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2006

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Articles 10921 - 10950 of 11369

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Molecular Mass And Dynamics Of Poly(Methyl Acrylate) In The Glass Transition Region, Burak Metin, Frank D. Blum Jan 2006

Molecular Mass And Dynamics Of Poly(Methyl Acrylate) In The Glass Transition Region, Burak Metin, Frank D. Blum

Chemistry Faculty Research & Creative Works

The segmental dynamics of bulk poly(methyl acrylate) (PMA) were studied as a function of molecular mass in the glass-transition region using 2H NMR and modulated differential scanning calorimetry (MDSC). Quadrupole-echo 2H NMR spectra were obtained for four samples of methyl-deuterated PMA-d3 with different molecular masses. The resulting spectra were fit using superpositions of simulated spectra generated from the MXQET simulation program, based on a model incorporating nearest-neighbor jumps from positions on the vertices of a truncated icosahedron (soccer-ball shape). The lower molecular-mass samples, influenced by the presence of more chain ends, showed more heterogeneity (broader distribution) and lower glass transitions …

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Segmental Dynamics Of Poly(Isopropyl Acrylate)-D7 On Silica, Piyawan Krisanangkura, Frank D. Blum Jan 2006

Segmental Dynamics Of Poly(Isopropyl Acrylate)-D7 On Silica, Piyawan Krisanangkura, Frank D. Blum

Chemistry Faculty Research & Creative Works

For a polymer film deposited on a surface, the strength of the surfacesegment interaction affects the mobility of polymer-chain segments. The selfconsistent field lattice model of Scheutjens and Fleer,1 based on mean-field lattice models of polymer at interfaces,2 has been used to describe the distribution of conformations of polymers on surfaces. Adsorbed-polymer segments may be classified as belonging to loops, trains or tails. There are different techniques used to study the molecular motion of the polymer including modulated differential scanning calorimetry (MDSC)3 and nuclear magnetic resonance (NMR).4,5 in this work, solid-state deuterium (2H) NMR was used to characterize the polymer …

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Segmental Mobility Of Chain Ends In Poly(Methyl Acrylate)-D3, Burak Metin, Frank D. Blum Jan 2006

Segmental Mobility Of Chain Ends In Poly(Methyl Acrylate)-D3, Burak Metin, Frank D. Blum

Chemistry Faculty Research & Creative Works

Better control of polymeric materials can be achieved with a thorough understanding of the dynamics of their constituents. In the present study, we consider polymer chains as composed of chain middles and chain ends. Even though chain ends do not comprise much of the sample by mass, they may play a crucial role in the ultimate properties of the polymers. Although chain ends have been assigned a higher mobility, as compared to chain middles, there have not been a large number of experimental studies that directly probe their mobility. Among those, the studies of Kitahara et al.1 and Miwa et …

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Separation And Quantification Of N-Acetylcysteine-Amide (Naca) By Hplc With Fluorescence Detection, Wei Wu, Glenn Goldstein, Craig D. Adams, Richard H. Matthews, Nuran Ercal Jan 2006

Separation And Quantification Of N-Acetylcysteine-Amide (Naca) By Hplc With Fluorescence Detection, Wei Wu, Glenn Goldstein, Craig D. Adams, Richard H. Matthews, Nuran Ercal

Chemistry Faculty Research & Creative Works

N-acetyl-l-cysteine (NAC) is a well-known antioxidant that is capable of facilitating glutathione (GSH) biosynthesis and replenishing intracellular GSH under oxidatively challenging circumstances. N-acetyl-cysteine-amide (NACA), the amide form of NAC, is a newly designed and synthesized thiol-containing compound which is believed to be more lipophilic and permeable through cell membranes than NAC. The metabolic and antioxidant effects of these compounds in vitro and in vivo are under investigation. However, an analytical method that can separate and quantify both compounds simultaneously is not yet available, to the best of our knowledge. Because of their structural similarities, the two compounds are difficult to …

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Synthesis And Thermal Behavior Of Poly(Methyl Acrylate) Attached To Silica By Surface-Initiated Atrp, Manikantan B. Nair, Frank D. Blum Jan 2006

Synthesis And Thermal Behavior Of Poly(Methyl Acrylate) Attached To Silica By Surface-Initiated Atrp, Manikantan B. Nair, Frank D. Blum

