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Infrared Laser Desorption/Ionization Mass Spectrometry: Fundamental And Applications, Mark Little

LSU Doctoral Dissertations

This dissertation on infrared laser desorption/ionization mass spectrometry encompasses fundamental studies of the desorption/ionization process and direct-from-gel laser desorption/ionization applications. Understanding of the fundamentals behind desorption and ionization can lead to improvements in the technique and to new applications. Experiments aimed at advancing this goal are wavelength studies and two-laser infrared/ultraviolet matrix-assisted laser desorption/ionization experiments. The direct-from-gel laser desorption/ionization application in which infrared laser desorption/ionization of analytes directly ionized after gel electrophoretic separation will also be presented. Protein and peptide standards were used as test analytes and the infrared lasers used were a 10.6 micrometers carbon-dioxide laser and a mid-IR …

Characterization Of Beta-Amyloid Peptide Aggregation And Acceleration With Non-Fibrillar Forming Peptide-Based Mediators, Nadia J. Edwin

LSU Doctoral Dissertations

Protein aggregation occurs under many circumstances, from the dynamic assembly of tubulin to form microtubules, the aggregation of actin into filaments, as well as plaque formation by amyloid precipitation. One important requirement in studying the mechanism of amyloid aggregation is the ability to monitor the growth kinetics over a wide range in size scales (10 nm to microns) with time that spans microseconds to seconds. Understanding the mechanisms of the aggregation may then lead to improved design of drugs to help control or suppress the aggregation process. In this dissertation, the physical characterization of the â-amyloid peptide and its interaction …

Synthesis, Characterization And Properties Of Cooper(Ii) Beta-Diketonate Macrocycles, Sylvester Burton

LSU Doctoral Dissertations

This dissertation deals with the synthesis and properties of multidentate β-diketone ligands and their transition-metal complexes. (1) We prepared two bis(β-diketones), C₁BAH₂ and p-XBAH₂ (see sketch below), determined their crystal structures, and studied their reactions with copper(II). We envisioned that they would form macrocyclic complexes with 3-6 metal atoms. In both cases, although the initial products are soluble, as expected for the desired molecular products, we were unable to isolate well-behaved molecular solids. In the case of C₁BAH₂, this may be because the cyclic product requires an unusual combination of conformations of …

Use Of Atomic Force Microscopy To Study A Molecular Micelle As An Anionic Polymer For Polyelectrolyte Multilayer Deposition On Polymeric Substrates, Angela Nakeeta Douglas

LSU Master's Theses

Polyelectrolyte multilayers (PEMs) have been used as stationary phases for various chiral and achiral separations in open-tubular electrochromatagraphy (OT-CEC). However, the physical characteristics of PEMs are not well understood. The production of PEM coatings involves flowing alternating rinses of positive and negative charged polyelectrolytes onto a surface. Although PEMs are typically deposited on fused silica capillaries, there is growing interest to use this approach in conjunction with microchip devices to enhance separation characteristics. Since microchips are fabricated using polymeric substrates, the deposition of PEMs on these substrates needs to be examined. The study reported in this thesis uses atomic force …

Mesoscale Predictions For The Dynamic Compaction Of Explosively-Coated Aluminum Micro-Particles, Michael Wayne Crochet

LSU Master's Theses

Conventional granular explosives are widely used in aerospace and defense-related industries. Powdered metals are often mixed with high explosives to enhance detonation. The effectiveness of these mixtures is limited by the slow burning of the metal relative to the explosive and their sensitivity to mechanical loading. Granular energetic composites, composed of an aluminum core coated with a layer of the high explosive RDX (C₃H₆N₆O₆), may be a high-performance alternative to conventional explosives because of a higher metal combustion rate and lower impact sensitivity. Though the technology required to manufacture granular energetic composites …

A Generalized Approach For The Control Of Micro-Electromechanical Relays, Mohamed Abdelrahman Younis

