Digital Commons Network^™

Advances In Multiagent Systems Control: Multiplex Information Networks-Based Approaches And Beyond, Kimberly Witke

USF Tampa Graduate Theses and Dissertations

Multiagent systems control designs offer numerous advantages to increasingly complex civilian, military, and scientific tasks ranging from intelligent satellite swarm controls or autonomous traffic controls to remote triage and repair or remote wildlife observation, where the performance of a single agent is insufficient to execute the task at hand. Traditional methods in multiagent systems controls, however, have been infeasible for use in scalable, large-group formation controls.

With this in mind, the contribution of this dissertation is to bridge the gap in knowledge through both theoretical and experimental validation of multiagent systems control architectures. It addresses the challenges presented by unreliable, …

Deep Learning Enhancement And Privacy-Preserving Deep Learning: A Data-Centric Approach, Hung S. Nguyen

USF Tampa Graduate Theses and Dissertations

Deep Learning and its applications have become attractive to a lot of research recentlybecause of its capability to capture important information from large amounts of data. While most of the work focuses on finding the best model parameters, improving machine learning performance from data perspective still needs more attention. In this work, we propose techniques to enhance the robustness of deep learning classification by tackling data issue. Specifically, our data processing proposals aim to alleviate the impacts of class-imbalanced data and non- IID data in deep learning classification and federated learning scenarios. In addition, data pre-processing strategies such that dimensionality …

Analysis Of Ostds Failure Potential Due To Sea-Level Rise And Other Inundation Factors: An Integrated Geo-Spatial Analysis, Alec Colarusso

USF Tampa Graduate Theses and Dissertations

While many aspects of climate change are well-studied, the vulnerability of Onsite Sewage Treatment and Disposal Systems (OSTDS) to sea-level rise (SLR) has not been thoroughly examined despite the potentially significant environmental impacts, including nutrient and pathogen loading. Research gaps include the need to determine the suitability of models to predict groundwater inundation due to SLR and the consequent impact on OSTDS. As such, this study aims to compare Bathtub/hydrostatic and physics-based/MODFLOW/3D numerical modeling methods of simulating groundwater inundation from SLR to identify OSTDS vulnerability to failure due to a reduction in the height of the vadose zone (saturation or …

Study On Versatile S(Vi) Reagents Towards Synthesis Of S(Iv) And S(Vi) Functional Groups, Shun Teng

USF Tampa Graduate Theses and Dissertations

This dissertation mainly covers the latest methodology development in the field of sulfur-containing functional groups in synthetic chemistry. There are two parts. The first part is the asymmetric synthesis of sulfoximines, sulfonimidamides, sulfonimidoyl fluorides, and sulfinamides enabled by a versatile enantiopure S(VI) reagent. The second part is the Grignard reagent-triggered divergent S-editing synthesis via a bench-stable S(VI) reagent.

In the first part, the asymmetric synthesis of sulfoximines, sulfonimidamides, sulfonimidoyl fluorides, and sulfinamides is reported. This report focuses on the development of a bifunctional S(VI) reagent and its utility in synthesis. It employed the enhanced stability of sulfonimidoyl fluorides and the …

Applications In Opioid Analysis With Faims Through Control Of Vapor Phase Solvent Modifiers, Nathan Grimes

USF Tampa Graduate Theses and Dissertations

Field Asymmetric Ion Mobility Spectrometry (FAIMS), often coupled with mass spectrometry (MS), offers rapid analytical ion filtration, useful in reducing matrix interference and differentiating isomeric compounds. This study focuses on augmenting FAIMS-MS analyses through the incorporation of gas phase solvents, or "modifiers," inducing dynamic microsolvation, a particularly potent method of analysis enhancement.

Initially, the research utilized a bubbler-based system, incorporating a humidity sensor, improving modifier concentration control when using water. Our application in opioid detection and differentiation revealed considerable advancements. Notably, an increased peak capacity in an opioid mixture and successful separation of the isobaric opioid pair, alfentanil and ortho-isopropyl …

Ice-Core Reveals Flavors Of Hydroclimate Extremes In The American Southwest, Laura Calabrò

USF Tampa Graduate Theses and Dissertations

A small number of caves and lava tubes worldwide host perennial ice deposits, which occur at elevations well below those of mountain glaciers and in areas outside the permafrost climatic belt, where no surface glaciation exists. These settings make any of the ice deposits in caves or lava tubes particularly susceptible to the current warming trend, leading to the imminent loss of some untapped cryospheric paleoenvironmental archives.

