Digital Commons Network^™

The Development Of Aapeptides, Lulu Wei

USF Tampa Graduate Theses and Dissertations

Non-natural peptide mimics are referred to as peptidomimetics, which contains unnatural backbones that mimic the primary peptide structure. There are a large number of peptidomimetics that have been developed including α-peptides, β-peptides, peptoids, arylamide oligomers, cationic polymers, and other peptidomimetics in the last decades. Compared to conventional peptides, these peptidomimetics have many advantages such as resistance to proteolysis, improved bioavailability, and reduced immunogenicity. However, the development of peptidomimetics is still far below the expectation due to the limitation of the availability of backbones. It is an urgent need to generate a new diverse library for novel drug discovery, design antimicrobial …

Controlling Properties Of Light: Metamaterials Design And Methodology, Darrick Hay

USF Tampa Graduate Theses and Dissertations

Electromagnetic metamaterials are materials that have designed electromagnetic properties. In general metamaterials are subwavelength and can be treated as homogeneous media with an effective permittivity and permeability. Early metamaterial designs were developed to exhibit electromagnetic responses not typically found in naturally occuring materials, but this is not a strict requirement. Metamaterials have shown promise for applications throughout the electromagnetic spectrum. The goal of this work is to present a coherent methodology for metamaterials design, fabrication and application while also describing all of the relevant physics of the designed metamaterials.

Chapter 1 is comprised of an introduction into the field of …

Analytical Methods And Critical Analyses Supporting Thermodynamically Consistent Characterizations Of The Marine Co2 System, Jonathan D. Sharp

USF Tampa Graduate Theses and Dissertations

Chemical equilibria describing the unique behavior of gaseous and ionic forms of dissolved carbon dioxide (CO₂) in seawater comprise what is known as the marine CO₂ (or carbonate) system. Observations of the marine CO₂ system with high degrees of accuracy, reproducibility, spatial coverage, and temporal resolution are critical for evaluating natural cycles of carbon within the Earth system, as well as chemical and biological responses to anthropogenic CO₂ emissions.

One component of the CO₂ system is the carbonate ion (CO²−₃), a dissolved ion that is produced when carbonic acid (H …

Multimodal Data Fusion And Attack Detection In Recommender Systems, Mehmet Aktukmak

USF Tampa Graduate Theses and Dissertations

The commercial platforms that use recommender systems can collect relevant information to produce useful recommendations to the platform users. However, these sources usually contain missing values, imbalanced and heterogeneous data, and noisy observations. Such characteristics render the process of exploiting the information nontrivial, as one should carefully address them during the data fusion process. In addition to the degenerative characteristics, some entries can be fake, i.e., they can be the outcomes of malicious intents to manipulate the system. These entries should be eliminated before incorporation to any recommendation task. Detecting such malicious attacks quickly and accurately and then mitigating them …

Transformational School Leadership And Students' Gaokao Performance In China: A Multilevel Mediation Analysis, Yanzheng Li

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine how teachers’ psychological contract fulfillment (PCF) and organizational commitment (OC) mediated the effects of principals’ transformational school leadership (TSL) on students’ Gaokao performance in China by testing a hypothesized multilevel model. Survey data were collected online from 893 teachers at 10 public senior high schools in a city located in Northern China. The first city-wide mock Gaokao exam results were used as the indicator of students’ Gaokao performance. Data analysis techniques included correlational analysis, multiple regression analysis, confirmatory factor analysis, structural equation modeling analysis, and multilevel mediation analysis. Results indicated a relatively …

Unifying Security Policy Enforcement: Theory And Practice, Shamaria Engram

USF Tampa Graduate Theses and Dissertations

Security policies stipulate restrictions on the behaviors of systems to prevent themfrom behaving in harmful ways. One way to ensure that systems satisfy the constraints of a security policy is through the use of security enforcement mechanisms. To understand the fundamental limitations of such mechanisms, formal methods are employed to prove properties and reason about their behaviors. The particular formalism employed, however, typically depends on the time at which a mechanism operates.

