Digital Commons Network^™

Applications Of Titanium-Mediated Reductive Coupling And Cyclocarbonylation Reactions Toward Natural Product Synthesis, Maria A. Appeaning

LSU Doctoral Dissertations

Previous work in our laboratory has demonstrated not only a synthetic value of tandem reductive cyclization - carbonylation reactions in the preparation of complex molecules but also the interesting stereoselectivity observed therein. The first part of this work employs the titanium-mediated cyclocarbonylation of tethered dienals for the synthesis of prostaglandin analogues, in particular PGF_2α and methyl jasmonate. Based on this hetero Pauson-Khand strategy, we have established an efficient racemic route to both the prostaglandin and the methyl jasmonate core skeletons. Moderate to excellent selectivities with regard to the hetero Pauson-Khand reaction were observed in both cases. The second part …

How Cue-Dependent Is Memory?: Internal Reinstatement And Cueing Effects In Recognition And Source Memory, Jeffrey Joseph Starns

LSU Doctoral Dissertations

This study explored the role of internal context reinstatement in masking the effects of external context cues on recognition and source memory. Participants studied words paired with pictures of male and female faces. Following the study phase, participants completed either a source test in which they decided whether each test word was studied with a male or female face (Experiments 1, 3, and 4) or a recognition test in which they decided whether each test word appeared in the study phase (Experiment 2). On selected trials, a studied face was reinstated at test to serve as a cue for the …

Active Control Of Spray Combustion, Onur Tuncer

LSU Doctoral Dissertations

Effect of a forced dilution air jet on air-fuel spray mixing and emissions has been investigated. Temperature measurements have been made at a number of forcing frequencies in the range of 100-1100 Hz and blowing ratios between 6-15. Open-loop flame response to forcing has also been acquired by recording pressure and heat release spectra. The results show that the mean temperature field inside the flame can be altered due to jet modulation. Significant effects are observed by forcing at locations close to the dump plane. Enhancements in temperature of the order of 100–200 ˚C, and reduction in pattern factor of …

Age-Phasing And The Use Of Life-Cycle Funds, Shelley Farr

Theses : Honours

The Superannuation Guarantee legislation has made many Australian employees compulsory investors. The reality that many Australian employees are failing to save adequate retirement benefits highlights the importance of selecting an appropriate superannuation investment strategy. With a majority of members having their employer-sponsored contributions in Defined Contribution Funds, it is ultimately members who are responsible for making investment decisions. Given that Australian employees are faced with myriad investment options, it is opportune to examine how members are exercising investment choice. A key factor for a member to consider is whether their investment strategy should be influenced by their age. Using the …

Attention Driven Reference Resolution In Multimodal Contexts, John D. Kelleher

Articles

In recent years a a number of psycholinguistic experiments have pointed to the interaction between language and vision. In particular, the interaction between visual attention and linguistic reference. In parallel with this, several theories of discourse have attempted to provide an account of the relationship between types of referential expressions on the one hand and the degree of mental activation on the other. Building on both of these traditions, this paper describes an attention based approach to visually situated reference resolution. The framework uses the relationship between referential form and preferred mode of interpretation as a basis for a weighted …

Vashegyite From Gaura Cu Muscă Cave (Locvei Mountains, Romania): A New And Rare Phosphate Occurrence, Bogdan P. Onac, Luminiţa Zaharia, Joe Kearns, Daniel Veres

International Journal of Speleology

This study investigated the occurrence of vashegyite from a guano-rich deposit located in the Gaura cu Muscă Cave, Romania. Analytical methods used include optical microscopy, X-ray powder diffraction (XRD), scanning electron-microscopy (SEM), inductively coupled plasma-atomic emission spectrometry (ICP-AES), thermal investigations and Fourier-transform infrared (FT-IR) analyses. Vashegyite occurs as friable, chalky white, irregular nodules of up to 2.5 cm in diameter, within a 15 cm thick sequence of organic and minerogenic sediments. The chemical structural formula is: (Al_10.91Fe³⁺_0.06Na_0.1Ca_0.02Mg_0.08)_Σ=11.17[(PO₄)_8.78(SiO₄)_0.056]_Σ=8.83(OH) …

The Distribution Of Diatom Flora In Ice Caves Of The Northern Yukon Territory, Canada: Relationship To Air Circulation And Freezing, Bernard Lauriol, Clément Prévost, Denis Lacelle