The present work is the result of a paleoclimate study based on ice deposits accumulated within lava tubes in El Malpais National Monument (ELMA, western New Mexico). The ice cores span from 7,000 …

Autonomous Professional Learning Through Practitioner Inquiry: A Study Of Growth Plan System Experiences, Daina Kelly Gaputis

USF Tampa Graduate Theses and Dissertations

The need for quality science education has long been established, but despite reform after reform, it remains a current concern. What we know as good teaching is not happening, perhaps because there is an increase in science teachers using alternative certification programs to enter the field. This lack of formal training causes teachers to have a reliance on professional learning opportunities to learn about reform-based science education. Unfortunately, traditional forms of professional learning are often inadequate, so newer professional learning designs have been established. Some of these newer designs, such as practitioner inquiry, offer teachers autonomy over how they assess …

Synthesis, Characterization, And Separation Of Loaded Liposomes For Drug Delivery, Sandra Khalife

USF Tampa Graduate Theses and Dissertations

Liposomes are viable candidates for drug delivery vehicles due to their ability to protect loaded compounds, dampen side effects of drugs, and be delivered to target sites in the body. The amphipathic nature of these lipid vesicles makes them very customizable through careful selection of bilayer and aqueous core components as well as synthetic and downsizing methods. However, synthetic methods may result in unencapsulated compounds remaining present alongside loaded liposomes, which require removal before the liposome suspension can be used.

This work explores the use of model DOPC as well as DOPC and CHOL liposomes and the methods that were …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Stable Isotope Analysis Of Doryteuthis (Amerigo) Pealeii Eye Lenses To Determine Migratory Patterns In The Eastern Gulf Of Mexico Using Statoliths For Age Determination, Hannah M. Schwaiger

USF Tampa Graduate Theses and Dissertations

Doryteuthis (Amerigo) pealeii is a common fisheries squid that occurs in the Gulf of Mexico (GoM) and along the east coast of the United States. These squid are an important link in the food web, linking higher and lower trophic positions (Madsen et al., 2007), and they are also used for human consumption. The migration patterns of D. pealeii populations in the northwestern North Atlantic have been thoroughly studied when compared to those in the GoM. This research aims to combine statolith aging and stable isotope analysis to enhance the understanding of D. pealeii migration patterns throughout their short, sub-annual …

An Empirical Investigation Of Network Topology On Majority Illusion, Behavior Adoption, And Polarization, Sreeja Sreekantan Nair

USF Tampa Graduate Theses and Dissertations

Social influence plays a significant role in shaping opinions and behaviors both online and inthe physical world. The ways in which we interact with others and the information we receive can significantly influence our beliefs and attitudes towards different issues. While online social media provide platforms for such interactions, the underlying network structure can impact various social influence phenomena, including majority illusion, behavior adoption, and polarization.

This dissertation examines the role of network topology in three social influence processes:majority illusion, behavior adoption, and polarization. The majority illusion refers to a perception bias that occurs when individuals believe that an opinion …

Effect Of Dual Inhibition Of Atypical Pkc Signaling And Pi3k/Akt Signaling On Cell Viability And Apoptosis In Clear Cell Renal Cell Carcinoma (Ccrcc)., Khandker M. Khalid

USF Tampa Graduate Theses and Dissertations

Renal Cell Carcinoma (RCC) is the most common type of kidney cancer (85%); 75% of the cases involve conventional clear cell RCC (ccRCC). The choice of treatments recommended for clear cell carcinoma and non-clear cell carcinoma include partial nephrectomy (Stage I), radical nephrectomy (Stages II and III), and chemotherapy (stage IV). Phosphatidylinositol-3-kinase (PI3K) inhibitors can be a viable candidate in the chemotherapy of ccRCC because the PI3K/Akt pathway is frequently activated in RCC. Hence, PI3K inhibitors like Alpelisib (BYL719) can be chosen as a treatment. In addition, aPKCs (PKC-ί and PKC ζ) are overexpressed in most cancer cells, and they …

Investigation Of Challenging Transformations In Gold Catalysis, Qi Tang

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains three parts: 1) Divergent gold catalysis for alkyne trifunctionalization, encompassing three distinct modes to achieve the simultaneous formation of C-N, C-O, and C-C bonds in a single step 2) the study and development of a new method to synthesize azaborine derivatives; and 3) the construction of benzotriazole boranes (BTAB) as stable four-coordinate N-B heterocycles through gold-catalyzed alkyne hydroboration.

