Digital Commons Network^™

Polytetrahydrofuran-And Dendrimer-Based Novel Sol-Gel Coatings For Capillary Microextraction (Cme) Providing Parts Per Trillion (Ppt) And Parts Per Quadrillion (Ppq) Level Detection Limits In Conjunction With Gas Chromatography And Flame Ionization Detection (Fid), Abuzar Kabir

USF Tampa Graduate Theses and Dissertations

Sol-gel capillary microextraction (CME) is a new direction in solvent-free extraction and preconcentration of trace analytes. CME presents significant interest in environmental, pharmaceutical, petrochemical, biomedical, agricultural, food, flavor, and a host of other important areas. Sol-gel CME utilizes advanced material properties of organic-inorganic hybrid sol-gel polymers to perform efficient extraction and enrichment of target analytes from a variety of matrices. In this dissertation, two novel sol-gel coatings were developed for CME: (a) sol-gel benzyl-terminated dendrimer coating, and (b) sol-gel polytetrahydrofuran (poly-THF) coating. A detailed investigation was conducted to evaluate the performance of the newly developed sol-gel coatings in solvent-free extraction …

The Role Of Sensation Seeking In Children’S Ability To Learn Alcohol Expectancy Associations, Nicole M. Bekman

USF Tampa Graduate Theses and Dissertations

Sensation seeking is a personality characteristic associated with problematic alcohol use and positive alcohol expectancies, but little research has examined the relationship between sensation seeking and the acquisition of alcohol expectancy information. In a recent study (Steinberg, 2003), sensation seeking was associated with how quickly and accurately college-aged students were able to learn alcohol-expectancy word pairs in a paired associate learning task. In this age group, however, the individuals had fully developed alcohol expectancies that may have influenced their rates of learning.

The current study sought to minimize the influence of previously held alcohol expectancies by exploring this relationship in …

Stable Motions Of Vehicle Formations, Anca Williams, Gerardo Lafferriere, J. J. P. Veerman

Mathematics and Statistics Faculty Publications and Presentations

We investigate stable maneuvers for a group of autonomous vehicles while moving in formation. The allowed decentralized feeback laws are factored through the Laplacian matrix of the communication graph. We show that such laws allow for stable circular or elliptical motions for certain vehicle dynamics. We find necessary and sufficient conditions on the feedback gains and the dynamic parameters for convergence to formation. In particular, we prove that for undirected graphs there exist feedback gains that stabilize rotational (or elliptical) motions of arbitrary radius (or eceentricity). In the directed graph case we provide necessary and sufficient conditions on the curvature …

A Solvable Model For Gravity Driven Granular Dynamics, J. J. P. Veerman

Mathematics and Statistics Faculty Publications and Presentations

We discuss a toy model to study the dynamics of individual particles in avalanches. The model describes a particle launched from an inclined infinite staircase. The particle is not allowed to bounce when it collides with the staircase. During the collision, the particle loses some energy, and after that slides on to the end of the step it landed on. The process then repeats itself. The dynamics of this no-bounce model can essentially be completely understood. Partial versions of some results were stated and argued in previous work. Here we give a full description together with all the proofs. We …

Flocks And Formations, J. J. P. Veerman, Gerardo Lafferriere, John S. Caughman Iv, A. Williams

Mathematics and Statistics Faculty Publications and Presentations

Given a large number (the “flock”) of moving physical objects, we investigate physically reasonable mechanisms of influencing their orbits in such a way that they move along a prescribed course and in a prescribed and fixed configuration (or “in formation”). Each agent is programmed to see the position and velocity of a certain number of others. This flow of information from one agent to another defines a fixed directed (loopless) graph in which the agents are represented by the vertices. This graph is called the communication graph. To be able to fly in formation, an agent tries to match the …

The Kerf Toolkit For Intrusion Analysis, Javed Aslam, Sergey Bratus, David Kotz, Ronald Peterson

Dartmouth Scholarship

No abstract provided.

