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Process Optimization And Consumable Development For Chemical Mechanical Planarization (Cmp) Processes, Subrahmanya R. Mudhivarthi

USF Tampa Graduate Theses and Dissertations

Chemical Mechanical Planarization (CMP) is one of the most critical processing steps that enables fabrication of multilevel interconnects. The success of CMP process is limited by the implementation of an optimized process and reduction of process generated defects along with post CMP surface characteristics such as dishing and erosion. This thesis investigates to identify various sources of defects and studies the effect of factors that can be used to optimize the process. The major contributions of this work are: Understanding the effect of temperature rise on surface tribology, electrochemistry and post CMP pattern effects during the CMP process; investigating the …

Linkage-Based Prosthetic Fingertips: Analysis And Testing, Issa A. Ramirez

USF Tampa Graduate Theses and Dissertations

This thesis consists of the research on linkage-based fingertips for prosthetic hands. These fingertips consists of small polycentric mechanisms attached to what would be the pulp in normal anatomical fingers. These mechanisms allow the prosthetic hand to conform to the shape of objects during grasp. The goal of these prosthetic fingertips is to maximize the functionality of the hand while minimizing the number of inputs that the user has to control. The stability of the fingertip mechanisms is analyzed using the principle of virtual work. From this analysis we are able to show that the fingertip mechanism is stable for …

Automatic Geo-Referencing By Integrating Camera Vision And Inertial Measurements, Duminda I. B Randeniya

USF Tampa Graduate Theses and Dissertations

Importance of an alternative sensor system to an inertial measurement unit (IMU) is essential for intelligent land navigation systems when the vehicle travels in a GPS deprived environment. The sensor system that has to be used in updating the IMU for a reliable navigation solution has to be a passive sensor system which does not depend on any outside signal. This dissertation presents the results of an effort where position and orientation data from vision and inertial sensors are integrated. Information from a sequence of images captured by a monocular camera attached to a survey vehicle at a maximum frequency …

Determinants Of Female Labor Force Participation In Venezuela: A Cross-Sectional Analysis, Betilde Rincon De Munoz

USF Tampa Graduate Theses and Dissertations

The purpose of this study is to fill the gap in research about women in Venezuela by investigating the determinants of their labor force participation between 1995 and 1998. The Central Office of Statistics and Information in Venezuela provides cross-sectional data collected semiannually about individual, demographic, socio-economic and geographical characteristics of individuals living in Venezuela during this period. This study uses binomial and multinomial logit models to test a number of hypotheses. First, the full sample of women between 15 and 60 years old is used to investigate the importance of individual, demographic, socioeconomic, and geographical characteristics in the labor …

Destabilization And Characterization Of Libh4/Mgh2 Complex Hydride For Hydrogen Storage, Luis A. Rivera

USF Tampa Graduate Theses and Dissertations

The demands on Hydrogen fuel based technologies is ever increasing for substitution or replacing fossil fuel due to superior energy sustainability, national security and reduced greenhouse gas emissions. Currently, the polymer based proton exchange membrane fuel cell (PEMFC), is strongly considered for on-board hydrogen storage vehicles due to low temperature operation, efficiency and low environmental impact. However, the realization of PEMFC vehicles must overcome the portable hydrogen storage barrier. DOE and FreedomCAR technical hydrogen storage targets for the case of solid state hydrides are: (1) volumetric hydrogen density > 0.045 kgH2/L, (2) gravimetric hydrogen density > 6.0 wt%, (3) operating temperature < 150 degrees C, (4) lifetimes of 1000 cycles, and (5) a fast rate of H2 absorption and desorption. To meet these targets, we have focused on lithium borohydride systems; an alkali metal complex hydride with a high theoretical hydrogen capacity of 18 wt.%.

