Digital Commons Network^™

Synthesis And Characterization Of Metal Decorated Bamboo Structured Carbon Nanotubes For Hydrogen Storage, Sean Charles Mickey

Doctoral Dissertations

"Although hydrogen has been considered as a viable alternative fuel, the storage systems used to contain the hydrogen must be improved for large scale use. A variety of conceivable storage options exist ranging from compressed gas, cryogenic liquid, chemical solid state storage, and adsorptive surfaces. Carbon nanotubes (CNTs) provide a potentially viable option for hydrogen storage applications as a high surface area, lightweight media for adsorptive storage, but do not efficiently store hydrogen at ambient temperatures. Metal hydrides, on the other hand, are able to store large weight percents of hydrogen in a chemical solid state, but generally have unfavorable …

Low-Thrust Control Of Orbital Elements, Nathan Harl

Doctoral Dissertations

"This dissertation presents a method for controlling the orbital elements of a spacecraft using continuous low-thrust systems. The method involves the use of a general performance index, which is designed to minimize the difference between the instantaneous orbital elements of a spacecraft and some desired set of orbital elements. Due to the generality of the controller design, the resultant controller can be applied to a wide variety of scenarios about various bodies in space. To minimize the designed performance index, a shooting method and a Sequential Quadratic Programming algorithm are utilized and compared.

The primary application of the general controller …

Characterization Of The Corrosion Protection Mechanism Of Cerium-Based Conversion Coatings On High Strength Aluminum Alloys, William R. Pinc

Doctoral Dissertations

"The aim of the work presented in this dissertation is to investigate the corrosion protection mechanism of cerium-based conversion coatings ( CeCCs) used in the corrosion protection of high strength aluminum alloys. The corrosion resistance of CeCCs involves two general mechanisms; barrier and active. The barrier protection mechanism was influenced by processing parameters, specifically surface preparation, post-treatment, and the use of gelatin. Post-treatment and the addition of gelatin to the coating solution resulted in fewer cracks and transformation of the coating to CeP0₄, which increased the corrosion resistance by improving the barrier aspect of CeCCs. CeCCs were found to best …

Nmr Investigations Of Biomass-To-Fuel Conversions By Hydrothermal Processes, Wenjia Zhang

Doctoral Dissertations

"Biofuels have gained significant attention as the most promising alternative energy and fuel supply for the near future because of two dominant reasons: first, biofuels are environmentally friendly; and second, they afford a sustainable technology. Biofuels can be synthesized from biomass by several different processes, among which, hydrothermal conversion is considered to be more energy efficient. However, scientific efforts to improve hydrothermal biomass-to-fuel (HT-BTF) conversion efficiencies are severely limited because little is known about the salient reaction mechanisms and intermediates. This study is aimed at a better understanding of the hydrothermal biomass degradation kinetics by advanced NMR spectroscopy and, accordingly, …

Dependency Of Machinability In Gray Cast Iron On Nitride-Induced Age Strengthening, Jared Teague

Doctoral Dissertations

"Work of previous researchers has suggested that room temperature age strengthening in gray cast irons improves machinability. Verification and quantification of the machinability improvement is important to industry. Improved machinability will reduce overall manufacturing costs and reduce raw material consumption by decreasing the rate at which tools are replaced. Experimental work was performed to determine a connection between improved machinability in gray cast iron and changes in machining mechanics. An industrial tool wear study verified that age strengthening improved machinability by reducing tool wear to less than one-quarter of the unaged value. Laboratory tests on iron castings from the same …

Sensor Data-Based Decision Making, Ahmet Soylemezoglu

Doctoral Dissertations

"Increasing globalization and growing industrial system complexity has amplified the interest in the use of information provided by sensors as a means of improving overall manufacturing system performance and maintainability. However, utilization of sensors can only be effective if the real-time data can be integrated into the necessary business processes, such as production planning, scheduling and execution systems. This integration requires the development of intelligent decision making models that can effectively process the sensor data into information and suggest appropriate actions. To be able to improve the performance of a system, the health of the system also needs to be …