Chemistry Faculty Research & Creative Works

The modification of the surface of an object dictates the response of the object to an external environment.1 Surface-modified materials and nanoparticles have attracted immense interest due to the various desirable electronic, optical and magnetic properties they possess.2 Silica is widely used as an inorganic filler. Surface modification of the silica, with a variety of organic moieties, facilitates the utilization of silica in conjunction with organic systems. The resulting organic/inorganic hybrid materials have significant potential applications. This work reports the synthesis and characterization of modified silica, and poly(methyl acrylate) attached to the modified silica. An observation of the thermal behavior …

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Conformal Internal Coating Of Macroporous Co-Continuous Mcf-Silicas With Isocyanate Derived Polymers, Nicholas Leventis, Chariklia Sotiriou-Leventis, Xiaojiang Wang, Sudhir Mulik Jan 2006

Conformal Internal Coating Of Macroporous Co-Continuous Mcf-Silicas With Isocyanate Derived Polymers, Nicholas Leventis, Chariklia Sotiriou-Leventis, Xiaojiang Wang, Sudhir Mulik

Chemistry Faculty Research & Creative Works

Since their discovery in 1992,1,2 templating sol-gel silica with structuredirecting agents has resulted in new materials with ordered mesoporous (2-50 nm) structure that is investigated for application in areas as diverse as high surface area supports for caralysts or as nanostructured drug storage and release platforms.3 Structure-directing agents are typically surfactants ranging from cationic detergents such as alkyl-trimethylammonium salts with C8-C18 hydrocarbon chains to non-ionic tertiary amines, polyethylene oxide or amphiphilic triblock copolymers such as poly(ethyleneoxide)-blockpoly( propyleneoxide)-block-poly(ethyleneoxide) (e.g., Pluronic P123). Depending on the surfactant and the conditions (e.g., kind and concentration of catalyst) the structure of the mesopores may vary …

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Effect Of Processing Conditions On Chemical Makeup Of Di-Isocyanate Crosslinked Silica Aerogels, Mary Ann B. Meador, Nicholas Leventis, Lynn A. Capadona, Plousia Vassilaras Jan 2006

Effect Of Processing Conditions On Chemical Makeup Of Di-Isocyanate Crosslinked Silica Aerogels, Mary Ann B. Meador, Nicholas Leventis, Lynn A. Capadona, Plousia Vassilaras

Chemistry Faculty Research & Creative Works

Sol-gel derived silica aerogels are attractive candidates for many unique thermal, optical, catalytic, and chemical applications1 because of their low density and high mesoporosity. However, their inherent fragility has restricted their use to, for example, insulation in extreme temperature environments such as Mars. We have previously reported crosslinking the mesoporous silica structure of an aerogel with di-isocyanates reacted with silanols on the surface,2,3 or epoxies reacting with an amine decorated silica surface.4 Either approach has been shown to significantly increase the strength of the aerogel with only a small effect on density or porosity. Thus, these hybrid materials may be …

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Neural Network-Based Output Feedback Controller For Lean Operation Of Spark Ignition Engines, Brian C. Kaul, Jagannathan Sarangapani, J. A. Drallmeier, Jonathan B. Vance, Pingan He Jan 2006

Neural Network-Based Output Feedback Controller For Lean Operation Of Spark Ignition Engines, Brian C. Kaul, Jagannathan Sarangapani, J. A. Drallmeier, Jonathan B. Vance, Pingan He

Electrical and Computer Engineering Faculty Research & Creative Works

Spark ignition (SI) engines running at very lean conditions demonstrate significant nonlinear behavior by exhibiting cycle-to-cycle dispersion of heat release even though such operation can significantly reduce NOx emissions and improve fuel efficiency by as much as 5-10%. A suite of neural network (NN) controller without and with reinforcement learning employing output feedback has shown ability to reduce the nonlinear cyclic dispersion observed under lean operating conditions. The neural network controllers consists of three NN: a) A NN observer to estimate the states of the engine such as total fuel and air; b) a second NN for generating virtual input; …

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Neuro Control Of Nonlinear Discrete Time Systems With Deadzone And Input Constraints, Pingan He, Wenzhi Gao, Jagannathan Sarangapani Jan 2006

Neuro Control Of Nonlinear Discrete Time Systems With Deadzone And Input Constraints, Pingan He, Wenzhi Gao, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