LSU Master's Theses

MEMS (Micro-Electromechanical Systems) is an area of research and applications that is becoming increasingly popular. It's mainly concerned with integrating micro-mechanical transducers with micro-electronic circuits on common substrates, traditionally silicon, through micro-fabrication. Instead of traditionally having the transducer and the communicating (or control) circuit as two separate entities, MEMS miniaturizes and combines them on a single chip, giving it several advantages, saving space, money, and increasing the sensitivity and accuracy of the integrated system. A micro-electromechanical relay is a type of MEM devices that is becoming increasingly important in a wide range of industries such as the computer industry, the …

Genetic Effects Influencing Salinity And Cold Tolerance In Tilapia, Alvaro M. Armas-Rosales

LSU Master's Theses

Genetic effects influencing salinity tolerance (ST) and cold tolerance (CT) were evaluated in two full diallel mating designs using six tilapia varieties: Oreochromis aureus (BL), O. mossambicus (MO), O. niloticus (NI), O. niloticus crossbreds (RE), Mississippi commercial strain (MC) and Florida red tilapia (FL). Statistical analyses provided estimates of direct heterosis (h_i), cross heterosis (h_ij), maternal effects (m_i), line effects (l_i), reciprocal and specific reciprocal effects (r_ij and r**_ij), and general and specific combining abilities (GCA and S_ij). Analysis of genetic effects for ST indicated that FL …

The Bioturbation Transport Of Chemicals In Surface Soils, Maria D. Rodriguez

LSU Master's Theses

Large quantities of chemicals, such as pesticides, fertilizers, and industrial wastes, have been found throughout the environment raising concerns due to their ecological impacts and implications to human health. Soil is the most important repository of many organic chemicals in the environment. The objective of the present study was to determine the importance of the soil solid phase in the transport of chemicals in soils, and yield quantitative information to better describe bioturbation and its role in the movement of soil particles. Vertical movement of chemicals in the soil solid phase occurs by mixing mechanisms, such as bioturbation, cryoturbation, and …

Glacial Deposits, Vol. 34, 2005-2006, Department Of Geography-Geology

Glacial Deposits

Newsletter of the Department of Geography-Geology

Impacts Of Red Imported Fire Ants (Solenopsis Invicta Buren) On Native Faunal Communities In Two Pine-Dominated Forests, Lee A. Womack

LSU Master's Theses

Impacts red imported fire ants (RIFA) exert on native faunal communities were monitored in two pine-dominated ecosystems in Louisiana. After suppression of established RIFA populations with Amdro®, cotton mice (Peromyscus gossypinus), herpetofaunal, ground-dwelling invertebrate, Lycosidae, and non-target ant communities were compared between untreated-control and treated plots with respect to possible ecological impacts of RIFA on these communities. Efficacy of Amdro® (A. I. 0.7% hydramethylnon) was tested at Alexander State Forest and Sandy Hollow WMA, and was found to be effective at both sites for 99-42.3% and 97-48%, respectively, suppression of RIFA on treated plots, for three to seven months, with …

The Supreme Court's Role In The Growing School Choice Movement, Kevin D. Brown

Articles by Maurer Faculty

The expansion of school choice in elementary and secondary education, particularly in urban areas, is one of largest current educational reform movements sweeping the nation. This is true despite the fact that it is still too early for a consensus to develop about the educational benefits of increased choice. 1 Society always precedes schooling. Thus, major educational reforms pass in and out of favor depending on social conditions and how prevailing patterns of understanding interpret those conditions.2 Among the most significant social developments influencing educational reforms are legal decisions. Since the Supreme Court is the final authority on constitutional law, …

The Cost And Availability Of The Thrifty Food Plan In Southeast Louisiana, Blair Suzanne Buras

LSU Master's Theses

Low-income individuals in Southeast Louisiana consume poor quality diets and have high rates of nutrition-related health problems such as cardiovascular disease, type 2 diabetes mellitus, and obesity. The United States Department of Agriculture created the Thrifty Food Plan to help food stamp recipients consume a minimal cost, nutritious diet. It is unknown whether the food lists designed to support the Thrifty Food Plan are affordable and available to the food stamp reliant population in Southeast Louisiana. In 29 supermarkets and large grocery stores located in East Baton Rouge Parish and seven surrounding parishes, the cost and availability of two weekly …