Phase Equilibria In Iron Phosphate System, Liying Zhang

Doctoral Dissertations

"The main objectives of this research were to synthesize iron phosphate compounds, study phase equilibria in the iron phosphate system, focusing on the glass forming area, and investigate glass formability and properties based on the liquidus regions. Twelve iron phosphate compounds were successfully prepared and studied in terms of liquidus temperature or decomposition behavior. The liquidus surface of the Fe₃PO₇- Fe(PO₃)₃ system was re-determined and found to be significantly different from that originally presented by Wentrup in 1935. Eutectic points exist at 58.0 mole% Fe₂O₃ (1070⁰C), 42.7 mole% Fe₂O₃ (925°C), and 37.0 mole% Fe₂O₃ (907°C). The latter two eutectic points …

Robust Frequency-Domain Turbo Equalization For Multiple-Input Multiple-Output (Mimo) Wireless Communications, Jian Zhang

Doctoral Dissertations

"This dissertation investigates single carrier frequency-domain equalization (SC-FDE) with multiple-input multiple-output (MIMO) channels for radio frequency (RF) and underwater acoustic (UWA) wireless communications. It consists of five papers, selected from a total of 13 publications. Each paper focuses on a specific technical challenge of the SC-FDE MIMO system. The first paper proposes an improved frequency-domain channel estimation method based on interpolation to track fast time-varying fading channels using a small amount of training symbols in a large data block. The second paper addresses the carrier frequency offset (CFO) problem using a new group-wise phase estimation and compensation algorithm to combat …

Dead Time And Count Loss Determination For Radiation Detection Systems In High Count Rate Applications, Amol Patil

Doctoral Dissertations

"This research is focused on dead time and the subsequent count loss estimation in radiation detection systems. The dead time is the minimum amount of time required between two events to permit detection of those events individually by a radiation detection system. If events occur during the system dead time, they are lost. Such lost information can be important in many applications including high-precision spectroscopy, positron emission tomography (PET), and the scanning of spent nuclear fuel. Understanding of the behavior of radiation detection systems is important; thus this work included a comprehensive review of dead time and pulse pile-up models …

Effects Of Optimized And Sub-Optimum Two Degree Of Freedom Lining Tolerances On Modeled Inlet Acoustic Attenuation And Normal Incidence Impedance Measurement At Elevated Temperatures, David R. Burd

Doctoral Dissertations

"This work first investigates the effect of manufacturing tolerances on realized attenuation for two degree-of-freedom linings with the use of lining models and finite element duct propagation codes. Acoustic linings were created for two turbofan engines that optimize attenuation at takeoff/sideline and approach conditions. Lining physical and geometric parameters were set, which best meet the optimum impedance requirements at two target frequencies. Similar linings were created to investigate sub-optimum designs. Variations of these parameters representing realistic manufacturing tolerances were used to systematically examine the effect on installed impedance and predicted attenuation. Attenuation at sideline and approach conditions was found to …

Factors Controlling Ductility In Ultrafine Grain Aluminum Alloys Under Monotonic And Cyclic Loading, Partha Sarathi De

Doctoral Dissertations

"Ultrafine grained (UFG) Al processed by severe plastic deformation (SPD) methods are characterized by high strength and a limited uniform ductility. Friction stir processing (FSP), an offshoot of friction stir welding has emerged as a new technique to produce UFG alloys. FSP-UFG Al alloys show a distinctly different behavior with higher uniform elongation and improved high cycle fatigue life as compared to other SPD processed variants. The objective of this work was to study the microstructural basis for such mechanical behavior in FSP-UFG Al alloys.

To study the mechanical behavior of FSP Al alloys, a subsize bending fatigue and uniaxial …

Experimental And Computational Investigations Of Hydrogen Safety, Dispersion And Combustion For Transportation Applications, Shravan K. Vudumu

Doctoral Dissertations

"Hydrogen is an energy carrier that can be produced from a variety of sources, offering one of the viable solutions to the increasing demands for clean and sustainable energy. Compared to the conventional fuels, hydrogen has distinct properties that need to be properly accounted for during its safer storage and delivery as well as more efficient and cleaner utilization. The broader objective of this study is to contribute to the scientific knowledge necessary to overcome key technical barriers to the widespread implementation of hydrogen in transportation applications. Specifically, lower flammability limit of hydrogen is first measured with an enhanced experimental …

