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Sense Of Coherence And Quality Of Life In Women Family Members Of The Seriously Mentally Ill, M. Jane Suresky, Jaclene Zauszniewski, Abir K. Bekhet

College of Nursing Faculty Research and Publications

Providing care to a family member with serious mental illness (SMI) can reduce a family's quality of life. Quality of life, however, can be positively influenced by the caregiver's sense of coherence (SOC). Antonovsky's Salutogenic Health Model was examined in this secondary analysis of data from 60 women family members of adults with SMI. The results indicated that greater perceived stress decreased SOC and QoL, greater SOC enhanced QoL, and SOC partially mediated the effects of perceived stress on QoL. The findings suggest the need for reducing stress and strengthening SOC to promote optimal QoL for family members of adults …

Theoretical Substruction Illustrated By The Theory Of Learned Resourcefulness (Article), Abir K. Bekhet, Jaclene A. Zauszniewski

College of Nursing Faculty Research and Publications

This article describes the process of theoretical substruction and uses this process to examine the significance of Rosenbaum's resourcefulness theory for nursing research and practice. The article discusses relocation as a phenomenon of interest to gero-psychiatric nurses working with elders who have relocated to retirement communities, illustrated by the theory of learned resourcefulness. The literature was reviewed to assess the congruence between the theoretical and operational systems suggested by Rosenbaum's resourcefulness theory. A model of learned resourcefulness is presented that includes middle-range concepts, relational statements, and propositions derived from the research literature. Theoretical substruction provides a mechanism for testing middle-range …

Kinetic, Spectroscopic, And X-Ray Crystallographic Evidence For The Cooperative Mechanism Of The Hydration Of Nitriles Catalyzed By A Tetranuclear Ruthenium-Μ-Oxo-Μ-Hydroxo Complex, Chae S. Yi, Tonya N. Zeczycki, Sergey V. Lindeman

Chemistry Faculty Research and Publications

The tetranuclear ruthenium-oxo-hydroxo-hydride complex {[(PCy₃)(CO)RuH]₄(μ₄-O)(μ₃-OH)(μ₂-OH)} (1) was found to be a highly cooperative catalyst for the nitrile hydration reaction. The cooperative mechanism of the hydration of benzonitrile was established by Hill inhibition kinetics. The treatment of a nitrile substrate with complex 1 led to the catalytically relevant nitrile-coordinated tetraruthenium complex 3. The X-ray structure of the nitrile-coordinated complex 3 showed a considerably “relaxed” tetrameric core structure compared to that of 1. The hydration of para-substituted benzonitriles p-X-C₆H₄CN with an electron-withdrawing …

Chiral Ionic Liquids:  Synthesis, Properties, And Enantiomeric Recognition, Shaofang Yu, Sergey V. Lindeman, Chieu D. Tran

Chemistry Faculty Research and Publications

We have synthesized a series of structurally novel chiral ionic liquids which have a either chiral cation, chiral anion, or both. Cations are an imidazolium group, while anions are based on a borate ion with spiral structure and chiral substituents. Both (or all) stereoisomeric forms of each compound in the series can be readily synthesized in optically pure form by a simple one-step process from commercially available reagents. In addition to the ease of preparation, most of the chiral ILs in this series are liquid at room temperature with a solid to liquid transformation temperature as low as −70 °C …

Double Carbon−Hydrogen Activation Of 2-Vinylpyridine: Synthesis Of Tri- And Pentanuclear Clusters Containing The Μ-Nc5H4Ch═C Ligand, Kazi A. Azam, Dennis W. Bennett, Mohammad R. Hassan, Daniel T. Haworth, Graeme Hogarth, Shariff E. Kabir, Sergey V. Lindeman, Luca Salassa, Sultana R. Simi, Tasneem Siddiquee

Chemistry Faculty Research and Publications

Reactions of 2-vinylpyridine with the triruthenium complexes [Ru₃(CO)₁₂] and [Ru₃(CO)₁₀(μ-dppm)] leads to a previously unknown double carbon−hydrogen bond activation of the β-carbon of the vinyl group to afford the pentaruthenium and triruthenium complexes [Ru₅(CO)₁₄(μ₄-C₅H₄CH═C)(μ-H)₂] (1) and [Ru₃Cl(CO)₅(μ-CO)(μ-dppm)(μ₃-NC₅H₄CH═C)(μ-H)] (2), respectively. Crystal structures reveal two different forms of bridging of the dimetalated 2-vinylpyridyl ligand, capping a square face in 1 and a triangular face in 2.