It …

Automatic Generation Of Global Phase Equilibrium Diagram From Equation Of State, Keyurkumar S. Patel

USF Tampa Graduate Theses and Dissertations

A computational tool that uses an automated and reliable procedure for systematic generation of global phase equilibrium diagram (GPED) is developed for binary system using equation of state and its extension to the ternary system is discussed. The proposed algorithm can handle solid phase and also can predict all major six types of phase diagrams. The procedure enables automatic generation of GPED which incorporates calculations of all important landmarks such as critical endpoints, quadruple point (if any), critical line, liquid-liquid-vapor line (if any), solid-liquid-liquid line (if any) and solid-liquid-vapor line. The method is also capable of locating all azeotropic phenomena …

Design Of Surface Acoustic Wave Sensors With Nanomaterial Sensing Layers: Application To Chemical And Biosensing, Subramanian K.R.S Sankaranarayanan

USF Tampa Graduate Theses and Dissertations

Surface acoustic wave (SAW) sensors detect chemical and biological species by monitoring the shifts in frequency of surface acoustic waves generated on piezoelectric substrates. Incorporation of nanomaterials having increased surface area as sensing layer have been effective in improving the sensitivity as well as miniaturization of SAW sensors. Selectivity, sensitivity and speed of response are the three primary aspects for any type of sensor. This dissertation focuses on design and development of SAW devices with novel transducer configurations employing nanomaterial sensing layers for enhanced sensing, improved selectivity, and speed of response. The sensing mechanism in these SAW sensors is a …

Reconstructing The Past: Heritage Research And Preservation Activities In Tampa Bay Communities, Courtney Ross Spillane

USF Tampa Graduate Theses and Dissertations

There are numerous ways in which cultural heritage can be preserved, such as: physical museums, virtual museums, tours of historic homes, and community meetings. For this project, I participated in and observed heritage preservation activities in two very different communities--- Sulphur Springs and Seminole Heights in Tampa, Florida. My internship appointment was with OSHNA (Old Seminole Heights Neighborhood Association) under the direction of Dr. Steve Gluckman. My primary focus was assisting heritage preservation committee members in each of the two communities with heritage preservation projects specific to their community needs and interests. One project is the development of a heritage …

Scissors Paper Rock, Barbara St. Clair

USF Tampa Graduate Theses and Dissertations

Scissors Paper Rock is based on the true story of Amy Biel, a young and idealistic American woman who went to South Africa to support the political effort against Apartheid. She worked there as a volunteer organizer during a time of great political turmoil, and was days away from returning home to the United States, when she was violently killed in a riot. While Amy's death was not an accident--four men were found guilty for taking her life--it is certainly possible to think of her death as a tragedy. Amy's idealism and belief in her power to do good, allowed …

Crystal Engineering Of Co-Crystals And Their Relevance To Pharmaceutical Forms, Tanise R. Shattock

USF Tampa Graduate Theses and Dissertations

The research presented herein focus upon crystal engineering of co-crystals with an emphasis upon the exploration of co-crystals in the context of delineation of the reliability of hydrogen bonded supramolecular synthons and their hierarchies. The approach involves a combination of systematic Cambridge Structural Database analysis and a series of model co-crystal experiments. In addition, the viability of solid state methodologies toward supramolecular synthesis of co-crystals and the effect on polymorphism is also addressed. The application of the acquired knowledge is towards the crystal engineering of pharmaceutical co-crystals. The rational design and synthesis of pharmaceutical co-crystals accomplished by the selection of …

Greater Flexibility, Greater Growth: A Comparative Study Of Labor And Capitalist Models In Japan, Germany And The United States, Jay Arthur Thompson

USF Tampa Graduate Theses and Dissertations

After the end of the Second World War, three major economic powers emerged. Japan in Asia, Germany in Europe, and the United States in North America, quickly became the economic engines of their respective regions. Japan, with its "catch-up" and producer centered economy, grew so fast and so large, that there were worries in America that the Japanese would end up winning the economic war. West Germany, supported by the capitalist world, became a miracle economy, and the economic power of the European Union. In the past fifteen years however, these two economies have faltered and stagnated. In Japan, the …

Sensitivity Analysis Of The Transit Boardings Estimation And Simulation Tool (Tbest) Model, Dajana Vuckovic

USF Tampa Graduate Theses and Dissertations

Public transportation, although modest in the United States carrying about 2 percent trips, still serves millions of people as the main and only means of transportation. Recently released data set by Census, the 2006 American Community Survey (ACS) shows the main mode of travel for work commute is not surprisingly the automobile with over 86 percent and public transportation with nearly 5 percent users. Transit agencies strive to provide effective, convenient, and desirable transport. Because of the constant changes in our environment, being able to predict the response of riders to different network or system changes is extremely useful. Ridership …