Ground Penetrating Radar Investigations In Upper Kama Potash Mines, Oleg N. Kovin

Doctoral Dissertations

"An understanding of the structure and state of the rock mass surrounding underground openings in the potash mines is critically important for safe mining, planning the methods of extraction of an orebody, and preventing the influx of ground water. Continuous common offset ground penetrating radar (GPR) data were acquired in the potash mine operated by the Joint Stock Company (JSC) "Silvinit" (Russia) as part of an investigation of both pre-existing fractures exposed by mine workings and other anomalous geological structures. During the course of GPR investigation, the electrical properties of salt-bearing units were determined, site-specific data acquisition techniques and object-oriented …

Behavior Of Externally Bonded Fiber Reinforced Polymer Systems For Strengthening Concrete Girders In Shear, Michael Shawn Murphy

Doctoral Dissertations

"Deficiencies in shear resistance are a primary concern in concrete members due to the sudden and unpredictable nature of shear failures. Shear deficiencies in concrete structures can arise due to improper design, long-term deterioration, man-made damages, increases in loads, or as a result of over strengthening in flexure. A number of shear strengthening techniques offer a cost effective means for restoring or enhancing the shear capacity of a concrete member. The use of externally bonded fiber reinforced polymers (FRP) is one such technique that has gained recent recognition for its high strength-to-weight ratio and simplicity of application. The development of …

The Functionalization Of Single Wall Carbon Nanotubes For Bioapplications, Pu Zhang

Doctoral Dissertations

"In the past few years, the functionalization of carbon nanotubes has received considerable attention due to their extraordinary mechanical, electrical, optical and thermal properties. Using single wall carbon nanotube as a platform in bioanalytical and biomedical applications has also been extensively studied. This dissertation consists of four papers. In the first paper, various methods to functionalize single wall carbon nanotubes with immobilized enzyme for bioanalytical application were investigated. It was found that the covalent functionalization method was not an ideal methodology for enzyme addition neither in terms of enzyme loading amount nor activity retention compared to other methods. Use of …

Faculty Hiring Committees Perceptions Of Hiring Processes And Subjectivity, Laura Caraleen Foster

Dissertations and Theses @ UNI

Hiring the most capable applicants has a large impact on the bottom line of an organization. The most effective tools to identify talent are well known to IndustrialOrganizational Psychologists, but these analytical tools are used less frequently than less effective intuitive procedures, such as the traditional unstructured job interview. In a survey of university faculty, we found that the most important factor influencing the use of a selection tool was its perceived validity, but these perceptions were not wellcalibrated to actual criterion related validity. We found some evidence that perceived validity was influenced by implicit beliefs about hiring. A body …

Ceramic Dielectrics For High Energy Density Capacity Application, Sheng Chao

Doctoral Dissertations

"The objective of this dissertation is to investigate the relationship between the processing parameters, microstructural development, defect chemistry and electrical properties of titanium oxide (TiO₂) dielectrics for high energy density capacitor applications. The effects of aliovalent dopants on the dielectric properties of TiO₂ ceramics were investigated, aiming to further improve the desired dielectric properties especially at elevated temperatures (up to 200°C). Due to the segregation of acceptor type impurities in the starting powders, space charge polarization took place in TiO₂ ceramics with relative large grain size (>̲500nm), leading to high dielectric loss and low energy storage efficiency. Increased ratio …

Borate Based Bioactive Glass Scaffolds For Hard And Soft Tissue Engineering, Steven B. Jung

Doctoral Dissertations

"The main objectives of this dissertation were to evaluate bioactive borate glass scaffolds for hard and soft tissue applications and determine the potential toxicity of the borate glasses on the adjacent and systemic tissues. Porous randomly oriented fiber scaffolds composed of bioactive borate glass were implanted in subcutaneous soft tissue sites and in calvaria defects of laboratory rats and no signs of toxicity (necrotic tissue, increase in macrophages or other immune cells) were detected in any of the adjacent tissues (hard or soft). Systemic organs (kidney and liver) of laboratory rats implanted with bioactive borate scaffolds were analyzed for possible …

