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Syntheses Of Trimethylamine- And Phosphonate- Substituted Carboranylporphyrins For Application In Boron Neutron Cancer Therapy, Michael William Easson Jan 2008

Syntheses Of Trimethylamine- And Phosphonate- Substituted Carboranylporphyrins For Application In Boron Neutron Cancer Therapy, Michael William Easson

LSU Doctoral Dissertations

Chapter 1 contains an introduction to porphyrins and carboranylporphyrins, including their physical properties, history, methods of synthesis, medicinal applications, and an overview of recently published compounds. Chapter 2 contains the total synthesis of a series of trimethylamine- and phosphonate-substituted carboranylporphyrins for application in boron neutron capture therapy (BNCT), including characterization by proton nuclear magnetic resonance spectroscopy, matrix-assisted time-of-flight mass spectroscopy, high resolution mass spectroscopy, UV-Vis spectrophotometry, X-ray crystallography, and melting point apparatus. Chapter 3 contains synthetic methods which were investigated as alternate routes to porphyrin synthesis and functionalization. Chapter 4 presents the in vitro biological evaluation of trimethylamine- and phosphonate-substituted …


Influences Of Maternal Corticosterone On Incubation Length And Hatchability Of Eggs Laid By Quail Hens Selected For Divergent Adrenocortical Stress Responsiveness, Jason Berante' Schmidt Jan 2008

Influences Of Maternal Corticosterone On Incubation Length And Hatchability Of Eggs Laid By Quail Hens Selected For Divergent Adrenocortical Stress Responsiveness, Jason Berante' Schmidt

LSU Master's Theses

Unstressed and stressed quail hens selected for exaggerated (HS, high stress) rather than reduced (LS, low stress) plasma corticosterone (B) response to brief restraint deposit more B into their eggs than do their LS hen counterparts. HS hens implanted with B also show reduced egg lay when compared to LS- and HS-control and LS-B-implanted hens. Herein, the effects of stress line on length of egg incubation (LEI) and chick body weight at emergence (BWTE) (Exp. 1) and the interactive influences of line with maternal B-treatment (sub-Q control, CON-, or B-implants) on LEI (Exp. 2) and on egg fertility (FERT), total …


Application Of The Hyman Model To Evaluate The Water And Salt Budgets In Three Mangrove Sites Along Shark River, Everglades, Cheng-Feng Tsai Jan 2008

Application Of The Hyman Model To Evaluate The Water And Salt Budgets In Three Mangrove Sites Along Shark River, Everglades, Cheng-Feng Tsai

LSU Master's Theses

Mangrove trees play an important role in the maintenance and sustainability of coastal wetlands due to their ability to adapt and survive in a wide range of saline and tidal conditions. Hydrologic processes (e.g., inundation frequency) and salinity are important regulators controlling the growth and productivity of mangrove forests. To quantify how changes in landscape-level hydrology will influence these regulators in mangrove forests, the hydrology model (HYMAN) was applied to three sites with distinct tidal forcings along the Shark River estuary in the Everglades National Park. HYMAN model uses mass balance equation to determine daily water and salt budgets as …


Listen, Sing And Learn: The Effects Of Musical Activities On Phonemic Awareness In The Foreign Language Classroom, Kelli White Jan 2008

Listen, Sing And Learn: The Effects Of Musical Activities On Phonemic Awareness In The Foreign Language Classroom, Kelli White

LSU Master's Theses

Traditionally, there has been a lack of emphasis placed on proper second language (L2) pronunciation in recent theoretical perspectives on foreign language pedagogy. Pronunciation is important because it is indicative of a learner’s level of phonemic awareness, an important component of second language acquisition. Inaccurate pronunciation (and therefore poor phonemic awareness) is often the result of a lack of training in this area due to the focus on grammar and syntax in many language classrooms. One often-neglected method of training students in L2 pronunciation discussed in some theoretical literature is the use of authentic materials in the form of musical …


Swamp Ecology In A Dynamic Coastal Landscape: An Investigation Through Field Study And Simulation Modeling, Susanne Sigrid Hoeppner Jan 2008