Realizing Ternary Quantum Switching Networks Without Ancilla Bits, Marek Perkowski, Guowu Yang, Xiaoyu Song, Jinzhao Wu

Electrical and Computer Engineering Faculty Publications and Presentations

This paper investigates the synthesis of quantum networks built to realize ternary switching circuits in the absence of ancilla bits. The results we established are twofold. The first shows that ternary Swap, ternary NOT and ternary Toffoli gates are universal for the realization of arbitrary n × n ternary quantum switching networks without ancilla bits. The second result proves that all n×n quantum ternary networks can be generated by NOT, Controlled-NOT, Multiply-Two and Toffoli gates. Our approach is constructive.

Biotic Resistance To Invasion: Native Predator Limits Abundance And Distribution Of An Introduced Crab, Catherine E. De Rivera, Greg M. Ruiz, Anson Hines, Paul Jivoff

Environmental Science and Management Faculty Publications and Presentations

Introduced species frequently escape the natural enemies (predators, competitors, and parasites) that limit their distribution and abundance in the native range. This reduction in native predators, competitors, and parasites may result in ecological release in the introduced range. However, biological interactions also can limit the establishment and spread of nonnative populations. The extent to which such biotic resistance occurs is poorly resolved, especially for marine ecosystems. Here we test whether a native predator, the blue crab Callinectes sapidus, affects the abundance and geographic range of the introduced European green crab Carcinus maenas in eastern North America. Both crab species …

Broad-Scale Non-Indigenous Species Monitoring Along The West Coast In National Marine Sanctuaries And National Estuarine Research Reserves, Catherine E. De Rivera, Greg Ruiz, Jeff Crooks, Kerstin Wasson, Steve Lonhart, Paul Fofonoff, Brian Steves, Steven S. Rumrill, Mary Sue Brancato, Scott Pegau, Doug Bulthuis, Rikke Kvist Preisler, Carl Schoch, Ed Bowlby, Andrew Devogelaere, Maurice Crawford, Steve Gittings, Anson Hines, Lynn Takata, Kristen Larson, Tami Huber, Anne Marie Leyman, Esther Collinetti, Tiffany Pascot, Suzanne Shull, Mary Anderson, Sue Powell

Environmental Science and Management Faculty Publications and Presentations

Nonindigenous species have caused substantial environmental and economic damage to coastal areas. Moreover, the extent and impacts of nonindigenous species are increasing over time. To develop predictive models and to identify which areas should be targeted for impact mitigation or early detection, we need a basic foundation of knowledge about the spatial and temporal patterns of invasions. This project was developed because we lacked the necessary data to rigorously evaluate the patterns of coastal invasions. This collaborative project, between the Smithsonian Environmental Research Center, the National Estuarine Research Reserve System (NERRS) and the National Marine Sanctuary Program (NMSP), established a …

Predicting Childhood Sexual Or Physical Abuse: A Logistic Regression Geo-Mapping Approach To Prevention, Roland K. Tadoum, Kamila Smolij, Michelle A. Lyn, Craig W. Johnson

Faculty, Staff and Student Publications

This study investigates the degree to which gender, ethnicity, relationship to perpetrator, and geomapped socio-economic factors significantly predict the incidence of childhood sexual abuse, physical abuse and non- abuse. These variables are then linked to geographic identifiers using geographic information system (GIS) technology to develop a geo-mapping framework for child sexual and physical abuse prevention.

Using Technology To Teach Technology: Design And Evaluation Of Bilingual Online Physician Education About Electronic Medical Records, Sarah R. Edmonson, Adol Esquivel, Pallavi Mokkarala, Craig W. Johnson, Cynthia L. Phelps

Faculty, Staff and Student Publications

The "EMR Tutorial" is designed to be a bilingual online physician education environment about electronic medical records. After iterative assessment and redesign, the tutorial was tested in two groups: U.S. physicians and Mexican medical students. Split-plot ANOVA revealed significantly different pre-test scores in the two groups, significant cognitive gains for the two groups overall, and no significant difference in the gains made by the two groups. Users rated the module positively on a satisfaction questionnaire.