Development Of Embedded Modulated Scatterer Technique: Single- And Dual-Loaded Scatterers, Kristen M. Donnell

Doctoral Dissertations

"Health monitoring of infrastructure is an important ongoing issue. Therefore, it is important that a cost-effective and practical method for evaluating complex composite structures be developed. A promising microwave-based embedded sensor technology is developed based on the Modulated Scatterer Technique (MST). MST is based on illuminating a probe, commonly a dipole antenna loaded with a PIN diode (also referred to as a single-loaded scatterer, or SLS), with an electromagnetic wave. This impinging wave induces a current along the scatterer length, which causes a scattered field to be reradiated. Modulating the PIN diode also modulates the signal scattered by the probe, …

Motion Of The Multisegmental Foot In Hallux Valgus, Karl Canseco, Leah Rankine, Jason T. Long, Thomas Smedberg, Richard Marks, Gerald F. Harris

Biomedical Engineering Faculty Research and Publications

Hallux valgus is a common condition characterized by lateral deviation of the large toe and medial deviation of the first metatarsal. While some gait analyses of patients with hallux valgus have been performed using plantar pressures, very little is known about the kinematics of gait in this population. The purpose of this study was to evaluate triplanar kinematics in patients with hallux valgus using a multisegmental foot model. Materials and Methods: A 15-camera Vicon Motion Analysis System was used to evaluate the gait of 38 feet in 33 patients with mild to severe hallux valgus. The Milwaukee foot model was …

Integration Mechanisms For Heading Perception, Elif M. Sikoglu, Finnegan J. Calabro, Scott A. Beardsley, Lucia M. Vaina

Biomedical Engineering Faculty Research and Publications

Previous studies of heading perception suggest that human observers employ spatiotemporal pooling to accommodate noise in optic flow stimuli. Here, we investigated how spatial and temporal integration mechanisms are used for judgments of heading through a psychophysical experiment involving three different types of noise. Furthermore, we developed two ideal observer models to study the components of the spatial information used by observers when performing the heading task. In the psychophysical experiment, we applied three types of direction noise to optic flow stimuli to differentiate the involvement of spatial and temporal integration mechanisms. The results indicate that temporal integration mechanisms play …

Leisure: Definitions, Patterns, And Constraints: A Study Of University Students In China, Shisi Zhou

Dissertations and Theses @ UNI

China has witnessed tremendous social transformation in the last three decades due to the introduction of the "open door" policy and economic reforms in the late 1970s, which has resulted in great changes in Chinese culture and identity considerations. University students, as one of the most energetic and creative groups of individuals in the society, are playing and will play an important role in leading leisure lifestyles in China in the future. The purpose of this study was to examine the understanding of leisure (xiuxian in Chinese), leisure patterns, and constraints among university students in China.

Undergraduate students (N = …

Molecular Simulation Of The Infrared Absorption Cross Section And Thermophysical Properties Of A Polyatomic Fluid, Zhi Liang

Doctoral Dissertations

"The work presented in this dissertation aims at ab initio calculations of the infrared absorption cross section, heat capacity, self-diffusion coefficient, shear viscosity and thermal conductivity of a polyatomic fluid with the aid of statistical mechanics. The simulation is firstly focused on calculating single-molecule properties such as molecular structure, vibrational energy eigen values and transition dipole moments using an efficient method based on the density functional theory. Based on these ab initio results, the infrared absorption cross sections are determined by the Fermi's Golden rule, and the thermophysical properties are determined from molecular dynamics simulations. Using carbon dioxide as an …

Solid Oxide Fuel Cell Electrode Characterization And Improvement For Fuel Flexibility And Supplemental Power Production, Isaiah D. Kellogg

Doctoral Dissertations

"Solid oxide fuel cells (SOFC) were fabricated and the electrodes tested for their individual catalytic effectiveness in various fuels by exposing each electrode to mixed gas while the opposite electrode was exposed to its respective pure gas. Mixed hydrogen and oxygen gas was successfully utilized as fuel in a single chamber SOFC (SC-SOFC). The conditions at which the porous nickel-yttria-stabilized zirconia (Ni-YSZ) cermet anode performed well did not significantly overlap the conditions at which the La₀.₈Sr₀.₂Fe₀.₈Co₀.₂ oxide (LSCF) cathode performed well, but there was significant catalytic activity at both electrodes which increased the open circuit voltage (OCV) beyond that predicted …

