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Friction Stir Channeling: An Innovative Technique For Heat Exchanger Manufacturing, Nagarajan Balasubramanian

Doctoral Dissertations

"Friction stir processing (FSP) is an emerging processing technique based on the principles of friction stir welding (FSW), which is a relatively new solid-state metal joining process developed by The Welding Institute, UK. Some of the unique features of FSW such as the low amount of heat generated, extensive plastic deformation and controlled flow of material is being exploited to develop new material modification and manufacturing processes. Friction stir channeling (FSC) is one such adaptation of FSP that can produce continuous and stable internal channels for application in heat exchanging equipment. Friction stir channeling produces these channels if the defect …

Synthesis And Evaluation Of Vegetable (Soybean) Oil Based Epoxy Resin For Beverage Can Coating And Enzymatic Synthesis And Characterization Of Tailored N&C End Protected Oligopeptides, Ying Gao

Doctoral Dissertations

"Research described in this dissertation covers two topics. Part-I is related to the development of a soybean oil based epoxy resin and its application in beverage can coatings. Interior surfaces of beverage can are invariably coated with polymer coating. The most commonly used coatings at present are derived from bisphenol A (BPA) based epoxy reins. However, due to perceived endocrine disrupting nature of BPA and consequential adverse effects on humans and wildlife concerns for the use of BPA based coatings and its leaching into beverages have been expressed. The research in the first part describes the synthesis and evaluation of …

Multiple-Input Multiple-Output Wireless Communications With Imperfect Channel Knowledge, Christopher Potter

Doctoral Dissertations

"In the first work a recurrent neural network (RNN) is employed for MIMO channel prediction. A novel PSO-EA-DEPSO off-line training algorithm is presented and is shown to outperform PSO, PSO-EA, and DEPSO. This predictor is shown to be robust to varying channel scenarios. New expressions for the received SNR, array gain, average probability of error, and diversity gain are derived. Next, a new expression for the outage capacity of a MIMO system with no CSI at the transmitter and an estimate at the receiver is presented. Since the outage capacity is a function of the first and second moments of …

Geological Sequestration Of Carbon Dioxide By Hydrous Carbonate Formation In Steelmaking Slag, C. Hank Rawlins

Doctoral Dissertations

"The formation of carbonate solids from the alkaline earth oxide phases in steelmaking slag was investigated in dry and aqueous conditions as a vehicle for carbon dioxide sequestration. The goal of this research was to determine the process conditions that would increase the kinetics of the carbonate formation process under hydrous conditions, enabling direct removal of carbon dioxide from steelmaking offgas"--Abstract, page iv.

Thin Film Techniques For The Fabrication Of Nano-Scale High Energy Density Capacitors, James N. Reck

Doctoral Dissertations

Dielectric thin films of either TiO₂ or BaTiO₃ were sputtered in O₂/Ar plasmas on Si wafers to thicknesses ranging from approximately 25 to 200 nm with patterned Ni or Pt electrodes sputtered in Ar plasmas at thicknesses from about 20 to 250 nm to form nano-capacitors. Statistical design of experiments (DOE) was used to determine the effects of the deposition power, plasma composition, and deposition temperature on the measured electrical properties of the nano-capacitors. Additional tests to determine the effects of the dielectric and electrode thickness on the measured dielectric responses of the devices were also undertaken. Characterization was performed …

Inter-Area Oscillation Damping In Large Scale Power Systems With Unified Power Flow Controllers, Mahyar Zarghami

Doctoral Dissertations

"Power system oscillations occur in power networks as a result of contingencies such as faults or sudden changes in load or generation. They are detrimental to the operation of the system since they affect system stability and the optimal power flow through it. These oscillations do not usually damp out in tie-lines unless certain controls are applied to the system. Local and inter-area oscillations have traditionally been controlled by Power System Stabilizers (PSS). However, Flexible Alternating Current Transmission Controllers (FACTS) have significant potential as alternatives to PSS. The main goal of this research is to damp inter-area oscillations by Unified …

Modeling, Analysis And Experimentation For Building Ice Parts With Supports Using Rapid Freeze Prototyping, Frances D. Bryant

Doctoral Dissertations

"Rapid Freeze Prototyping (RFP) is a freeform fabrication method that freezes water droplets into ice in a layer-by-layer manner to additively create a 3-dimensional part. Each layer of a geometry is deposited and allowed to freeze before the next layer is added. Ice parts produced by RFP can be used in investment casting to replace wax patterns and in other applications which may benefit from the unconventional method of using ice as a pattern or mold. More recently, a sacrificial support material has been incorporated into RFP so that over-hung areas and complex geometries can be fabricated. The research presented …

