Digital Commons Network^™

Novel Approach To Integrate Can Based Vehicle Sensors With Gps Using Adaptive Filters To Improve Localization Precision In Connected Vehicles From A Systems Engineering Perspective, Abhijit Vasili

USF Tampa Graduate Theses and Dissertations

Research and development in Connected Vehicles (CV) Technologies has increased exponentially, with the allocation of 75 MHz radio spectrum in the 5.9 GHz band by the Federal Communication Commission (FCC) dedicated to Intelligent Transportation Systems (ITS) in 1999 and 30 MHz in the 5.9 GHz by the European Telecommunication Standards Institution (ETSI). Many applications have been tested and deployed in pilot programs across many cities all over the world.

CV pilot programs have played a vital role in evaluating the effectiveness and impact of the technology and understanding the effects of the applications over the safety of road users. The …

The Ecological Role Of Cassiopea In Shallow Mangrove Habitats, David Marcel Durieux

USF Tampa Graduate Theses and Dissertations

Upside-down jellyfish, Cassiopea sp., can be locally abundant in shallow mangrove habitats throughout the tropics and subtropics. Unlike other jellyfish, Cassiopea sp. are epibenthic. Due to this unique lifestyle and their ability to achieve high population densities, an understanding is needed of their ecological impacts both individually and in aggregations, particularly given that Cassiopea sp. ranges are expanding poleward due to global climate change. We quantified the fluid flow produced by Cassiopea sp. feeding currents and found that an average-sized Cassiopea sp. can transport over 200 l/h of water in the vertical excurrent jet of their feeding current. Populations of …

Mechanistic Insight Into Β-Lactamase Catalysis, Inhibitor Design And Resistance, Michael Trent Kemp

USF Tampa Graduate Theses and Dissertations

The emergence of antibiotic resistance and spread of Gram negative bacteria poses a very real health threat to the public. The main mode of resistance within Gram negative bacteria is the production of β-lactamase enzymes that catalyze the breakdown of β-lactam antibiotics through a hydrolysis mechanism. Once the β-lactam ring is hydrolyzed and opened, the drug loses its efficacy, which allows for the bacteria to grow and proliferate uninhibited. These β-lactamase enzymes are organized into four categories based on the Ambler classification, with classes A, C and D being denoted as serine-based β-lactamase enzymes. Class B is composed of metalloenzymes …

Light Harvesting In Photoactive Guest-Based Metal-Organic Frameworks, Christopher R. Mckeithan

USF Tampa Graduate Theses and Dissertations

Harvesting sunlight as a clean and renewable energy source has long been a goal of the scientific community. One potential route for developing artificial light harvesters is using a bioinspired approach which utilizes the critical features found in these natural systems. Such features include a way in which to capture a broad range of the solar spectrum, fixed distance and orientation of redox pairs to facilitate efficient directional transfer of electrons, transfer of electrons to a terminal acceptor, and recovery of the systems for repeated use. Metal organic frameworks (MOFs) are attractive candidates for developing light harvesting systems due their …

Computationally Driven Design Of Shape-Controlled Polymeric Nanostructures, Davindra Tulsi

USF Tampa Graduate Theses and Dissertations

In the realm of shape control involving synthetic soft materials, block copolymers are ubiquitously exploited due to their ability to spontaneously self-assemble into a plethora of morphologies. The growing need in areas such as drug delivery, lithography, and microelectronics to generate new nanostructures demands ever finer control of copolymer self-assembly. It is desirable to better control the shape and size of soft nanostructures, with minimal post processing techniques to assert stability.

While there is an abundance of literature on diblock copolymer assembly, few relationships exist for sequence-controlled copolymers. It is well known that biological macromolecules are highly sequence specific and …

Contribution Of Retinal Ganglion Cells To Brown-Norway Rat Spatiotemporal Visual Perception And The Electroretinogram, Nicholas P. Johnson

USF Tampa Graduate Theses and Dissertations

Retinal Ganglion Cells (RGCs) are the sole cells through which visual information is transmitted from the eye to the brain. As such, RGC dysfunction has a dramatic effect on vision and perception. Retinal neurodegenerative diseases, such as glaucoma, are one of the leading causes of blindness worldwide. The study of these diseases requires well-characterized models in order to swiftly and effectively develop diagnostic tools and therapeutics. This dissertation aims to characterize specific properties of the visual system of the Brown-Norway rat. First, visual processing was evaluated in awake, freely moving rats. Contrast sensitivities of Brown-Norway rats were characterized by discrimination-driven …