Information Analysis Of Dna Sequences, Riyazuddin Mohammed

LSU Master's Theses

The problem of differentiating the informational content of coding (exons) and non-coding (introns) regions of a DNA sequence is one of the central problems of genomics. The introns are estimated to be nearly 95% of the DNA and since they do not seem to participate in the process of transcription of amino-acids, they have been termed “junk DNA.” Although it is believed that the non-coding regions in genomes have no role in cell growth and evolution, demonstration that these regions carry useful information would tend to falsify this belief. In this thesis, we consider entropy as a measure of information …

Assessing The Potential Impact Of Microbes In The Edwards And Trinity Aquifers Of Central Texas, Kelli Willson Randall

LSU Master's Theses

The Edwards Aquifer in central Texas is one of the largest carbonate aquifers in the United States, supplying nearly two million people with water. The role of microorganisms in the development of deep carbonate aquifers has not been thoroughly investigated. The Edwards Aquifer is composed of a freshwater zone and a sulfidic, saline water zone. Down-well video surveys show an abundance of white filamentous and planktonic biomass floating in the water column, indicating that the saline water may serve as a habitat for microbes and provide a unique opportunity to investigate microbially enhanced deep subsurface karstification. A combination of geochemical …

Petrological And Geochemical Investigations Of Deep Sea Turbidite Sands In The Pandora And Moresby Troughs: Source To Sink Papua New Guinea Focus Area, Luke Jeremiah Patterson

LSU Master's Theses

The Moresby and Pandora Troughs of the northern Coral Sea are components of the deep-sea depositional system that is the ultimate sink for the Source to Sink Papua New Guinea (PNG) Focus Area. Cores collected from the R/V Melville during March-April 2004 reveal marine volcaniclastic and terrigenous turbidites deposited in these troughs during the Quaternary. Constraining the spatial, temporal, and provenance characteristics for these terrigenous sands through mineralogical, chemical, and textural analysis is the primary focus of this study. All cores contain thinly-bedded sandy turbidite packages interlayered with hemipelagic marls and typical centimeter-to-meter-thick turbidite sequences. The Moresby Trough core JPC22 …

Nutrient-To-Cost Comparisons Of Daily Dietary Intake, Food Security Status, And Body Mass Index In Female Food Stamp Recipients Residing In Southeast Louisiana, Shanna Lundy

LSU Master's Theses

Diets are typically poorer and risk of chronic disease is greatest in low-income populations. A relationship has been established in the literature between food costs and diet quality, where lower cost diets are generally those of the poorest quality. Food group intake, energy/nutrient intake, and diet cost were assessed in 64 female food stamp recipients in Southeast Louisiana. From one 24-hour dietary recall collected at the beginning of the monthly resource cycle (Day 1) and one at the end (Day 2), nutrient intakes and diet costs were able to be analyzed between different time frames. Participants were divided among food …

Caliche As A Geologic Repository For Atmospheric Sulfate, Katie Jane Howell

LSU Master's Theses

Recent studies demonstrate that important information on sulfur source, oxidation pathway, transport pattern, and reaction kinetics of the oxidation reactions of reduced sulfur gases in the atmosphere may be uncovered by measuring multiple sulfur and oxygen isotope compositions of the oxidation product — secondary atmospheric sulfate (SAS). SAS from Earth’s distant past, however, is rarely preserved in the rock record because of its high solubility and small quantity. Caliche, a pedogenic carbonate formed in arid to semi-arid continental settings and common in the geologic record, could serve as a repository for ancient SAS. Two major groups of caliche samples: 1) …

Green Hydrogen: Site Selection Analysis For Potential Biomass Hydrogen Production Facility In The Texas-Louisiana Coastal Region, Bryan Michael Landry

LSU Master's Theses

Hydrogen and the “Hydrogen Economy” are increasingly becoming buzzwords in discussions regarding future U.S. energy scenarios. Hydrogen energy offers a multitude of economic and environmental advantages over the current world energy structure. Despite this attention, there have been very few geographical studies of a possible transition to a hydrogen system. Even these studies have been limited in scope to demand-side analyses. This thesis attempts to rectify this situation by broadening the scope of geographical studies of hydrogen through the analysis of supply-side scenario. This study is a site selection model for a biomass hydrogen facility in the Gulf Coast of …