The Proliferating Sacred: Secularization And Postmodernity, Donald Surrency

USF Tampa Graduate Theses and Dissertations

When analyzing the role religion plays in contemporary American society, one is forced to address the notion of secularization. This is a term that broadly refers to the marginalization of religious influence in culture and society that began at the outset of the Enlightenment, sometime during the sixteenth and seventeenth centuries, but, as Peter Berger argues, can actually be traced back to the times of the great Israelite prophets who emerged during the Axial Age (800-200 BCE). Throughout the available literature, proponents of the secularization thesis extend the marginalization of religious influence from the societal level to the level of …

Assistive Force Feedback For Path Following In 3d Space For Upper Limb Rehabilitation Applications, Ramya Swaminathan

USF Tampa Graduate Theses and Dissertations

The primary objective of this research was the design of an easy to use C++ Graphical User Interface (GUI) which helps the user to choose the task that he/she wants to perform. This C++ application provides a platform intended for upper arm rehabilitation applications. The user can choose from different tasks such as: Assistive Function in 3D Space to Traverse a Linear Trajectory, User Controlled Velocity Based Scaling, Fitts' Task in X, Y, Z Directions. According to a study conducted by the scientific journal of the American Academy of Neurology, stroke patients aided by robotic rehabilitation devices gain significant improvement …

Tourist, Shopertainment, Eatertainment, Edutainment, Nature Tourism, Mass Tourism, Stephanie Tomita Wong

USF Tampa Graduate Theses and Dissertations

Predictive models for diffusion-controlled particle dissolution are important for designing advanced and efficient solid products for controlled release applications. A computer-aided modeling framework was developed to derive the effective dissolution rates of multiple particles as the solid surface material eroded gradually into the surrounding liquid phase. The mathematical models were solved with numerical methods using the computational software MATLAB. Results from the models were imported into COMSOL Script to create three-dimensional plots of the particle size data as a function of time. The release model found for the monodispersed particles was manipulated to incorporate polydisperse solids, as these are found …

Synthesis, Characterization, And Applications Of Cvd Micro- And Nanocrystalline Diamond Thin Films, Zhenqing Xu

USF Tampa Graduate Theses and Dissertations

In this thesis, a systematic study has been carried out on the synthesis, characterization and applications of microcrystalline diamond (MCD) and nanocrystalline diamond (NCD) thin films deposited by the chemical vapor deposition (CVD) method. Firstly, an overview of diamond films synthesized from carbon-containing gas plasmas is presented. A parameter study was performed to grow diamond thin films. The transition from micro- to nanocrystallinity of diamond grains was achieved by controlling the Ar/Hydrogen gas ratio. The nanocrystallinity is the result of a new growth mechanism which involves the insertion of carbon dimmer into carbon-carbon and carbon-hydrogen bonds. Secondly, characterization of diamond …

Synthesis And Characterization Of Interfaces Between Naturally Derived And Synthetic Nanostructures For Biomedical Applications, Souheil Zekri

USF Tampa Graduate Theses and Dissertations

The use of nanotechnology to develop methods for fabrication and characterization of organized hybrid nanostructures that include integrated polymeric, biological and inorganic compounds has increased exponentially during the last decade. Such bio-nano-composite materials could be used in solving current biomedical problems spanning from nanomedicine to tissue engineering and biosensing. In this dissertation, a systematic study has been carried out on the synthesis, characterization, of two interfaces between naturally derived and synthetic nanostructures. Carbon nanotubes and porous silicon represent the synthetic nanostructures that were developed for the purpose of interfacing with the naturally derived bovine type I collagen and respiratory syncytial …

Investigation Into Workplace Culture For Medication Error Reporting In Pharmacy, Tamala Lavelle Gulley

USF Tampa Graduate Theses and Dissertations

This study determined impacts on reported medication errors in pharmacy by analyzing the culture in an undisclosed pharmacy in Florida. SPSS Statistical Software was used to determine the relationship between medication errors and workplace culture. Workplace culture was analyzed by distributing a 43-question culture survey to the pharmacists. There were two treatment groups, Control and Intervention, and the culture survey was two-fold, pre-survey and post-survey, utilizing identical questions to note the difference in a comparative analysis. During the pre-survey, the pharmacists in the Intervention Group received an informational sheet which contained information on a non-punitive culture as well as information …