A neural network (NN) controller in discrete time is designed to deliver a desired tracking performance for a class of uncertain nonlinear systems with unknown deadzones and magnitude constraints on the input. The NN controller consists of two NNs: the first NN for compensating the unknown deadzones; and the second NN for compensating the uncertain nonlinear system dynamics. The magnitude constraints on the input are modeled as saturation nonlinearities and they are dealt with in the Lyapunov-based controller design. The uniformly ultimate boundedness (UUB) of the closed-loop tracking errors and the neural network weights estimation errors is demonstrated via Lyapunov …

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Segmental Dynamics In Poly(Methyl Acrylate) On Silica: Molecular-Mass Effects, Burak Metin, Frank D. Blum Jan 2006

Segmental Dynamics In Poly(Methyl Acrylate) On Silica: Molecular-Mass Effects, Burak Metin, Frank D. Blum

Chemistry Faculty Research & Creative Works

The effect of molecular mass on the segmental dynamics of poly(methyl acrylate) (PMA) adsorbed on silica was studied using deuterium quadrupole-echo nuclear magnetic resonance (NMR) and modulated differential scanning calorimetry. Samples adsorbed on silica (all about 1.5 mg PMA/m2 silica) were shown to have more restricted segmental mobility, and higher Tg's, than the corresponding bulk PMA samples. Around the glass-transition region, adsorbed samples exhibited segmental mobility, which could be classified as heterogeneous due to a superposition of more-mobile and less-mobile components present in the deuterium NMR spectra. This heterogeneity was consistent with a motional gradient with more-mobile segments near the …

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Segmental Dynamics Of Poly(Vinyl Acetate)- D₃ Absorbed On Silica By Solid State 2hnmr: Effect Of Small Molecule Plasticizer, Rakesh R. Nambiar, Frank D. Blum Jan 2006

Segmental Dynamics Of Poly(Vinyl Acetate)- D₃ Absorbed On Silica By Solid State 2hnmr: Effect Of Small Molecule Plasticizer, Rakesh R. Nambiar, Frank D. Blum

Chemistry Faculty Research & Creative Works

There has been significant progress in understanding the behavior of polymeric thin films on surfaces. The change in the apparent glass transition temperature (Tg) of supported thin polymer films with thickness (Tg -nanoconfinement effect) has been widely studied over the last fifteen years. While many studies focused on the thickness dependence of Tg, there are other aspects which are important to understand in a nanoconfined polymer system. For example, polymeric photoresists contain small-molecule photoactive compounds, plasticizers, and processing aids. These components interact with the polymer chains and affect the segmental mobility, which, in turn, affects the Tg - nanoconfinement effect. …

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Novel Sum-Of-Sinusoids Simulation Models For Rayleigh And Rician Fading Channels, Chengshan Xiao, Y. Rosa Zheng, N. C. Beaulieu Jan 2006

Novel Sum-Of-Sinusoids Simulation Models For Rayleigh And Rician Fading Channels, Chengshan Xiao, Y. Rosa Zheng, N. C. Beaulieu

Electrical and Computer Engineering Faculty Research & Creative Works

The statistical properties of Clarke's fading model with a finite number of sinusoids are analyzed, and an improved reference model is proposed for the simulation of Rayleigh fading channels. A novel statistical simulation model for Rician fading channels is examined. The new Rician fading simulation model employs a zero-mean stochastic sinusoid as the specular (line-of-sight) component, in contrast to existing Rician fading simulators that utilize a non-zero deterministic specular component. The statistical properties of the proposed Rician fading simulation model are analyzed in detail. It is shown that the probability density function of the Rician fading phase is not only …

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Power System Control With An Embedded Neural Network In Hybrid System Modeling, Seung-Mook Baek, Jung-Wook Park, Ganesh K. Venayagamoorthy Jan 2006

Power System Control With An Embedded Neural Network In Hybrid System Modeling, Seung-Mook Baek, Jung-Wook Park, Ganesh K. Venayagamoorthy

Electrical and Computer Engineering Faculty Research & Creative Works

The output limits of the power system stabilizer (PSS) can improve the system damping performance immediately following a large disturbance. Due to non-smooth nonlinearities from the saturation limits, these values cannot be determined by the conventional tuning methods based on linear analysis. Only ad hoc tuning procedures can been used. A feedforward neural network (FFNN) (with a structure of multilayer perceptron neural network) is applied to identify the dynamics of an objective function formed by the states, and thereafter to compute the gradients required in the nonlinear parameter optimization. Moreover, its derivative information is used to replace that obtained from …

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Decentralized Power Control With Implementation For Rfid Networks, Kainan Cha, Anil Ramachandran, David Pommerenke, Jagannathan Sarangapani Jan 2006

