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Ceria-Zirconia Oxide High Temperature Desulfurization Sorbent, Kwang Bok Yi

LSU Doctoral Dissertations

High temperature desulfurization of highly reducing coal-derived gases using ceria and ceria-zirconia sorbents is the primary object of this dissertation research. If H2S concentration is reduced to less than 1 ppmv the product gas may be used with fuel cells and downstream catalytic process. CeO2 is reduced to a non-stoichiometric oxide, which is superior to CeO2 in removing H2S. Moreover, ZrO2 addition to CeO2 to form a solid solution, Ce1-xZrxO2, increases the reducibility of CeO2. This should also result in improved desulfurization performance. Pure CeO2 and sorbents, both commercially available and prepared at LSU, were tested. XRD analysis indicated that …

Dynamic Performance Of Bridges And Vehicles Under Strong Wind, Suren Chen

LSU Doctoral Dissertations

The record of span length for flexible bridges has been broken with the development of modern materials and construction techniques. With the increase of bridge span, the dynamic response of the bridge becomes more significant under external wind action and traffic loads. The present research targets specifically on dynamic performance of bridges as well as the transportation under strong wind. The dissertation studied the coupled vibration features of bridges under strong wind. The current research proposed the modal coupling assessment technique for bridges. A closed-form spectral solution and a practical methodology are provided to predict coupled multimode vibration without actually …

A Historical Study Of The Emergence Of Social Movements: Case Study Of The Sierra Leone Women's Forum In The 1990s, Agnes Mariama Farma

Electronic Theses and Dissertations

The emergence of the Women's Forum during the 1990's in Sierra Leone is analyzed using the political process model proposed by Douglas McAdam. The strength of the indigenous organizations, the political opportunities presented by the civil strife of the period and the emergence of insurgency consciousness on the part of the women of Sierra Leone were identified as significant in contributing to the success of the movement in bringing an end to the civil war and influencing the peace process to address women's issues, indicating the usefulness of this model in analyzing the emergence of social movements in the Sierra …

Replication Of Metal-Based High-Aspect Microscale Structures By High Temperature Micromolding, Dongmei Cao

LSU Doctoral Dissertations

In microsystem technology a large range of materials will be available only after the necessary microfabrication technologies have been developed or adapted. More than a decade ago, the existing microfabrication technologies were restricted to structuring and shaping techniques producing three-dimensional microstructures out of silicon, mostly unfilled plastics or a few pure metals or binary alloys. However, the choice of materials for microcomponents is determined by the function and conditions of use of microsystems. Some microdevices can only work well when made of specific metal components. To meet this need, several microfabrication techniques have been developed, such as second electroforming of …

Modeling The Effects Of Rainfall Intensity And Deep Chiseling On Infiltration And Runoff Within Drainmod For Alluvial Soils, Daniel Nyabiba Moriasi

LSU Doctoral Dissertations

Accurate hydrologic models are needed to aid engineers and researchers design, install and evaluate efficient and cost-effective agricultural water management systems to reduce risks associated with food production, and to reduce soil erosion and water pollution. One model used for the alluvial soils of Louisiana is DRAINMOD. This model does not accurately predict infiltration and runoff for the crusting-prone alluvial soils of Louisiana. The main goal of this study was to modify the current DRAINMOD model to incorporate the effects of rainfall intensity and deep chiseling to improve its estimation of infiltration and surface runoff. The second goal was to …

Chemical Production Complex Optimization, Pollution Reduction And Sustainable Development, Aimin Xu

LSU Doctoral Dissertations

The objective of this research is to propose, develop and demonstrate chemical production complex optimization to determine the optimal configuration of chemical plants in a superstructure of possible plants. The Chemical Complex Analysis System is a new methodology that has been developed to determine the best configuration of plants in a chemical production complex based on the AIChE Total Cost Assessment (TCA) for economic, energy, environmental and sustainable costs. All new, energy-efficient, and environmentally acceptable plants using greenhouse gases that can produce potentially commercial products designed with HYSYS were integrated into the chemical complex using the System. The optimum configuration …

Numerical Methods For The Unsteady Incompressible Navier-Stokes Equations And Their Application To The Direct Numerical Simulation Of Turbulent Flows, Frank Herbert Muldoon

LSU Doctoral Dissertations

Two new methods for the efficient parallel computation of the unsteady incompressible Navier-Stokes equations are presented. Such efficient methods are desired for large scale parallel computations of unsteady turbulent flows such as Direct Numerical Simulations (DNS). The performance of the new methods has a distinct advantage over the artificial compressibility method, in that the methods exhibit robust convergence for a variety of flow problems without extensive need for tuning computational parameters. These methods and others have been implemented in a computer program designed for massively parallel computer architectures, written by the author and used to obtain all results in this …

Entry-Level Job Skills Needed By Wildlife Management Professionals, Billy Warren Delany, Jr.

