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Dynamics Of Carbon Allocation In A Deep-Water Population Of The Deciduous Kelp Pleurophycus Gardeneri (Laminariales), Clare M. Dominik, Richard C. Zimmerman

OES Faculty Publications

Pleurophycus gardneri (Laminariales) is common in the low intertidal of the Northeast Pacific, but dominates many deep (30 to 40 m) rocky reefs in central California. Seasonal dynamics of productivity and resource allocation of a deep-water population of this deciduous, stipitate kelp were studied to understand how blade abscission affects the annual carbon budget. Patterns of growth, metabolism, and carbon storage and mobilization were measured monthly for 1 yr relative to in situ light and temperature, and used to model the annual carbon budget. The resulting carbon budget was used to determine if blade abscission effectively reduced respiratory demand during …

Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron

OES Faculty Publications

Total dissolvable iron (TDFe) was measured in sections of ice cores recovered from Law Dome on the coast of Wilkes Land, East Antarctica. These samples include ice dating from the Last Glacial Maximum (LGM), the Last Deglaciation, and the early and mid Holocene as well as samples from the Anthropocene that have been dated with seasonal to annual resolution. Combining our TDFe concentration data with estimates of the ice accumulation rate, we estimate the atmospheric iron deposition for Law Dome and the adjacent Southern Ocean during these periods. Our results indicate that the atmospheric iron deposition flux to this region …

Red And Black Tides: Quantitative Analysis Of Water-Leaving Radiance And Perceived Color For Phytoplankton, Colored Dissolved Organic Matter, And Suspended Sediments, Heidi M. Dierssen, Raphael M. Kudela, John P. Ryan, Richard C. Zimmerman

OES Faculty Publications

Using field measurements and quantitative modeling, we demonstrate that red coloration of the sea surface is not associated with any particular group of phytoplankton and is strongly dependent on the physiology of the human visual system. Red or brown surface waters can be produced by high concentrations of most types of algae, colored dissolved organic matter, or suspended sediment. Even though light reflected by red tides commonly peaks in the yellow spectral region (570–580 nm), human color perception requires consideration of the entire spectrum of light relative to receptors within the human eye. The color shift from green to red …

The Role Of Lipids During Embryonic Development Of The Euphausiids Euphausia Pacifica And Thysanoessa Spinifera, Se-Jong Ju, H. Rodger Harvey, Jaime Gómez-Gutiérrez, William T. Peterson

OES Faculty Publications

To understand the role of lipids during early embryogenesis, major lipid classes together with individual fatty acid and sterol composition were determined in embryos from multiple developmental stages of the euphausiids Euphausia pacifica and Thysanoessa spinifera. Average lipid content in embryos of E. pacifica and T. spiniferafrom the earliest stage (multicell) were 4.45 and 3.69 µg embryo^-1,respectively. During development, the lipid content decreased at similar rates in the embryos of both species. In contrast to many crustacean eggs, phospholipids were the dominant lipid class in all embryonic stages, with decreasing concentrations seen during development. Individual …

Nitrogen Fixation And Release Of Fixed Nitrogen By Trichodesmium Spp. In The Gulf Of Mexico, Margaret R. Mulholland, Peter W. Bernhardt, Cynthia A. Heil, Deborah A. Bronk, Judith M. O'Neil

OES Faculty Publications

During a 3-yr study in the Gulf of Mexico, we measured dinitrogen (N₂) fixation and nitrogen (N) release by Trichodesmium and compared these rates with water column N demand and the estimated N necessary to support blooms of Karenia brevis, a toxic dinoflagellate that severely affects the West Florida shelf. Net and gross N₂ fixation rates were compared in simultaneous incubations using ¹⁵N₂ uptake and acetylene reduction, respectively. The difference between net and gross N₂ fixation is assumed to be an approximation of the rate of N release. Results demonstrate that Trichodesmium in …

Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero

OES Faculty Publications

[1] Mg/Ca ratios in the planktonic foraminifera Globigerinoides ruber from Colombian Basin core ODP 999A suggest that Caribbean sea surface temperatures ( SSTs) were from 2.1 to 2.7°C colder than the present during the last three glacial maximums. In comparison, faunal derived SSTs ( SIMMAX method) show that August SSTs in the Caribbean varied < 2° over the past 360 kyr, whereas February SSTs varied between 21.0°C and 26.5°C. Changes in the Mg/Ca-SST record contain a strong 23 kyr periodicity, suggesting the Mg/Ca-SST record reflects a warm season weighted SST average rather than an annual mean SST. Combining several dissolution indices, we identify brief periods of decreased carbonate preservation in our record and show that MIS 11 stands out as the most intensive dissolution cycle in the Caribbean over the last 460 kyr. Comparison of Caribbean SST change with a similar estimate of tropical SST variability in the western Pacific over the past 360 kyr reveals shifts in the east-west tropical SST gradient that are coeval with glacial-interglacial climate change and consistent both with a southward migration of the glacial ITCZ and with a glacial El Niño-like mode of tropical circulation.