International Journal of Speleology

In the late 1980’s and early 1990’s, various media in karst environments in the Northern Yukon Territory were examined for their diatom content. Cryogenic cave calcite powders, grus and various ice formations (ice plugs, ice stalagmites and floor ice) were collected from three freezing caves and one slope cave to make an inventory of the diatom content, and to explain the spatial distribution of the diatoms within the caves. The results show that approximately 20% of diatoms in the caves originate from external biotopes and habitats (e.g., river, lake, stream), with the remaining 80% of local origin (i.e., from subaerial …

Potential Of Vibrational Spectroscopy In The Diagnosis Of Human Tumours., Eoghan O'Faolain

Doctoral

Just fewer than 20,000 people are annually diagnosed with some form of cancer in Ireland and one in three people are likely to contract some form of cancer by age 74. With the number of cases increasing at an annual rate of 2%, the early detection and treatment of cancer is becoming increasingly important. Both IR and Raman spectroscopy offer the potential for real time, quantitative detection of cancer and even precancer. This study investigates the potential of Raman and Fourier transform infrared, both benchtop and synchrotron spectroscopies for the detection of cervical cancer. The tissue was classified and its …

Evaluation Of The Effect Of Vehicle Performance On Consumer Satisfaction, Elizabeth A. Cudney

Doctoral Dissertations

"Value is the relationship of functionality or benefit to the cost of a product or service. Consumers appear to seek value, but not all consumers are alike in their needs and wants. Common characteristics that consumers desire in automobiles include a high level of value relative to the product's cost. Consumers measure vehicle performance in terms of twenty-three attributes such as roominess, ride, reliability, handling, brake pedal feel, visibility, interior noise, acceleration, etc. Problems arise when automakers try to translate these characteristics into vehicle performance specifications and capabilities.

Quality is an essential element for both the consumer and producer since …

Designing And Modeling Of A New Continuous Steelmaking Process, Jörg Peter

Doctoral Dissertations

"Continuous steel production has the potential to lower the cost of steelmaking as compared to current batch operations. However, experiences from past attempts to develop and commercialize continuous steelmaking processes show that there are several engineering hurdles to overcome. The objective of this research was the development of a fully continuous steelmaking process that would incorporate the lessons from past experiences, address the foreseen challenges, and meet the requirements to justify the possible replacement of the current EAF-LMF steelmaking route.

The design of the new process consists of five interconnected vessels. Preheated scrap would be continuously charged, melted, and superheated …

Comparative Phylogenomics Of Clostridium Difficile Reveals Clade Specificity And Microevolution Of Hypervirulent Strains., Denise Drudy

Articles

No abstract provided.

Weasel Numbers, Reza Dibadj

Cardozo Law Review

No abstract provided.

Improving Data Access For Computational Grid Applications, Ron Oldfield, David Kotz

Dartmouth Scholarship

High-performance computing increasingly occurs on “computational grids” composed of heterogeneous and geographically distributed systems of computers, networks, and storage devices that collectively act as a single “virtual” computer. A key challenge in this environment is to provide efficient access to data distributed across remote data servers. Our parallel I/O framework, called Armada, allows application and data-set providers to flexibly compose graphs of processing modules that describe the distribution, application interfaces, and processing required of the dataset before computation. Although the framework provides a simple programming model for the application programmer and the data-set provider, the resulting graph may contain bottlenecks …

Polynomial Quandle Cocycles, Their Knot Invariants And Applications, Kheira Ameur

USF Tampa Graduate Theses and Dissertations

A quandle is a set with a binary operation that satisfies three axioms that corresponds to the three Reidemeister moves on knot diagrams. Homology and cohomology theories of quandles were introduced in 1999 by Carter, Jelsovsky,Kamada, Langford, and Saito as a modification of the rack (co)homology theory defined by Fenn, Rourke, and Sanderson. Cocycles of the quandle (co)homology, along with quandle colorings of knot diagrams, were used to define a new invariant called the quandle cocycle invariants, defined in a state-sum form. This invariant is constructed using a finite quandle and a cocyle, and it has the advantage that it …

Markets For Markets: Origins And Subjects Of Information Markets, Miriam A. Cherry, Robert L. Rogers

All Faculty Scholarship

This Article focuses on why information markets have covered certain subject areas, sometimes of minor importance, while neglecting other subject areas of greater significance. To put it another way, why do information markets exist to predict the outcome of the papal conclave and the Michael Jackson trial, but no information markets exist to predict government policy conclusions, Supreme Court decisions, or the rulings in Delaware corporate law cases? Arguably, from either a dollar value or a social utility perspective, these areas of law and business would be more important than the outcome of, say, the Jackson trial. Why, then, do …

Salt Ingestion Caves, Charles A. Lundquist, William W. Varnedoe Jr.