Exercise And Peripheral Vascular Function In Health And Disease, Arturo Arce

LSU Doctoral Dissertations

“Chronic disease will never reach its clinical horizon to compromise health if it is attacked at its origin” [1]. Knowledge that one’s risk for cardiovascular events is related to the severity of endothelial dysfunction, and evidence that exercise training can improve endothelial function, has prompted speculation that measures of vascular function may serve as a “barometer” for cardiovascular health. This dissertation consists of three experiments intended to study vascular function and the manner in which it may influence or may be influenced by physical function. Project one examined the influence of high and low volume circuit weight training on forearm …

Dactyls Reveal Evolutionary Patterns In Decapod Crustaceans, Jeffrey Guy Agnew

LSU Doctoral Dissertations

Because of their high preservation potential and uses in foraging and defense, decapod crustacean dactyls (movable fingers of claws) are potentially excellent test subjects for an ongoing debate concerning the relative importance of top-down (predators) and bottom-up (prey) controls on morphologic diversification and evolution. The utility of dactyls for inferring evolutionary patterns were evaluated using living and subfossil xanthoid crabs sampled from the southeast U.S. Atlantic and Gulf of Mexico coasts, and were used to: (1) distinguish the roles of selection and constraint on dactyl morphology through allometric and shape comparisons in the context of the crab’s phylogenetic relationships and …

Growth And Properties Of Metal-On-Metal Nanostructures: Ag On Cu(110) And Co On Ag(110), Indrajith Chandima Senevirathne

LSU Doctoral Dissertations

Heteroepitaxial nanostructures have a diverse array of applications and show novel phenomena that arise from the exotic physics exhibited in reduced dimensions. We have investigated two nano-structured systems in order to gain insights into the dynamics of their nucleation, growth and have observed striking differences, due in part to a competition between lattice strain, surface and interfacial free energies. When Ag is deposited on clean, single-crystal Cu(110), it initially wets the surface with a (111) monolayer, and spontaneously nucleates nanowires as the coverage is increased. The nanowires nucleate at defects and step edges and grow aligned along the [1–10] direction. …

Numerical Simulations Of Flow And Mass Transport In Micro-Fluidic Components For Modular Bio-Analytic Chip Applications, Sudheer D. Rani

LSU Doctoral Dissertations

Microfluidics has received a great deal of attention in the past decade. The ability of modular microfluidic chips to miniaturize integrate chemical and biological systems (µTAS) can be greatly productive in terms of cost and efficiency. During the design of these modular devices, misalignment of materials, geometrical or both is one of the most common problems. These misalignments can have adverse effect in both pressure driven and electrokinetically driven flows. In the present work, Numerical Simulations have been performed to study the effect of material and geometrical mismatch on the flow behavior and species progression in microfluidic interconnects. In the …

Cluster Kinetics Modeling Of Glassforming Materials, Lisa Ann Brenskelle

LSU Doctoral Dissertations

In this work, a new model relating temperature and pressure to dielectric relaxation or viscosity of a glassformer is developed. The model is based upon cluster kinetics, reaction-like mechanisms describing interactions between glassformer monomers and their clusters. Mathematical solutions of population balance equations for monomer and cluster lead to molar concentrations in terms of rate coefficients of the reaction-like mechanisms. These are then related to viscosity or dielectric relaxation time through free volume theory. The resulting equations are tested against data for a variety of pure glassformers, fragile, non-fragile, large, and small molecules over a wide range of temperatures, pressures, …

Dynamic Shear Bands In Metals Under High Strain Rates, Amin Hisham Almasri

LSU Doctoral Dissertations

Adiabatic shear bands have been observed for a long time to occur under different conditions in many applications. Analysis of these localizations highly depends on the selection of the constitutive model. Hence, two constitutive models that take temperature and strain rate effect into account are proposed. The first model is a physically based model that depends on basic physical quantities, such as dislocation densities, Burgers vector, and activation energy. The second model is a simple empirical power model with a softening term. The empirical constitutive law is seen to be more successful in capturing the mechanical behavior of steel alloy …

Synthesis And Surface Characterization Of Silica-Polypeptide Composite Particles, Erick Isael Soto-Cantu