Response Of Sagebrush Steppe Species To Elevated Co2 And Soil Temperature, Melissa S. Lucash, Blake Farnsworth, William E. Winner

Environmental Science and Management Faculty Publications and Presentations

Elevated atmospheric CO₂ may cause long-term changes in the productivity and species composition of the sagebrush steppe. Few studies, however, have evaluated the effects of increased CO₂ on growth and physiology of species important to this ecosystem. Since the response of plants to elevated CO₂ may be limited by environmental factors, soil temperature was also examined to determine if low soil temperatures limit CO₂ response. To determine how CO₂ and soil temperature affect the growth of species native to the sagebrush steppe, bottlebrush squirreltail [Elymus elymoides (Raf.) Swezey], Thurber needlegrass (Stipa thurberiana Piper), …

Temporal Variation In Nutrient Uptake Capacity By Intact Roots Of Mature Loblolly Pine, Melissa S. Lucash, J. Devereux Joslin, Ruth D. Yanai

Environmental Science and Management Faculty Publications and Presentations

Nutrient uptake is generally thought to exhibit a simple seasonal pattern, but few studies have measured temporal variation of nutrient uptake capacity in mature trees. We measured net uptake capacity of K, NH+ 4, NO 3 −, Mg and Ca across a range of solution concentrations by roots of mature loblolly pine at Calhoun Experimental Forest in October 2001, July 2001, and April 2002. Uptake capacity was generally lowest in July; rates in October were similar to those in April. Across a range of concentrations, antecedent nutrient solution concentrations affected the temporal patterns in uptake in July but not in …

Rcu Semantics: A First Attempt, Paul E. Mckenney, Jonathan Walpole

Computer Science Faculty Publications and Presentations

There is not yet a formal statement of RCU (read-copy update) semantics. While this lack has thus far not been an impediment to adoption and use of RCU, it is quite possible that formal semantics would point the way towards tools that automatically validate uses of RCU or that permit RCU algorithms to be automatically generated by a parallel compiler. This paper is a first attempt to supply a formal definition of RCU. Or at least a semi-formal definition: although RCU does not yet wear a tux (though it does run in Linux), at least it might yet wear some …

Energy Aware Topology Control Protocols For Wireless Sensor Networks, Shilpa Dhar

LSU Master's Theses

Wireless Sensor Network has emerged as an important technology of the future due to its potential for application across a wide array of domains. The collaborative power of numerous autonomousremote sensing nodes self configured into a multi hop network permits in-depth accurate observation of any physical phenomenon. A stringent set of computational and resource constraints make the design and implementation of sensor networks an arduous task. The issue of optimizing the limited and often non-renewable energy of sensor nodes due to its direct impact on network lifetime dominates every aspect of wireless sensor networks. Existing techniques for optimizing energy consumption …

Depth-Shifting Of Shallow Water Guide Source Observations, Lisa M. Zurk, Brian H. Tracey

Electrical and Computer Engineering Faculty Publications and Presentations

In theory, matched field processing offers the significant benefit of higher signal gains and increased localization capability. However, this has not been robustly observed in practice because of inherent uncertainties about details of the shallow water propagation environments which limit the prediction of the channel response. The use of guide sources to directly measure the transfer function between source and receiver arrays has been proposed as a means for reducing mismatch. However, the guide source measurement only provides a measured transfer function at the guide source location. In this paper a method of depth-shifting guide source observations is proposed, making …

Spectra: Secure Power Efficient Clustered Topology Routing Algorithm, Waqaas Siddiqui

Theses

Wireless Sensor Networks (WSNs) have emerged as one of the hottest fields today due to their low-cost, self-organizing behavior, sensing ability in harsh environments, and their large application scope. One of the most challenging topics in WSNs is security. In some applications it is critical to provide confidentiality and authentication in order to prevent information from being compromised. However, providing key management for confidentiality and authentication is difficult due to the ad hoc nature, intermittent connectivity, and resource limitations of the network. Though traditional public keybased security protocols do exist, they need large memory bandwidths and complex algorithms, and are …

Free Vibration Of Sandwich Plates With Viscoelastic Cores, Devlin Hayduke

Theses

The analysis of the free vibration of rectangular sandwich plates with viscoelastic cores is purposed. The analysis focuses on evaluating two displacement theories of sandwich plates for various geometric and material properties and boundary conditions. The first theory was developed for the vibratory bending of unsymmetrical sandwich plates by Rao and Nakra1. The theory is a layerwise theory that models the displacement of the face layers with classic plate theory (i.e. normals to the midplane remain normal to the midplane and undeformed after deformation of the plate) and the continuity of the displacements at the interfaces between the face layers …