International Journal of Speleology

Large vertebrate herbivores, when they find a salt-bearing layer of rock, say in a cliff face, can produce sizable voids where, over generations, they have removed and consumed salty rock. The cavities formed by this natural animal process constitute a unique class of caves that can be called salt ingestion caves. Several examples of such caves are described in various publications. An example in Mississippi U.S.A., Rock House Cave, was visited by the authors in 2000. It seems to have been formed by deer or bison. Perhaps the most spectacular example is Kitum Cave in Kenya. This cave has been …

Unconfined Versus Confined Speleogenetic Settings: Variations Of Solution Porosity, Alexander Klimchouk

International Journal of Speleology

Speleogenesis in confined settings generates cave morphologies that differ much from those formed in unconfined settings. Caves developed in unconfined settings are characterised by broadly dendritic patterns of channels due to highly competing development. In contrast, caves originated under confined conditions tend to form two- or three-dimensional mazes with densely packed conduits. This paper illustrates variations of solution (channel) porosity resulted from speleogenesis in unconfined and confined settings by the analysis of morphometric parameters of typical cave patterns. Two samples of typical cave systems formed in the respective settings are compared. The sample that represents unconfined speleogenesis consists of solely …

Tracer-Test Design For Losing Stream–Aquifer Systems, Malcolm S. Field

International Journal of Speleology

Hydrological tracer testing is an effective way for assessing the significance and extent of leakage through the bed of an influent (losing and sinking) stream. In karstic terranes, leakage from losing and sinking streams typically resurge at downstream springs, but flow may be intercepted by production wells. Although sinking streams that disappear into swallow holes and caves are relatively easy to trace, developing a tracer test design for a losing stream that allows slow percolation through its bed is complicated by the lack of basic knowledge regarding leakage rate, leakage locations along its length, and temporal variability. To overcome these …

Studies Of Condensation/Evaporation Processes In The Glowworm Cave, New Zealand, C. R. De Freitas, A. Schmekal

International Journal of Speleology

The condensation/evaporation process is important in caves, especially in tourist caves where there is carbon dioxide enriched air caused by visitors. The cycle of condensation and evaporation of condensate is believed to enhance condensation corrosion. The problem is condensation is difficult to measure. This study addresses the problem and reports on a method for measuring and modelling condensation rates in a limestone cave. Electronic sensors for measuring condensation and evaporation of the condensate as part of a single continuous process of water vapour flux are tested and used to collect 12 months of data. The study site is the Glowworm …

Radon In Caves: Clinical Aspects, Stephen A. Craven, Berend J. Smit

International Journal of Speleology

Historical, experimental and clinical evidence is presented to suggest that radon constitutes a relatively small carcinogenic risk for casual visitors to caves. The risk is dependent on radon levels and the smoking of tobacco. Show cave guides, chronically exposed to radon, may be at increased risk for lung cancer due to the effects of radon, especially if they are smokers of tobacco.

Identification Of Cave Minerals By Raman Spectroscopy: New Technology For Non-Destructive Analysis, William B. White

International Journal of Speleology

The identification of minerals from caves generally requires that samples be removed from the cave for analysis in the laboratory. The usual tools are X-ray powder diffraction, the optical microscope, and the scanning electron microscope. X-ray diffraction gives a definitive fingerprint by which the mineral can be identified by comparison with a catalog of reference patterns. However, samples must be ground to powder and unstable hydrated minerals may decompose before analysis is complete. Raman spectroscopy also provides a fingerprint useful for mineral identification but with the additional advantage that some a-priori interpretation of the spectra is possible (distinguishing carbonates from …

Imsa 2006 Profile, Office Of College And Academic Counseling

IMSA Profile

The Illinois Mathematics and Science Academy® (IMSA) is an internationally-recognized pioneering educational institution created by the State of Illinois to develop talent and leadership in mathematics, science and technology. IMSA's advanced residential college preparatory program enrolls 650 Illinois students (grades 10-12) who are academically talented and who demonstrate a passion for mathematics and science. Admission is competitive. As part of the overall academic experience, IMSA requires all students to reside on campus. IMSA employs 57 teaching faculty members, all of whom have advanced degrees, with 42% holding doctorate degrees. In addition, 23% of faculty members are certified by the National …