A Tour-De-Force In Polymer Crosslinked Aerogels, Sudhir Mulik

Doctoral Dissertations

"In the quest of building mechanically strong materials with low density and high porosity, polymer crosslinked aerogels stand as the most promising nano-engineered examples. Covalent attachment of polymers and bridging of skeletal nanoparticles of typical aerogels is demonstrated by using surface initiated polymerization (SIP) with a bidentate free-radical initiator structurally related to azobisisobutyronitrile (AIBN) and confined on mesoporous silica surfaces. Different monomers were introduced in the mesopores and upon heating at 70⁰C, all mesoporous surfaces throughout the entire skeletal framework were coated conformally with a 10-12 nm thick polymer layer indistinguishable spectroscopically from the respective commercial bulk materials. The new …

Speculation And Hedging With Virtuals, Prasenjit Shil

Doctoral Dissertations

"Virtual bid" and "Virtual offer" are purely financial products offered in certain electricity markets. Theoretically, virtual bids and offers can change the electricity price as the bids and offers are stacked along with the demand and supply, respectively. This dissertation discusses how virtuals can be used to hedge and speculate in the electricity market. A statistical simulation model is developed based on the day-ahead (DA) demand and real time (RT) load data from Midwest Independent Transmission System Operator's (MISO) footprint and DA and RT price observed at Cinergy hub. The simulation models are intended to mimic the load and price …

Virtual Prototyping With Surface Reconstruction And Freeform Geometric Modeling Using Level-Set Method, Weihan Zhang

Doctoral Dissertations

"More and more products with complex geometries are being designed and manufactured by computer aided design (CAD) and rapid prototyping (RP) technologies. Freeform surface is a geometrical feature widely used in modern products like car bodies, airfoils and turbine blades as well as in aesthetic artifacts. How to efficiently design and generate digital prototypes with freeform surfaces is an important issue in CAD. This paper presents the development of a Virtual Sculpting system and addresses the issues of surface reconstruction from dexel data structures and freeform geometric modeling using the level-set method from distance field structure. Our virtual sculpting method …

Densification, Microstructure, And Mechanical Properties Of Zirconium Diboride Based Ultra-High Temperature Ceramics, Sumin Zhu

Doctoral Dissertations

"The first part of this dissertation was aimed at studying the densification of ZrB₂ ceramics by pressureless sintering techniques. Various processes have been applied to coat ZrB₂ powders with polymer precursors, which were used to produce C after charring. After sintering at 1900⁰C, relative density increased of ~70% for uncoated ZrB₂ to >99% for ZrB₂ coated with at least 1.0 wt% C. Thermodynamic analysis suggested that C reacted with and removed oxide impurities (ZrO₂ and B₂O₃) that were present on the ZrB₂ particle surfaces, which promoted densification by minimizing grain coarsening"--Abstract, page iv.

The Effect Of Free Chlorine And Monochloramine On Lead In Drinking Water And Epitaxial Electrodeposition Of Tin Sulfide, Sansanee Boonsalee

Doctoral Dissertations

"Electrochemical deposition is utilized in various electronic and photovoltaic applications and in the protective coating industries. This dissertation primarily addresses the environmental aspects of electrochemical deposition. In the first part of this study, Pb dissolution in drinking water was investigated in the presence of two disinfectants: free chlorine (in the form of HOCI/OCr) and monochloramine (NH₂Cl). In the second part of this study, epitaxial SnS nanodisks were electrodeposited onto a Au(100) substrate. Water utility systems use either free chlorine or monochloramine in their disinfection program. Whereas free chlorine reacts with natural organic matter in the water to produce halogenated organic …

Uncertainty Analysis And Sensitivity Analysis For Multidisciplinary Systems Design, Jia Guo

Doctoral Dissertations

"The objective of this research is to quantify the impact of both aleatory and epistemic uncertainties on performances of multidisciplinary systems. Aleatory uncertainty comes from the inherent uncertain nature and epistemic uncertainty comes from the lack of knowledge. Although intensive research has been conducted on aleatory uncertainty, few studies on epistemic uncertainty have been reported. In this work, the two types of uncertainty are analyzed. Aleatory uncertainty is modeled by probability distributions while epistemic uncertainty is modeled by intervals. Probabilistic analysis (PA) and interval analysis (IA) are integrated to capture the effect of the two types of uncertainty. The First …

Characterization And Synthesis Of Nanoscale Materials, Jinfeng Wang

Doctoral Dissertations

"This dissertation focuses on the systematic study of techniques for characterization and synthesis of nanoscale materials. We have achieved several goals. Firstly, high number density uniform zinc oxide nanostructure growth has been achieved using thermal evaporation, through control of experimental parameters that include source material temperature, substrate temperature, substrate material, gas flow rate, and choice of catalyst. Aligned zinc oxide nanowires, randomly oriented zinc oxide nanowires, zinc oxide container-shaped structures, and zinc oxide nanobelts have been synthesized with high yield. Secondly, using a one parameter family of lattice fringe geometry curves, we show how to examine the epitaxial relationship between …