LSU Doctoral Dissertations

The synthesis and sequential surface characterization of silica-polypeptide composite particles is described. Nearly monodisperse colloidal silica cores were obtained by the alkaline hydrolysis of tetraethyl orthosilicate (TEOS). The hydrodynamic radius can be easily controlled in the range of ƒî 20-140 nm by the water/TEOS ratio in the starting reaction mixture. The surface of the synthesized silica cores was further passivated/functionalized (P/F) by a mixture of (3-aminopropyl) trimethoxysilane (APS) and methyl-trimethoxysilane (MTMS). The amino groups were quantified using UV-Vis spectrometry after reaction with ninhydrin. The use of zeta potential measurements of the P/F silica particles at low pH is presented as …

Fast Marching Methods - Parallel Implementation And Analysis, Maria Cristina Tugurlan

LSU Doctoral Dissertations

Fast Marching represents a very efficient technique for solving front propagation problems, which can be formulated as partial differential equations with Dirichlet boundary conditions, called Eikonal equation: $F(x)|\nabla T(x)|=1$, for $x \in \Omega$ and $T(x)=0$ for $x \in \Gamma$, where $\Omega$ is a domain in $\mathbb{R}^n$, $\Gamma$ is the initial position of a curve evolving with normal velocity F>0. Fast Marching Methods are a necessary step in Level Set Methods, which are widely used today in scientific computing. The classical Fast Marching Methods, based on finite differences, are typically sequential. Parallelizing Fast Marching Methods is a step forward for …

Incorporation Of Cα,Α-Disubstituted Amino Acids Into Model Peptide Systems: Conformational Analysis And Possible Applications As Therapeutic Agents, Marcus A. Etienne

LSU Doctoral Dissertations

A diverse set of human diseases is associated with the misfolding of proteins into insoluble fibrillar structures that have predominantly β-sheet secondary structure. Thus it is imperative to elucidate the structural elements that contribute to β-sheet formation and stability. Peptides that autonomously form β-sheets are ideal models to study principles of protein folding and design. Gellman and coworkers first introduced an automonously folded β-hairpin (H-Arg-Tyr-Val-Glu-Val-Yyy-Xxx-Orn-Lys-Ile-Leu-Gln-NH2) that remained monomeric up to ~1 mM. Circular dichroism (CD) and nuclear magnetic resonance (NMR) analyses revealed that incorporation of non-stereogenic Aib-Xxx dipeptidyl sequences into i+1 and i+2 positions of a model peptide nucleates a …

Landscape Analysis Of Vegetation Change In Coastal Louisiana Following Hurricanes Katrina And Rita, Gregory Dean Steyer

LSU Doctoral Dissertations

Investigations of hurricane disturbances on coastal vegetated communities are common, but relatively few are comprehensive across broad geographic regions. The 2005 hurricanes, Katrina and Rita, exposed Louisiana coastal landscapes to physical modifications and extensive and prolonged flooding, resulting in measurable physicochemical changes. This research used remote sensing and field investigations to regionally assess (1) porewater salinity and sulfide impacts to and recovery of coastal Louisiana vegetation communities, and (2) the importance of mineral sediment deposition on accretionary processes. Hurricane effects were most direct and prominent in eastern Louisiana from Katrina and western Louisiana from Rita, compared to central Louisiana exposed …

The Investigation Of Treatment Outcomes For Adults With Chronic Brain Injury Following Intensive Multidisciplinary Treatment, Donna Mineo Fitzgerald-Dejean

LSU Doctoral Dissertations

Although communication sciences and disorders (COMD) research supports intensive treatment for individuals with chronic brain injury, funding to provide these services is limited. This study explored the use of interdepartmental university resources to provide an intensive, multidisciplinary chronic brain injury program. Methodologically, treatment regimes were designed with clinical faculty as practicum experiences for COMD master’s degree students. Subjects with a single onset head injury or cerebral vascular accident greater than one year were recruited to participate in the Intensive Treatment, Weekly Treatment or Control Groups. Pre, Post, and Post-Post Testing were used to measure cognitive-linguistic, quality of life and physical …

Phonemic Awareness And Sight Word Reading In Toddlers, Alicia Tonya Mcinnis

LSU Doctoral Dissertations

This study investigated emerging phonemic awareness skills and printed sight word recognition abilities in two-year-old toddlers using plain text and MorphoPhonic Face words on flash cards. MorphoPhonic Face words were used to determine if this learning process is enhanced when words are iconically represented to show the first sound and the word's meaning (purposefully creating idiosyncratic cues) using pictures superimposed into the letters. Sixteen (16) age-matched toddlers were assigned to alternate treatment groups and received exposure to both printed and MorphoPhonic pictured words three times weekly for six weeks. During each session, children were taught 16 sight words (8 in …