The Challenges Of Itil Implementations, Jason Gray

Theses : Honours

Originating from the UK, the IT Infrastructure Library (ITIL) is an IT Service Management framework whose adoption is rapidly spreading throughout Canada, Netherlands, South Africa, India, USA, and Australia. Promoted as a collection of "Best Practices" in IT service management, ITIL is gaining a reputation as a "silver bullet" to IT Service Management woes and is now .gaining popularity amongst IT vendors and leaders of best practices worldwide. Increased IT productivity, IT accountability, increased compliance and reduced IT costs, are just some of the promised list of benefits. More and more organisations are plam1ing to embark on ITIL implementations as …

Radio Frequency Enabled Soil Redox Potential Sensor Networks, Chris Holme

Theses : Honours

There is a need for' cost effective tools and data collection methods for field measurements; to increase both productivity and volumes of collected data in the quest for enhanced understanding and management of environmental systems. To such end, various technologies that may be combined into a cost effective soil redox sensor network were explored. Suitability of each technology, as a component of said network was evaluated. A prototype soil redox sensor network was constructed and basic laboratory and field testing was completed. Results indicate that the prototype sensor network functions correctly within bounds. Both laboratory and field testing show that …

The Determination Of Probes For The Indirect Detection Of Anions In Capillary Zone Electrophoresis Using Light Emitting Diode Detection, Peter Ashley Balding

Theses : Honours

This study investigated the potential of a number of compounds to act as probes for the indirect detection of inorganic and organic anions separated by capillary zone electrophoresis and using light emitting diodes (LED) as the light source. Desirable characteristics of the probe anion included: high molar absorptivity, moderate to high electrophoretic mobility, and having a wavelength of maximum absorbance near the maximum emission wavelength of a LED. A preliminary study led to the evaluation of eleven possible compounds. Two of these, p-nitrophenol and 4-hydroxy-3,5-dinitrobenzoic acid were selected for further study as they fulfilled the criteria previously mentioned. The optimised …

The Role Of Implicit Memory In Visual Word Recognition: Principles And Processes Of Long- And Short-Term Repetition Priming, Matthew Robert Merema

Theses : Honours

This review examines the role of long- and short-term repetition priming research in the theoretical debate between episodic and abstractionist accounts of implicit memory. The empirical research and theoretical accounts of priming reviewed indicate that neither episodic or abstractionist theories alone can successfully account for the processes of long- and short-term repetition priming. The major variations between studies in experimental methods used to measure repetition priming are also examined, providing a possible explanation for contrasting results obtained within repetition priming research and a reason for why the episodic versus abstractionist debate persists. Finally, research examining the underlying mechanisms responsible for …

Evaluating The Impact Of Peer Review And Participation Awareness In An Online Collaborative Document Authoring Environment, Greg Baatard

Theses : Honours

Online Learning Environments (OLEs) have been widely adopted by higher education facilities, offering distance education with the potential to support the social and collaborative aspects deemed crucial to modern constructivist pedagogy. Groupware, a form of software which aims to facilitate group work, has been the subject of much research, from both educational and enterprise perspectives. This research introduced Reportal, an online groupware system designed to facilitate the collaborative authoring of a document. Reportal's peer review and participation awareness features were the focus of this research, and their impact was measured against the elements of online collaboration, a typology established by …

The Influence Of Genetics And The Environment On Human Personalities, Relationships And Experiences, Patrice Smith

Theses : Honours

It's no mystery that our genetic make-up plays an integral part in the outcome of our lives, but to what extent exactly are our personalities, relationships and experiences pre-determined by this genetic code? There are two forces that contribute to the outcome of these aspects of our lives. Genetics and Environment. The significance of the environment, i.e., our upbringing, lifestyle and the world around us is often emphasized by psychologists as the more dominant force, however our genes are just as, if not more, influential on our lives. My choreographic process is directly in relation to the group of artists …

An Attitude And Perception Study Of Wireless Network Usage In Home Environments, Patryk Szewczyk

Theses : Honours

Research on the use of 802.11 wireless networking and wireless security has in the past focused predominantly on corporations who generally have access to resources specifically allocated to computer and network security. Research has also focused on identifying the flaws in wireless network security, and developing stronger and safer methods which may be incorporated. To date there has been a lack of research into determining what the individual at home perceives towards wireless security. As broadband Internet connections are now predominantly chosen, the amount of available bandwidth open to exploitation is significantly higher than the now becoming obsolete dialup connection. …

The Dancing Mind, Rebecca Mccormac

Theses : Honours

How is it that we go from the unknown to the known? Is there a parallel relationship between mind and body? How does the brain inform the body? An active approach to cognition conceives of the mind as one with the body. The human brain controls feeling, cognition, perception, action, learning and other basic functions, and therefore it is vital to consider the influence of neuroscience on the development of cognitive psychology and vice versa, when looking at a dancing body/mind.