LSU Doctoral Dissertations

The research purpose was to identify the job skills needed by entry-level wildlife managers, which was accomplished by utilizing a Delphi panel of wildlife management experts from the academic, private and public employment sectors. The Delphi panel was selected from a committee nominated, pool of 81 innovative wildlife management experts. The panel for Rounds One, Two, and Three of this Delphi survey consisted of 31, 32, and 31 members, respectively. The Delphi process involved three survey rounds. Round One consisted of collecting and developing entry-level job skill items from the panel, which resulted in 382 items. Round Two developed initial …

Development Of Dynamic Travel Demand Models For Hurricane Evacuation, Haoqiang Fu

LSU Doctoral Dissertations

Little attention has been given to estimating dynamic travel demand in transportation planning in the past. However, when factors influencing travel are changing significantly over time – such as with an approaching hurricane - dynamic demand and the resulting variation in traffic flow on the network become important. In this study, dynamic travel demand models for hurricane evacuation were developed with two methodologies: survival analysis and sequential choice model. Using survival analysis, the time before evacuation from a pending hurricane is modeled with those that do not evacuate considered as censored observations. A Cox proportional hazards regression model with time-dependent …

Analysis Of Bacterial Diversity And Biogeography At The Central Arizona-Phoenix Long Term Ecological Research (Cap Lter) Site, Brian Anthony Rash

LSU Doctoral Dissertations

The limiting factor involved in past assessments of soil bacterial diversity when using culture-independent techniques has often been the lack of sampling and replication. As a result, analyses of community structural shifts across soil environments have lacked statistical power. In this study, 23 16S rRNA gene clone libraries consisting of over 11,000 clones were constructed from soils at the Central Arizona Phoenix Long Term Ecological Research (CAP LTER) site. Subsequent ARDRA fingerprinting and partial 16S rRNA gene sequencing allowed for a more robust investigation of various components that may explain any observed variations in bacterial species composition. The designated land …

Investigation Of Insect-Weed Interactions In The Rice Agroecosystem, Kelly V. Tindall

LSU Doctoral Dissertations

Interactions between graminaceous weed and insect pests of rice and between management practices for these pests were investigated. Studies were conducted to examine preference and performance of rice water weevil, Lissorhoptrus oryzophilus Kuschel, on several weeds commonly found in rice fields. Several weeds were more preferred than rice, and larvae were present on several dicotyledonous weeds, suggesting the host range of L. oryzophilus is broader than previously thought. Effects of the presence of barnyardgrass, (Echinochloa crus-galli Beauv.), on rice stink bugs, Oebalus pugnax F., and L. oryzophilus populations in rice fields were investigated. Presence of barnyardgrass and the synchrony …

Multifunctional Nanocomposite Co-Containing Diamondlike Carbon Thin Films, Fengli Wang

LSU Doctoral Dissertations

Metal-containing, hydrogenated carbon films (Me-a-C:H) is a special class of nanocomposite films of particular interest since they can be multifunctional through the synergistic interaction of their individual components. Thus, nanocomposite thin films possess high potential in a wide field of engineering applications, especially in small scale devices. A series of multifunctional nanocomposite Co-a-C:H thin films have been synthesized by a hybrid chemical vapor deposition (CVD) and physical vapor deposition (PVD) process to uncover the relationship between synthesis, microstructure and properties. The effects of deposition parameters on the microstructural evolution and properties have been systematically studied. The results showed that the …

Morphological Evolution And Instabilities Of Solid Thin Films And Wires, Wanxi Kan

LSU Doctoral Dissertations

This dissertation can be divided into four parts. In part I (Chapter 2), the diffusion controlled growth of multiple compound phases is studied with the nonlinear Kirkendall effect included. This part analyzes the growth of N compound phases. The method of finding intrinsic diffusion coefficients from only the positions of interfaces is found for two layers. In addition, the asymptotic analysis valid for small concentration gradients is applied to the “multi-foil” method of measuring intrinsic diffusion coefficients and yields an analytic solution for the displacement curve. A bounded solid film on a substrate can breakup from the edge into islands …

The Later Heidegger And Contemporary Theology Of God, Daniel Martino

Electronic Theses and Dissertations

Martin Heidegger was a central figure in 20th century Western philosophy. In evaluating his work from the perspective of the early 21st century it is clear that his influence crossed disciplinary lines. This work aims to address one area where Heidegger's thinking has had tremendous impact -- theology. Specifically, Heidegger's later writings are selectively examined in order to determine the bearing they have on the issue of God.