Energy Efficient Clustering And Secure Data Aggregation In Wireless Sensor Networks, Julia Albath

Doctoral Dissertations

"Communication consumes the majority of a wireless sensor network's limited energy. There are several ways to reduce the communication cost. Two approaches used in this work are clustering and in-network aggregation. The choice of a cluster head within each cluster is important because cluster heads use additional energy for their responsibilities and that burden needs to be carefully distributed. We introduce the energy constrained minimum dominating set (ECDS) to model the problem of optimally choosing cluster heads in the presence of energy constraints. We show its applicability to sensor networks and give an approximation algorithm of O(log n) for solving …

Integrated Process Planning For A Hybrid Manufacturing System, Lan Ren

Doctoral Dissertations

"A hybrid manufacturing system integrated CNC machining and laser-aided layered deposition and achieves the benefits of both processes. In this dissertation, an integrated process planning framework which aims to automate the hybrid manufacturing process is investigated. Critical components of the process planning, including 3D spatial decomposition of the CAD model, improvement of the toolpath generation pattern, repairing strategies using a hybrid manufacturing system, etc., are discussed"--Abstract, page iv.

System And Ic Level Analysis Of Electrostatic Discharge (Esd) And Electrical Fast Transient (Eft) Immunity And Associated Coupling Mechanisms, Jayong Koo

Doctoral Dissertations

"The exposure of electronic circuits to lightning, electrostatic discharge (ESD), electrical fast transients (EFT) or sine wave signals can reveal RF immunity problems. Typical problems include temporary malfunctions or permanent damage of integrated circuits (ICs). In an effort to reproduce those disturbances, a series of electromagnetic compatibility standards has been developed. However, a complete understanding of the root cause of the immunity problems has yet to be established. This dissertation discusses immunity problems in three papers, starting at the system level, via the coupling path into the IC"--Abstract, page iv.

Design And Optimization Of Abrasive Slurry Feed System, Control Circuit And Jet Drilling Tool For Mining Applications,, Pradeep Nambiath

Doctoral Dissertations

"This dissertation focused on an investigation of small diameter hole drilling using abrasive slurry jet (ASJ) technology. The existing ASJ feed systems were reviewed and found inadequate to satisfy the requirements of an ASJ drill. A novel feed system was designed which improved on existing systems by resolving problems with the inability to perform stop/start operations and ensure precise metering of abrasive feed. This system met standards of consistency and evenness of feed required for machining aircraft component parts for Air Force Research Laboratory (AFRL). Theoretical and experimental analysis of the power of an ASJ stream yielded valuable design information …

Formation And Removal Of Pesticides And Pesticide Transformation Products During Water Treatment, Evelyn F. Chamberlain

Doctoral Dissertations

"A comprehensive suite of over 60 pesticides (herbicides, insecticides, and fungicides) representing a variety of classes at environmentally relevant concentrations (low µg/L) were screened for reactivity under typical drinking water conditions and dosages. The most common oxidants/transformation agents in water treatment systems were examined for reactivity including free and combined chlorine, chlorine dioxide, permanganate, ozone, hydrogen peroxide, ultraviolet radiation, and high pH (alkaline hydrolysis). Due to the broad nature of the study, pesticide compounds were analyzed as multiple mixes broken into two groups based on analytical methods, those analyzed by GC/ECD and those by LC/MS. Combinations of reactive disinfectant/oxidant and …

Examination Of Practices Used By Rural Georgia School Principals In Hiring Highly Qualified Teachers, Steven Dale Rhodes

College of Graduate Studies: Theses & Dissertations

The purpose of the study was to understand hiring practices used by rural high performance Georgia school principals. The study used a qualitative design. The researcher utilized semi-structured interviews and reviews of documents related to hiring to understand hiring practices currently being used by rural Georgia school principals, hiring practices perceived to be working best to attract teachers, hiring practices most influential to the final selection of the teacher, and principals suggested improvements to the hiring process. Each of the three participants was purposefully chosen for the study, was assured confidentiality, and was given a fictitious name. The accounts of …

Women In Science: Stories From The Margins, Laura Mathis Mulvanity

College of Graduate Studies: Theses & Dissertations

Women are significantly underrepresented in the hard sciences and engineering. While the number of women seeking degrees in these fields has increased in the last forty years, a substantial gap still exists between the sexes. The purpose of this dissertation is to examine one area of influence on career choice -- the curriculum. Women scientists are underrepresented in the school curriculum. This dissertation examines the discourse of curriculum and the role it has in the gendering of the field of science. The nature of the development of a curriculum lends itself to the practice of exclusion. The construction of curriculum …

Georgia Southern Magazine, Georgia Southern University

Georgia Southern Magazine

• Campus News
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Glimpses Of The Priest As Dean, Legislator, And Friend, Paul F. Rothstein

Georgetown Law Faculty Publications and Other Works

Professor Rothstein offers details on how he crossed paths with Father Drinan and how they became good friends and professional colleagues.