Swamp Ecology In A Dynamic Coastal Landscape: An Investigation Through Field Study And Simulation Modeling, Susanne Sigrid Hoeppner

LSU Doctoral Dissertations

Increased flooding, nutrient and sediment deprivation, and saltwater intrusion have been implicated as probable causes of coastal swamp deterioration in the Mississippi Delta. An understanding of the interactive effects of these factors is required to enable successful planning of wetland restoration activities. I used field data collected from 2000 till 2005 at forty study sites to characterize the baseline conditions of the Maurepas swamp. I used a cluster analysis to identify four swamp habitat clusters, and characterized the clusters on the basis of soil properties, salinity, basal area, stem density, and other tree-related variables. ANOVA and related statistical techniques showed …


Mercury Transport Through A Capped Sediment, Jianrong Liu Jan 2008

Mercury Transport Through A Capped Sediment, Jianrong Liu

LSU Doctoral Dissertations

Laboratory simulation cells were employed to evaluate the effectiveness of a sand cap for containing highly mercury-contaminated lake sediments and the resultant impacts on the mercury fate beneath the cap. Sand cap can delay and reduce the migration of mercury into the overlying water; however, due to the small partition coefficient of mercury between sand and water, a capping material with higher partition coefficient is better for the long-term containment of mercury. In the following study, efforts were made to identify and investigate an active capping material which works effectively at containing and inhibiting the methylation of mercury. Based on …


Ecological Genomics Of High Altitude Adaptation In Rufous-Collared Sparrows (Zonotrichia Capensis), Zachary A. Cheviron Jan 2008

Ecological Genomics Of High Altitude Adaptation In Rufous-Collared Sparrows (Zonotrichia Capensis), Zachary A. Cheviron

LSU Doctoral Dissertations

Adaptation is among the most prominent subjects in evolutionary biology. Despite its ubiquity in nature, many details of how adaptation occurs in natural populations remain poorly understood. Of particular interest are the genes and biochemical pathways that underlie adaptive phenotypes and how plasticity in these systems contributes to adaptive evolution. In this dissertation, I address these questions by investigating the molecular genetic basis of high-altitude adaptation in the Rufous-collared Sparrow (Zonotrichia capensis), a species with a broad altitudinal distribution in the Andes. First, I examined the role that variable selection pressures along elevational gradients play in the population genetic structure …


Environmental Influences On Adherence To Self-Management Behaviors And Glycemic Control In African American Patients With Type 2 Diabetes Mellitus, Brooke L. Barbera Jan 2008

Environmental Influences On Adherence To Self-Management Behaviors And Glycemic Control In African American Patients With Type 2 Diabetes Mellitus, Brooke L. Barbera

LSU Master's Theses

Diabetes mellitus is a chronic illness effecting approximately 20.8 million individuals in the United States. Minorities are adversely affected, with age-adjusted prevalence 1.7 times higher in African Americans than Caucasians. Type 2 diabetes is significantly affected by behavioral and environmental risk factors, including the presence of co-occurring diseases (i.e., hypertension, hyperlipidemia), obesity, age, and lack of physical activity, and each of these risk factors is more prevalent among African Americans. The treatment of diabetes is largely self-managed, with patients and their families handling 95% of their own care. Adherence to the multi-component diabetic treatment regimen requires daily care, often occurring …


Degradation And Water Quality Dynamics Of Sugarcane Residue In South Louisiana, Jose Roberto Deras Jan 2008

Degradation And Water Quality Dynamics Of Sugarcane Residue In South Louisiana, Jose Roberto Deras

LSU Doctoral Dissertations

PURPOSE: This research was conducted to assess methods to manage the residue blanket to avoid open field burning in sugarcane. Experiments were conducted in the state of Louisiana to evaluate methods to asses and potentially reduce water quality issues. METHODS: Concentrations and frequencies of biological compost tea were sprayed on sugarcane combine-harvester residue blanket to increase degradation rate and reduce potential for runoff water to transport nutrients and sediments that may impair water bodies, while sustaining suitable sugarcane yield. Carbon dioxide evolution rate (mg CO2-C) and CO2 fluxes were measured in laboratory and in open field conditions; as an index …


