Digital Commons Network^™

Matrix Decomposition For Data Disclosure Control And Data Mining Applications, Jie Wang

University of Kentucky Doctoral Dissertations

Access to huge amounts of various data with private information brings out a dual demand for preservation of data privacy and correctness of knowledge discovery, which are two apparently contradictory tasks. Low-rank approximations generated by matrix decompositions are a fundamental element in this dissertation for the privacy preserving data mining (PPDM) applications. Two categories of PPDM are studied: data value hiding (DVH) and data pattern hiding (DPH). A matrix-decomposition-based framework is designed to incorporate matrix decomposition techniques into data preprocessing to distort original data sets. With respect to the challenge in the DVH, how to protect sensitive/confidential attribute values without …

Carbon Nanotube Supported Metal Catalysts For NoX Reduction Using Hydrocarbon Reductants, Eduardo Santillan-Jimenez

University of Kentucky Doctoral Dissertations

Nitrogen oxides (NO_x) are atmospheric pollutants that pose a serious threat to both the environment and human health. Although catalytic deNO_x technologies for engines working under stoichiometric air-to-fuel ratios (i.e., most gasoline engines) are already available, their performance is unsatisfactory under excess air conditions like those under which diesel engines operate.

The selective catalytic reduction of NO_x with hydrocarbon reductants (HC-SCR) is a potential deNO_xsolution for diesel engines, whose operating temperatures are 150-500 ºC. Given that is unlikely for a single catalyst to show acceptable activity throughout this entire temperature span, the use of …

The Influence Of Ca2+ Regulation In Synaptic Facilitation Of Motor Nerve Terminals In Crayfish And Drosophila As Well As In The Physiological Regulation Of Larval Drosophila Heart, Mohati Desai-Shah

University of Kentucky Doctoral Dissertations

Intracellular Ca²⁺ ions are highly regulated in animal cells for them to function normally. Since the tight regulation of [Ca²⁺]i is so ubiquitous among cells, it is not surprising that altered function in [Ca²⁺]i regulation is associated with a myriad of disease states in humans. This is particularly evident in pacing myocytes and nerve terminals related to synaptic transmission. A common thread through this dissertation is on the role of three regulators proteins that are common to many cell types. These are the plasmalemmal Na⁺/Ca²⁺ exchanger (NCX), the Ca²⁺-ATPase (PMCA) …

Pre-Testing As A Method Of Conveying Learning Objectives, Wendy S. Beckman

Journal of Aviation/Aerospace Education & Research

Teaching methodologies involving student pre-testing have been used in K-12 education for a number of years. Although pre-testing has been conducted in some collegiate classrooms, there have been very few studies published regarding the effectiveness of the concept. This paper reports the results of a study in which one Introduction to Aerospace class was given a pre-test at the start of each unit of study, while a second class received a list of specific learning objectives at the start of each unit. The post-test unit test results of the two classes were then compared. The results of the study indicate …

Partnering With Faculty Through Liaison Activities, Linda Lambert, Tami Echevarria Robinson, Bob Triplett

The Christian Librarian

Anything worthwhile requires time and effort. Such is the case in building effective working relationships between librarians and teaching faculty. This article discusses collaborating and partnering with teaching faculty through library liaison relationships and shares experiences of the authors partnering with faculty at their institutions. This article is an outgrowth of a panel presentation at the 2007 ACL Conference by liaison librarians representing libraries in the Southeast, the Midwest, and the Pacific Northwest. While partnering with faculty is both challenging and time consuming, it can be one of the most gratifying and productive activities in which librarians can be engaged.

Psr J1856+0245: Arecibo Discovery Of A Young Energetic Pulsar Coincident With The Tev G-Ray Source Hess J1857+026, J. W.T. Hessels, D. J. Nice, B. M. Gaensler, V. M. Kaspi, D. R. Lorimer, D. J. Champion, A. G. Lyne, M. Kramer, J. M. Cordes, P. C.C. Freire, Fredrick A. Jenet

Physics & Astronomy Faculty Publications

We present the discovery of the Vela-like radio pulsar J1856+0245 in the Arecibo PALFA survey. PSR J1856+0245 has a spin period of 81 ms, a characteristic age of 21 kyr, and a spin-down luminosity Ä– p 4.6 x 10 36 ergs s-1. It is positionally coincident with the TeV γ-ray source HESS J1857+026, which has no other known counterparts. Young, energetic pulsars create wind nebulae, and more than a dozen pulsar wind nebulae have been associated with very high energy (100 GeV-100 TeV) γ-ray sources discovered with the HESS telescope. The γ-ray emission seen from HESS J1857+026 is potentially produced …