Robot Data And Control Server For Internet-Based Training On Ground Robots, Dmitry Kalyadin

USF Tampa Graduate Theses and Dissertations

To facilitate the emerging need for remote robot training and reach back, this thesis describes a system that allows for convenient web browser based robot operation over the Internet, while providing the means for recording and playback of all video, data and user actions. Training of first responder personnel on rescue robots is hindered by the fact that these devices are very expensive and are only affordable by a few specialized organizations that make them available by request at the time of a disaster. The system described in this thesis will allow first responders to practice on the robots without …

Barium Strontium Titanate Films For Tunable Microwave And Acoustic Wave Applications, Venkataramanan Gurumurthy

USF Tampa Graduate Theses and Dissertations

The composition-dependent Curie temperature and bias-dependant dielectric permittivity of Barium Strontium Titanate (BST) makes it very attractive for tunable application in the RF/Microwave regime. In this research work, the performance of BST varactors fabricated on the conventional Pt/Ti/SiO2/Si bottom electrode stack were compared with those fabricated using chemical vapor deposited Nanocrystalline Diamond (NCD) as the diffusion barrier layer instead of SiO2. The varactors fabricated on NCD films displayed much better symmetry in capacitance-voltage behavior and better overall quality factors than varactors fabricated on SiO2. The improvement in performance can be attributed to existence of stable interfaces in the devices fabricated …

Voice Recognition System Based On Intra-Modal Fusion And Accent Classification, Srikanth Mangayyagari

USF Tampa Graduate Theses and Dissertations

Speaker or voice recognition is the task of automatically recognizing people from their speech signals. This technique makes it possible to use uttered speech to verify the speaker's identity and control access to secured services. Surveillance, counter-terrorism and homeland security department can collect voice data from telephone conversation without having to access to any other biometric dataset. In this type of scenario it would be beneficial if the confidence level of authentication is high. Other applicable areas include online transactions,database access services, information services, security control for confidential information areas, and remote access to computers. Speaker recognition systems, even though …

System Approach To Embedded System Design, Vikram Prabhakar Mehendale

USF Tampa Graduate Theses and Dissertations

During this research, the concepts of Systems Engineering were applied to embedded system design. The objective was to apply the Systems Engineering methodology to the design of a particular embedded system. A Video Surveillancesystem was chosen as the particular embedded system. Systems Engineering concepts provide the foundation for an optimized design process and for the coordination between system modules. The functionality of the Video Surveillance system was achieved through the partitioning of the overall system functionality into three separate modules. The three modules were Image Capture, Image Processing and Image Transmission. The methodology employed resulted in a system that was …

Warm: Wearable Assistant With Remote Monitoring, Lisa Michelle Provenzano Heugel

USF Tampa Graduate Theses and Dissertations

Wearable computing has been in existence as part of our attire for many years, a few examples being the watches, cell phones and MP3 players. Recently, many researchers have been devising ways to incorporate wearable devices seamlessly into our lives with the goal of making them an indispensable part of our daily routines. In this thesis, a new wearable computing device called WARM (Wearable Assistant for Remote Monitoring) for use by the elderly and the handicapped is proposed and its software architecture is defined and described. The physically challenged or the elderly, living on their own, but who require assistance …

Evaluation Of Scrap Tire-Derived Porous Rubber Tubing As A Green Membrane For Sustainable Water Filtration (Ecol-Mem Process), Ana Maria Garcia

USF Tampa Graduate Theses and Dissertations

Increasing population and extensive urbanization have strained resources around the world, promoting water scarcity and solid waste accumulation. Addressing the issues of access to safe drinking water and basic sanitation in developing countries is challenging due to limited technological and financial resources. Therefore, it is imperative that durable, low-cost, and sustainable technologies are developed to help alleviate these problems. At the same time, the production of solid waste has increased and includes waste tires, which pose a health and environmental hazard. Although efforts have been made to develop new markets for recycled scrap tires, a vast majority are still being …