Syntheses And Evaluation Of Phthalocyanine Derivatives For Applications In Photodynamic And Boron Neutron Capture Therapies For Cancer, Hairong Li Jan 2008

Syntheses And Evaluation Of Phthalocyanine Derivatives For Applications In Photodynamic And Boron Neutron Capture Therapies For Cancer, Hairong Li

LSU Doctoral Dissertations

Chapter I introduced the background of phthalocyanines including its physical properties and various synthetic methods of free-base and metallo-phthalocyanines. The background of PDT and BNCT was introduced and the objective of ideal sensitizers was described. Chapter II described the synthesis and characterization of a series of pyridiloxy-substituted zinc phthalocyanines with different length of alkyl groups. Pyridiloxy-substituted silica phthalocyanines bearing different associated axial ligands, were alkylated with methyl or PEG chains. Biological study was performed on these cationic pyridiloxy-substituted zinc phthalocyanines. Chapter III introduced the synthesis and photophysical properties of A3B-type zinc phthalocyanines conjugated with one or two cobalta-carborane cages. They …


Learning Styles And Student's Perception Of Teachers' Attitudes And Its Relation To Truancy Among African Americans Students In Secondary Education, Kenyetta Quenishia Nelson-Smith Jan 2008

Learning Styles And Student's Perception Of Teachers' Attitudes And Its Relation To Truancy Among African Americans Students In Secondary Education, Kenyetta Quenishia Nelson-Smith

LSU Doctoral Dissertations

Many researchers have examined the effect of truancy and student achievement. However, there has been little or no focus on the effect of truancy and non-attendance among ethnic minorities. The current study examined how African American students’ learning styles and their perceptions of teachers’ attitudes toward them and the learning environment influenced their decision to become high truants. Additionally, the study sought to find if selected demographic factors had any relevance on the truancy rate of African American students. The researcher used several assessment instruments to measure the variables being tested. The Index of Learning Styles Questionnaire (ILS), developed by …


When Shakespeare Meets Al Gore: Imagine Interactions, Communication Competence, And Immediacy Traditional And Online-Based Distance Education, Tammy L. Croghan Jan 2008

When Shakespeare Meets Al Gore: Imagine Interactions, Communication Competence, And Immediacy Traditional And Online-Based Distance Education, Tammy L. Croghan

LSU Doctoral Dissertations

The growth of distance education, in its many forms, has had consequences for both online universities as well as more traditional universities. This study examines instructional behaviors and communication strategies used in face-to-face and online educational settings. The purpose of this study is to explore student perceptions of instructor immediacy, motivation, and communicator competence in addition to their own motivation and intrapersonal communication use in higher education settings. This dissertation follows a social scientific organizational pattern: introduction, literature review, methods, results, and discussion. The first two chapters examine the purpose of the study and the appropriate research on distance education, …


Effect Of Hydrology On The Structure And Function Of Mangrove Ecosystems In The Can Gio Mangrove Biosphere Reserve, Vietnam, Loi Tan Le Jan 2008

Effect Of Hydrology On The Structure And Function Of Mangrove Ecosystems In The Can Gio Mangrove Biosphere Reserve, Vietnam, Loi Tan Le

LSU Doctoral Dissertations

The influence of hydrology on the mangrove forests of Vietnam has received little scientific attention, even though hydrology is recognized as the primary forcing function in mangrove ecosystems worldwide. The purpose of this dissertation research was to determine the effects of hydrology on specific structural attributes and functional processes within the mangrove forests of Can Gio, a province in southeastern Vietnam. Khe Vinh (KV) and Mui O (MO), two locations within compartment 17 of the Can Gio Mangrove Biosphere Reserve, were chosen as study sites. This research addressed two questions: (1) What are the characteristics of the hydrological regime at …


Influence Of Row Spacing And Debris Distribution On Vegetation And Small Mammals In Louisiana Pine Plantations, Anne M. Bechard Jan 2008

Influence Of Row Spacing And Debris Distribution On Vegetation And Small Mammals In Louisiana Pine Plantations, Anne M. Bechard