Mechanisms operating before a program's execution are static mechanisms, and mechanisms operating during a program's execution are dynamic mechanisms. Static mechanisms are fundamentally limited in the types of …

Multifunctional Metal-Organic Frameworks (Mofs) For Applications In Sustainability, Gaurav Verma

USF Tampa Graduate Theses and Dissertations

Climate change, affordable and clean energy, and responsible consumption and production are some of the important goals to be achieved for sustainable development. The current technologies used to address these challenges are energy and resource intensive. Furthermore, there are various limitations related to cost, storage, scalability and safety.Adsorbent materials are seen as a promising alternative remediation system due to their low energy consumption and minimal chemical waste production. However, most of the traditional adsorbents, such as activated carbon and zeolites lack the structural tunability to have long-term effectiveness and their use is limited. As discussed in Chapter 1, metal organic-frameworks …

Digital Identity: A Human-Centered Risk Awareness Study, Toufic N. Chebib

USF Tampa Graduate Theses and Dissertations

Cybersecurity threats and compromises have been at the epicenter of media attention; their risk and effect on people’s digital identity is something not to be taken lightly. Though cyber threats have affected a great number of people in all age groups, this study focuses on 55 to 75-year-olds, as this age group is close to retirement or already retired. Therefore, a notable compromise impacting their digital identity can have a major impact on their life.

To help guide this study, the following research question was formulated, “What are the risk perceptions of individuals, between the ages of 55 and 75 …

Sustainable Non-Noble Metal Based Catalysts For High Performance Oxygen Electrocatalysis, Swetha Ramani

USF Tampa Graduate Theses and Dissertations

Current energy crisis has dramatically shifted the focus of technological advancements towards clean and renewable forms of energy. Continued dependence and utilization of fossil fuels has created global awareness on harmful greenhouse gas emissions and climate change. A need for sustainable technology has gained a lot of significance in the recent years. This has led to the development of devices and technologies that rely on environmentally friendly electrochemical conversion and storage of energy. One such advancement that generates electrical energy from chemical reactions is known as fuel cell technology. While fuel cells have demonstrated potential in replacing the conventional technologies …

The Use Of Spanish Moss As A Biological Indicator To Examine Relationships Between Metal Air Pollution, Vegetation Cover, And Environmental Equity In Tampa, Florida, Yousif Abdullah

USF Tampa Graduate Theses and Dissertations

Studies of inequality in exposure to less common air pollutants, like metals, are often limited by the costs of high spatial resolution measurements. Spanish moss (Tillandsia usneoides) is a promising bioindicator for measuring air pollution due to its lower cost, enabling capture of time-average environmental concentrations at high spatial resolution. This study had three major aims. First, I aimed to use Spanish moss as a bioindicator to characterize ambient concentrations of selected metals (Ti, Cr, Mn, Co, Ni, Cd, Hg, Pb, As, and Sb) in Tampa, Florida. My second goal was to determine the impact of vegetation cover on metals …

Chinese International Students’ Narratives Of Their Experiences In A Graduate Pathway Program: An Exploratory Study, Lu Norstrand

USF Tampa Graduate Theses and Dissertations

Because of the tremendous growth of Chinese international students’ enrollment in American higher education and the rapid rise and development of Pathway programs in American universities, I determined the main purpose of this research was to determine the experiences of three Chinese international students in a Graduate Pathway program at a public four-year university in the Southeastern U.S. Three research questions were addressed:

1. How do three Chinese international students describe their academic experiences in a Graduate Pathway program in the U.S.?
2. How do these students describe differences in their learning experiences between the U.S. and China?
3. How do these students …

The Efficiency And Accuracy Of Yolo For Neonate Face Detection In The Clinical Setting, Jacqueline Hausmann

USF Tampa Graduate Theses and Dissertations

There are many face detection classification models available for download and use in the modern technological world. Based in the field of deep neural networks, these off-the-shelf solutions are generally inadequate to solve real world challenges. This work presents how current approaches biased towards detecting adult human faces must be modified in order to better accommodate face detection of the neonate in a NICU setting.