In the first part, alkyne trifunctionalization via divergent gold catalysis will be introduced. This novel approach involves a sequence of reactions that combine gold π-activation, vinyl gold nucleophilic addition, and gold (III) reductive elimination. By utilizing this methodology, …

Gold-Catalyzed Diyne-Ene Cyclization: Synthesis Of Hetero Polyaromatic Hydrocarbons And 1,2-Dihydropyridines, Jingwen Wei

USF Tampa Graduate Theses and Dissertations

Homogeneous gold catalysts are known as a powerful tool for selectively activating alkynes and are well-developed in the construction of C-C, C-N, and C-O bonds to form complex compounds that are widely used in pharmaceuticals, industries, agriculture, etc. The investigation of gold(I) catalysis on conjugated diyne (compounds having two acetylene groups) enriches the complexity of the bond construction and allows the building of interesting skeletons in organic synthesis. One typical kind of substrate, diyne-ene, has both a conjugated diyne part and a 1,6- enyne part. We developed a new methodology to allow its divergent synthesis to heterocycles.

This dissertation mainly …

Institutional And Individual Approaches To Change In Undergraduate Stem Education: Two Framework Analyses, Stephanie B. Feola

USF Tampa Graduate Theses and Dissertations

The overarching goal of this dissertation is to examine institutional change initiatives in STEM and to understand the impact of engaging with a specific change strategy on a biochemistry educator’s instructional practice. Institutional change initiatives involve executing an intentional strategy to influence teaching practices within a specific institution. This research investigates NSF-funded change initiatives at three public research universities that were focused on encouraging the adoption of evidenced-based instructional practices (EBIPs) by STEM faculty. As part of an effort to understand how the three institutions approached this task, framework analysis was performed using the initiative’s annual reports to NSF. Further …

Metachronal Locomotion: Swimming, Scaling, And Schooling, Kuvvat Garayev

USF Tampa Graduate Theses and Dissertations

This dissertation deals with one type of underwater locomotion called metachronal swimming in which the organism sequentially beats its multiple appendages allowing phase lag between adjacent neighbors. Metachronally swimming species are widespread and include copepods, shrimp, ctenophores, and tomopterid worms to name few. First, using the high-speed recording and planar particle image velocimetry (PIV) measurement, I report on kinematics of fast metachronal swimmer and constructive vortex interactions among its appendages and discuss its implications for improved performance regarding the swimming. Second, I show how hydrodynamic performance of all metachronal swimmers (paramecia, copepods, tomopterid worms, krill etc.) can be scaled by …

Applications Of Seismic And Geodetic Data To Earthquake Hazard Research, Mahsa Afra

USF Tampa Graduate Theses and Dissertations

Being a part of a seismically active zone, including large and crowded cities such asTehran, Qazvin and Semnan, Central Alborz experiences many local earthquakes. Knowl- edge of crustal velocity structure in this area is thus necessary considering its economical and political importance, a large concentration of population, and relatively poor construc- tion practice which increases the earthquake risks in this region. In second chapter of this thesis, we aim at obtaining the 3D crustal velocity structure of the Central Alborz region in northern Iran using local earthquake tomography. We also validate anomalies inferred from our velocity model using an independent …

Insect Classification And Explainability From Image Data Via Deep Learning Techniques, Tanvir Hossain Bhuiyan