Efficient Management Of Nitrogen And Phosphorus At Centralized Water Reclamation Facilities, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

A variety of process configurations are employed at municipal water reclamation facilities (WRFs), such as 5-stage Bardenpho, oxidation ditch, modified Ludzack-Ettinger (MLE) process, and sidestream recycle. However, all of these configurations face certain challenges in achieving optimum treatment of nitrogen and phosphorus. In this dissertation, the driving objectives were to: (1) quantitatively assess the fate of nitrogen and phosphorus (mass fluxes) at a treatment facility that employs biological nutrient removal, aerobic digestion, and sidestream recycle, (2) evaluate the performance of a microbial fuel cell (MFC) as a technology to remove nitrogen from sidestreams at a treatment plant that employs that …

Copper Electrodeposition Assisted By Hydrogen Evolution For Wearable Electronics: Interconnections And Fiber Metallization, Sabrina M. Rosa Ortiz

USF Tampa Graduate Theses and Dissertations

The current project focused on studying an innovative and novel method, called hydrogen evolution assisted (HEA) electroplating, for rapid and localized electrochemical copper deposition that can be applied for integration of electronic circuits to printed circuit boards (PCBs) and fabrics for developing smart textile (e-textile) and advanced wearable electronics. This method has shown a great enhancement to the deposition rate of copper compared to the conventional galvanostatic electroplating method, opening new venues for patterning conductive circuit layouts on fabrics and for the direct integration of devices into fabrics. While due to the slow growth rate and low mechanical flexibility of …

Pressure Retarded Osmosis: A Potential Technology For Seawater Desalination Energy Recovery And Concentrate Management, Joshua Benjamin

USF Tampa Graduate Theses and Dissertations

Currently, a significant challenge with reverse osmosis-based desalination is reducing the energy consumption and environmental impacts of the process. This project analyzed the viability of using pressure-retarded osmosis (PRO) for energy recovery in seawater desalination facilities using brine concentrate (the draw solution) and other water sources (the feed solution) such as wastewater effluent. The primary goal of this project is to decrease the cost and overall energy consumption of seawater desalination through PRO-based energy recovery. Process modeling, statistical and sensitivity analysis, energy and cost analysis, geospatial and GIS analysis, laboratory-scale testing, water quality analysis, SEM-EDS microscopy, computational fluid dynamics (CFD), …

Crystal Structure Prediction Of Materials At Extreme Conditions, Ashley S. Williams

USF Tampa Graduate Theses and Dissertations

The prediction of the structure of a crystal given only the constituent elements is one of the greatest challenges in both materials science and computational science alike. If one were to try to predict a novel crystal by brute force, meaning by arranging the atoms in every possible position of the unit cell and optimizing the geometry to find the energy minima of the potential energy surface, the amount of computer resources required to complete the calculation on the timescale of a few years would vastly exceed the currently installed computational capacity of the entire world. Fortunately, several methods have …

The Photophysical Studies Of Transition Metal Polyimines Encapsulated In Metal Organic Frameworks (Mof’S), Jacob M. Mayers

USF Tampa Graduate Theses and Dissertations

Light harvesting systems provide a platform that converts solar energy into other forms of energy. One of the most common examples of photon capturing and conversion into chemical energy is observed in photosynthetic organisms in both Eurkaroyic and Prokaryotic domains. Nature provides a model for successful light harvesting platforms which includes the compartmentalization of antenna complexes that contain separated donor and acceptor pairs that participate in efficient electron transfer processes. In order to mimic such systems, crystalline porous materials that exhibits regular cavities and pore dimensions provides an excellent starting place. Metal organic frameworks (MOFs) are a class of porous …

Shortcut Nitrogen Removal In Photo-Sequencing Batch Reactor, Experiments, Dynamic Model And Full-Scale Design, Sahand Iman Shayan

USF Tampa Graduate Theses and Dissertations

Nitrogen is one of the essential elements for life; however, inefficient use of nitrogen creates major environmental problems. Nitrogen-rich streams from urban areas, farms, and wastewater treatment plants (WWTPs) lead to surface and groundwater contamination, resulting in eutrophication, hypoxia, and notable environmental, public health and economic damage. Ammonia is a form of nitrogen that can be created during industrial or biological nitrogen fixation or decomposition of biomass. Anaerobic digesters (ADs) in WWTP generate biogas from collected sludge from primary and secondary clarifiers to achieve energy recovery in the plant. However, sidestream effluent from dewatering AD sludge contains high concentrations of …