Past Glacial And Interglacial Conditions In The Arctic Ocean And Marginal Seas - A Review, Dennis A. Darby, Leonid Polyak, Henning A. Bauch

OES Faculty Publications

Past changes in the Arctic Ocean and its marginal seas have been profound, even during the last 10,000 years. Understanding these changes, such as those occurring during the transition from glacial to interglacial climates, are important for research on modern processes, because this knowledge provides a framework and unique perspective in which to view the modern physical and biological processes. This paper discusses our current understanding of past environmental change and processes relative to those currently in progress. Special emphasis is placed on the most recent transition from a glacial state to the modern interglacial conditions.

Quantifying Impacts Of White-Tailed Deer On Woodland Plant Communities, Brent E. Wachholder

Masters Theses

High population densities of white-tailed deer are changing woodland plant communities in the eastern United States. Deer populations subjectively characterized as overabundant are widely perceived as a threat to forest succession and conservation of rare plant species. I conducted a survey of 11 deer exclosures located at 7 sites through the state of Illinois in order to 1) determine the broad effects of deer at various densities on community attributes and 2) attempt to quantify the population density at which deer are overabundant, i.e., have negative effects on a) community attributes such as richness and diversity and b) survival of …

The Response Of Macroinvertebrate Communities To Habitat Fragmentation, Ross W. Widinski

Masters Theses

Aquatic fragmentation may be characterized as a lack of connectivity between upstream and downstream populations or sites (Page et al. 1997). Fragmentation in stream ecosystems occurs when changes in the surrounding landscape (loss/modification of riparian zone vegetation) render the in-stream habitats unsuitable for aquatic organisms. Additionally, Page et al. (1997) suggest that organisms also can be impacted or fragmented by in-stream modifications (dams, bridges) that further eliminate usable aquatic habitat and prevent movement through the aquatic system.

Intact riparian zones are of utmost importance in maintaining a healthy aquatic environment. Riparian zones with abundant vegetative cover serve to shade the …

Spectroscopic Investigation Of Metal-Substitution Of Cytochrome C, Deepthi Kandi

Masters Theses

We study, by absorbance spectroscopy, the incorporation of various metal ions (Cu²+ and Zn2*) into metal-free porphyrin cytochrome c (H₂cyt) as well as the various conformational forms of metal-substituted cytochromes. The H2cyt and desired metalsubstituted cytochromes have significantly different absorption spectra, providing a simple means of monitoring the incorporation of Cu²* or Zn2* into the empty porphyrin prosthetic group. The rates of metal-ion incorporation were studied under protein denaturating conditions using chemical denaturants, like urea and guanidine hydrochloride (GuHCI), and temperature that partially and completely unfold H2cyt, facilitating the incorporation of a metal ion. Moreover, the structural stability of copper …

The Study Of Carbon Acylation Of Highly Delocalized Enolates Using Catalytic Dmap On 3-Phenyl Benzofuranone Derivatives, Xiguang Zhao

Masters Theses

Benzofuranones along with their derivatives compose a diverse array of natural products and drugs, and show a wide variety of biological effects. Several synthetic methods have been published that describe the preparation of 2-(3H)-benzofuranones having mono alkyl or aryl substituents attached to the fused furanone ring with moderate to high yields. To date, reports describing the preparation of disubstituted 2-(3H)-benzofuranones, especially with one acyl group, are rare. Early approaches are limited by low yields, economical expenditure and environmental risk.

Direct acylation of benzofuranones consistently provides O-acylated isomers rather than C-acylated isomers, which are desired products in the great majority of …

Components Of Academic Motivation: A Multidimensional Overview Of Millennial Female Students At Eastern Illinois University, Karen Huseman

Masters Theses

The purpose of the present study was to examine the components of academic motivation among millennial female college students. More specifically, the purpose was to assess multiple factors that contribute to academic motivation among African American and European American millennial college women. The participants for the present study were selected from the female population at a mid-sized state-supported institution located in the Midwest.