Do You See What I Mean? Measuring Consensus Of Agreement And Understanding Of A National Weather Service Informational Graphic, Lorna M. Geggis

USF Tampa Graduate Theses and Dissertations

Media use of hurricane graphics to apprise populations vulnerable to severe weather provides a persuasive demonstration of the importance and complexity of visual communication. Surprisingly little research, however, has explored how audiences interpret weather graphics. This study examined whether the general public and the National Weather Service share a common understanding of selected weather related terms and meaning of a NWS informational graphic. Using a coorientation model, general public responses to a questionnaire were compared to definitions prescribed by the NWS. Additionally, the public were asked questions to measure trust of the NWS as a credible and reliable source of …

Relationship Between Biofilm Removal And Membrane Performance Using Dunedin Reverse Osmosis Water Treatment Plant As A Case Study, Joshua E. Goldman

USF Tampa Graduate Theses and Dissertations

Membrane biofouling is a common occurrence in water treatment plants that utilize reverse osmosis (RO). As bacteria and biofilm material build up on the membrane surface, it becomes more difficult for clean water to permeate through the membrane, and more pressure is required to produce the same amount of water. When pressures become critically high, membranes must be cleaned. This process is expensive in terms of chemical cost, labor, and downtime. Even after membranes have been cleaned, they can re-foul quickly if the cleaning did not effectively remove the biofilm. The water treatment plant in Dunedin, FL, which uses RO …

Nanoripples Formation In Calcite And Indium Phosphide (Inp) Single Crystals, Ramakrishna Gunda

USF Tampa Graduate Theses and Dissertations

In this project we studied the formation of nanoripples in calcite and InP single crystals by continuous scanning using the nanoindenter in the ambient environment and by Argon ion irradiation under ultra high vacuum conditions, respectively. Formation of tip induced nanowear ripples is studied on a freshly cleaved calcite single crystal as a function of scanning frequency and contact load of the diamond tip. At lower loads, initiation of the ripples takes place at the bottom of the surface slope at 3 Hz scanning frequency, which continue to propagate as scanning progresses. The orientation of these ripple structures is perpendicular …

A Paradox Of Diversity: Billions Invested, But Women Still Leave, Rebekah S. Heppner

USF Tampa Graduate Theses and Dissertations

In 2005, women made up 46.4 percent of the United States labor force but only 1.6 percent of Fortune 500 CEOs (Catalyst 2006). Although gains have been made since the passage of the Civil Rights Act in 1964, there is clearly something stopping women from equal representation at the top. Since the late 1980s, businesses have spent billions of dollars on initiatives designed to assist them in dealing with the anticipated increase in the "diversity" of their workplaces (Lubove 1997; Stodghill II 1996; Johnston and Packer 1987). Is there potential for diversity initiatives to help women conquer the "glass ceiling?" …

Numerical Analysis Of Heat Transfer During Jet Impingement On Curved Surfaces, Cesar F. Hernandez-Ontiveros

USF Tampa Graduate Theses and Dissertations

The flow structure and convective heat transfer behavior of a free liquid jet ejecting from a round nozzle impinging vertically on a hemispherical solid plate and a slot nozzle impinging vertically on a cylindrical curved plate have been studied using a numerical analysis approach. The simulation model incorporated the entire fluid region and the solid hemisphere or curved plate. Solution was done for both isothermal and constant heat flux boundary conditions at the inner surface of the hemispherical plate and the constant heat flux boundary condition at the inner surface of the cylindrical shaped plate. Computations for the round nozzle …

The Gothic As Counter-Discourse: Mark Twain, Charles Chesnutt And Toni Morrison, Hyejin, Kim

USF Tampa Graduate Theses and Dissertations

Revisiting the American Gothic via Julia Kristeva's theory of "the abject" demonstrates how Gothic strategies expose the historical contradictions of race in works by Mark Twain, Charles W. Chesnutt, and Toni Morrison. As theorized by Kristeva in Powers of Horror, the archaic process in which the subject attempts to constitute itself as homogeneous by casting off or "abjecting" all that cannot be assimilated to the self-same necessarily opens the way to repeated returns of the abject(ed) and the "horror" it provokes. Because the Gothic enacts the return of the abject, it was itself abjected from the literary canon until recently. …