, Terry J. Klopfenstein, Galen E. Erickson, Haishun Yang, Daniel T. Walters, Kenneth G. Cassman

Department of Agronomy and Horticulture: Faculty Publications

Environmental regulations on greenhouse gas (GHG) emissions from corn (Zea mays L.)-ethanol production require accurate assessment methods to determine emissions savings from coproducts that are fed to livestock. We investigated current use of coproducts in livestock diets and estimated the magnitude and variability in the GHG emissions credit for coproducts in the corn-ethanol life cycle. The coproduct GHG emissions credit varied by more than twofold, from 11.5 to 28.3 g CO₂e per MJ of ethanol produced, depending on the fraction of coproducts used without drying, the proportion of coproduct used to feed beef cattle (Bos taurus …

Diapycnal Diffusivities In Homogeneous Stratified Turbulence, D. D. Stretch, S. K. Venayagamoorthy

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Quantifying diapycnal mixing in stably stratified turbulence is fundamental to the understanding and modeling of geophysical flows. Data of diapycnal mixing from direct numerical simulations of homogeneous stratified turbulence and from grid turbulence experiments, are analyzed to investigate the scaling of the diapycnal diffusivity. In these homogeneous flows the instantaneous diapycnal diffusivity is given exactly by Kd= ∈ρ/ (∂ ρ /∂z)²where ∈ρ is the dissipation rate of density fluctuations, and ∂ ρ /∂z is the mean density gradient. The diffusivity Kd may be expressed in terms of the large-scale properties of the turbulence as K d = γLE …

High-Strength Selfconsolidating Concrete Girders Subjected To Elevated Compressive Fiber Stresses, Part 1: Prestress Loss And Camber Behavior, Jared E. Brewe, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The design of prestressed concrete members is restricted by the requirement that the extreme compressive fiber stress at midspan of simply supported members be less than 60% of the concrete compressive strength at release of prestressing. the purported purpose of this limit is to address serviceability performance, but it places unnecessary limits on the capability of the materials. for this research program, six prestressed concrete girders were produced with high-strength self-consolidating concrete and subjected to compressive fiber stress levels ranging from 65% to 84% of the concrete compressive strength at release of prestressing. Time dependent concrete surface strains were measured …

Modeling Permanent Deformation Of Unbound Granular Materials Under Repeated Loads, Cheng Chen, Louis Ge, Jiansheng Zhang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Finite-element analysis on a pavement structure under traffic loads has been a viable option for researchers and designers in highway pavement design and analysis. Most of the constitutive drivers used were nonlinear elastic models defined by empirical resilient modulus equations. Few isotropic/kinematic hardening elastoplastic models were used but applying thousands of repeated load cycles became computationally expensive. in this paper, a cyclic plasticity model based on fuzzy plasticity theory is presented to model the long-term behavior of unbound granular materials under repeated loads. the discussion focuses on the model parameters that control long-term behavior such as elastic shakedown. the performance …

Special Issue On Modeling In Geotechnical Engineering For Design And Materials, R. A. Tarefder, D. H. Chen, Y. N. Ge

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

No abstract provided.

Effect Of Radar-Rainfall Uncertainties On The Spatial Characterization Of Rainfall Events, Pradeep V. Mandapaka, Gabriele Villarini, Bong Chul Seo, Witold F. Krajewski

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Remotely sensed precipitation products, due to their large areal coverage and high resolution, have been widely used to provide information on the spatiotemporal structure of rainfall. However, it is well known that these precipitation products also suffer from large uncertainties that originate from various sources. In this study, we selected radar-rainfall (RR) data corresponding to 10 warm season events over a 256 x 256 km² domain with a data resolution of 4 x 4 km² in space and 1 h in time. We characterized their spatial structure using correlation function, power spectrum, and moment scaling function. We then …

The Emperor's Clothes: Evaluating Head Of State Immunity Under International Law, Mary Margaret Penrose

Faculty Scholarship

To date, most attempts at prosecuting heads of state have fallen short. At best, such attempts, even the modern attempts stretching from Iraq to Yugoslavia to Sierra Leone, have occurred under less than ideal circumstances, often far, far away from the actual place of alleged crime, or so distant in time to have lost some of its meaning. While academics, international lawyers and human rights advocates all praise the "Pinochet precedent" as paving the way for prosecuting deposed despots and ending the luxurious exiles of former dictators, in the end Pinochet was released from custody and returned home to Chile …

Inoculation With Arbuscular Mycorrhizal Fungi Or Crop Rotation With Mycorrhizal Plants Improves The Growth Of Maize In Limed Acid Sulfate Soil, Hasao Higo, Katsunori Isobe, Dong-Jin Kang, Kazuhiro Ujie, Rhae A. Drijber, Ryuichi Ishii

Department of Agronomy and Horticulture: Faculty Publications

Arbuscular mycorrhizal fungi (AMF) improve the uptake of immobile mineral nutrients such as phosphate, thereby improving plant growth. In acid sulfate soil (ASS), AMF spore density is generally low which impacts root colonization and phosphate uptake. Thus, inoculation may help increase AMF colonization of crops grown in ASS. AMF spore density decreases after cultivation of a non-host crop or bare fallow. In addition, preceding crops affect the growth and yield of subsequent crops. The production of AMF inocula requires AMF-compatible plants. The objective of the present study is to elucidate the effect of preceding crops on the persistence of inoculated …

Creating Local Networks In The Cloud, José R. Sánchez E.

Theses

The resources and services offered by cloud computing platforms have been opening new alternatives of expansion to several research areas. The cloud computing platform applications to the educative area have been creating interest in different educative organizations. This thesis proposes the use of the Amazon EC2 cloud computing platform to build networking laboratories for the computational and networking educative areas. Within this paper, several options are evaluated in order to fulfill this objective. The final proposed design introduces a practical scenario for networking laboratories. Future enhancements of the final design are proposed.

Fractured Membership: Deconstructing Territoriality To Secure Rights And Remedies For The Undocumented Worker, D. Carolina Nuñez

Faculty Scholarship

Relied upon but unwelcome, among us but uninvited, undocumented workers in the United States – now numbering over 8 million – labor on the border of inclusion and exclusion, between a status-based conception of membership and a territorial approach to membership. Although mere presence in the U.S. secures undocumented workers many of the same labor protections afforded to authorized workers, undocumented status often forecloses certain remedies otherwise available for employer breaches of those protections. Many commentators have criticized this effective status-based denial of rights to undocumented workers as inimical to the goals underlying labor and immigration law. While this Article …

The Manifold Operations Of The Gothic Double, Brian Demars

Master's Theses and Doctoral Dissertations

The gothic novel’s emergence as a dominant genre in the 19th century is illustrative of a shift in popular ideology taking place in Western Europe during this period. Competing viewpoints, particularly between opposing classes, directly reflect the uncertainties, anxieties, and aspirations of a continent undergoing a significant transition. Because the gothic draws upon the tension between contending attitudes—spiritualism and secularism, realism and romanticism, nationalism and imperialism, and aristocratic and bourgeois—it exposes how ideology embedded in these concepts either adds to or detracts from the greater good of the community.

The technique of doubling is utilized to locate divergent ideologies and …