Decentralized Power Control With Implementation For Rfid Networks, Kainan Cha, Anil Ramachandran, David Pommerenke, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

In radio frequency identification (RFID) systems, the detection range and read rates will suffer from interference among high power reading devices. This problem grows severely and degrades system performance in dense RFID networks. In this paper, we investigate a suite of feasible power control schemes to ensure overall coverage area of the system while maintaining a desired read rate. The power control scheme and MAC protocol dynamically adjusts the RFID reader power output in response to the interference level seen locally during tag reading for an acceptable signal-to-noise ratio (SNR). We present novel distributed adaptive power control (DAPC) and probabilistic …

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International Working Group On Assurance Cases (For Security), S. Guerra, M. Masera, Ann K. Miller, C. B. Weinstock, R. E. Bloomfield Jan 2006

International Working Group On Assurance Cases (For Security), S. Guerra, M. Masera, Ann K. Miller, C. B. Weinstock, R. E. Bloomfield

Electrical and Computer Engineering Faculty Research & Creative Works

Critical systems are aptly named - from electric power to water and gas to the telephone system and the Internet, they're all critical to some aspect of our daily lives. We''re a networked society and as such, it's important to both know whether critical systems are trustworthy and be able to communicate, review, and debate the level of trust achieved in them. In the safety domain, explicit safety cases are increasingly required by law, regulations, and standards. In this article, we outline what a small, international group of experts, spanning various disciplines in safety, security, reliability, and critical infrastructure, been …

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Multiple Statcom Allocation And Sizing Using Particle Swarm Optimization, Ganesh K. Venayagamoorthy, J. C. Hernandez, Yamille Del Valle, Ronald G. Harley Jan 2006

Multiple Statcom Allocation And Sizing Using Particle Swarm Optimization, Ganesh K. Venayagamoorthy, J. C. Hernandez, Yamille Del Valle, Ronald G. Harley

Electrical and Computer Engineering Faculty Research & Creative Works

No abstract provided.

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Origin-Destination (O-D) Trip Table Estimation Using Traffic Movement Counts From Vehicle Tracking System At Intersection, S. Lee, Hojong Baik Jan 2006

Origin-Destination (O-D) Trip Table Estimation Using Traffic Movement Counts From Vehicle Tracking System At Intersection, S. Lee, Hojong Baik

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

A new video-based vehicle tracking system is proposed to provide accurate information on directional traffic counts at intersections. The extracted counts are fed to estimate an origin- destination trip table which is necessary information for traffic impact study and transportation planning. The system utilizes a fisheye lens to expand the area covered by a single camera and uses a particle filtering method to track an individual vehicle. The filter is designed to handle environmental changes and multiple motion dynamics. Experimental results show its strong ability on tracking in various conditions. The paper shows how to use the tracking outputs in …

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Unexpected Higher-Order Effects In Charged Particle Impact Ionization At High Energies, M. Foster, Jerry Peacher, Michael Schulz, Don H. Madison, Zhangjin Chen, H. R. J. Walters Jan 2006

Unexpected Higher-Order Effects In Charged Particle Impact Ionization At High Energies, M. Foster, Jerry Peacher, Michael Schulz, Don H. Madison, Zhangjin Chen, H. R. J. Walters

Physics Faculty Research & Creative Works

Most of the experimental and theoretical studies of electron-impact ionization of atoms, referred to as (e, 2e), have concentrated on the scattering plane. The assumption has been that all the important physical effects will be observable in the scattering plane. However, very recently it has been shown that, for C6+-helium ionization, experiment and theory are in nice agreement in the scattering plane and in very bad agreement out of the scattering plane. This lack of agreement between experiment and theory has been explained in terms of higher-order scattering effects between the projectile and target ion. We have examined electron-impact ionization …

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Adaptive And Probabilistic Power Control Algorithms For Dense Rfid Reader Network, Kainan Cha, Anil Ramachandran, Jagannathan Sarangapani Jan 2006

Adaptive And Probabilistic Power Control Algorithms For Dense Rfid Reader Network, Kainan Cha, Anil Ramachandran, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

In radio frequency identification (RFID) systems, the detection range and read rates may suffer from interferences between high power devices such as readers. In dense networks, this problem grows severely and degrades system performance. In this paper, we investigate feasible power control schemes to ensure overall coverage area of the system while maintaining a desired data rate. The power control should dynamically adjust the output power of a RFID reader by adapting to the noise level seen during tag reading and acceptable signal-to-noise ratio (SNR). We present a novel distributed adaptive power control (DAPC) and probabilistic power control (PPC) as …