USF Tampa Graduate Theses and Dissertations

Since the dawn of the Industrial Revolution, humanity has always tried to make labor more efficient and automated, and this trend is only continuing in the modern digital age. With the advent of artificial intelligence (AI) techniques in the latter part of the 20th century, the speed and scale with which AI has been leveraged to automate tasks defy human imagination. Many people deeply entrenched in the technology field are genuinely intrigued and concerned about how AI may change many of the ways in which humans have been living for millennia. Only time will provide the answers. This dissertation is …

The Applicability Of The Postmortem Submersion Interval Estimation Formula For Human Remains Found In Subtropical Aquatic Environments, Kara L. Dicomo

USF Tampa Graduate Theses and Dissertations

Within the past decade, several attempts have been made to standardize a method for estimating postmortem submersion intervals (PMSI); however, the majority of these studies have focused on data from a temperate climate which cannot be taken as representative of large portions of the globe. Thus, there are large portions of the earth in which the methodology from these studies may not be able to accurately estimate PMSI which has the potential to leave investigators in these other climatic zones at a disadvantage. This presentation presents a case study into the applicability of two Total Body Scoring Systems (TADS) utilized …

Supramolecular Architectures Generated By Self-Assembly Of Guanosine And Isoguanosine Derivatives, Mengjia Liu

USF Tampa Graduate Theses and Dissertations

This dissertation is primarily divided into three parts: 1) Anion, solvent-mediated, tunable self-assemblies of isoguanosine (isoG). 2) Post-assembly modification of the non-covalent isoG-pentaplex for Cesium extraction. 3) Supramolecular asymmetric amine catalysis.

The structural conformational design of the isoG decamer was employed for systematic investigations involving various substituted groups at the C8 position of purine and ribose. A series of isoG analogs with C8-phenyl substitutions were synthesized and utilized for Cesium coordination. The proximity between purine and ribose structures limited pentaplex formation for C8-phenyl substituted isoG derivatives. Based on this observation, a deoxy isoG derivative with a modified ribose was employed …

Dynamical Polymer Chain Heterogeneities And Their Impacts On The Glass Transition, William Forrest Drayer

USF Tampa Graduate Theses and Dissertations

The utilization of polymeric materials has endured since prehistory, at first unknowinglyin the form of natural biopolymers such as wood and leather, culminating and continuing through the development of the plastics industry in the early twentieth century. Polymers, along with other materials including silicate glasses, readily exhibit the glass transition upon quenching: a continuous but rapid change from viscous (liquid) to elastic (solid) behavior. The physics surrounding the glass transition have been studied for over a century; while considerable progress has been made, there remains no universally accepted predictive theory of the glass transition. Modern development of glassy materials consists …

Geoarchaeology Of Estuarine Seascapes In Tampa Bay, Florida., Kendal R. Jackson

USF Tampa Graduate Theses and Dissertations

This dissertation investigates the geological, ecological, and archaeological histories of Tampa Bay, Florida’s largest open-water estuary system. Previous geoscientific and archaeological work has studied the evolution of Florida’s estuaries as ‘pre-anthropogenic’ ecosystems and conceptualized Indigenous maritime societies as mostly passive inhabitants of dynamic ‘natural’ environments. Further, the environmental legacies of more recent, industrial-scale estuary modification attending Florida’s 20th-century population boom have been understudied—leading to popular and scientific confusion about historical conditions. The work composing this dissertation research seeks to reconceptualize Tampa Bay as a complex mosaic of cultural seascapes that have been variously altered and modified by human societies across …

Cybersecurity: Stochastic Intensity Function And Monitoring Indicators, Hackers Demographics, Statistical Analysis And Treatment Of Ovarian Cancer, Ranju Karki

USF Tampa Graduate Theses and Dissertations

One of the major tasks in the present day-era is securing computer systems against unauthorized access. Every year we lost millions of dollars because of cyber attacks and thousands of people suffer economically and psychologically. Rapid development in the field of information technology increases the challenges to the Information technology personnel working on protecting against cyber attacks. In cyber security, vulnerabilities and hackers play a major role. Researchers are putting in enormous efforts to develop methods and models to control vulnerabilities and psychological behavior and motivation of hackers. Our study defines two important aspects of the computer operating system concerning …

Enhanced Methods In Forensic Mass Spectrometry For Targeted And Untargeted Drug Analysis, Dina M. Swanson