The route to God, in a strict confessional sense, is neither easy nor direct in the Heideggerian corpus. As a result, the first methodological tack used throughout this study establishes Heidegger's abiding …

A Distributed Quadtree Dictionary Approach To Multi-Resolution Visualization Of Scattered Neutron Data, Rion Dooley

LSU Doctoral Dissertations

Grid computing is described as dependable, seamless, pervasive access to resources and services, whereas mobile computing allows the movement of people from place to place while staying connected to resources at each location. Mobile grid computing is a new computing paradigm, which joins these two technologies by enabling access to the collection of resources within a user's virtual organization while still maintaining the freedom of mobile computing through a service paradigm. A major problem in virtual organization is needs mismatch, in which one resources requests a service from another resources it is unable to fulfill, since virtual organizations are necessarily …

An Assessment And Analysis Of Using Dedicated Short-Range Communications (Dsrc) Technology For Incident Detection On Rural Freeways, Joseph D. Crabtree

University of Kentucky Doctoral Dissertations

This report describes an assessment of using dedicated short-range communications(DSRC) technology to perform travel time monitoring and automated incident detectionon a segment of rural freeway. The assessment used the CORSIM traffic simulation toolto simulate traffic and incidents on a segment of rural freeway. Output data from thesimulation was subjected to post-processing to produce the "probe and beacon" data thatwould be produced by a DSRC-based system. An incident detection algorithm wasdeveloped, which used a travel time threshold and a counter. Travel times exceeding thethreshold incremented the counter, while travel times below the threshold decrementedthe counter (unless it was at zero). An …

Probabilistic Databases And Their Applications, Wenzhong Zhao

University of Kentucky Doctoral Dissertations

Probabilistic reasoning in databases has been an active area of research during the last twodecades. However, the previously proposed database approaches, including the probabilistic relationalapproach and the probabilistic object approach, are not good fits for storing and managingdiverse probability distributions along with their auxiliary information.The work in this dissertation extends significantly the initial semistructured probabilistic databaseframework proposed by Dekhtyar, Goldsmith and Hawkes in [20]. We extend the formal SemistructuredProbabilistic Object (SPO) data model of [20]. Accordingly, we also extend the SemistructuredProbabilistic Algebra (SP-algebra), the query algebra proposed for the SPO model.Based on the extended framework, we have designed and implemented …

Optimization Of Blowing And Suction Control On Naca0012 Airfoil Using Genetic Algorithm With Diversity Control, Liang Huang

University of Kentucky Doctoral Dissertations

Active control of the flow over an airfoil is an area of heightened interest in the aerospace community. Previous research on flow control design processes heavily depended on trial and error and the designers knowledge and intuition. Such an approach cannot always meet the growing demands of higher design quality in less time. Successful application of computational fluid dynamics (CFD) to this kind of control problem critically depends on an efficient searching algorithm for design optimization. CFD in conjunction with Genetic Algorithms (GA) potentially offers an efficient and robust optimization method and is a promising solution for current flow control …

Piano Inside Out: The Expansion Of The Expressive, Technical, And Sonorous Spectrum In Selected Twentieth-Century Art-Music Repertoire For The Modern Acoustic Piano, Mira Kruja

University of Kentucky Doctoral Dissertations

Art Music for the acoustic piano has changed tremendously during the twentieth century. Some of the techniques and skills pianists need to master in order to be able to perform successfully twentieth-century art piano music include: a refined ability to discriminate varied layers of sonorities; sophisticated pedal combinations; a sometimes percussive technique; and superior control of complex metric and rhythmic passages. New combinations of patterns that require specific technical preparation pose substantial pianistic challenges. Todays pianist needs to master a variety of glissandi, chords, or single melody textures played directly on the strings inside the piano and to combine such …

Additional Xps Studies On The Degradation Of Poly(Methyl Methacryalte) And Polystyrene Nanocomposites, Jianxin Du, Jianqi Wang, Shengpei Su, Charles A. Wilkie