Beating The Spin-Down Limit On Gravitational Wave Emission From The Crab Pulsar, B. P. Abbott, R. Abbott, R. Adhikari, Mario C. Diaz, Roberto Grosso, Kazuhiro Hayama, Soumya Mohanty, Soma Mukherjee, Joseph D. Romano, Robert Stone

Physics & Astronomy Faculty Publications

We present direct upper limits on gravitational wave emission from the Crab pulsar using data from the first 9 months of the fifth science run of the Laser Interferometer Gravitational-wave Observatory (LIGO). These limits are based on two searches. In the first we assume that the gravitational wave emission follows the observed radio timing, giving an upper limit on gravitational wave emission that beats indirect limits inferred from the spin-down and braking index of the pulsar and the energetics of the nebula. In the second we allow for a small mismatch between the gravitational and radio signal frequencies and interpret …

Denaturation Transition Of Stretched Dna, Andreas Hanke, Martha G. Ochoa, Ralf Metzler

Physics & Astronomy Faculty Publications

We generalize the Poland-Scheraga model to consider DNA denaturation in the presence of an external stretching force. We demonstrate the existence of a force-induced DNA denaturation transition and obtain the temperature-force phase diagram. The transition is determined by the loop exponent c, for which we find the new value c=4ν−1/2 such that the transition is second order with c=1.85DNA, corresponding to a lower melting temperature T(F), in agreement with single-molecule DNA stretching experiments.

Search Of S3 Ligo Data For Gravitational Wave Signals From Spinning Black Hole And Neutron Star Binary Inspirals, B. P. Abbott, R. Grosso, Mario C. Diaz, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres

Physics & Astronomy Faculty Publications

We report on the methods and results of the first dedicated search for gravitational waves emitted during the inspiral of compact binaries with spinning component bodies. We analyze 788 hours of data collected during the third science run (S3) of the LIGO detectors. We searched for binary systems using a detection template family specially designed to capture the effects of the spin-induced precession of the orbital plane. We present details of the techniques developed to enable this search for spin-modulated gravitational waves, highlighting the differences between this and other recent searches for binaries with nonspinning components. The template bank we …

Search For Gravitational Waves From Binary Inspirals In S3 And S4 Ligo Data, B. P. Abbott, R. Abbott, Mario C. Diaz, R. Grosso, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres

Physics & Astronomy Faculty Publications

We report on a search for gravitational waves from the coalescence of compact binaries during the third and fourth LIGO science runs. The search focused on gravitational waves generated during the inspiral phase of the binary evolution. In our analysis, we considered three categories of compact binary systems, ordered by mass: (i) primordial black hole binaries with masses in the range 0.35M⊙

Search For Gravitational Waves Associated With 39 Gamma-Ray Bursts Using Data From The Second, Third, And Fourth Ligo Runs, B. P. Abbott, R. Abbott, Mario C. Diaz, R. Grosso, Wm. R. Johnston, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres

Physics & Astronomy Faculty Publications

We present the results of a search for short-duration gravitational-wave bursts associated with 39 gamma-ray bursts (GRBs) detected by gamma-ray satellite experiments during LIGO’s S2, S3, and S4 science runs. The search involves calculating the crosscorrelation between two interferometer data streams surrounding the GRB trigger time. We search for associated gravitational radiation from single GRBs, and also apply statistical tests to search for a gravitational-wave signature associated with the whole sample. For the sample examined, we find no evidence for the association of gravitational radiation with GRBs, either on a single-GRB basis or on a statistical basis. Simulating gravitational-wave bursts …

All-Sky Search For Periodic Gravitational Waves In Ligo S4 Data, B. P. Abbott, R. Abbott, Mario C. Diaz, R. Grosso, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres

Physics & Astronomy Faculty Publications

We report on an all-sky search with the LIGO detectors for periodic gravitational waves in the frequency range 50–1000 Hz and with the frequency’s time derivative in the range −1×10−8  Hz s−1 to zero. Data from the fourth LIGO science run (S4) have been used in this search. Three different semicoherent methods of transforming and summing strain power from short Fourier transforms (SFTs) of the calibrated data have been used. The first, known as StackSlide, averages normalized power from each SFT. A “weighted Hough” scheme is also developed and used, which also allows for a multi-interferometer search. The third method, …

Data Assimilation And Visualization For Ensemble Wildland Fire Models, Soham Chakraborty