YOLO is a powerful object detection algorithm. Due to optimizations such as Cross mini-batch Normalization, Modified Spatial Attention Modules, Modified Path Aggregation Networks, Self-Adversarial Training, Mosaic Data Augmentation, DropBox Regularization, Multi-Input Weighted Residual Connections and …

Spatial Stereo Sound Source Localization Optimization And Cnn Based Source Feature Recognition, Cong Xu

USF Tampa Graduate Theses and Dissertations

In the process of propagating as a carrier of information in space, in addition to transmitting the information itself, the acoustic signal also contains the position information of the sound source itself and its related physical characteristics. Acoustic signal uses the medium (such as air, water, steel, etc.) in the space to transmit mechanical vibration and longitudinal waves from the sound source to the outside world. The traditional single audio collection device cannot collect position information and sound source characteristic information. Therefore, the signals processed in the audio signal processing process are all mixed source acoustic signals after spatial reverberation. …

Assessment And Integration Of Socioeconomic And Demographic Factors In The Implementation Of Integrated Water Resources Management In The Lake Chad Basin, Nodjidoumde Mbaigoto

USF Tampa Graduate Theses and Dissertations

Most developing countries have responded to the 2002 World Summit on Sustainable Development (WSSD) call to implement Integrated Water Resources Management (IWRM) in their national water policy to reach water sustainability and socioeconomic welfare. Despite the Lake Chad Basin Commission's adoption of the IWRM principles, the basin experiences a massive humanitarian crisis driven by the lake's shrinkage, the water shortage for food production, the rapid population growth, and the terrorist attacks perpetrated by Boko Haram. This study sought to assess the socioeconomic and demographic status of people living upstream of Lake Chad in order to understand the challenges associated with …

Use Of Sugarcane Bagasse Ash As Partial Cement Replacement In Interlocking Stabilized Soil Blocks (Issbs), Adah Shair

USF Tampa Graduate Theses and Dissertations

Global infrastructure needs for adequate housing, water provision and improved sanitation are on the rise. UN-Water estimates that 1 in 3 people still lack access to safe drinking water and about 4.2 billion people across the globe lack access to safely managed sanitation services. Rapid urbanization and the global refugee crisis have also increased the demand for adequate and efficient housing. UN Sustainable Development Goals cannot be achieved until these needs are met. Given the high environmental impact and cost of cement-heavy construction, alternate construction techniques like appropriate earth technologies need to be adopted. Interlocking stabilized soil blocks (ISSBs), a …

The Quantification Of Heavy Metals In Infant Formulas Offered By The Florida Wic Program, Naya Martin

USF Tampa Graduate Theses and Dissertations

Many infants rely on the WIC program to provide their main source of sustenance in theform of infant formula. In 2016, about 86% of the eligible infant population participated in this program. Infants in Florida account for about 30% of participation in the Southeast. For this reason, it is necessary to ensure that the formulas offered by this program provide the best opportunity for an optimal health outcome.

Exposure to heavy metals can have detrimental effects on the development of infants and children. Arsenic, lead, and cadmium specifically have been commonly found in certain types of infant formulas. Significant exposures …

Why Are Women Leaving Stem? An Examination Of Workplace Rivalry, Joseph Regina

USF Tampa Graduate Theses and Dissertations

Past research on workplace rivalry has framed the construct as a motivating force that is desirable for individuals and organizations. Using social comparison theory as a framework, the potential harmful correlates of rivalry were examined. Specifically, the relationships between the status of having a rival, as well as one’s perception of their relative standing to (i.e. being better or worse than) their rival, and the outcomes of turnover intention, perceived competence, and imposter syndrome were analyzed. Further, to examine how STEM fields may be particularly impacted by these relationships, both job and STEM turnover were measured, and the moderating effect …

Control Of A Human Arm Robotic Unit Using Augmented Reality And Optimized Kinematics, Carlo Canezo

USF Tampa Graduate Theses and Dissertations

There are more than 350000 amputees in the US who suffer loss of functionality in their daily living activities, and roughly 100000 of them are upper arm amputees. Many of these amputees use prostheses to compensate part of their lost arm function, including power prostheses. Research on 6-7 degree of freedom powered prostheses is still relatively new, and most commercially available powered prostheses are typically limited to 1 to 3 degrees of freedom. Due to the myriad of possible options for various powered protheses from different manufacturers, each configuration is governed by a distinct control scheme typically specific to the …

Analysis Of Computational Modeling Methods As Applied To Single-Crystal Organohalide Perovskites, Jon M. Bebeau