Chemistry Faculty Research and Publications

XPS studies have been undertaken on exfoliated nanocomposites of polystyrene and poly(methyl methacrylate). One can clearly see that carbon is lost and that oxygen, silicon and aluminum accumulate at the surface of the degrading polymer. The concentration of aluminum at the surface is very low at the beginning of the experiment but makes a large jump at the same temperature at which carbon is lost and oxygen begins to accumulate at the surface. It appears that the ratio of silicon to aluminum changes as the polymer is lost. A brief discussion is given to explain the origin of oxygen at …

Synthysis Of Polymer/Nano-Droplet Composites From Reverse Microemulsion Polymerization, Liehui Ge

Master's Theses and Doctoral Dissertations

L₁ and L₂ domains of the water/AOT/MMA ternary system were investigated at 22±1°C. Free radical polymerizations were conducted in L₂ domain. Only opaque polymer rods were obtained. Acrylamide, a water soluble monomer, plays a role of co-surfactant which greatly expands the L₂ domain. However, polymerizations only yielded opaque material. SEM showed images of phase separation.

MDOS (2-Methacryloyloxy)ethyl trimethylammonium bis(2-ethylhexyl) sulfosuccinate, was synthesized by ion exchange method. L₁ and L₂ domains of the water/MDOS/MMA ternary system were also investigated at 22±1°C. Free radical polymerizations were conducted in L₂ domain. Transparent polymer was produced. The …

Construct Validation Of An Arabic Version Of The Learning Transfer System Inventory For Use In Jordan, Samer Abdelkarim Khasawneh

LSU Doctoral Dissertations

Organizations in Jordan have invested heavily in employee training. However, these training efforts may not be as effective. One area of particular interest is learning transfer, or the extent to which learning from training is applied on the job. Recent research efforts have led to the development of the Learning Transfer System Inventory (LTSI), the only valid and reliable measure of key transfer system factors. This study validated the constructs of the LTSI for use in Jordan. By doing so, HRD practitioners in Jordan can use such instrument to diagnose early problems with learning transfer, the key to training effectiveness …

Application Of Disturbance Theory To Assess Impacts Associated With A Three-Dimensional Seismic Survey In A Freshwater Marsh In Southwest Louisiana, Aaron Stuard Bass

LSU Doctoral Dissertations

This study examined various practical and theoretical aspects of disturbance in a coastal wetland marsh in southern Louisiana. A literature review approached disturbance ecology from both practical and theoretical perspectives and assessed its applicability to developing broad predictive models. However, specific knowledge of environmental variables, competitive relationships, and the interactive effects of multiple disturbances are required for meaningful usage of these models. The Lacassine National Wildlife Refuge (LNWR) proved to be an ideal laboratory to test various aspects of ecological disturbance theory. I found that the primary disturbances affecting the LNWR have been hurricanes, droughts, water-level manipulations, prescribed burning, oil …

Numerical Modeling Of Strain Localization In Granular Materials Using Cosserat Theory Enhanced With Microfabric Properties, Mustafa Alsaleh

LSU Doctoral Dissertations

Finite element solution in the updated Lagrangian frame is used to investigate the strain localization phenomenon "shear bands" in granular materials. The micro-polar theory was used as the mathematical foundation for the continuum formulations. A laboratory testing results are used for verification and comparison with the numerical simulation. Silica sand and glass beads with different shape indices, size and surface roughness were tested under biaxial and triaxial loading conditions to investigate the physics of the problem. The shape non-uniformity and the irregular surface roughness of the grains were studied carefully to evaluate their effect on shear band characteristics. To this …

An Analysis Of György Ligeti's Nonsense Madrigals, Dennis Malfatti

LSU Doctoral Dissertations

While other contemporary composers have written works called madrigals, Ligeti's Nonsense Madrigals are truly unique as exemplified by the myriad of influences that went into their creation, the technical challenges of their performance, and in the aesthetic result, one which is incomparable to most musical compositions past or present including works by Ligeti himself. Ligeti’s compositional style in these works include the parodying of compositional techniques from the 14th century as well as the rhythmic provocativeness of jazz. The use of parody in these works is compatible with Ligeti’s choice of texts which includes literary parodies by Lewis Carroll. In …

Internal Revenue Service Restructuring And Reform Act Of 1998: A Test Of New Public Management, William Meriwether Vandenburgh