A System Architecture For Water Distribution Networks, Noha Abdel-Mottaleb

USF Tampa Graduate Theses and Dissertations

This dissertation examines structure-function relationships of water distribution networks (WDNs), with focus on improving the decision-making process for water utilities. WDNs are lifeline infrastructure systems, necessary for the functioning of cities. Yet water utilities around the world struggle with emerging challenges that include but are not limited to aging infrastructure components, limited budgets, increased interdependencies between infrastructure systems, increased rates of urbanization, and increasing extreme weather conditions. This is why enhancing the performance of WDNs is a priority for water utilities around the world. This research begins to delineate a system architecture for WDNs and evaluates the use of various …

Examining The Effects Of Hydrology And Reclaimed Water Application On Nutrient Retention In Wetlaculture Mesocosms In Southwest Florida, Andrew Wilson

USF Tampa Graduate Theses and Dissertations

The substantial increase among agricultural and urban land use over the past century is widely regarded as the leading cause in a variety of negative environmental impacts, particularly regarding eutrophication of both salt and fresh surface waters. Usage of both synthetic and natural fertilizers on agricultural fields and residential lawns has increased significantly in order to achieve maximum crop yield and green lawns. The nitrogen and phosphorus in these fertilizers inevitably run off the landscape and into downstream surface waters. The geographic scale of this issue makes it a challenge to overcome, as targeting specific sources/polluters is nearly impossible. Landscape-scale …

Learning State-Dependent Sensor Measurement Models To Improve Robot Localization Accuracy, Troi André Williams

USF Tampa Graduate Theses and Dissertations

This dissertation proposes a novel method called state-dependent sensor measurement models (SDSMMs). Such models dynamically predict the state-dependent bias and uncertainty of sensor measurements, ultimately improving fundamental robot tasks such as localization. In our first investigation, we introduced the state-dependent sensor measurement model framework, described their properties, stated the input and output of these models, and described how to train them. We also explained how to integrate such models with an Extended Kalman Filter and a Particle Filter, two popular robot state estimation algorithms. We validated the proposed framework through a series of localization tasks. The results showed that our …

Metastatic Mat Phenotype Driven By Noncanonical Epha2 Signaling In Melanoma, Chao Zhang

USF Tampa Graduate Theses and Dissertations

Acquired BRAF/MAPK/extracellular signal‒regulated kinase inhibitor resistance in melanoma results in a new transcriptional state associated with an increased risk of metastasis. In this study, we identified noncanonical ephrin receptor (Eph) EphA2 signaling as a driver of the resistance-associated metastatic state. We used mass spectrometry‒based proteomic and phenotypic assays to demonstrate that the expression of active noncanonical EphA2-S897E in melanoma cells led to a mesenchymal-to-amoeboid transition driven by Cdc42 activation. The induction of mesenchymal-to-amoeboid transition promoted melanoma cell invasion, survival under shear stress, adhesion to endothelial cells under continuous-flow conditions, increased permeability of endothelial cell monolayers, and stimulated melanoma transendothelial cell …

An Assessment And Exploration Of Recent Methodological Advances In Safety Data Analysis, Suryaprasanna Kumar Balusu

USF Tampa Graduate Theses and Dissertations

The injury severity and frequency of traffic crashes can be further reduced by implementing appropriate traffic safety measures. Several advanced methodologies have been developed in the recent decades to more accurately identify the factors affecting road safety. Such methodologies have helped policy makers formulate appropriate safety measures directed toward increasing seatbelt and helmet use, reducing speed limits in school zones, implementing adolescent driver programs, and so on. However, each methodological approach has its own strengths and weakness and could lead to different inferences. This dissertation assesses and explores a number of recently developed methodologies and their application to traffic safety …

Spin Coupling In Magnetic Core - Shell Nanoparticles, Corisa Kons

USF Tampa Graduate Theses and Dissertations

Magnetic nanoparticles (NPs) have garnered much interest due to the unique properties that emergewhen compared to their bulk counterparts. In particular, core-shell (CS) NPs offer the ability to tailor the magnetic properties of the system through careful selection of core and shell constituent materials. In this work, the magnetic ordering of CS NPs with contrast in core/shell features (moment, anisotropy, coercivity, etc.) have been investigated using a combination of X-ray magnetic circular dichroism spectroscopy (XMCD) and polarized small angle neutron scattering (SANS). First, temperature-dependent analyses of XMCD and SANS studies were carried out for CS NPs featuring a core composed …