Results from the study include that both intrinsic and extrinsic rewards helped to jump-start academic motivation. The role of family support was highly valued in the women's desire to achieve and personal self-confidence and support from others …

Student Perceptions Of Intrusive And Non-Intrusive Advising Approaches, Josephine Robinson

Masters Theses

The primary purpose of the present study was to assess students' perceptions of intrusive advisement approaches used by Gateway Program staff at Eastern Illinois University in comparison to non-intrusive advisement approaches utilized by faculty advisors in academic departments. To date, no research has been conducted in this area at this institution. A secondary purpose of the present study was to ascertain the perceptions of students regarding their student/advisor relationships and the knowledge levels of advisors regarding the university and degree requirements. A third purpose for the present study was to assess students' perceptions of the effects academic advisement had on …

American Books Of The Dead: Mourning And Denial In The Fiction Of Don Delillo And Cormac Mccarthy, Allan E. Crandell

Masters Theses

The novels of Don DeLillo and Cormac McCarthy are heavily pervaded by themes of mortality and its denial. DeLillo's White Noise (1985), with its emblematic centerpiece of an "Airborne Toxic Event," was succeeded by the slim depiction of mourning deferred, The Body Artist (2001). Likewise, Cormac McCarthy's epic Appalachian novel, Suttree (1979), is ridden with images of death and strangled mourning, a work followed by Blood Meridian or the Evening Redness in the West (1985), a historiographic depiction of unrelenting, culturally repressed bloodshed. This thesis maintains that DeLillo and McCarthy warn us in these novels about the American way of …

Boundary-Crossers: Observation, Chance, And Change In The Fiction Of Thomas Hardy, D. Levi Woolen-Danner

Masters Theses

Thomas Hardy creates in his fiction a world that demands love lead to failure. His hero and heroine are tragic nearly without exception, as if desire were not just a burden, but a catalyst for disaster. Perhaps this is due to the period in which Hardy was living, and his need to reconcile his memories of an idyllic past with the dramatic social and econonomic changes contemporary to his period of novel-writing. Perhaps he is trying to discover a new model of living-one that will not be trapped by human desires. He has created a figure, one I refer to …

The Semantics Of Color In Anna Akhmatova's Early Poetry, Alsu Shakirova

Masters Theses

Anna Akhmatova (1889-1966), a Russian post-Symbolist poet, published a variety of poems in the Russian language, which were later translated into English. Her works include the collections Evening (1912), Rosary (1914), White Flock (1917), Plantain (1921), Anno Domini (1922), From Six Books (1940), Seventh Book (1936- 1964), Poems (1958), Requiem (1963), and Poem Without a Hero (1940-1966). This work focuses on her early poetry collections Evening, Rosary, White Flock, and Anno Domini and analyzes the semantic relationship between color and concrete objects in order to discover how Akhmatova conveys the image, mood, and state of the persona's transforming self through …

The Correlation Between Date Violence And Disordered Eating In College Aged Women, Kenzia N. Hartman

Masters Theses

Objective: Research has shown a correlation between date violence and disordered eating behaviors in adolescent females. Those who have experienced verbal, physical, or sexual date violence report an increased incidence in the use of unhealthy weight control practices such as fasting,g diet pills, laxatives, vomiting, and binge eating. In addition to unhealthy eating practices, lowered body image has also been associated with date violence. This study was designed to determine if there is a correlation between date violence, disordered eating behaviors, and lowered body image in college age women. Method: Questionnaire data were gathered from 150 college-aged female students at …

Perceptions Of Violence Among High School Students, Beth Sanner

Masters Theses

The purpose of this study was to determine the perceptions of violence among high school students. The researcher analyzed the differences in the perceptions of the severity of violence among high school students in the following demographic characteristics: ethnicity, gender, academic achievement, regional location and family e-up. In addition, the differences in the severity of physical, verbal and social violence was found and also compared among the above mentioned demographic characteristics. The sample included 145 high school students in Illinois. A quantitative causal comparative design was used to compare perceptions of violence among existing groups of high school students. Additionally, …

Sexual Abuse Prevention Programs In Illinois Schools, Mary Ann Seaton

Masters Theses

The purpose of this study was to complete an in depth exploration of programs designed to teach children the skills necessary to keep them safe from sexual abuse. Educational programs have been utilized to aid in the prevention and acknowledgement of childhood sexual abuse for many years. While sexual abuse programs for children are used across the United States, little contemporary research exists related to the use of these programs.