LSU Master's Theses

Site preparation after clearcuts directly affects surrounding small mammal populations. Differences in bed row spacing and arrangement of debris can impact structure and composition of vegetation communities, which influence small mammal habitat. We surveyed vegetation and small mammals in 2 different row spacings (14 ft and 20 ft) and 2 different debris distributions (piled and scattered) in 4 clearcuts owned by Weyerhaeuser in Louisiana during 2006-2007. Our objectives were to examine effects of row spacing and debris distribution on vegetation, to look at responses of small mammal densities to row spacing and debris distribution, and to see how small mammals …


Wetland Mitigation Banks And The No-Net-Loss Requirement: An Evaluation Of The Section 404 Permit Program In Southeast Louisiana, Abbey Anne Tyrna Jan 2008

Wetland Mitigation Banks And The No-Net-Loss Requirement: An Evaluation Of The Section 404 Permit Program In Southeast Louisiana, Abbey Anne Tyrna

LSU Master's Theses

Section 404 of the Clean Water Act provides regulatory oversight for wetland conservation. One goal of the Section 404 program is to achieve a no-net-loss of the remaining wetland acres and functions. Wetland mitigation banks have been incorporated into wetland policy because of their potential advantage in achieving the no-net-loss requirements. This study analyzed four wetland mitigation banks with credits sold between 1991 and 2007 in southeastern Louisiana to determine if they were contributing to the goal of no-net-loss. The goal of no-net-loss is reached when there is complete compensation of wetland structure and function. The study area for this …


Brachial Artery Flow Mediated Vasodilation: Effect Of Chemical Analytes, Diet, Exercise, And Genetic Markers, Joanie Brocato Wilson Jan 2008

Brachial Artery Flow Mediated Vasodilation: Effect Of Chemical Analytes, Diet, Exercise, And Genetic Markers, Joanie Brocato Wilson

LSU Doctoral Dissertations

The goal of this research was to gain a better understanding of interplay between molecular biology, physiology, biochemistry, functionality with disease and interventions. The primary findings of the first study were that there was a significant inverse correlation between homocysteine and brachial artery flow mediated dilation (BAFMD) and baseline brachial artery diameter. Interestingly, there was a significant difference in BAFMD between methylene tetrahydrofolate reductase (MTHFR) genotype groups. Regression analysis indicated that the MTHFR genotype, homocysteine and age were significant predictors of BAFMD. The second study revealed that vascular reactivity as measured by BAFMD was modifiable. A meta-analysis of 22 intervention …


Survival, Growth, And Behavior Of Helicoverpa Zea (Boddie) And Heliothis Virescens (F.) (Lepidoptera: Noctuidae) On Genetically Engineered Cotton Expressing The Vip3a Insecticidal Protein, Padma Latha Bommireddy Jan 2008

Survival, Growth, And Behavior Of Helicoverpa Zea (Boddie) And Heliothis Virescens (F.) (Lepidoptera: Noctuidae) On Genetically Engineered Cotton Expressing The Vip3a Insecticidal Protein, Padma Latha Bommireddy

LSU Doctoral Dissertations

Larval behavior, survivorship, and injury potential of Helicoverpa zea (Boddie), and tobacco budworm, Heliothis virescens (F.), was evaluated on cotton plants genetically engineered to express Bacillus thuringiensis (Bt) insecticidal proteins, Vip3A and Vip3A +Cry 1Ab (VipCot™). Larvae (2-d-old) of both species were infested on plant terminals of vegetative or flowering stage cotton plants. Regardless of species, more larvae migrated from the plant terminals of Vip3A and VipCot plants compared to larvae infested on a conventional non-Bt cotton line (Coker 312). Larval (2-d-old) survivorship on VipCot™ plant structures was generally lower than that on similar structures of the Vip3A cotton line. …


Academic Impropriety: Violation Of Normative Teaching Behaviors As Identified By Nursing Educators, Melanie Hilburn Green Jan 2008

Academic Impropriety: Violation Of Normative Teaching Behaviors As Identified By Nursing Educators, Melanie Hilburn Green