The Impact Of Hypoxia On Mercury Methylation In Bottom Sediment Of Northern Gulf Of Mexico, Mei Huey Tan

LSU Master's Theses

Widespread concern has developed about high mercury content in fish in the Gulf of Mexico and adjacent estuaries and bays. Among the areas implicated as possible sources of the mercury that moves up the food chain from the methylmercury formed in sediments and anoxic waters is the seasonal hypoxic zone in the northern Gulf. This research was designed to determine if methylmercury formation is stimulated by the anaerobic sediment conditions accompanying the onset of summer hypoxia in the Gulf. Both field and laboratory studies were carried out. For the field study sediment samples were collected at three stations (i.e. C4, …

Salt Marsh Restoration With Sediment-Slurry Amendments Following A Drought-Induced, Large-Scale Disturbance, Angela Marie Schrift

LSU Master's Theses

A large-scale, drought-induced disturbance occurred in Louisiana during the spring and summer of 2000. Approximately 100,000 acres of Spartina dominated marshes died-back and turned brown. This die-off caused considerable concern because in the absence of recovery dieback marshes can transform to mudflats, which can subside leading to open ponds. The state of Louisiana is attempting to restore some of the dieback marshes through the addition of sediment-slurries. The sediment-slurry generated significantly different marsh elevations: high elevation (mean and 95 % confidence interval: 29, 26 to 32 cm above ambient marsh), medium elevation (21, 19 to 24 cm), low elevation (14, …

Links Between Environmental Mercury, Special Education, And Autism In Louisiana, Jessica Rury

LSU Master's Theses

The number of children born every year with neurological disorders is increasing and some of this increase may be attributed to mercury exposure. Pregnant women ingest contaminated fish, which transfers high mercury concentrations to the unborn fetus. This exposure may result in methyl mercury buildup in the brain of the unborn fetus. Symptoms ranging from minor to severe may be observed as special educational needs in school systems. These include learning disorders, developmental delays, and autism. Louisianans are especially susceptible to mercury contamination because fish and shellfish are a major portion of their cultural diet. This study, through the use …

Evaluation Of Tcp Based Congestion Control Algorithms Over High-Speed Networks, Yaaser Ahmed Mohammed

LSU Master's Theses

The Additive Increase Multiplicative Decrease (AIMD) algorithm of the Transport Control Protocol (TCP) had worked remarkably well over low speed networks and had guaranteed fairness to the users all over these years, but at present, the demands for transferring large quantities of data over very high-speed networks are increasing at a tremendous rate. Because of its AIMD algorithm to control its window growth function accompanied by a slow response function which is inadequate over high-speed links, TCP has been proven to underutilize the available network bandwidth and leave a considerable amount of unused bandwidth. To overcome this limitation of TCP, …

Coastal Marsh Restoration Using Terraces: Effects On Waterbird Habitat In Louisiana's Chenier Plain, Jessica L. O'Connell

LSU Master's Theses

Terracing is a novel technique used to combat coastal marsh loss in Louisiana and Texas. Terraces are assumed to slow marsh erosion, decrease pond depth, and encourage vegetation expansion. Terraced ponds have never been evaluated as habitat for waterbirds, which heavily depend on Louisiana�s coastal marshes. From April 2005 to April 2006, I monitored waterbird species richness and density through time to estimate effects that terracing has on habitat quality. Water quality (turbidity, salinity, conductivity, water temperature, and water depth) also was measured. Submerged aquatic vegetation (SAV) biomass and nekton density were measured from April 2005 to September 2005. I …

California's Punitive Damages Law: Continuing To Punish And Deter Despite State Farm V. Campbell, Kathleen S. Kizer

UC Law Journal

In State Farm v. Campbell, the U.S. Supreme Court held that the punitive damages awarded in a particular case must be proportional to the amount of compensatory damages awarded in that case. Although the Court refrained from setting a "bright-line ratio," many courts reviewing awards after State Farm have time and again reduced punitive damages awards, using factors between four and nine in reliance on proclamations made by the Court in State Farm. In addition, State Farm casts doubt on whether a defendant's financial condition is relevant to the issue of punitive damages. Both of these assertions-that punitive damages must …