Government As Educator: A New Understanding Of First Amendment Protection Of Academic Freedom And Governance, Judith C. Areen

Georgetown Law Faculty Publications and Other Works

In Garcetti v. Ceballos, 547 U.S. 410 (2006), the Supreme Court held that statements made pursuant to the official duties of public employees are not shielded by the First Amendment from employer discipline, despite a warning from three dissenting justices that the holding could "imperil First Amendment protection of academic freedom in public college and universities." This article responds to the invitation in Garcetti to identify constitutional interests that support academic freedom and that are not fully accounted for by public-employee speech jurisprudence. It also argues that, contrary to common understanding, academic freedom is about more than faculty research and …

Climate Change In The Supreme Court, Lisa Heinzerling

Georgetown Law Faculty Publications and Other Works

In Massachusetts v. Environmental Protection Agency, the Supreme Court confronted the issue of climate change for the first time. The Court held that the Clean Air Act gives the Environmental Protection Agency the authority to regulate greenhouse gases and that the agency may not decline to exercise this authority based either on factors not present in the statute or inconclusive gestures toward uncertainty in the science of climate change. I had the privilege of serving as the lead author of the winning briefs in this case. This Article provides an insider's perspective on the choices that went into bringing and …

Gone In Sixty Milliseconds: Trademark Law And Cognitive Science, Rebecca Tushnet

Georgetown Law Faculty Publications and Other Works

Trademark dilution is a cause of action for interfering with the uniqueness of a trademark. For example, consumers would probably not think that "Kodak soap" was produced by the makers of Kodak cameras, but its presence in the market would diminish the uniqueness of the original Kodak mark. Trademark owners think dilution is harmful but have had difficulty explaining why. Many courts have therefore been reluctant to enforce dilution laws, even while legislatures have enacted more of them over the past half century. Courts and commentators have now begun to use psychological theories, drawing on associationist models of cognition, to …

Sight, Sound And Meaning: Teaching Intellectual Property With Audiovisual Materials, Rebecca Tushnet

Georgetown Law Faculty Publications and Other Works

This article addresses the author's experience using audiovisual materials from the Georgetown Intellectual Property Teaching Resources database. She used audiovisual materials extensively in class to allow students to see the subject matter of the cases rather than just reading verbal descriptions and enable them to apply the principles they read about to new, concrete examples. Many students in IP courses have special interests in music, film, or the visual arts, and the database allows her--and other teachers--to present materials that engage them. She found that students are more willing to speak up in class when they can see or hear …

Disintegration, Girardeau A. Spann

Georgetown Law Faculty Publications and Other Works

The silver lining behind the Supreme Court's decision to disintegrate the Seattle and Louisville public schools is that the decision also runs the risk of disintegrating judicial review. Parents Involved in Community Schools v. Seattle School District No. 1 holds that the Constitution bars voluntary, race-conscious efforts by two local school boards to retain the racial integration that they worked so hard to achieve after Brown. In so holding, the Court curiously reads the Equal Protection Clause as preventing the use of race to pursue actual equality, and instead insists on a type of formal "equality" that has historically …

The Choice Between Madison And Fdr, Randy E. Barnett

Georgetown Law Faculty Publications and Other Works

This exchange is about three clauses that have often been used by the courts since the New Deal to expand federal power: the Commerce Clause, the Necessary and Proper Clause, and the Taxation Clause, from which the spending power has (at least until today) been construed. This Essay addresses the originalist interpretation of the Necessary and Proper Clause.

Guilty Pleas Or Trials: Which Does The Barrister Prefer?, Peter W. Tague

Georgetown Law Faculty Publications and Other Works

Barristers in England and attorneys in the United States have been upbraided for pursuing their interests to their clients' detriment in recommending guilty pleas over trials. While this accusation against American attorneys could be true since their incentives are sometimes skewed to favor guilty pleas, it is not accurate with respect to barristers in England. This is because the latter’s selfish incentives--to maximize income and avoid sanction--incline them to prefer trials over guilty pleas. In Melbourne and Sydney, barristers have never been similarly accused. Indeed, the topic has not been studied. Based on interviews with legal professionals in those cities, …