LSU Doctoral Dissertations

With public criticism of American higher education on the rise, it is prudent for those in the academy to reflect upon their responsibilities to their students. Of particular salience is an examination of what constitutes misconduct within the faculty role. This dissertation reports the results of a study designed to identify what nursing educators believe to be the violation of normative teaching behaviors. A sequential explanatory mixed methods design was utilized to develop an understanding of the actions that constitute academic impropriety. The College Teaching Behaviors Inventory, a survey instrument designed by Braxton and Bayer (1999), was distributed to deans …


Bile Salts As Olfactory And Gustatory Stimuli In The Channel Catfish, Shane Howell Rolen Jan 2008

Bile Salts As Olfactory And Gustatory Stimuli In The Channel Catfish, Shane Howell Rolen

LSU Doctoral Dissertations

A chemotopic map of biologically relevant odorants (that include amino acids, bile salts and nucleotides) exists in the olfactory bulb (OB) and forebrain (FB) of channel catfish, Ictalurus punctatus (Chapter one). Neurons processing bile salt odorant information lie medially within these bilaterally symmetric structures; however, information as to how single neurons discriminate and process this odorant information is lacking. Chapters two and three of the dissertation identify the range of odorant bile salt molecules that excite these neurons [i.e. the excitatory molecular receptive range (EMRR)] within the bile salt chemotopic zones of the OB and FB. The results of the …


Avian Diversification In The Afrotropics, Ben D. Marks Jan 2008

Avian Diversification In The Afrotropics, Ben D. Marks

LSU Doctoral Dissertations

Widespread bird species endemic to the lowlands of the Guineo-Congolian rainforest of Africa have traditionally been thought to lack substantial intraspecific structure. This view owes largely to their widespread distributions coupled with the absence of discrete geographic variation in plumage. In the following chapters I examine the phylogeographic patterns of three such species using a combination of molecular and morphometric data. The three species investigated are the Green Hylia (Hylia prasina), the Red-tailed Bristlebill (Bleda syndactylus), and the Yellow-whiskered Greenbul (Andropadus latirostris). Using the phylogeographic patterns from these data, I assess 1) models of rainforest species diversification, 2) current taxonomy, …


Reading Poe Reading Blackwood’S: The Palimpsestic Subtext In "The Fall Of The House Of Usher”, Diane Hoeveler Jan 2008

Reading Poe Reading Blackwood’S: The Palimpsestic Subtext In "The Fall Of The House Of Usher”, Diane Hoeveler

English Faculty Research and Publications

No abstract provided.


How Do Securities Laws Influence Affect, Happiness, & Trust?, Peter H. Huang Jan 2008

How Do Securities Laws Influence Affect, Happiness, & Trust?, Peter H. Huang

Publications

This Article advocates that securities regulators promulgate rules based upon taking into consideration their impacts upon investors' and others' affect, happiness, and trust. Examples of these impacts are consumer optimism, financial stress, anxiety over how thoroughly securities regulators deliberate over proposed rules, investor confidence in securities disclosures, market exuberance, social moods, and subjective well-being. These variables affect and are affected by traditional financial variables, such as consumer debt, expenditures, and wealth; corporate investment; initial public offerings; and securities market demand, liquidity, prices, supply, and volume. This Article proposes that securities regulators can and should evaluate rules based upon measures of …


Authentic Happiness, Self-Knowledge And Legal Policy, Peter H. Huang Jan 2008

Authentic Happiness, Self-Knowledge And Legal Policy, Peter H. Huang

Publications

This Article analyzes three questions: can, how, and should legal policy help people in their individual quests for authentic happiness. This Article adopts psychologist Martin Seligman's definition of the phrase authentic happiness. This Article provides an introduction to examples of legal policies based upon empirical and experimental research in positive psychology, measures of subjective well-being, and quality of life studies.