Child sexual abuse prevention programs in central Illinois schools are provided through the public schools by various non-profit community organizations. The sample of this study consisted of five organizations, each …

Characterization Of Putative In Vitro Hybrids Within The Genus Flammulina, Sean C. Jones

Masters Theses

The genus Flammulina (Basidiomycetes, Agaricales, Tricholomataceae) includes a group of saprobic mushrooms that grow in the wild and are also cultivated and sold commercially throughout the world under the name "enoki" or "enoki-take". Until the 1960s, the genus Flammulina was believed to consist of a single species with a pan-Northern Hemisphere distribution. Flammulina velutipes (Curt.: Fr.) Singer was more or less applied to all collections in the genus whether naturally or commercially produced (Buchanan 1993) until the mid 1960s. In the interim, 14 additional taxa have been described in Flammulina. Knowledge of hybridization within the Flammulina velutipes group is crucial …

Biodiversity Loss And The Taxonomic Bottleneck: Emerging Biodiversity Science, Ke Chung Kim, Loren B. Byrne

Arts & Sciences Faculty Publications

Human domination of the Earth has resulted in dramatic changes to global and local patterns of biodiversity. Biodiversity is critical to human sustainability because it drives the ecosystem services that provide the core of our life-support system. As we, the human species, are the primary factor leading to the decline in biodiversity, we need detailed information about the biodiversity and species composition of specific locations in order to understand how different species contribute to ecosystem services and how humans can sustainably conserve and manage biodiversity. Taxonomy and ecology, two fundamental sciences that generate the knowledge about biodiversity, are associated with …

Current Practices In Engineering Capstone Education: Further Results From A 2005 Nationwide Survey, Jessica Wilbarger, Susannah Howe

Engineering: Faculty Publications

This work further details a survey of engineering capstone design courses nationwide conducted in 2005. The survey is a follow-up to one conducted in 1994 by Todd et al., reprising the questions of its predecessor plus requesting additional information. We implemented the 2005 survey online, with requests sent via email to representatives of all ABET-accredited engineering programs (1724 programs at 350 institutions, as of 2004). The online survey yielded a strong response, with 444 programs from 232 institutions submitting responses. This corresponds to a 26% response rate from engineering programs and a 66% response rate from institutions. This paper focuses …

Changes In The Diet Of Lake Trout (Salvelinus Namaycush) In Near-Shore Lake Michigan With The Invasion Of The Round Goby (Neogobius Melanostomus): 1995-2005, Marybeth Kathryn Brey

Masters Theses

The predator-prey base of the Great Lakes has been altered since the early 1900's, with the majority of these changes occurring due to invasive species such as the sea lamprey (Petromyzon marinus), alewife (Alosa pseudoharangus), and rainbow smelt (Osmerus mordax). These changes have forced large piscivorous fish to find alternate prey species. One predator, the lake trout (Salvelinus namaychush) has experienced a series of diet shifts in the last century, due to a changing prey base. In recent years the Great Lakes, particularly Lake Michigan has experience a new invader, the round goby (Neogobius melanostomus), which has colonized the …

Formation Of Yttrium(Iii) Complexes With Salicylic Acid Derivatives In Aqueous Solution, Rahmi̇ye Aydin, Ulvi̇ye Özer

Turkish Journal of Chemistry

Complexes of yttrium(III) formed with 5-sulphosalicylic acid, 5-SSA (H_3L), and 5-nitrosalicylic acid, 5-NSA (H_2L), were investigated in 0.1 mol.dm^{-3} sodium perchlorate ionic medium at 25.0 \pm 0.1 °C potentiometrically for various molar ratios of Y(III) to these salicylic acid, SA (H_2L), derivatives. Y(III) forms YL and YL_2^{3-} type complexes with 5-SSA that have rather high stabilities (log \beta _1 = 7.91 \pm 0.01 and log \beta _2 = 14.56 \pm 0.06). In the Y(III):5-NSA system, YL^+ and YL_2^- type complexes appear with high stabilities (log \beta _1 = 7.39 \pm 0.02 and log \beta _2 = 13.50 \pm 0.07). Y(III):5-SSA …

Organotin (Iv) Derivatives Of 1-Ethyl-1,4-Dihydro-7-Methyl-4-Oxo- 1,8-Naphthyridine-3-Carboxylic Acid (Nalidixic Acid): Synthesis, Structural Elucidation And Biological Activities, Sajjad Ahmed, Moazzam Hussain Bhatti, Saqib Ali, Fiaz Ahmed

Turkish Journal of Chemistry

Organotin carboxylates of the general formulae R_2SnL_2 and R_3SnL, where R = CH_3, n-C_4H_9, C_6H_5, CH_2C_6H_5 and L = 1-ethyl-1,4-dihydro-7-methyl-4-oxo-1,8-naphthyridine-3-carboxylic acid (nalidixic acid), have been prepared. These compounds were characterized by FT-IR, mass and multinuclear NMR (^1H, ^{13}C and ^{119}Sn) spectroscopy. The geometry around the tin atom is compared both in solution and in solid state. These compounds were also screened for their antifungal and antibacterial activities.