Rice Straw Fiber Polymer Composites: Thermal And Mechanical Performance, Fei Yao

LSU Doctoral Dissertations

Rice straw fiber can be considered as important potential reinforcing filler for thermoplastic composite because of its lignocellulosic characteristics. It is thus of practical significance to understand and predict the thermal decomposition process of rice straw fibers. A method proposed by Málek, Šesták, and co-workers was used to investigate and model thermal decomposition process of common natural fibers with detailed analysis on rice straw system. Assuming a global model occurring within the entire degradation of natural fibers with consideration of fiber as one pseudo-component, model can be used to describe both isothermal and non-isothermal degradation process of most selected fibers …

Functional Studies On The Extrinsic Proteins Of Photosystem Ii, Haijun Liu

LSU Doctoral Dissertations

The function of the PsbO and the PsbR protein in Arabidopsis thaliana were studied. The Arabidopsis mutant psbo1 contains a point mutation in the psbO-1 gene leading to defective expression of the PsbO-1 protein. Functional studies demonstrated both the reducing-side and oxidizing-side of Photosystem II are significantly altered. Using the psbo1 mutant plant as a transgenic host, two plant lines were produced, which contained an N-terminally His6-tagged PsbO-1 protein. Photosystem II closure kinetics demonstrated that the defective double reduction of QB and the delayed exchange of QBH2 with the plastoquinone pool in the psbo1 mutant were effectively restored to the …

Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry For The Analysis Of Collected Bioaerosols, Alton John Dugas

LSU Doctoral Dissertations

The goal of this dissertation was to demonstrate collection, detection and identification of microorganisms from bioaerosols using offline matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) for the analysis of proteins. MALDI-MS intact bacteria techniques were adapted for use with an orthogonal MALDI quadrupole-time-of-flight mass spectrometer. Results indicate the instrument is capable of analyzing intact whole-cells. The first phase was to evaluate three bioaerosol samplers, an Andersen N6 single-stage impactor (AI), a cyclone impactor, and a vacuum filter system. The samplers collected test bioaerosols using a constructed bioaerosol exposure chamber (BEC). The BEC allowed all three samplers to operate in parallel. Each …

Limit On The Muon Neutrino Magnetic Moment And A Measurement Of The Ccpip To Ccqe Cross Section Ratio, Serge Arisitde Ouedraogo

LSU Doctoral Dissertations

A search for the muon neutrino magnetic moment was conducted using the Mini- BooNE low energy neutrino data. The analysis was performed by analyzing the elastic scattering interactions of muon neutrinos on electrons. The analysis looked for an excess of elastic scattering events above the Standard Model prediction from which a limit on the neutrino magnetic could be set. In this thesis, we report an excess of 15.3}6.6(stat)}4.1(syst) elastic scattering events above the expected background. At 90% C.L., we derived a limit on the muon neutrino magnetic moment of 12.7~ 10−10ƒÊB. The other analysis reported in this thesis is a …

Heterogeneous Catalyzed Macromolecular Hydrogenations In Oscillating Systems, Alan Bussard

LSU Doctoral Dissertations

An examination of novel oscillatory (alternating gas and liquid phase) reactors and heterogeneous catalysts for multi-phase macromolecular reactions was carried out. A monolith-containing square die with Pd/Al2O3 catalysts was used to successfully hydrogenate poly(styrene) (PS). The inherent pulse behavior of the extruder was found to be sufficient to approach intrinsic kinetics at low polymer concentrations. At higher (10 wt% PS) concentrations, forced pulsing was shown to have a greater impact on observed reaction rates. Selectivity with this extruder-fed reactor was better than with a stirred tank in all cases, due to a more plug-flow-like residence time distribution. While accurate control …

Continuous Reservoir Model Updating By Ensemble Kalman Filter On Grid Computing Architectures, Xin Li

LSU Doctoral Dissertations

A reservoir engineering Grid computing toolkit, ResGrid and its extensions, were developed and applied to designed reservoir simulation studies and continuous reservoir model updating. The toolkit provides reservoir engineers with high performance computing capacity to complete their projects without requiring them to delve into Grid resource heterogeneity, security certification, or network protocols.