Human-Centric Cybersecurity Research: From Trapping The Bad Guys To Helping The Good Ones, Armin Ziaie Tabari

USF Tampa Graduate Theses and Dissertations

The issue of cybersecurity has become much more prevalent over the last few years, with a number of widely publicised incidents, hacking attempts, and data breaches reaching the news. There is no sign of an abatement in the number of cyber incidents, and it would be wise to reconsider the way cybersecurity is viewed and whether a mindset shift is necessary. Cybersecurity, in general, can be seen as primarily a human problem, and it is for this reason that it requires human solutions and tradeoffs. In order to study this problem, using two perspectives; that of the adversaries and that …

Modeling, Identification, And Stability Analysis Of Inverter-Based Resources Integrated Systems, Miao Zhang

USF Tampa Graduate Theses and Dissertations

More and more stability issues have been observed in real-world inverter-based resources (IBRs) power systems. Stability analysis is highly requested in the industrial area. To have an insight into the root causes of stability issues within IBR integrated systems, e.g, PV, wind, and battery storage systems, the dynamic characteristics should be fully understood.

The approaches are different when considering the presupposition of investigated IBR systems. A reduced-order analytical model of the IBR integrated system can be built if the IBR is treated as a white box. Since the parameters and control structures of converter control can be accessed. This analytical …

Theory And Algorithms For Systems Optimization, Vahid Mahmoodian

USF Tampa Graduate Theses and Dissertations

This dissertation presents four sets of contributions in the field of theory and algorithms for system optimization. In the first set, we introduce a simulation optimization method for redistributing bikes in a free-floating bike sharing system. The second set of contributions is a framework for batching queries in large databases to optimize the data retrieval time. The third set includes two branch-and-bound algorithms to solve minimum multiplicative programming problems and one branch-and-bound algorithm to solve the maximum form of the mentioned problems. At last, the fourth set presents an approach to fairlyassign delivery tasks in an outsourcing last-mile delivery system …

Microencapsulation Of Thermochromic Materials For Thermal Storage And Energy Efficiency Of Buildings, Abdullatif Hakami

USF Tampa Graduate Theses and Dissertations

Thermochromism and thermochromic materials research and development are of great interest in various applications such as energy efficient building structures, textile industries, thermal or heat storage, antique maintenance processing, and sensors, etc. In general, thermochromic materials have been classified into four categories, including inorganic, organic, polymeric, and hybrid systems, based on their unique material properties and operating conditions. Thermochromic materials have been prepared via different physico-chemical techniques with some of them combined to maximize the yield, stability, and efficiency of the prepared TCMs. Pristine TCMs often undergo severe degradation when exposed to various external stimuli including UV irradiation from sunlight …

Investigation Of Immobilized Enzymes In Confined Environment Of Mesoporous Host Matrices, Xiaoliang Wang

USF Tampa Graduate Theses and Dissertations

Enzyme immobilization in metal-organic frameworks (MOFs) as a promising strategy, is attracting the interest of scientists from different disciplines with the expansion of MOF’s development. Different from other traditional host materials, their unique strengths of high surface areas, large yet adjustable pore sizes, functionalizable pore walls, and diverse architectures make MOFs an ideal platform to investigate hosted enzymes, which is critical to the industrial and commercial process. In addition to the protective function of MOFs, the extensive roles of MOFs in the enzyme immobilization are being well-explored by making full use of their remarkable properties like well-defined structure, high porosity, …

Internship And Job Acquisition Experiences Of Veterans In A Graduate Cybersecurity Degree Program, Stephen P. Gary

USF Tampa Graduate Theses and Dissertations

My purpose in this qualitative inquiry was to explore how student veterans experience cybersecurity internships and job acquisitions. I chose Schlossberg’s individual transition theory viewed through a constructivist lens to support the inquiry. Five participants, who completed graduate cybersecurity internships and acquired cybersecurity positions, provided responses. I employed semi-structured interviews to collect data from the participants. I engaged reflexive thematic analysis to guide my data analysis. Based on my analysis, I generated the following discoveries applicable to the inquiry: (a) opportunities for developing practical experience are regarded as essential for successful participation in an internship; (b) a flexible internship program …