Common Ground: The Case For Collaboration Between Anti-Poverty Advocates And Public Interest Intellectual Property Advocates, Deborah J. Cantrell Jan 2008

Common Ground: The Case For Collaboration Between Anti-Poverty Advocates And Public Interest Intellectual Property Advocates, Deborah J. Cantrell

Publications

This article examines the previously unappreciated common ground between scholars and advocates who work to eliminate poverty, and scholars and advocates who work on intellectual property issues in the public interest. The article first illustrates how scholars and advocates working on poverty and on public interest intellectual property have relied on rights talk to frame their social movements. Under the conventional narrative, the framing has accentuated differences between the movements. As the Article explains, the two movements share core principles and should recognize shared interests and goals. By developing a new model of how to view public interest movements, the …


Interferon Alfacon 1 Inhibits Sars-Covinfection In Human Bronchial Epithelial Calu-3 Cells, Y. Kumaki, C. W. Day, M. K. Wandersee, B. P. Schow, J. S. Madsen, D. Grant, J. P. Roth, Donald F. Smee, L. M. Blatt, Dale L. Barnard Jan 2008

Interferon Alfacon 1 Inhibits Sars-Covinfection In Human Bronchial Epithelial Calu-3 Cells, Y. Kumaki, C. W. Day, M. K. Wandersee, B. P. Schow, J. S. Madsen, D. Grant, J. P. Roth, Donald F. Smee, L. M. Blatt, Dale L. Barnard

Animal, Dairy, and Veterinary Science Faculty Publications

The primary targets for SARS-CoV infection are the epithelial cells in the respiratory and intestinal tract. The angiotensin-converting enzyme 2 (ACE-2) has been identified as a functional receptor for SARS-CoV. ACE-2 has been shown to be expressed at the apical domain of polarized Calu-3 cells. In this report, interferon alfacon 1 was examined for inhibitory activities against SARS-CoV on human lung carcinoma epithelial Calu-3 cell line and the other three African green monkey kidney epithelial cell lines. Interferon alfacon 1 demonstrated significant antiviral activity in neutral red uptake assay and virus yield reduction assay. The data might provide an important …


The Child Protection Pretense: States' Continued Consignment Of Newborn Babies To Unfit Parents, James G. Dwyer Jan 2008

The Child Protection Pretense: States' Continued Consignment Of Newborn Babies To Unfit Parents, James G. Dwyer

Faculty Publications

No abstract provided.


Expressing Community Values Through Family Law Adjudication, Vivian E. Hamilton Jan 2008

Expressing Community Values Through Family Law Adjudication, Vivian E. Hamilton

Faculty Publications

No abstract provided.


Hearts, Minds, Hands: A Dream Team For Mental Health, Julianne Gold Brunson, Judy Molner, Miriam Nathan Lerner Jan 2008

Hearts, Minds, Hands: A Dream Team For Mental Health, Julianne Gold Brunson, Judy Molner, Miriam Nathan Lerner

Articles

Interpreting in a mental health setting with hearing staff members and deaf clientele, the ethical situations fly fast and furious, providing the interpreter with a wealth of war stories with which to regale neophyte students of this dynamic profession. Much has been written to improve the many and varied mental health services being extended to deaf populations. The most commonly described dyads are that of hearing therapist and deaf patient. However, consider the case of a deaf psychologist treating hearing clients. In this instance, the interpreter becomes the liaison between the deaf professional and the hearing patient. When an interpreter …


Riparian Owner's Guidebook For Watershed Management, Annis Water Resources Institute Jan 2008

Riparian Owner's Guidebook For Watershed Management, Annis Water Resources Institute

Environmental Guidebooks and Model Ordinances

This guidebook can help riparian landowners manage and maintain their property to ensure the continued existence of safe, clean, and natural waterways. It can also provide a better understanding of problems facing our water supplies and what preventative and corrective action we as landowners can put into effect. The guidebook is divided by issues that affect water quality, with possible problems and best management practices (BMPs) mentioned for each topic.


Septic System Owner's Guidebook For System Performance, Annis Water Resources Institute Jan 2008

Septic System Owner's Guidebook For System Performance, Annis Water Resources Institute

Environmental Guidebooks and Model Ordinances

This guidebook can help onsite system owners understand and care for their septic systems by explaining their basic components and function, techniques for caring for them, and where the waste goes when it is removed from the system.