Application Of Quality Engineering To Investment Portfolio Selection And Optimization, Vivek Kulinchandra Jikar

Doctoral Dissertations

"The Taguchi System of Quality Engineering (TSQE) is a widely accepted philosophy and set of tools and techniques to rapidly design and manufacture high quality, low cost products and services. It is heavily focused on creating stable system designs that allow a product or system to perform as desired by customers in the environment of their choice. This research demonstrates the power of the TSQE to manage an investment portfolio. In particular, it uses the concept of design stability to select investments and optimize portfolios. It proposes a new design stability-based investment screening metric and discusses its application. Further, this …

Losing My Edge: The Copyright Implications Of Audio Blogging And Why Blogs Matter To The Music Industry, Steven M. Reilly

Vanderbilt Journal of Entertainment & Technology Law

In the past decade, the information distribution channels for music have changed dramatically. Not only have they largely moved from radio and print to online sources, but many audioblogs have formed to cover various niches according to the individual tastes of bloggers. This democratization of music criticism has been popular with listeners, as the information is easily and immediately available as well as tailored to a particular interest.

A defining feature of the audioblog is the inclusion of a downloadable MP3 in each post. In some cases, especially for more popular audioblogs, the download is approved by the copyright holder. …

Unveiling The Distinction Between The University And Its Academic Researchers: Lessons For Patent Infringement And University Technology Transfer, Jennifer Carter-Johnson

Vanderbilt Journal of Entertainment & Technology Law

This Article explores the idea that a faculty member acting in the role of an academic researcher in the scientific disciplines should be viewed in the context of patent law as an autonomous entity within the university rather than as an agent of the university. The structure of the university laboratory within the university and the social norms associated with the activities that members of the research laboratory conduct supports such a view. Additionally, the data from the implementation of the Bayh-Dole Act reveal that universities and faculty scientists have different goals and motivations regarding the transfer of new technology …

Libraries, Digital Content, And Copyright, Laura N. Gasaway

Vanderbilt Journal of Entertainment & Technology Law

Libraries use, acquire, create and host generate digital content. They digitize their existing collections of works such as letters, diaries and manuscripts and post them on library websites. Increasingly, libraries are utilizing digital technology to preserve library works which may or may not be made available to the public. Libraries also create, manage and host user generated content such as posts on discussion boards, blogs, wikis, RSS feeds, social bookmarking, tagging, and social networks. Libraries use user generated content for internal library purposes, such as displays and events and for teaching. Further, libraries often are asked to assist users who …

A Preliminary First Amendment Analysis Of Legislation Treating News Aggregation As Copyright Infringement, Alfred C. Yen

Vanderbilt Journal of Entertainment & Technology Law

The newspaper industry has recently experienced economic difficulty. Profits have declined because fewer people read printed versions of newspapers, preferring instead to get their news through so-called "news aggregators" who compile newspaper headlines and provide links to stories posted on newspaper websites. This harms newspaper revenue because news aggregators collect advertising revenue that newspapers used to enjoy.

Some have responded to this problem by advocating the use of copyright to give newspapers the ability to control the use of their stories and headlines by news aggregators. This proposal is controversial, for news aggregators often do not commit copyright infringement. Accordingly, …

Google Books: Page By Page, Click By Click, Users Are Reading Away Privacy Rights, Kathleen E. Kubis

Vanderbilt Journal of Entertainment & Technology Law

Google Books will likely become the world's most extensive book and magazine search and browsing resource, library, and bookstore--combined. However, as users necessarily reveal personal identifying information through their book searches and reading habits, this service poses a significant threat to personal privacy.

Because the Google Books Amended Settlement Agreement neglects to meaningfully address user privacy, the only available privacy protections are the limited rights bestowed by the Google Books Privacy Policy and the Google Privacy Policy. Unfortunately, these Privacy Policies protect the interests of Google at the expense of users.

The enactment of federal privacy statutes, which include provisions …