Metal Complexes Of Schiff Bases: Preparation, Characterization, And Biological Activity, Gehad Genidy Mohamed, Mohamed Mohamed Omar, Ahmed Mohamed Hindy

Turkish Journal of Chemistry

Metal complexes of Schiff bases derived from 2-furancarboxaldehyde and o-phenylenediamine (L^1), and 2-thiophenecarboxaldehyde and 2-aminothiophenol (HL^2) are reported and characterized based on elemental analyses, IR ^1H NMR, solid reflectance, magnetic moment, molar conductance, and thermal analysis (TGA). The ligand dissociation, as well as the metal-ligand stability constants were calculated, pH-metrically, at 25 °C and ionic strength \mu = 0.1 (1 M NaCl). The complexes are found to have the formulae [M(L^1)(H_2O)_2](Cl)_n \cdot yH_2O (where M = Fe(III), Ni(II), Cu(II); n = 2-3, y = 2-4); [M(L^1)](X)_2 \cdot yH_2O (where M = Co(II), Zn(II), UO_2(II), X = Cl, AcO or NO_3, …

Synthesis Of Vic-Dioxime Derivatives With Hydrazone Side Groups And Their Metal Complexes, İlknur Babahan, Hüseyi̇n Anil, Nursabah Sarikavakli

Turkish Journal of Chemistry

Two novel vic-dioxime (L^1H_2, L^2H_2) compounds bearing hydrazone side groups and their transition metal complexes Ni(II), Co(II), Cu(II), and Zn(II) were synthesized. The vic-dioxime ligands bearing hydrazone side groups were synthesized by reacting anti-glyoximehydrazine (GH_2) with 4-nitroacetophenone and 4-methylacetophenenone, respectively. Ligands form mononuclear complexes [(LH)_2M] with a metal to ligand ratio of 1:2 with M=Co(II)(H_2O)_2, Ni(II), and Cu(II). Zn(II) forms complexes [(LH)(H_2O)(Cl)Zn] with a metal to ligand ratio of 1:1. The Co(II) complexes of the ligands are proposed to be octahedral with water molecules as axial ligands, the Ni(II) and Cu(II) complexes are proposed to be square planar, and the …

The Mechanism And Crystal Structure Of 2-Methoxy-2-Methyl-4-Phenyl-3,4,4a, 10b-Tetrahydro-2h,5h-Pyrano[3,2-C]Chromen-5-One. Acetal Of Warfarin Acid, Saira Shahzadi, Saqib Ali, Irum Asif, Rizwana Ashraf, Guo-Xin Jin

Turkish Journal of Chemistry

Acetal of warfarin acid has been synthesized via a hemi acetal intermediate and structurally characterized by X-ray diffraction. The crystal structure shows that the title compound was formed by the hydrolysis of warfarin acid in methanol at pH 3, with space group P2_1/n and unit cell parameters a = 5.859 (17), b =16.745 (5), c = 16.402 (5) Å, \alpha = 90.00; \beta = 94.853 (4), and \gamma = 90.00°.

Finite Element Analysis Of Bjork-Shiley Convexo-Concave Heart Valve, Srinivas Avasarala

Theses and Dissertations

No abstract provided.

Censorship And Censureship: Insiders, Outsiders, And The Attack On Bhandarkar Institute, Adheesh Sathaye

Journal of Hindu-Christian Studies

On January 5, 2004, the Bhandarkar Institute, a large Sanskrit manuscript library in Pune, was vandalized because of its involvement in James Laine's controversial study of the Maharashtrian king Shivaji. While most of the manuscripts escaped damage, less fortunate was the academic project of South Asian studies, which now faces some serious questions. if our intellectual pursuits should result in the destruction of the very materials we study, or injury to those who help us to study them, are they worth conducting at all? Or might they be conducted in such a way as to avoid violent reaction? As groundwork …