LSU Doctoral Dissertations

The enactment of the 1998 Internal Revenue Service (IRS) Reform Act resulted directly from perceived lapses in the federal taxation administration, which was publicly highlighted in Congressional hearings. Congress reacted by fundamentally altering the IRS’s implementation of the Internal Revenue Code (for the first time since 1952). The Joint Committee on Taxation noted that the overall objective of the 1998 IRS Reform Act was to have “a well-run IRS [which] is critical to the operation of our tax system.” From a public administration paradigm, the IRS moved from a traditional tax management methodology to a New Public Management (NPM) methodology. …

A National Set Of Competencies For Paraprofessionals In Residential College Or Living/Learning Programs, Debora Elise Baker

LSU Doctoral Dissertations

A competency model, for supporting student learning, was developed for the paraprofessional position (R.A., Community Assistant, etc.) in residential college or living/learning programs. The researcher developed the model through a two-stage process. In the first stage, the critical incident technique was applied utilizing the experiences of paraprofessionals at 15 different universities to develop an initial set of competencies and related tasks. In the second stage, the Delphi Technique was used to allow faculty and staff from 17 universities to refine and validate the competencies and related tasks. The final competency model includes twelve competencies related to linking hall community programs …

Tissue Culture And Transformation Of Introducing Genes Useful For Pest Management In Rice, Shuli Zhang

LSU Doctoral Dissertations

Sheath blight (SB), caused by Rhizoctonia solani K¨¹hn, is a major rice disease internationally and in the southern rice area of the Unites States, including Louisiana. Breeders have incorporated partial resistance into commercial rice varieties to control the disease, but a higher level of resistance is needed. It has been demonstrated that the pathogenesis-related (PR) proteins ¦Â-1, 3-glucanase and chitinase are components of effective defense mechanisms for protecting plants against fungal pathogens. This research was conducted to co-transform the ¦Â-1, 3-glucanase, chitinase and bar genes into the rice variety Taipei 309 using the hpt gene for resistance to hygromycin B …

Modeling The Hydrologic And Particulate Loadings From Paved Urban Surfaces, Chad Michael Cristina

LSU Doctoral Dissertations

This dissertation details the results of recent investigations concerning non-colloidal particulate matter found in urban rainfall-runoff and urban snowmelt. Three forms of the power law model (PLM) were used to model particle number density. It was found that significant model error could be introduced into PLMs when the median diameter particle was used to estimate the number of particles per interval, but the SSE of continuous PLMs could be significantly reduced through the use of correction factors when the sieve interval was large (P<0.05). Additionally, a multiple PLM analysis may be more appropriate than a single PLM analysis when changes in particle population occur within a single gradation. PLMs were also used to model the relationship between cumulative granulometric mass and cumulative particulate-bound metal mass. The use of such calibrated PLMs provided considerable cost reduction when compared to conventional direct measurements of particulate-bound metal mass. A first flush analysis indicated that only events with average volumetric flow rates approaching 1 L/min/m of drainage width exhibit a rapid depletion of particulate matter consistent with the concentration-based definition of the first flush. An analysis of particle separation mechanisms indicated that 90% of these particles, by mass, could be removed from the discharge with detention times of 30 min and 120 min for snowmelt and rainfall-runoff, respectively, in a typical roadside drainage system. It was also found that the kinematic wave model could accurately model significant aspects of rainfall-runoff events in traffic-impacted watersheds provided that abstractions were incorporated into the modeling process. For this watershed the source of abstraction was attributable to vehicular traffic. For high-intensity events with more than 10 vehicles per runoff volume (VPV) the runoff coefficient varied between 0.6 and 0.9 while for low-intensity events with fewer than 10 VPV the coefficient ranged between 0.2 and 0.4.

Numerical Simulation And Field Verification Of Inclined Piezocone Penetration Test In Cohesive Soils, Lei Wei

LSU Doctoral Dissertations

A large strain finite element analysis is performed to analyze the effect of soil anisotropy on the inclined piezocone penetration test in normally consolidated cohesive soils. The piezocone penetration is numerically simulated using the commercial finite element code ABAQUS. The saturated clay is modeled as a two-phase material and the effective stress principle is used to describe its behavior. A frictional contact interface utilizing Mohr-Coulomb's theory was chosen to represent interactions between the surface of the cone and the soil. The Anisotropic Modified Cam Clay Model (AMCCM) by Dafalias (1987) was chosen and implemented into ABAQUS through user subroutine UMAT. …