University of Kentucky Master's Theses

This thesis describes an observation function for a dynamic data driven application system designed to produce short range forecasts of the behavior of a wildland fire. The thesis presents an overview of the atmosphere-fire model, which models the complex interactions between the fire and the surrounding weather and the data assimilation module which is responsible for assimilating sensor information into the model. Observation plays an important role in data assimilation as it is used to estimate the model variables at the sensor locations. Also described is the implementation of a portable and user friendly visualization tool which displays the locations …

Integrated Geophysical Imaging Of Subsurface Geologic Conditions Across A Contaminant Plume, Mccracken County, Kentucky, Cora A. Blits

University of Kentucky Master's Theses

Over 7.8 km of seismic reflection data and 2 km of electrical resistivity data were acquired, processed, and interpreted during this multi-method geophysical study. Objectives included the definition of geologic conditions underlying a contaminant plume in McCracken County, western Kentucky, and the determination of the potential for structural control on the rate and direction of plume migration. Both geophysical methods indicate the presence of multiple high-angle normal faults outlining a series of asymmetric grabens ranging in width from 160 m to almost 300 m and striking between N40°E and N45°E. There was agreement between the two methods on fault location …

Tunneling Phase Gate For Neutral Atoms In A Double-Well Lattice, Frederick W. Strauch, Mark Edwards, Eite Tiesinga, Carl Williams, Charles W. Clark

Physics & Astronomy: Faculty Publications

We propose a two-qubit phase gate for ultracold atoms in a tilted double-well optical lattice. Such a lattice is capable of confining pairs of atoms in a two-dimensional array of double-well potentials where both the barrier height and the energy difference of the minima of the two wells (known as the “tilt”) can be controlled. The four lowest single-particle motional states can be used to form spatially separated qubits. We present a time-dependent scheme to manipulate the tilt to induce tunneling oscillations which produce a collisional phase gate. Numerical simulations demonstrate that this gate can be performed with high fidelity.

We Are All Entrepreneurs Now, David E. Pozen

Faculty Scholarship

A funny thing happened to the entrepreneur in legal, business, and social science scholarship. She strayed from her capitalist roots, took on more and more functions that have little to do with starting or running a business, and became wildly popular in the process. Nowadays, "social entrepreneurs" tackle civic problems through innovative methods, "policy entrepreneurs" promote new forms of government action, "norm entrepreneurs" seek to change the way society thinks or behaves, and "moral entrepreneurs" try to alter the boundaries of duty or compassion. "Ethnification entrepreneurs," "polarization entrepreneurs," and other newfangled spinoffs pursue more discrete objectives. Entrepreneurial rhetoric has never …

Overseers Or "The Deciders" – The Courts In Administrative Law, Peter L. Strauss

Faculty Scholarship

For the second time in a short period, Professors Miles and Sunstein have brought powerful tools of statistical analysis and diligent coding of circuit court of appeals opinions together to demonstrate what the Realists long ago taught us to suspect, that significant elements of judging can be explained in terms of the jurist's political world view – that the tension between law and politics is alive in judicial work as elsewhere and that it is only an aspiration to seek a world of laws and not of men. Elements of their work, though, appear as if in criticism of contemporary …

Chiral Recognition Of Amino Acids By Use Of A Fluorescent Resorcinarene, Gerald I. Richard, Hadi M. Marwani, Shan Jiang, Sayo O. Fakayode, Mark Lowry, Robert M. Strongin, Isiah M. Warner

Chemistry Faculty Publications and Presentations

The spectroscopic properties of a chiral boronic acid based resorcinarene macrocycle employed for chiral analysis were investigated. Specifically, the emission and excitation characteristics of tetraarylboronate resorcinarene macrocycle (TBRM) and its quantum yield were evaluated. The chiral selector TBRM was investigated as a chiral reagent for the enantiomeric discrimination of amino acids using steady-state fluorescence spectroscopy. Chiral recognition of amino acids in the presence of the macrocycle was based on diastereomeric complexes. Results demonstrated that TBRM had better chiral discrimination ability for lysine as compared to the other amino acids. Partial least squares regression modeling (PLS-1) of spectral data for macrocycle-lysine …

Light Vector Mesons In The Nuclear Medium, M. H. Wood, M. J. Amaryan, H. Bagdasaryan, S. L. Careccia, K. V. Dharmawardane, G. E. Dodge, G. Gavalian, N. Guler, C. E. Hyde-Wright, H. G. Juengst, N. Kalantarians, A. Klein, K. V. Klimenko, S. E. Kuhn, J. Lachniet, M. R. Niroula, R. A. Niyazov, S. Tkachenko, L. B. Weinstein, J. Zhang, Clas Collaboration