Feasability Of Printing Rfid Antennas On Corrugated Paperboard, Juthamart Sayampol

Theses

Radio Frequency Identification (RFID) is a trace-and-track technology using RF signals for communication. RFID system was expected to replace barcodes and magnetic stripes because of its extra benefits for the supply chain: multiple items tracking and operation without line-of-sight. A major limitation of RFID technology was the cost of implementation. Since the existing method for RFID applications - "Slap and Ship" - was costly and time-and-labor consuming, this study was aimed to investigate whether the new method - printed-RFID-antenna - could be used in corrugated packaging industry for cost reduction purpose, and also whether those printed antennas could function under …

Harmonic Analysis Of Causal Operators And Their Spectral Properties, Ilya A. Krishtal, A.G. Baskakov

Faculty Articles, Papers, and Other Scholarship

The definition and study of causal operators are based on the representation theory of group algebras. We study the structure of the spectra of causal operators, obtain conditions for causal invertibility and state criteria for a causal operator to belong to the radical.

Linear Versus Cyclic Inorganic/Organic Hybrid Oligomeric Molecules, Christopher Roland Sparrow

LSU Master's Theses

The synthesis of the new aryl bis(β-diketone) ligand m-phenylenebis(acetylacetone) (m-pbaH2) allowed for complexation with copper(II) to form a 4-membered ring Cu4(m-pba)4. An alternate route, via a phospholene adduct, was implemented after difficulties in preparing the ligand via an azo sulfide conversion from m-phenylenediamine. The connection of two m-pba ligands coordinated to a Cu(II) metal ion causes a distortion along the axial position of the metal center. The pore has a diameter of (Cu-----Cu = 14.317 Å) when viewing opposite metal centers. An open coordination site along Cu(II) axial position may facilitate host-guest binding interactions. The concave shape of the host …

Examining Sponsorship And Cosponsorship In The U.S. House Of Representatives, 1973-2002, Kelly Marie Burke

LSU Master's Theses

The purpose of this paper is to uncover the effects of background characteristics on members of Congress' legislative activity. I intend to measure legislative activity using the total number of bills sponsored and cosponsored during each Congress. Beginning in 1973, this original dataset includes over 6,000 observations and is the most comprehensive study of this subject. Because my dataset begins in 1973, I will be able to identify any effect that the unrestricted ability to cosponsor, which began in 1978, had on legislative activeness. It is my intention to contribute to our scholarly understanding of sponsorship and cosponsorship activity in …

Development Of Non-Dairy Frozen Dessert Containing Soy Protein And Coconut Milk, Luciana Soler

LSU Master's Theses

As consumers have pursued healthier lifestyles in recent years, consumption of soy foods has risen steadily, encouraged by scientific studies showing health benefits from these products. There is a large market for ice cream in the United States. However, since ice cream contains dairy ingredients, a number of Americans are not able to consume it because of dietary habits due to religious beliefs, lactose intolerance, vegetarianism or other related ideologies. For years, these groups of consumers have been able to substitute ice cream with frozen desserts containing soy protein as a substitute for milk protein, but never in the United …

Learning Discrete Hidden Markov Models From State Distribution Vectors, Luis G. Moscovich

LSU Doctoral Dissertations

Hidden Markov Models (HMMs) are probabilistic models that have been widely applied to a number of fields since their inception in the late 1960’s. Computational Biology, Image Processing, and Signal Processing, are but a few of the application areas of HMMs. In this dissertation, we develop several new efficient learning algorithms for learning HMM parameters. First, we propose a new polynomial-time algorithm for supervised learning of the parameters of a first order HMM from a state probability distribution (SD) oracle. The SD oracle provides the learner with the state distribution vector corresponding to a query string. We prove the correctness …

Modeling The Fate And Transport Of Chlorinated Benzenes In Baton Rouge Bayou, Sudheer Nimmagadda