The Voting Rights Act And The Racial Gap In Lost Votes, Paul Moke, Richard B. Saphire

UC Law Journal

Recent presidential and gubernatorial elections have exposed serious flaws in the process by which American voters participate in the democratic franchise. Studies have shown that African- Americans who use inferior punch card technology are more likely than non-African-Americans to be disenfranchised because of unintentional errors in the use of voting equipment. Following the disputed 2000 presidential election, several civil rights and civil liberties organizations used section 2 of the Voting Rights Act to challenge state voting technology, arguing that punch card equipment has an adverse impact on racial minorities.

This Article examines the empirical evidence on voting technology, residual votes, …

Instantaneously Trained Neural Networks With Complex And Quaternion Inputs, Adityan V. Rishiyur

LSU Master's Theses

Neural network architectures such as backpropagation networks, perceptrons or generalized Hopfield networks can handle complex inputs but they require a large amount of time and resources for the training process. This thesis investigates instantaneously trained feedforward neural networks that can handle complex and quaternion inputs. The performance of the basic algorithm has been analyzed and shown how it provides a plausible model of human perception and understanding of images. The motivation for studying quaternion inputs is their use in representing spatial rotations that find applications in computer graphics, robotics, global navigation, computer vision and the spatial orientation of instruments. The …

Ignoring The Supreme Court: State V. White, The Civil Commitment Of Sexually Violent Predators, And Majoritarian Judicial Pressures, Eric W. Buetzow

UC Law Journal

In Kansas v. Hendricks, the Supreme Court upheld the constitutionality of state statutes that allow for the civil commitment of "sexually violent predators" after completion of their criminal sentences. But the Court in Hendricks left uncertain the precise requirements demanded by substantive due process in this context. Specifically, questions remained regarding whether, and to what degree, a defendant must suffer from volitional inability for the commitment to pass constitutional muster. The Supreme Court responded five years later in Kansas v. Crane, where it held that "there must be proof of serious difficulty in controlling behavior." This could have been considered …

Comparison Of Data Mining And Statistical Techniques For Classification Model, Rochana Lahiri

LSU Master's Theses

The purpose of this study is to observe the performance of three statistical and data mining classification models viz., logistic regression, decision tree and neural network models for different sample sizes and sampling methods on three sets of data. It is a 3 by 2 by 3 by 8 study where each statistical or data mining method has been employed to build a model for each of 8 different sample sizes and two different sampling methods. The effect of sample size on the overall performance of each model against two sets of test data are observed and compared. It is …

Ice Sheet Grounding Zone Deposits On Ross Sea Continental Shelf (Antarctica): Seismic Facies Analysis And P-Wave Reflectivity Attributes, Adeniyi Adewumi Saanumi

LSU Master's Theses

Subglacial till and overlying glaciomarine deposits are difficult to distinguish because the physical properties of subglacial till may vary depending on the drainage conditions of the rock directly beneath the ice sheet. Based on approximately 120 kilometers of multi-channel seismic data, detailed seismic facies analysis and amplitude variation with offset (AVO) analysis are carried out to examine the distribution of ice sheet grounding zone deposits on the continental shelf of the Northern Basin, Ross Sea (Antarctica) and infer the physical properties of interpreted subglacial till. Seismic facies analysis led to the differentiation of distinct sub-environments around a grounded ice sheet: …

Asymmetry Of Tidal Plume Fronts In An Eastern Boundary Current Regime, David A. Jay, Jiayi Pan, Philip M. Orton, Alexander R. Horner-Devine

Civil and Environmental Engineering Faculty Publications and Presentations

The Columbia River tidal plume or near-field is formed twice daily by the ebb outflow of the Columbia River. It is a part of a larger, anticyclonic plume bulge, which in turn is embedded in far-field plume and coastal waters. Because of the mixing caused directly and indirectly by plume fronts, the interaction of the tidal plume and bulge with the California Current upwelling regime plays a vital role in coastal productivity on the Oregon and Washington shelves. The tidal plume is initially supercritical with respect to the internal Froude number on all stronger ebbs. It is separated from the …