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Adaptive Critic Design Based Neuro-Fuzzy Controller For A Static Compensator In A Multimachine Power System, Salman Mohagheghi, Ganesh K. Venayagamoorthy, Ronald G. Harley Jan 2006

Adaptive Critic Design Based Neuro-Fuzzy Controller For A Static Compensator In A Multimachine Power System, Salman Mohagheghi, Ganesh K. Venayagamoorthy, Ronald G. Harley

Electrical and Computer Engineering Faculty Research & Creative Works

This paper presents a novel nonlinear optimal controller for a static compensator (STATCOM) connected to a power system, using artificial neural networks and fuzzy logic. The action dependent heuristic dynamic programming, a member of the adaptive Critic designs family, is used for the design of the STATCOM neuro-fuzzy controller. This neuro-fuzzy controller provides optimal control based on reinforcement learning and approximate dynamic programming. Using a proportional-integrator approach the proposed controller is capable of dealing with actual rather than deviation signals. The STATCOM is connected to a multimachine power system. Two multimachine systems are considered in this study: a 10-bus system …

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Density Estimation Using A Generalized Neuron, R. Kiran, Ganesh K. Venayagamoorthy, M. Palaniswami Jan 2006

Density Estimation Using A Generalized Neuron, R. Kiran, Ganesh K. Venayagamoorthy, M. Palaniswami

Electrical and Computer Engineering Faculty Research & Creative Works

Neural networks have been shown to be useful tools for density estimation. However, the training of neural network structures is time consuming and requires fast processors for practical applications. A new method with a generalized neuron (GN) for density estimation is presented in this paper. The GN is trained with the particle swarm optimization algorithm which is known to have fast convergence than the standard backpropagation algorithm. Results are presented to show that the GN can estimate the density functions for distribution functions with different means and variances. This density estimation method can also be applied to the multi-sensor data …

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Speeding Up Vlsi Layout Verification Using Fuzzy Attributed Graphs Approach, Nian Zhang, Donald C. Wunsch Jan 2006

Speeding Up Vlsi Layout Verification Using Fuzzy Attributed Graphs Approach, Nian Zhang, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

Technical and economic factors have caused the field of physical design automation to receive increasing attention and commercialization. The steady down-scaling of complementary metal oxide semiconductor (CMOS) device dimensions has been the main stimulus to the growth of microelectronics and computer-aided very large scale integration (VLSI) design. The more an Integrated Circuit (IC) is scaled, the higher its packing density becomes. For example, in 2006 Intel's 65-nm process technology for high performance microprocessor has a reduced gate length of 35 nanometers. In their 70-Mbit SRAM chip, there are up to 0.5 billion transistors in a 110 mm2 chip size with …

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Adapting User Interface To Expedite Physician Order Entry: A Frontline To Ensure Patient Safety, Chiang S. Jao, Daniel B. Hier Jan 2006

Adapting User Interface To Expedite Physician Order Entry: A Frontline To Ensure Patient Safety, Chiang S. Jao, Daniel B. Hier

Chemistry Faculty Research & Creative Works

Preventable Medical Errors Are a Major Problem in Healthcare. Maintenance of Accurate Problem Lists and Drug Lists in the Electronic Medical Record is Critical to the Practice of Medicine and Patient Safety. We Built a Simulator of a Clinical Decision Support System that Automates the Process of Maintaining an Electronic Problem List by Processing Drug Order Requests from a Simulated Computerized Physician Order Entry System. Preliminary Results Revealed that the Productivity of the System Increased When the User Interface Was Improved. This Study Highlights the Importance of an Enhanced User Interface as a Frontline in Expediting Physician Data Entry, Streamlining …

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Expanding Extracurricular Learning Opportunities Through International Engineering Student And Faculty Exchange, Mark Polczynski Jan 2006

Expanding Extracurricular Learning Opportunities Through International Engineering Student And Faculty Exchange, Mark Polczynski

Electrical and Computer Engineering Faculty Research and Publications

No abstract provided.