Physics Faculty Publications

The light vector mesons (ρ,ω, and ϕ) were produced in deuterium, carbon, titanium, and iron targets in a search for possible in-medium modifications to the properties of the ρ meson at normal nuclear densities and zero temperature. The vector mesons were detected with the CEBAF Large Acceptance Spectrometer (CLAS) via their decays to e+e−. The rare leptonic decay was chosen to reduce final-state interactions. A combinatorial background was subtracted from the invariant mass spectra using a well-established event-mixing technique. The ρ-meson mass spectrum was extracted after the ω and ϕ signals were removed in a nearly model-independent way. Comparisons …

First Measurement Of Target And Double Spin Asymmetries For Ep → Epπ° In The Nucleon Resonance Region Above The Δ (1232), Clas Collaborative, M. J. Amaryan, H. Bagdasaryan, S. Bültmann, G. E. Dodge, N. Guler, N. Kalantarians, A. Klein, S. E. Kuhn, S. Tkachenko, L. B. Weinstein, J. Zhang

Physics Faculty Publications

The exclusive channel polarized proton(polarized e,e' p)π⁰ was studied in the first and second nucleon resonance regions in the Q² range from 0.187 to 0.770 GeV² at Jefferson Lab using the CEBAF Large Acceptance Spectrometer (CLAS). Longitudinal target and beam-target asymmetries were extracted over a large range of center-of-mass angles of the π⁰ and compared to the unitary isobar model MAID, the dynamic model by Sato and Lee, and the dynamic model DMT. A strong sensitivity to individual models was observed, in particular for the target asymmetry and in the higher invariant mass region. This data …

Experimental Study Of Isovector Spin Sum Rules, A. Deur, P. Bosted, V. Burkert, D. Crabb, V. Dharmawardane, G. E. Dodge, T. A. Forest, K. A. Griffioen, S. E. Kuhn, R. Minehart, Y. Prok

Physics Faculty Publications

We present the Bjorken integral extracted from Jefferson Lab experiment EG1b for 0.05< Q² 2. The integral is fit to extract the twist-4 element f ^p−n₂ which appears to be relatively large and negative. Systematic studies of this higher twist analysis establish its legitimacy at Q² around 1  GeV². We also performed an isospin decomposition of the generalized forward spin polarizability γ₀. Although its isovector part provides a reliable test of the calculation techniques of chiral perturbation theory, our data disagree with the calculations.

Nlo Evolution Of Color Dipole, Ian Balitsky, Giovanni A. Chirilli

Physics Faculty Publications

No abstract provided.

Ratios Of 15N/12C And 4He/12C Inclusive Electroproduction Cross Sections In The Nucleon Resonance Region, P. E. Bosted, R. Fersch, G. Adams, M. Amaryan, S. Anefalos, M. Anghinolfi, G. Asryan, H. Avakian, H. Badasaryan, N. Baillie, M. Bektasoglu, S. Bültmann, S. L. Careccia, G. E. Dodge, K. V. Dharmawardane, T. A. Forest, G. Gavalian, N. Guler, C. E. Hyde-Wright, N. Kalantarians, A. Klein, S. E. Kuhn, J. Lachniet, R. A. Niyazov, L. M. Qin, F. Sabatié, S. Tkachenko, L. B. Weinstein, J. Zhang, Clas Collaboration

Physics Faculty Publications

The (W,Q²) dependence of the ratio of inclusive electron scattering cross sections for ¹⁵N/¹²C was determined in the kinematic ranges 0.8 < W < 2 GeV and 0.2 < Q² < 1 GeV² using 2.285 GeV electrons and the CLAS detector at Jefferson Lab. The ratios exhibit only slight resonance structure, in agreement with a simple phenomenological model and an extrapolation of deep-inelastic scattering ratios to low Q². Ratios of ⁴He/¹²C using 1.6 to 2.5 GeV electrons were measured with very high statistical precision and were used to correct for He in the N and C targets. …

Cleaning Up Lake River, Victor P. Goldberg

Faculty Scholarship

A casebook favorite for exploring the liquid dated damage/penalty clause distinction is Lake River Corp. v. Carborundum Co. in which Judge Posner found a minimum quantity clause to be an unenforceable penalty clause. In this paper I argue that the case was framed improperly. Had the litigators recognized that the contract afforded one party an option, the result should have been different. The contract was for the provision of a service – setting aside capacity – which was valuable to the buyer and costly for the seller to provide. The primary purpose of the minimum quantity clause was the pricing …