Continuous and real-time reservoir model updating is an important component of closed-loop model-based reservoir management. The method must rapidly and continuously update reservoir models by assimilating production data, so that the performance predictions and the associated uncertainty are up-to-date for optimization. The ensemble Kalman filter (EnKF), a Bayesian …

Bayesian Model Averaging On Hydraulic Conductivity Estimation And Groundwater Head Prediction, Xiaobao Li

LSU Doctoral Dissertations

Characterization of aquifer heterogeneity is inherently difficult because of the insufficiency of data, the inflexibility of parameterization methods, and non-uniqueness of parameterization methods. Groundwater predictions are greatly affected by multiple interpretations of aquifer properties and the uncertainties of model parameters. This study introduces a Bayesian model averaging (BMA) method along with multiple generalized parameterization (GP) methods to identify hydraulic conductivity and along with multiple simulation models to predict groundwater head and quantify the prediction uncertainty. Two major issues about BMA are discussed. The first problem is with using Occam’s window in usual BMA applications. Occam’s window only accepts models in …

Three Papers On The Behavior Modeling Of The Shrimp Fishermen In The Gulf Of Mexico, Tao Ran

LSU Doctoral Dissertations

The overall goal of this research is to empirically analyze shrimp fishermen behavior to help improve the management of the Gulf of Mexico shrimp fleet. Given that optimal management requires consideration of more than the net benefits derived from shrimp harvesting, this research also seeks to provide an empirical framework that would allow future investigators to measure benefits lost through bycatch-related management actions. This paper expands on previous fishing behavior literature by focusing on two of the most important short-run decisions confronting Gulf of Mexico shrimp fishermen (where to fish and how long to fish). A better understanding of these …

Adsorption And Photochemical Transformation Of Polycyclic Aromatic Hydrocarbons On Atmospheric Water Films, Jing Chen

LSU Doctoral Dissertations

Atmospheric water films affect the processing of chemicals in the atmosphere and have potential effects on human health and the environment. In this work, adsorption and photochemical transformations of gas-phase PAHs were studied in a flow-tube photo-reactor with a view to understanding the behavior of gas-phase PAHs occurring in thin water films such as those of aerosols and fog. Naphthalene and phenanthrene were chosen as model PAHs for this study. Bulk water-air and air-to-interface partition constants of naphthalene and phenanthrene were estimated from the experiments based on the dependence of the equilibrium uptake on the water film thickness. Theoretical computations …

A Novel Automated Approach Of Multi-Modality Retinal Image Registration And Fusion, Hua Cao

LSU Doctoral Dissertations

Biomedical image registration and fusion are usually scene dependent, and require intensive computational effort. A novel automated approach of feature-based control point detection and area-based registration and fusion of retinal images has been successfully designed and developed. The new algorithm, which is reliable and time-efficient, has an automatic adaptation from frame to frame with few tunable threshold parameters. The reference and the to-be-registered images are from two different modalities, i.e. angiogram grayscale images and fundus color images. The relative study of retinal images enhances the information on the fundus image by superimposing information contained in the angiogram image. Through the …

New Firm Emergence: The Significance Of Social Embeddedness And Resource Bootstrapping To The Process Of Nascent Firm Emergence, Warren Byabashaija

LSU Doctoral Dissertations

Firm founding is an evolutionary process. Part of this process involves undertaking a series of gestation activities. Start-ups undertaking these activities are referred to as firms in gestation and the process is termed nascent entrepreneurship. Empirical evidence shows that more than half of firms in gestation do not survive the first eighteen months. One of the reasons given for this high failure rate is that firms in gestation are subject to what Stinchcombe (1965) called liability of newness because, as new creations, they lack evaluative performance history. One of the consequences of this liability of newness is that new firms …

An Examination Of The Good Behavior Game And Behavior Specific Praise Statements On Student And Teacher Behavior, Robert Allen Wright

LSU Doctoral Dissertations

This study directly compares two interdependent group oriented contingency strategies, the GBG and the GBG with a behavior specific praise statement (BSPS) component (i.e., GBG+BSPS) to examine the relative effectiveness of each as a tool for class-wide behavior management, to inspect the effect on teacher interactions with students, and to assess the relative teacher and student acceptability of both games. The Good Behavior Game has been identified as an evidence-based intervention to manage class-wide behavior difficulties, but recently has been criticized for not being proactive in teaching appropriate classroom behavior. The relative effectiveness and acceptability of each game as a …

Performing Photographs: Memory, History, And Display, Melanie A. Kitchens

LSU Doctoral Dissertations

In my study, I place concepts and practices of photography and performance in dialogue to enable our understanding of how photographs perform and how performance contains or can contain elements we attribute to photographs. The connection between photography and performance that most intrigues me is how they make memories and when collected or restored in some socially shared way make histories too. My specific aim is to understand how photographs and performance might benefit from each other in how they make and transmit memories and histories. To activate the study, I select and focus on five specific events in which …