USF Tampa Graduate Theses and Dissertations

Forensic science has long used mass spectrometry for the analysis of drugsand metabolites. Traditionally, screening methods consisted of color tests or immunoassay and confirmation methods used gas chromatography with mass spectrometry, which was considered the gold standard for identification. In the last several decades, advances in liquid chromatography with mass spectrometry (LCMS) have brought this technology to the forefront of forensic drug identification. Drug identification in forensic drug chemistry and forensic toxicology has become increasingly challenging due to the rapid increase in illicit drug analogs including novel opioids such as fentanyl analogs. Traditional screening methodologies are often unable to identify …

Automated Approaches To Enable Innovative Civic Applications From Citizen Generated Imagery, Hye Seon Yi

USF Tampa Graduate Theses and Dissertations

Smart governance is an area, that is increasingly becoming important, not only in advanced countries, but all across the globe. Thanks to global scale network connectivity, permeance of smart-devices of various form-factors, and overall improvement in digital literary, we are now seeing "smartness" everywhere, or if not, the general public is expecting the same. Ultimately, the goal of smart governance is to facilitate state-of-the-art technologies to improve citizens’ lives. With the ubiquity of smart phone technologies today, citizens more readily participate in collaboration with public officials for improved quality of life and their communities. By utilizing optimal tools, public officials …

Real Data–Driven Analytical Predictive Modeling For Financial Systems: Stochastic Intensity Function And Monitoring Indicator, Jayanta Kumar Pokharel

USF Tampa Graduate Theses and Dissertations

Data contain important information and data driven decision making process is the most for any type of businesses to succeed. It is the fact that businesses which follow data driven decision making process will have competitive edge over their counterparts which contributes in value creation for any firm or individual. Statistical procedure and methodology is the heart of data science which helps to extract crucial information from the data scientifically. It is common technique to use algorithm on historical data to see the outcome for the future which we defined as “prediction”, and predictive modeling is one of major statistical …

Investigating Risk Factors Of The Development Of Compulsive Exercise And Eating Disorder Symptoms In College Students, Madeline Palermo

USF Tampa Graduate Theses and Dissertations

Compulsive exercise (e.g., high exercise frequency combined with the inability to reduce or stop exercising) is associated with a variety of maladaptive outcomes in college students, such as quality of life impairment, body dissatisfaction, and poor physical health outcomes. Recent research suggests that compulsive exercise is highly prevalent among college students and that engagement in compulsive exercise behaviors may increase over the first year of college. Given that college is an important developmental period for establishing behavioral patterns that affect long-term health, developing effective preventative interventions for compulsive exercise among early college students is paramount. Extant cross-sectional work suggests that …

Analysis And Model Of Sensor-Less Modified Direct Torque Control Surface Permanent Magnet Synchronous Machine For Electrical Submersible Pumping Applications, Mulu Woldeyohannes

USF Tampa Graduate Theses and Dissertations

This dissertation examines a novel sensor-less Direct Torque Control (DTC) strategy for Electrical Submersible Pump (ESP) systems using Surface Mounted Permanent Magnet Synchronous Motors (SPMSM) that are used for oil and gas production. As oil and gas are the two largest fuels in use today to generate energy, the technologies to improve efficiency, increase reliability and reduce carbon footprint are essential. SPMSM is one of the main motor topologies in use to improve the reliability and efficiency of ESP systems. Due to the absence of damper winding, SPMSM cannot be started using Direct On-Line (DOL) control. Instead, Variable Speed Drives …

Essays On Cybersecurity And Information Privacy, Moez Hamedani Farokhnia

USF Tampa Graduate Theses and Dissertations

This dissertation research focuses on two key aspects of cybersecurity research. Security safeguard allocation, and AI-powered tools for anomaly detection. The first dissertation essay (Chapter 1) proposes a novel framework for the allocation of security countermeasures in the presence of uncertainty using robust optimization technique. The second dissertation essay (Chapter 2) studies the impact of algorithmic bias on the practice of insider threat detection in Electronic Health Record Systems and proposes a mitigations strategy. The final dissertation essay (Chapter 3) investigates how the biases of anomaly detection algorithms, and the characteristics of ensemble methods relate to the ensembles’ accuracy and …