LSU Master's Theses

Knowledge of the fate and transport of chlorinated benzenes is necessary at certain sites for effective remediation of contaminated soils using plants. Current research is examining the capability of wetland plants to catalyze degradation or attenuate migration, but again requires knowledge of the uptake of contaminants from an aqueous environment. A two stage model was used to estimate the rate of uptake of contaminants from sediments. The first stage of the model predicts pollutant leaching rates from sediments to the overlying water, which would then be fed into the plant or bioreactor model systems. In this study the flux from …

Improving Homework In Adolescents With Adhd: Comparing Training In Self- Vs. Parent-Monitoring Of Homework And Study Skills Completion, Kara J. Meyer

LSU Master's Theses

Self-monitoring has been proven to be effective in increasing performance, on task behavior, and homework completion in students with learning disabilities and other academic difficulties. Parent supervision and involvement in homework also has been shown to improve performance. However, the effectiveness of parent vs. self-monitoring of homework completion and test preparation has never been examined in adolescents with Attention-Deficit/Hyperactivity Disorder (ADHD). The current study compared the effectiveness of self- and parent-monitoring of homework and study skills completion in middle school students with ADHD. Students were trained in the SQ4R study strategy and homework completion skills. In one group students monitored …

Use Of Terraced Marsh Habitats By Estuarine Nekton In Southwestern Louisiana, Bryan Paul Gossman

LSU Master's Theses

A variety of techniques have been employed in attempts to mitigate the extensive wetland loss occurring in coastal Louisiana. Marsh terracing is a wetland restoration technique that has rapidly gained in popularity in recent years. Terraces are assumed to benefit coastal restoration by providing areas for emergent plant growth, reducing wave energies, and increasing edge habitat to support nekton communities. The objectives of this study were to: 1) determine the effect of marsh terraces on adjacent water quality and sediment characteristics, 2) compare nekton abundance, species richness, and diversity in edge and open water habitats within terraced and unterraced ponds, …

Seasonal Space Use, Habitat Preference And Survival Of Female Wild Turkeys In A Louisiana Bottomland Hardwood Forest, Walker Blake Wilson

LSU Master's Theses

Female wild turkeys (Meleagris gallopavo) were captured and radio-marked in a bottomland hardwood forest in south-central Louisiana. Turkeys were monitored using radio telemetry from fixed points on Sherburne Wildlife Management Area, Atchafalaya National Wildlife Refuge, and Bayou des Ourses to observe seasonal patterns of space use, habitat preference and survival from 2002-04. The largest mean seasonal home range of 902.87 ha occurred during preincubation (15 Feb – 9 Apr; n = 24) when females typically search for suitable nest sites, and the smallest mean seasonal home range was 434.12 ha, during brood-rearing (1 Jun – 30 Sep; n = 32) …

"Is There A Translator In Teh [Sic] House?": Cultural And Discourse Analysis Of A Virtual Speech Community On An Internet Message Board, Tracy Rene Leblanc

LSU Master's Theses

In the newly emergent field of online ethnography, netspeak and online behavior are quickly becoming the next frontier of linguistic anthropology. The discourse analysis and cultural investigation of the virtual speech community of Penismightier.com reveal several salient aspects of culture through the lens of the internet and online human behavior. This thesis focuses on aspects of language use in the discourse on message board threads on the Penismightier website. The Pen speech community has innovated a lexicon of original and modified techie language, such as unique emoticons and alpha-numeric orthography. The orthographic innovations of this virtual speech community blur the …

Designation Of The Southwest National Wildlife Refuge Complex As Wetlands Of International Importance Under Ramsar, Convention On Wetlands Of International Importance, Mitchell Ward Coffman

LSU Master's Theses

The historical loss and continued threat of loss of Louisiana wetlands is a major environmental concern for the United States and the world. In 1971, the Ramsar Convention, an international environmental treaty was ratified to specifically address conservation planning and land use management issues involving wetlands of the world. Ramsar provides an international designation award called, the Wetlands of International Importance List, which formally acknowledges globally important wetland landscapes. Ramsar outlines specific criterion nominated wetland sites must possess for consideration of this listing.

The Southwest Louisiana National Wildlife Refuge Complex is an excellent candidate for nomination to the Ramsar Convention …