USF Tampa Graduate Theses and Dissertations

Perovskite, specifically MAPbI3, has exploded onto the electronic material forefront, with applications from photovoltaic to optical sensors. Still, there remain many unanswered questions about the electronic, structural and mechanical processes and properties of this perovskite. Computational software exists to model the electronic structure and material properties, to the nano scale, using density-functional theory. The goal of these models it to parallel the physical science of the substance in a computer simulation based on emerging mathematical models of the quantum mechanical behavior. In this study I review the historical use of perovskites in electronics, review the evolution of DFT algorithm developments …

Teacher Certification Pathway And Mathematical Quality Of Instruction, Gail Stewart

USF Tampa Graduate Theses and Dissertations

The formal documentation of alternative routes to teacher certification programs in the United States began in 1983 (Ludlow, 2011). According to the former US Secretary of Education’s Annual Report on teacher quality the high demand for teachers in high needs areas, such as mathematics, has caused growth in alternative certification routes for teachers (Paige, 2002). The many factors that influence teaching quality make it difficult to determine what impact, if any, a teacher’s preparation program has on the quality of their instruction. Current research on teacher quality shows varied results, making it hard to reach a conclusion about the effectiveness …

Humanistic Climate Philosophy: Erich Fromm Revisited, Nicholas Dovellos

USF Tampa Graduate Theses and Dissertations

Given the current juncture in history, humanity is faced with the herculean task of adapting to a tumultuous present and a gimmer future. Should climate projections be accurate, there is little time to waste. This work makes the claim that we are not only in a political gridlock but also in an academic one. Researching climate philosophy from its inception, the concluding view is that no major progress, outside of a standardized descriptive analysis, has been achieved. Thus, the work evaluates an array of climate philosophers e.g. Stephen Gardiner, James Garvey, Peter Singer, Walter Sinnott-Armstrong, etc., with specific emphasis on …

A Sustainability Machine: The Incineration-Based Waste Regime In Tampa, Fl, Usa, Kevin P. Martyn

USF Tampa Graduate Theses and Dissertations

Recent history has seen some significant changes in terms of how society thinks about and deals with its wastes. Increasingly troubling indications of the immediacy of ecological concerns, now often described by the Anthropocene concept, have been provocative of a reinvigorated fervor for a sustainability transition. As a result, sustainability has become well-established as both an urgent pursuit and an eminently pliable buzzword. This research describes and explains one key aspect of society’s pursuit of some version of sustainability: our relationship with waste.

The site of this research is Tampa, Florida, a sunbelt city with a unique waste management system. …

Using Geospatial Data To Predict The Locations Of Groundwater Discharge To Salmon-Bearing Streams, Alaska, Mary Gerlach

USF Tampa Graduate Theses and Dissertations

Identification and protection of groundwater resources are considerations of increasing interest as climate shifts but can be challenging to accomplish in remote areas. To that end, a series of GIS techniques and weight of evidence approach were applied to determine the feasibility of remotely identifying likely areas of ground discharge. Through the confluence of topographic analyses and a novel geologic dataset, these techniques were found to consistently identify areas characterized by either shallow subsurface or aquifer-fed groundwater discharge or evidence of ephemeral surficial water features. Two distinct GIS techniques to build spatial proxies of the effects of topography and geology …

Optimal Strategies For Grassland Restoration To Increase Spatial Carrying Capacity Of Florida Sandhill Cranes In Pasco County, Florida, Ibrahim Kaya

USF Tampa Graduate Theses and Dissertations

The Florida sandhill crane (Antigone canadensis pratensis) is a non-migratory bird species occurring throughout the Florida peninsula and the Okefenokee Swamp in southeastern Georgia. Human land-altering activities have led to a substantial decline in the amount and condition of suitable habitat, including grasslands, for the species in Florida, thereby decreasing the population size significantly. Grasslands located in close proximity to nesting locations are one of the habitat types on which the population viability of the species depends, as they provide foraging and brooding habitat which is crucial for successful reproduction. The purpose of this study is to propose the most …

Numerical Study Of Gap Distributions In Determinantal Point Process On Low Dimensional Spheres: L-Ensemble Of O(N) Model Type For N = 2 And N = 3, Xiankui Yang

USF Tampa Graduate Theses and Dissertations

Poisson point process is the most well-known point process with many applications. Unlike Poisson point process, which is the random set of non-intersecting points, determinantal point process refers to certain class of point processes where the points tend to interact with each other. The interaction often leads to more uniformly distributed points compared to those in Poisson point process.