Uncertainty Analysis And Sensitivity Analysis For Multidisciplinary Systems Design, Jia Guo

Doctoral Dissertations

"The objective of this research is to quantify the impact of both aleatory and epistemic uncertainties on performances of multidisciplinary systems. Aleatory uncertainty comes from the inherent uncertain nature and epistemic uncertainty comes from the lack of knowledge. Although intensive research has been conducted on aleatory uncertainty, few studies on epistemic uncertainty have been reported. In this work, the two types of uncertainty are analyzed. Aleatory uncertainty is modeled by probability distributions while epistemic uncertainty is modeled by intervals. Probabilistic analysis (PA) and interval analysis (IA) are integrated to capture the effect of the two types of uncertainty. The First …

Integrated Process Planning For A Hybrid Manufacturing System, Lan Ren

Doctoral Dissertations

"A hybrid manufacturing system integrated CNC machining and laser-aided layered deposition and achieves the benefits of both processes. In this dissertation, an integrated process planning framework which aims to automate the hybrid manufacturing process is investigated. Critical components of the process planning, including 3D spatial decomposition of the CAD model, improvement of the toolpath generation pattern, repairing strategies using a hybrid manufacturing system, etc., are discussed"--Abstract, page iv.

Behaviour Of Salicylaldehyde And Some Of Its Derivatives In The Biginelli Reaction For The Preparation Of Aryl Tetrahydropyrimidines, Eman M. H. Abbas, Shadia M. Abdallah, Mervat H. Abdoh, Hanaa A. Tawfik, Wageeh S. El-Hamouly

Turkish Journal of Chemistry

Salicylaldehyde and some of its derivatives react with urea (or thiourea) and ethyl acetoacetate (the Biginelli reaction) to give products that depend on the type of the substituent in the ortho-position to the hydroxyl group. Aldehydes having oxygen-bearing substituents ortho to the hydroxyl group (e.g., OCH_3, NO_2, COOH) undergo chelation with the hydroxyl proton and lead to 4-aryl-6-methyl-4-aryl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-ethyl carboxylate (the classical Biginelli product). Compounds not having such a property give oxacyclic products formed by addition of the hydroxyl proton to the C5-C6 double bond of the pyrimidine ring. This study also includes compounds having an amino group instead of the …

Synthesis And Characterization Of 4-(Alkylaminoisonitrosoacetyl)Diphenyl Ether And Some Of Their Metal Complexes, Ahmet Coşkun, Funda Yilmaz

Turkish Journal of Chemistry

4-(Chloroacetyl)diphenyl ether (I) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl_3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (II) derivative was prepared. Then 3 new substituted 4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from 4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for the ligands ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl) pyridine. Mononuclear or binuclear Co(II), Ni(II), Cu(II), and Cd(II) complexes of the ligands were synthesized. The structures of these ligands were identified by FT-IR, ^1H-NMR, and ^{13}C-NMR spectral data and elemental analysis, and the structures of the complexes were …

Cyanoacetamide Derivatives As Synthons In Heterocyclic Synthesis, Ahmed Ali Fadda, Samir Bondock, Ramy Rabie, Hassan Ali Etman

Turkish Journal of Chemistry

This review presents a systematic and comprehensive survey of the methods of preparation and the chemical reactivity of cyanoacetamide derivatives. These compounds are important intermediates for the synthesis of a variety of otherwise difficult to obtain synthetically useful and novel heterocyclic systems.

Microcontact Printing Of An Alkylsilane Monolayer On The Surface Of Glass, Gülşi̇n Arslan, Mustafa Özmen, İmren Hatay, İlkay Hi̇lal Gübbük, Mustafa Ersöz

Turkish Journal of Chemistry

This paper describes the use of microcontact printing (\mu CP) for patterning of self-assembled monolayers (SAMs) of (3-aminopropyl)-triethoxysilane (APTES) and octadecyltrichloro silane (OTS) on the surface of glass and functionalization of alkylsilane monolayers. After activation of the glass surface, which was patterned with OTS using a poly(dimethylsiloxane) (PDMS) stamp, the remaining bars of the surfaces were treated with APTES and then treated with a dye solution. The characterization of printed silane compounds was confirmed using fluorescence microscopy on the basis of the reaction between terminal amine groups of APTES and thionylchloride of Rhodamine-B dye. Quantitative 3-dimensional profiling was performed for …