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Spirobicyclic Diamines 1: Synthesis Of Proline-Derived Spirolactams Via Thermal Intramolecular Ester Aminolysis, Fintan Kelleher, Sinead Kelly Jan 2006

Spirobicyclic Diamines 1: Synthesis Of Proline-Derived Spirolactams Via Thermal Intramolecular Ester Aminolysis, Fintan Kelleher, Sinead Kelly

Articles

Proline derived [4.4]-spirolactams have been synthesised in good yields by a reductive-amination reaction followed by thermal cyclisation of the resulting amine onto the proline ester group in refluxing toluene. The synthesis of the corresponding [4.5]-spirolactams by the same method gave much reduced yields.

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Spirobicyclic Diamines 2: Synthesis Of Homochiral Diastereoisomeric Proline Derived [4,4]-Spirolactams, Fintan Kelleher, Sinead Kelly Jan 2006

Spirobicyclic Diamines 2: Synthesis Of Homochiral Diastereoisomeric Proline Derived [4,4]-Spirolactams, Fintan Kelleher, Sinead Kelly

Articles

L-Proline derived diastereoisomeric [4.4]-spirolactams have been prepared by a reductive-amination reaction of (R)- or (S)-alanine methyl ester followed by thermal cyclisation of the resulting amine onto the proline ester group in refluxing toluene. Under similar conditions (R)- or (S)-phenylalanine methyl ester gave no cyclisation products, while R- or S-a-methylbenzylamine required treatment with NaNH2 in refluxing toluene to induce cyclisation giving diastereoisomeric [4.4]-spirolactams

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Imsa 2006 Profile, Office Of College And Academic Counseling Jan 2006

Imsa 2006 Profile, Office Of College And Academic Counseling

IMSA Profile

The Illinois Mathematics and Science Academy® (IMSA) is an internationally-recognized pioneering educational institution created by the State of Illinois to develop talent and leadership in mathematics, science and technology. IMSA's advanced residential college preparatory program enrolls 650 Illinois students (grades 10-12) who are academically talented and who demonstrate a passion for mathematics and science. Admission is competitive. As part of the overall academic experience, IMSA requires all students to reside on campus. IMSA employs 57 teaching faculty members, all of whom have advanced degrees, with 42% holding doctorate degrees. In addition, 23% of faculty members are certified by the National …

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Language, Deals And Standards: The Future Of Xml Contracts, Lawrence A. Cunningham Jan 2006

Language, Deals And Standards: The Future Of Xml Contracts, Lawrence A. Cunningham

GW Law Faculty Publications & Other Works

eXtensible Markup Language (XML) structures information in documentary systems ranging from financial reports to medical records and business contracts. XML standards for specific applications are developed spontaneously by self-appointed technologists or entrepreneurs. XML's social and economic stakes are considerable, especially when developed for the private law of contracts. XML can reduce transaction costs but also limit the range of contractual expression and redefine the nature of law practice. So reliance on spontaneous development may be sub-optimal and identification of a more formal public standard setting model necessary. To exploit XML's advantages while minimizing risks, this Article envisions creating a publicly …

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Salt Ingestion Caves, Charles A. Lundquist, William W. Varnedoe Jr. Jan 2006

Salt Ingestion Caves, Charles A. Lundquist, William W. Varnedoe Jr.

International Journal of Speleology

Large vertebrate herbivores, when they find a salt-bearing layer of rock, say in a cliff face, can produce sizable voids where, over generations, they have removed and consumed salty rock. The cavities formed by this natural animal process constitute a unique class of caves that can be called salt ingestion caves. Several examples of such caves are described in various publications. An example in Mississippi U.S.A., Rock House Cave, was visited by the authors in 2000. It seems to have been formed by deer or bison. Perhaps the most spectacular example is Kitum Cave in Kenya. This cave has been …

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Unconfined Versus Confined Speleogenetic Settings: Variations Of Solution Porosity, Alexander Klimchouk Jan 2006

Unconfined Versus Confined Speleogenetic Settings: Variations Of Solution Porosity, Alexander Klimchouk

International Journal of Speleology

Speleogenesis in confined settings generates cave morphologies that differ much from those formed in unconfined settings. Caves developed in unconfined settings are characterised by broadly dendritic patterns of channels due to highly competing development. In contrast, caves originated under confined conditions tend to form two- or three-dimensional mazes with densely packed conduits. This paper illustrates variations of solution (channel) porosity resulted from speleogenesis in unconfined and confined settings by the analysis of morphometric parameters of typical cave patterns. Two samples of typical cave systems formed in the respective settings are compared. The sample that represents unconfined speleogenesis consists of solely …

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