Online Perceptions Of Panamanian Prisons And Incarcerated Persons: An Analysis Of Youtube User Comments, Mahaleth J. Sotelo

USF Tampa Graduate Theses and Dissertations

The purpose of this study is to explore and understand the frameworks in which prisons and incarcerated persons are discussed amongst commenters under YouTube videos displaying media on Panamanian prisons. The study incorporates a mixed methods approach by conducting a general content analysis of YouTuber comments to address themes within the discussion. Additionally, these themes were quantified and modeled using predictive variables collected such as number of comment likes, number of comment dislikes, and number of comment replies, alias type (screen name or name-like), presence of profile picture, and profile picture type. The themes found were 1) punitive, 2) justifying …

Sanitation Marketing In Uganda: The Impact Of Gender On Participation And Outcomes, Elizabeth Vicario

USF Tampa Graduate Theses and Dissertations

Uganda aims to reach universal access to basic sanitation under Sustainable Development Goal #6, but achieving this target by 2030 would require doubling the annual rate of progress. Women are disproportionately affected by poor sanitation due to their health needs and risk of facing violence, but they have historically been excluded from sanitation planning. Low household demand and poor service delivery have stalled progress in Uganda. Market-based sanitation (MBS) is a novel method of developing a sanitation market through stimulating demand and supporting a competitive atmosphere for product and service providers. This research studies the sanitation marketing activities implemented by …

Application Of Gold Nanoshells For Photothermal Therapy In Lung Cancer Cells, Yva K. Luc

USF Tampa Graduate Theses and Dissertations

Lung cancer is the leading cause of cancer deaths in the world. For the year 2020, it was estimated 1.8 million deaths were due to lung cancer alone, making it more lethal than breast cancer and prostate cancer combined. For the year 2021, it is estimated 235,760 new cases of lung cancer and 50% will lead to death. The primary cause of lung cancer is due to cigarette smoking, which accounts for 80% of all lung cancer deaths. Lung cancer screening relies on only different methods, biopsy, bronchoscopy, ultrasound, chest x-ray film, and sputum cytology. These techniques are used to …

Community Assessment Of Water Perceptions And Household Point-Of-Use Treatment Methods In Madagascar, Isabella Rose Silverman

USF Tampa Graduate Theses and Dissertations

One in four people around the world do not have access to safe drinking water, which means that two billion people globally lack access. In high-income countries, 0.02% of yearly deaths are attributed to unsafe water sources; however, an alarming 10.6% of deaths occur in Madagascar, for the same reason.

To achieve Sustainable Development Goal 6: Ensure access to water and sanitation for all, a collaboration between public health and engineering is critical. Within the public health sector, social marketing is commonly utilized to address a problem by using commercial marketing principles to change behavior for the good of society. …

Laboratory Examination Of Lead Weights Harvested From Pitcher Pumps In Eastern Madagascar, Madelyn Wilson

USF Tampa Graduate Theses and Dissertations

Previous sampling campaigns in Tamatave, Madagascar, conducted by the University of South Florida (USF) have identified lead contamination in drinking water sourced from self-supply pitcher pumps. The pitcher pump piston and foot valves were identified as the primary source of lead contamination since they are often manufactured from recycled lead acid batteries. The previous field sampling technique consisted of collecting an aliquot of a 10-15-liter composite sample from the pitcher pump for dissolved lead analysis; however, this technique (1) neglects the contribution of particulate lead, (2) does not properly account for the effects of water stagnation inside the pitcher pump …

Use Of Biochar And Zeolite For Landfill Leachate Treatment: Experimental Studies And Reuse Potential Assessment, Thanh Thieu Lam

USF Tampa Graduate Theses and Dissertations

Leachate is a highly colored liquid waste product of landfills that contains high concentrations of ammonia nitrogen (NH4+-N), refractory organic matter, and heavy metals. It is commonly disposed to local publicly owned treatment works (POTWs). With these potent characteristics, it interferes with the physical, biological, and chemical treatment processes within POTWs. Sequencing batch biofilm reactors (SBBR) and hybrid subsurface flow constructed wetlands (CW) have been used in the past to treat landfill leachate, but their design and performance can still be optimized. Addition of low-cost adsorbent materials to SBBRs and CWs, such as biochar and zeolite, have the potential to …