In this article, we study the gap distribution of certain class of determinantal point process, L-ensemble of O(n) model type, and compare the distribution with the ones from the other known determinantal point process that appears in random matrices. Our numerical …

Using Tidal Analysis To Examine Lake-Aquifer Connectivity On A Modern Carbonate Platform, Ronald A. Knoll

USF Tampa Graduate Theses and Dissertations

Lake-aquifer connectivity on carbonate platforms is governed by basin morphology which is influenced by diagenetic and depositional processes. Both these processes cause aquifer permeability to vary significantly with scale of measurement (i.e., pore-scale, well-scale, and regional-scale). Because coastal aquifers are well-known to have tidally controlled water level fluctuations, inland lakes may be used to expand the areal measurement of permeability and establish a link between well-scale and regional scale connectivity in the aquifer. To evaluate the impact of lake basin morphology on aquifer connectivity, water level fluctuations were collected at high temporal resolution in the ocean and twenty-four surface water …

Alcohol Expectancy Associates As A Probe Of The Motivational Processes That Lead To Drinking, Daniel C. Faraci

USF Tampa Graduate Theses and Dissertations

Consistent with theory, within-person alcohol expectancies monitored across a day predicted alcohol consumption levels later that day. These correlational findings could have been a function of any number of "third variables" including social influences or temporal cycles in affective state. To strengthen the inference that changes in expectancies validly reflect changes in the motivation to drink, we experimentally manipulated expectancy activation and measured subsequent changes in expectancy reports. The evening before expectancy monitoring, participants were informed that later the next day—a Monday, Tuesday, or Wednesday—they would be participating in a solitary taste-test of either alcohol or soft drinks. Alcohol expectancies …

Current And Projected Sustainability Of The Water-Energy-Food Nexus In Caribbean Small Island Developing States, Zachary S. Winters

USF Tampa Graduate Theses and Dissertations

Within Latin American and the Caribbean (LAC), small island developing states (SIDS) of the latter are wholly reliant on their natural environments for their tourism-dependent economies yet are experiencing declining environmental health. These effects are exacerbated by Caribbean susceptibility to climate change and growing populations. With limited size, elevation, GDP, and water resources compared to Latin America, the subregion requires management and solutions tailored to the needs of each country. This study examined current and future sustainability of the Caribbean SIDS by assessing the nexus of water-energy-food (WEF) resources at the national level. In addition, the potential for nature-based solutions …

Functional Gait Asymmetries Achieved Through Modeling And Understanding The Interaction Of Multiple Gait Modulations, Fatemeh Rasouli

USF Tampa Graduate Theses and Dissertations

Walking is an important determinant of human functionality. Gait disabilities affect millions of people worldwide every year. Investigating the science of walking advances recovery techniques and assistive devices for gait rehabilitation. A functional gait promotes productivity, independence, and quality of life. Human gait, like any other moving mechanism, is a dynamic system. Understanding and analyzing the dynamic aspects of gait improves the recovery methods to fundamentally affect and interact with lower limbs.

This dissertation aims to fill the gaps in mechanical simulations of gait and dynamic analysis of rehabilitation techniques. The solutions consider kinematic, kinetic, and spatiotemporal parameters of gait …

Design, Synthesis Of Axial Chiral Triazole, Jing Wang

USF Tampa Graduate Theses and Dissertations

This thesis contains three parts: 1) The briefly review of chiral P, N-ligands. 2) The summary of triazole as ligands. 3) The attempt of designing, synthesizing the chiral triazole ligands.

In the first part, we have reviewed all the major P, N-ligands in the history, including how they were synthesized and resolved into single enantiomer. We also used some examples to show their utility potential in different reactions.

In the second part, we summarized the triazole ligands which mainly developed by our group including their structures, their potential and utility in different types of chemical reactions.

In the last part, …